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BIO CHEMICAL REACTION
ENGINEERING
“TheArrhenius Equation”
Introduction
 It is a formula for the temperature
dependence of reaction rates.
 Proposed by Mr. Svante Arrhenius in 1889
based on the Dutch chemist, Mr. Jacobus
HenricusVan’t Hoff.
 It gives the dependence of rate constant(k)
of a chemical reaction on the absolute
temperature.
Mr. Jacobus Henricus Van’t
Hoff
Purposes of Arrhenius equation:
 Verify the effect ofTemperature, catalyst, Gas
constant.
 Temperature,T
To fit, this should be in Kelvin.
 The gas constant, R
Which comes from the PV=nRT
 Activation energy, E
Minimum energy for reaction to occur.
 The e=2.7182
 The frequency factor, A:
A term which includes factors like frequency
of collisions and their orientations.
Uses of Arrhenius equation:
 Used extensively to describe the effect of
temperature;Thermal death.
 To determine how the reac. rates and
diffusion changes with temperature.
Effect of Temeperature:
 On raising the temperature atleast for 10
degree centigrade, the rate constant gets
doubled.
 Therefore, we can say that, the rate constant
is directly proportional to the temperature.
Effect of catalyst:
 A catalyst provides route for the reaction
with a lower activation energy.
 On adding the catalyst..
Frequency factor
 The frequency factor A is considered to be a
constant and has very less effect on the
varience of rate constant.
Conclusion:
 Therefore, with the help of the
Arrhenius equation we came to
know that, the rate constant is
also dependent upon the
temperature, gas constant,
catalyst etc..
Thank you.

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Bcre ppt 2301

  • 2. Introduction  It is a formula for the temperature dependence of reaction rates.  Proposed by Mr. Svante Arrhenius in 1889 based on the Dutch chemist, Mr. Jacobus HenricusVan’t Hoff.
  • 3.  It gives the dependence of rate constant(k) of a chemical reaction on the absolute temperature.
  • 4. Mr. Jacobus Henricus Van’t Hoff
  • 5. Purposes of Arrhenius equation:  Verify the effect ofTemperature, catalyst, Gas constant.  Temperature,T To fit, this should be in Kelvin.  The gas constant, R Which comes from the PV=nRT
  • 6.  Activation energy, E Minimum energy for reaction to occur.  The e=2.7182  The frequency factor, A: A term which includes factors like frequency of collisions and their orientations.
  • 7. Uses of Arrhenius equation:  Used extensively to describe the effect of temperature;Thermal death.  To determine how the reac. rates and diffusion changes with temperature.
  • 8. Effect of Temeperature:  On raising the temperature atleast for 10 degree centigrade, the rate constant gets doubled.  Therefore, we can say that, the rate constant is directly proportional to the temperature.
  • 9. Effect of catalyst:  A catalyst provides route for the reaction with a lower activation energy.  On adding the catalyst..
  • 10. Frequency factor  The frequency factor A is considered to be a constant and has very less effect on the varience of rate constant.
  • 11. Conclusion:  Therefore, with the help of the Arrhenius equation we came to know that, the rate constant is also dependent upon the temperature, gas constant, catalyst etc..