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Contents lists available at ScienceDirect
Journal of Environmental Chemical Engineering
journal homepage: www.elsevier.com/locate/jece
A review on nickel(II) adsorption in single and binary component systems
and future path
Md. Aminul Islama,b,⁎⁎
, Md. Rabiul Awualc,d,⁎
, Michael J. Angovea
a
Department of Pharmacy and Biomedical Science, La Trobe Institute for Molecular Science (LIMS), La Trobe University, Bendigo, VIC-3550, Australia
b
Department of Arts and Sciences, Faculty of Engineering, Ahsanullah University of Science and Technology (AUST), Dhaka, 1208, Bangladesh
c
Materials Science and Research Center, Japan Atomic Energy Agency (JAEA), Hyogo 679–5148, Japan
d
Center of Excellence for Advanced Materials Research, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia
A R T I C L E I N F O
Keywords:
Adsorption
Nickel(II)
Wastewater
Single and binary
Surface complexation
Future path
A B S T R A C T
Water polluted with heavy-metal ion has been a major problem in recent years. Among various metal ions, nickel
(II) is a priority pollutant commonly found in industrial wastewater. As a highly toxic element at an elevated
concentration, Ni(II) can pose a serious threat to our ecological environment as well as human being. Ni(II)
adsorption from wastewater is a must for environmental management and sustainability. Remediation of Ni(II)
contaminated water is possible through adsorption onto various innovative adsorbents from the aquatic en-
vironment. The current review looks at the present status of the research done so far Ni(II) adsorption using
various adsorbents from wastewater. Ni(II) adsorption kinetics, edges, isotherm, thermodynamic parameters,
and Ni(II) adsorption mechanism have also been talked over. Efforts have also been made to steer out of the
advantages and disadvantages of adsorbents and the future research need in Ni(II) adsorption by adsorbents.
Agricultural based substrates and nanosized metal oxides have been found a hopeful alternative for Ni(II) ad-
sorption from wastewater. The Ni(II) primarily adsorbed onto a homogeneous substrate forming a monolayer. Ni
(II) generally formed outer-sphere complexes at low pH values while it formed inner-sphere complexes at higher
pH. More than one species is being sorbed, or more than one type of surface site is involved in Ni(II) adsorption
process or both. However, significant research is needed to understand Ni(II)-surface interaction mechanism at
the solid-water interface. This review can fill the lacuna of researchers who would like to do more research in
this related area in depth.
1. Introduction
Nickel (II) polluted water is a major problem in recent years due to
its toxicity and tendency to bioaccumulate [1]. Due to its hazardous
nature, Ni(II) has been recognized as priority pollutants that have found
to deposit in the environment causing adverse effects to animal species
[2]. The primary sources of Ni(II) are the industrial effluents from
mining, oil refining, mineral processing, electroplating, forging, silver
refining, paint formulation, battery manufacturer, and steam electric
power plants [2,3]. While at trace levels Ni(II) is micronutrient, it is a
toxic pollutant and influences animal and human health if excess Ni(II)
is ingested [4]. Acute ingestion or intake of Ni(II) has severe health
effects, including diarrhoea, renal oedema, gastrointestinal ache, pul-
monary fibrosis, cardiovascular and kidney disease and cancer [1,5]. In
addition, several Ni(II) compounds namely carbonyls are hazardous and
are readily absorbed by the human skin [6]. Thus, it is mandatory to
treat wastewater polluted with Ni(II) prior to their release into the
environment. However, the regulation limit for Ni(II) in the water, air,
soil, and food depend on many factors. A study conducted by Cempel
et al. [7] mentioned that the regulation limit for Ni(II) in water, air,
soil, and food were 20 μg/L, 0.025 μg m−3
, 50 mg/kg d.w. and 132 μg
/day respectively. Moreover, investigation of Ni(II) speciation at the
liquid-surface interface is vital for an understanding of its ecological
risks, toxicity and thus Ni(II) adsorption from the aquatic environment.
Nickel (atomic number 28 and 24th most commonly found) is an
element of environmental concern [8]. Ni(II) belongs to the suite of
toxic metal ions (Co2+
, Ni2+
, Cd2+
, Cu2+
, Zn2+
Pb2+
, Hg2+
) which
are subject to concentration limits in drinking water [8,9]. Wastewater
polluted with metal ions must be treated carefully before its disposal,
and its long-term behaviour in a geological repository or surface
https://doi.org/10.1016/j.jece.2019.103305
Received 21 May 2019; Received in revised form 25 June 2019; Accepted 19 July 2019
⁎
Corresponding author at: Materials Science and Research Center, Japan Atomic Energy Agency (JAEA), Hyogo 679–5148, Japan.
⁎⁎
Corresponding author at: Department of Pharmacy and Biomedical Science, La Trobe Institute for Molecular Science (LIMS), La Trobe University, Bendigo, VIC-
3550, Australia.
E-mail addresses: aminul.chem.as@aust.edu (Md. A. Islam), rawual76@yahoo.com (Md. R. Awual).
Journal of Environmental Chemical Engineering 7 (2019) 103305
Available online 22 July 2019
2213-3437/ © 2019 Elsevier Ltd. All rights reserved.
