Prepreg excellence days - Presentation

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Prepreg excellence days - Presentation

  1. 1. Advanced Materials DECEMBER, 2014 ADVANCED CHEMISTRIES RAISING PERFORMANCE
  2. 2. Advanced Materials FOCUSED INDUSTRIES ADVANCED CHEMISTRIES RAISING PERFORMANCE 2
  3. 3. Advanced Materials OUR HISTORY ADVANCED CHEMISTRIES RAISING PERFORMANCE Chemical Industry Basel (CIBA) is formed Ciba merges with J.R. Geigy to form Ciba-Geigy 1758 Ciba Specialty Chemicals independent of Novartis 1996 1884 1971 J.R. Geigy AG begins trading in chemicals and dyes Vantico is acquired by Huntsman and becomes AdMat division 2000 1997 Ciba-Geigy merges with Sandoz to form Novartis 2005 2003 Vantico is formed for Performance Polymers 2011 Huntsman becomes a public company 3
  4. 4. Advanced Materials GLOBAL PRESENCE ADVANCED CHEMISTRIES RAISING PERFORMANCE 2,300 employees, 80 countries, more than 1,500 products, over 2000 customers Americas: 527 Europe: 1,135 Bergkamen Moscow Duxford Bad Säckingen Monthey Vienna Pamplona Istanbul Basel Madrid Cairo Sadat City Dubai East Lansing Los Angeles McIntosh The Woodlands Seoul Shanghai Panyu Mumbai Hong Kong Tokyo Kobe Taipeh Chennai Singapore Taboão da Serra São Paulo Buenos Aires 3 regional headquarters 13 manufacturing sites 10 sales offices IMT: 188 Spartan Deer Park APAC: 448 4
  5. 5. Advanced Materials INNOVATION ADVANCED CHEMISTRIES RAISING PERFORMANCE Innovation comes from more than just new molecules It incorporates both new building blocks as well as a way of working together along the value chain. 5
  6. 6. Advanced Materials MILESTONES IN EPOXIES ADVANCED CHEMISTRIES RAISING PERFORMANCE 1930 1940 1950 1960 O O O O O - O O O 1980 CH2 - O O O CH2 - N O O N O O - - O TGMDA / TGPAP O N O - n DOW 2000 2010 O O - O - - FLUORENE O NEXT GENERATION EPOXIES NAPHTHALENE SHELL SUMITOMO UNION CIBA CIBA CARBIDE O O O TGMAP CIBA 2020 O O O EPN / ECN CIBA 1990 O N BISHENOL A EPOXIES Lab / pilot scale availability 1970 O HUNTSMAN DICHUNTSMAN N HUNTSMAN CoE Internal evaluation Customer evaluation Commercial scale availability Qualification 1st application Technical drivers CIBA DOW Aerospace Marine Electronics CIBA Electronics Structural Composites CIBA HUNTSMAN CIBA Structural composites Structural Structural composites composites HUNTSMAN Structural composites Superior mechanical performances to polyester and phenolics Thermal resistance superior to Bisphenol A epoxies Thermal resistance Mechanical performance Processability TP tougheners Compatibility Processability Modulus improvement Similar other performances Toughness and “20% UP” thermal resistance via reduction of cross linking density Araldite® GY 250 Araldite® LY 556 Araldite® MY 790 … Araldite® EPN 1138 Araldite® EPN 1139 Araldite® ECN 1273 Araldite® ECN 1299 … Araldite® MY720 Araldite® 9655, 9512, 9634… Araldite® M721 Araldite® MY0500 Araldite® MY0510 Araldite® MY0600 Araldite® MY0610 Araldite® MY 0816 6
  7. 7. Advanced Materials MILESTONES IN OTHER HIGH PERFORMANCE THERMOSETS ADVANCED CHEMISTRIES RAISING PERFORMANCE 1960 1970 O N -O 1980 1990 2000 2010 2020 O C H2 Me N HO O - OH Me - - - - BMI MDA Lab / pilot scale availability CYANATE ESTERS BMI MDA FREE BENZOXAZINES BISPHENOL A / F NEXT GENERATION BENZOXAZINES ? R.P. DOW CIBA GURIT ESSEX HUNTSMAN CoE CIBA Internal evaluation Customer evaluation Commercial scale availability Qualification 1st application Technical drivers R.P. DOW ? Electronics Higher thermal resistance to epoxies CIBA Structural composites CIBA (R.P.) Structural composites Electronics LONZA HUNTSMAN Structural composites Electronics HUNTSMAN Electronics Structural composites Lower toxicity Niche between FST / X-Free Thermal and Processability epoxies and BMIs mechanical performance Dielectric properties Matrimid® 5292 A/B AroCy® range Interiors Araldite® LZ 8280 N 75 XU 8282-1 Processing Low toxicity FST / X-Free Processing Thermal and mechanical performance Araldite® MT 35600 Araldite® MT 35700 7
