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Novel cycles for power generation with CO 2  capture using OMCM technology Rahul Anantharaman a ,  Olav Bolland a  and Knut Åsen b a   Department of Energy & Process Engineering Norwegian University of Science and Technology b  StatoilHydro Research Center GHGT-9 Washington D.C.
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
CO 2  capture processes and systems
Motivation ,[object Object],[object Object]
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Objective ,[object Object],[object Object],[object Object],[object Object]
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Oxygen Mixed Conducting Membrane ,[object Object],[object Object],[object Object],[object Object]
MCM Reactor Concept Integrating OMCM technology in a combined cycle ,[object Object],[object Object]
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Design Basis Thermodynamic evaluation ,[object Object],[object Object],[object Object],[object Object],GT  = Gas Turbine ST  = Steam Turbine BGT  = Bleed Gas Turbine CO 2 Comp  = CO 2  compressor aux  = Auxiliary power
Concept 1 Cycle with MCM reactor 1275   C
Concept 1 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.43 227.10 231.95 227.92 Steam turbine output(MWe) 125.5 162.45 161.28 164.97 161.42 Bleed gas turbine output (MWe) - - 61.25 - 62.85 CO 2  compression work (MWe) 4.5 4.53 14.43 7.39 22.18 Net power output (MWe) 299.4 392.87 429.74 383.05 423.49 Net Electric Efficiency (%) 49.3 53.34 55.10 50.27 51.2 Carbon capture rate (%)  100 84.3 84.92 97.51 98.2
Concept 2 Cycle with MCM reactor & Sequential burner 1425   C
Concept 2 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.10 231.95 227.92 Steam turbine output(MWe) 125.5 162.5 161.28 164.97 161.42 Bleed gas turbine output (MWe) - - 61.25 - 62.85 CO 2  compression work (MWe) 4.5 4.5 14.43 7.39 22.18 Net power output (MWe) 299.4 392.9 429.74 383.05 423.49 Net Electric Efficiency (%) 49.3 53.3 55.10 50.27 51.2 Carbon capture rate (%) 100 84.3 84.92 97.51 98.2
Concept 2 Sensitivity of the additional firing before the turbine
Concept 3 Cycle with MCM reactor, Sequential burner & Bleed gas turbine 1 bar
Concept 3 Results 55.1% is without bleed gas turbine cooling With steam cooling, efficiency was calculated to 54.0% Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 231.95 227.92 Steam turbine output(MWe) 125.5 162.5 161.3 164.97 161.42 Bleed gas turbine output (MWe) - - 61.3 - 62.85 CO 2  compression work (MWe) 4.5 4.5 14.4 7.39 22.18 Net power output (MWe) 299.4 392.9 429.7 383.05 423.49 Net Electric Efficiency (%) 49.3 53.3 55.1 50.27 51.2 Carbon capture rate (%) 100 84.3 84.9 97.51 98.2
Concept 4 Cycle with MCM reactor, ATR & Sequential burner ATR CO 2  capture using MDEA, 2.0 MJ/kg CO 2
Concept 4 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 232.0 227.92 Steam turbine output(MWe) 125.5 162.5 161.3 165.0 161.42 Bleed gas turbine output (MWe) - - 61.3 - 62.85 CO 2  compression work (MWe) 4.5 4.5 14.4 7.4 22.18 Net power output (MWe) 299.4 392.9 429.7 383.1 423.49 Net Electric Efficiency (%) 49.3 53.3 55.1 50.3 51.2 Carbon capture rate (%) 100 84.3 84.9 97.5 98.2
Concept 5 Cycle with MCM reactor, ATR, Sequential burner & Bleed gas turbine
Concept 5 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 232.0 227.9 Steam turbine output(MWe) 125.5 162. 5 161.3 165.0 161.4 Bleed gas turbine output (MWe) - - 61.3 - 62.9 CO 2  compression work (MWe) 4.5 4.5 14.4 7.4 22.2 Net power output (MWe) 299.4 392.9 429.7 383.1 423.5 Net Electric Efficiency (%) 49.3 53.3 55.1 50.3 51.2 Carbon capture rate (%) 100 84.3 84.9 97.5 98.2
Outline ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Concept Summary Represented in the CO 2  capture rate – Efficiency space
Conclusions ,[object Object],[object Object],[object Object],[object Object],[object Object],StatoilHydro has stopped development of the processes due to a variety of reasons with membrane stability being one of them
Thank you! TCCS-5 5 th  Trondheim Conference on CCS

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Novel Power Cycles With Omcm

  • 1. Novel cycles for power generation with CO 2 capture using OMCM technology Rahul Anantharaman a , Olav Bolland a and Knut Åsen b a Department of Energy & Process Engineering Norwegian University of Science and Technology b StatoilHydro Research Center GHGT-9 Washington D.C.