T

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A review on nickel(II) adsorption in single and binary component systems and future path

  • 1. Contents lists available at ScienceDirect Journal of Environmental Chemical Engineering journal homepage: www.elsevier.com/locate/jece A review on nickel(II) adsorption in single and binary component systems and future path Md. Aminul Islama,b,⁎⁎ , Md. Rabiul Awualc,d,⁎ , Michael J. Angovea a Department of Pharmacy and Biomedical Science, La Trobe Institute for Molecular Science (LIMS), La Trobe University, Bendigo, VIC-3550, Australia b Department of Arts and Sciences, Faculty of Engineering, Ahsanullah University of Science and Technology (AUST), Dhaka, 1208, Bangladesh c Materials Science and Research Center, Japan Atomic Energy Agency (JAEA), Hyogo 679–5148, Japan d Center of Excellence for Advanced Materials Research, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia A R T I C L E I N F O Keywords: Adsorption Nickel(II) Wastewater Single and binary Surface complexation Future path A B S T R A C T Water polluted with heavy-metal ion has been a major problem in recent years. Among various metal ions, nickel (II) is a priority pollutant commonly found in industrial wastewater. As a highly toxic element at an elevated concentration, Ni(II) can pose a serious threat to our ecological environment as well as human being. Ni(II) adsorption from wastewater is a must for environmental management and sustainability. Remediation of Ni(II) contaminated water is possible through adsorption onto various innovative adsorbents from the aquatic en- vironment. The current review looks at the present status of the research done so far Ni(II) adsorption using various adsorbents from wastewater. Ni(II) adsorption kinetics, edges, isotherm, thermodynamic parameters, and Ni(II) adsorption mechanism have also been talked over. Efforts have also been made to steer out of the advantages and disadvantages of adsorbents and the future research need in Ni(II) adsorption by adsorbents. Agricultural based substrates and nanosized metal oxides have been found a hopeful alternative for Ni(II) ad- sorption from wastewater. The Ni(II) primarily adsorbed onto a homogeneous substrate forming a monolayer. Ni (II) generally formed outer-sphere complexes at low pH values while it formed inner-sphere complexes at higher pH. More than one species is being sorbed, or more than one type of surface site is involved in Ni(II) adsorption process or both. However, significant research is needed to understand Ni(II)-surface interaction mechanism at the solid-water interface. This review can fill the lacuna of researchers who would like to do more research in this related area in depth. 1. Introduction Nickel (II) polluted water is a major problem in recent years due to its toxicity and tendency to bioaccumulate [1]. Due to its hazardous nature, Ni(II) has been recognized as priority pollutants that have found to deposit in the environment causing adverse effects to animal species [2]. The primary sources of Ni(II) are the industrial effluents from mining, oil refining, mineral processing, electroplating, forging, silver refining, paint formulation, battery manufacturer, and steam electric power plants [2,3]. While at trace levels Ni(II) is micronutrient, it is a toxic pollutant and influences animal and human health if excess Ni(II) is ingested [4]. Acute ingestion or intake of Ni(II) has severe health effects, including diarrhoea, renal oedema, gastrointestinal ache, pul- monary fibrosis, cardiovascular and kidney disease and cancer [1,5]. In addition, several Ni(II) compounds namely carbonyls are hazardous and are readily absorbed by the human skin [6]. Thus, it is mandatory to treat wastewater polluted with Ni(II) prior to their release into the environment. However, the regulation limit for Ni(II) in the water, air, soil, and food depend on many factors. A study conducted by Cempel et al. [7] mentioned that the regulation limit for Ni(II) in water, air, soil, and food were 20 μg/L, 0.025 μg m−3 , 50 mg/kg d.w. and 132 μg /day respectively. Moreover, investigation of Ni(II) speciation at the liquid-surface interface is vital for an understanding of its ecological risks, toxicity and thus Ni(II) adsorption from the aquatic environment. Nickel (atomic number 28 and 24th most commonly found) is an element of environmental concern [8]. Ni(II) belongs to the suite of toxic metal ions (Co2+ , Ni2+ , Cd2+ , Cu2+ , Zn2+ Pb2+ , Hg2+ ) which are subject to concentration limits in drinking water [8,9]. Wastewater polluted with metal ions must be treated carefully before its disposal, and its long-term behaviour in a geological repository or surface https://doi.org/10.1016/j.jece.2019.103305 Received 21 May 2019; Received in revised form 25 June 2019; Accepted 19 July 2019 ⁎ Corresponding author at: Materials Science and Research Center, Japan Atomic Energy Agency (JAEA), Hyogo 679–5148, Japan. ⁎⁎ Corresponding author at: Department of Pharmacy and Biomedical Science, La Trobe Institute for Molecular Science (LIMS), La Trobe University, Bendigo, VIC- 3550, Australia. E-mail addresses: aminul.chem.as@aust.edu (Md. A. Islam), rawual76@yahoo.com (Md. R. Awual). Journal of Environmental Chemical Engineering 7 (2019) 103305 Available online 22 July 2019 2213-3437/ © 2019 Elsevier Ltd. All rights reserved. T