  8. 8. Advanced Materials REACH FOR CHEMICALS ADVANCED CHEMISTRIES RAISING PERFORMANCE Registration, Evaluation, Authorization and Restriction Large financial and resource impact on the chemical components suppliers due to number of substances Analytical & toxicity studies, dossier preparation, chemical safety report, personal costs… We are spending several millions euros each year in order to maintain current supply Introduction of new molecules into the EU market may be commercially risky and expensive In worse case, more than 2 millions euros 8
  9. 9. Advanced Materials REGULATORY / LEGISLATION ADVANCED CHEMISTRIES RAISING PERFORMANCE Evolution in Europe for chemistries used in composite applications Statement Phenolics Epoxy Epoxy with resins formerly "R68” & currently "H341" labelled with resins "Others" BisMaleimides Cyanate Ester Benzoxazines Isocyanate NO ISSUE with REACH registration NO USAGE LIMITATION for composite application (prepregs or direct closed processes) Unknown ADDITIONAL PROTECTIVE MEASURES (not mandatory today) could be required at the working place (1) TGMDA (2) Naphthalene epoxy (4) TGPAP, TGMAP Subject to test programs results (3) (1) Formaldehyde is today under consultation for "Proposal for Harmonised Classification and Labelling" and it will be classified as Carc. 1A (2) Latest tests for REACH dossier allow removal from Mutagenic and Reprotoxic classification lists : "R68"/"H341" phrases to be removed by end 2013 (3) Mutagenic and reprotoxic tests running: Tests results expected between 2014 (MUT) and 2016 (REPRO) (4) REACH registration 2018 Remark: The above table represents Huntsman’s view based on current knowlegde at the date of the presentation and are subject to changes in regulation 9
  10. 10. Advanced Materials WHAT YOU SHOULD EXPECT FOR INNOVATION ADVANCED CHEMISTRIES RAISING PERFORMANCE SPECIALTY COMPONENTS PARTNER ROLE IN INNOVATION CONTSRUCT BUILDING BLOCKS MANAGE CHANGE (e.g. Huntsman) PROVIDE FOCUS 10
  11. 11. Advanced Materials CONSTRUCT BUILDING BLOCKS ADVANCED CHEMISTRIES RAISING PERFORMANCE Synthesize Customize Optimize EPN BUILDING BLOCKS SPE. COMP. PARTNER BIS-A DICY M5218 CHANGE PREPREGGER FOCUS TGMDA DDS BIS-F ECN IPDA 11
  12. 12. Advanced Materials MANAGE CHANGE ADVANCED CHEMISTRIES RAISING PERFORMANCE BUILDING BLOCKS CHANGES REGULATORY RAW MATERIAL VARIABILITY SUPPLY CHAIN CHANGE MITIGATIONS §  Processes that cover both internal and external stake holders along the value chain §  Product stewardship §  Apply predictive approach §  Communication of risks §  Process safety management FOCUS 12
  13. 13. Advanced Materials PROVIDE FOCUS ADVANCED CHEMISTRIES RAISING PERFORMANCE MASS COMMODITY SUPPLIER SPE. COMP. PARTNER TIER 1 PREPREGGER OEM MASS COMMODITY SUPPLIER MASS COMMODITY SUPPLIER BUILDING BLOCKS CHANGE 100 FOCUS 80 60 40 MC supplier SC supplier Prepregger Tier 1 OEM 20 0 MARKET FOCUS 13
  14. 14. Advanced Materials TAMING THE WILD ADVANCED CHEMISTRIES RAISING PERFORMANCE THE COMMODITY WILDERNESS §  General specifications with little regard to historical equivalence or customers §  Inconsistency or fluctuation of quality §  Change management that meets internal needs (mainly for safety) and not customer focused §  Reluctant to create “specialty” or “unique” materials §  “Here is our offering, take it or leave it” BUILDING BLOCKS CHANGE FOCUS 14
