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A numerical solution for the unsteady, natural convective flow of heat and mass transfer along an inclined plate is presented. The dimensionless unsteady, coupled, and non-linear partial differential conservation equations for the boundary layer regime are solved by an efficient, accurate and unconditionally stable finite difference scheme of the Crank-Nicolson type. The velocity, temperature, and concentration fields have been studied for the effect of Magnetic parameter, buoyancy ratio parameter, Prandtl number, radiation parameter and Schmidt number. The local skin-friction, Nusselt number and Sherwood number are also presented and analyzed graphically.