  • 2.
  • 3.
  • 4. CO 2 capture processes and systems
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13. Concept 1 Cycle with MCM reactor 1275  C
  • 14. Concept 1 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.43 227.10 231.95 227.92 Steam turbine output(MWe) 125.5 162.45 161.28 164.97 161.42 Bleed gas turbine output (MWe) - - 61.25 - 62.85 CO 2 compression work (MWe) 4.5 4.53 14.43 7.39 22.18 Net power output (MWe) 299.4 392.87 429.74 383.05 423.49 Net Electric Efficiency (%) 49.3 53.34 55.10 50.27 51.2 Carbon capture rate (%)  100 84.3 84.92 97.51 98.2
  • 15. Concept 2 Cycle with MCM reactor & Sequential burner 1425  C
  • 16. Concept 2 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.10 231.95 227.92 Steam turbine output(MWe) 125.5 162.5 161.28 164.97 161.42 Bleed gas turbine output (MWe) - - 61.25 - 62.85 CO 2 compression work (MWe) 4.5 4.5 14.43 7.39 22.18 Net power output (MWe) 299.4 392.9 429.74 383.05 423.49 Net Electric Efficiency (%) 49.3 53.3 55.10 50.27 51.2 Carbon capture rate (%) 100 84.3 84.92 97.51 98.2
  • 17. Concept 2 Sensitivity of the additional firing before the turbine
  • 18. Concept 3 Cycle with MCM reactor, Sequential burner & Bleed gas turbine 1 bar
  • 19. Concept 3 Results 55.1% is without bleed gas turbine cooling With steam cooling, efficiency was calculated to 54.0% Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 231.95 227.92 Steam turbine output(MWe) 125.5 162.5 161.3 164.97 161.42 Bleed gas turbine output (MWe) - - 61.3 - 62.85 CO 2 compression work (MWe) 4.5 4.5 14.4 7.39 22.18 Net power output (MWe) 299.4 392.9 429.7 383.05 423.49 Net Electric Efficiency (%) 49.3 53.3 55.1 50.27 51.2 Carbon capture rate (%) 100 84.3 84.9 97.51 98.2
  • 20. Concept 4 Cycle with MCM reactor, ATR & Sequential burner ATR CO 2 capture using MDEA, 2.0 MJ/kg CO 2
  • 21. Concept 4 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 232.0 227.92 Steam turbine output(MWe) 125.5 162.5 161.3 165.0 161.42 Bleed gas turbine output (MWe) - - 61.3 - 62.85 CO 2 compression work (MWe) 4.5 4.5 14.4 7.4 22.18 Net power output (MWe) 299.4 392.9 429.7 383.1 423.49 Net Electric Efficiency (%) 49.3 53.3 55.1 50.3 51.2 Carbon capture rate (%) 100 84.3 84.9 97.5 98.2
  • 22. Concept 5 Cycle with MCM reactor, ATR, Sequential burner & Bleed gas turbine
  • 23. Concept 5 Results Concept 1 Concept 2 Concept 3 Concept 4 Concept 5 Fuel thermal energy (MWth) 607.3 717.7 780.0 762.0 827.2 GT power output (MWe) 181.4 230.4 227.1 232.0 227.9 Steam turbine output(MWe) 125.5 162. 5 161.3 165.0 161.4 Bleed gas turbine output (MWe) - - 61.3 - 62.9 CO 2 compression work (MWe) 4.5 4.5 14.4 7.4 22.2 Net power output (MWe) 299.4 392.9 429.7 383.1 423.5 Net Electric Efficiency (%) 49.3 53.3 55.1 50.3 51.2 Carbon capture rate (%) 100 84.3 84.9 97.5 98.2
  • 24.
  • 25. Concept Summary Represented in the CO 2 capture rate – Efficiency space
  • 26.
  • 27. Thank you! TCCS-5 5 th Trondheim Conference on CCS