  15. 15. Advanced Materials CREATING FOCUS ADVANCED CHEMISTRIES RAISING PERFORMANCE THE PREPREGGER CIVILIZATION §  Focused needs §  Well defined specifications based on statistical equivalence rather than just a specification range §  Sensitive to change (effects on quality and processing time, potential breaching of approvals) §  Change management that incorporates value chain §  Values uniqueness BUILDING BLOCKS CHANGE FOCUS 15
  16. 16. Advanced Materials WORKING TOGETHER TO DRIVE INNOVATION ADVANCED CHEMISTRIES RAISING PERFORMANCE A common blueprint along the value chain evolves into a new civilization of value. 16
  17. 17. Advanced Materials LEGAL INFORMATION ADVANCED CHEMISTRIES RAISING PERFORMANCE Araldite® is a registered trademark of Huntsman Corporation or an affiliate thereof in one or more, but not all, countries. Sales of the product described herein (“Product”) are subject to the general terms and conditions of sale of either Huntsman Advanced Materials LLC, or its appropriate affiliate including without limitation Huntsman Advanced Materials (Europe) BVBA, Huntsman Advanced Materials Americas Inc., or Huntsman Advanced Materials (Hong Kong) Ltd. or Huntsman Advanced Materials (Guangdong) Ltd. (“Huntsman”). The following supercedes Buyer’s documents. While the information and re-com-mendations included in this publication are, to the best of Huntsman’s knowledge, accurate as of the date of publication, NOTHING CONTAINED HEREIN IS TO BE CONSTRUED AS A REPRESENTATION OR WARRANTY OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIMITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NONINFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHTS, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND THE BUYER ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES. No statements or recommendations made herein are to be construed as a representation about the suitability of any Product for the particular application of Buyer or user or as an inducement to infringe any patent or other intellectual property right. Data and results are based on controlled conditions and/or lab work. Buyer is responsible to determine the applicability of such information and recommendations and the suitability of any Product for its own particular purpose, and to ensure that its intended use of the Product does not infringe any intellectual property rights. The Product may be or become hazardous. Buyer should (i) obtain Material Safety Data Sheets and Technical Data Sheets from Huntsman containing detailed information on Product hazards and toxicity, together with proper shipping, handling and storage pro-cedures for the Prod-uct, (ii) take all steps necessary to adequately inform, warn and familiarize its employees, agents, direct and in-direct customers and contractors who may handle or be exposed to the Product of all hazards pertaining to and proper procedures for safe handling, use, storage, transportation and disposal of and exposure to the Product and (iii) comply with and ensure that its employees, agents, direct and indirect customers and contractors who may handle or be exposed to the Product comply with all safety information contained in the applicable Material Safety Data Sheets, Technical Data Sheets or other instructions provided by Huntsman and all applicable laws, regulations and standards relating to the handling, use, storage, distribution and disposal of and exposure to the Product. Please note that products may differ from country to country. If you have any queries, kindly contact your local Huntsman representative. © 2013 Huntsman Corporation. All rights reserved. Ref. No. Prepreg Excellence Days 12.13 _EN_EU 17

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