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Photovoltaic Solar Energy Conversion (PVSEC)
                                ‫إﻧﺘﺎج اﻟﻜﻬﺮﺑﺎء ﻣﻦ اﻟﻄﺎﻗﺔ اﻟﺸﻤﺴﻴﺔ‬

            Courses on photovoltaic for Moroccan academic staff; 23-27 April, ENIM / Rabat
                                                                 23 27



                  Workshop d
                  W k h and problem solving activities
                               bl     l i     ti iti
                                      Ahmed Ennaoui
                     Helmholtz-Zentrum Berlin für Materialien und Energie
                                ennaoui@helmholtz-berlin.de
This material is intended for use in lectures, presentations and as handouts to students, it can
be provided in Powerpoint format to allow customization for the individual needs of course
instructors. Permission of the author and publisher is required for any other usage.

                                 Sources: Stanford University/JOHN WILEY & SONS, INC., PUBLICATION
                                 Sources: Arizona State University
Aims of Classroom Workshop

 To clarify and illustrate the concepts of the theoretical courses
 To sharpen the communicative skills of the students, this includes
communication in other languages than the native tongue .
 To develop a global quality reflex and to accomplish a reality sense:
through critical observation, in learning the applicability and limits of
the theoretical concepts and experimental techniques
  To gain experience in working in groups and communicate towards
group members.
 To develop the analytical mind and the sense for synthesis
 To be able to report orally and by writing
Basic Laws of Radiation/ Black Body Radiation

- The following issues should be discussed:
- A photon is determined by the magnitude and the direction of its momentum
- direction of the associated electric field: p = ħ k
- Distinguish between: wave vector k with the Boltzmann constant kB.
- 2 states for photons corresponding to the two possibilities of polarization of the electric
field perpendicular to the direction of propagation.
- N b of possible states of th photons i a volume V i given by:
  Number f         ibl t t     f the h t       in     l    is i    b

                   1                        V 3                        β=
                                                                              1
      ns =                              2      3
                                                 dk                         k BT
              eβ S − 1
               βε
                                          (2π)
                                             )
      Average number of photons per unit volume having their wave vector between
            k and k + dk = the n mber of states x probabilit of each state
                               number             probability
Basic Laws of Radiation/ Black Body Radiation

                     2hc2         1
            E(λ, T) = 5
                      λ ⎡ ⎛ hc ⎞ ⎤
                          ⎢exp⎜
                              ⎜ λk T ⎟ − 1⎥
                                     ⎟
                          ⎣ ⎝ B ⎠ ⎦

c = 3 0 × 108 ms-1 ; h = 6 63 × 10-34 J ; k =1.38 × 10-23 JK-1
    3.0          1       6.63      34 J.s    1 38      23    1
Basic Laws of Radiation/ Black Body Radiation




                      Total area under the
                        curve is the total
                     radiant power emitted.

                                This area in (W/m2)
                               is the power emitted
                                between λ1 and λ2
Basic Laws of Radiation/ Black Body Radiation




                      Total area under the
                        curve is the total
                     radiant power emitted.
Basic Laws of Radiation/ Black Body Radiation




         [Watt] = [m] x [W/m2 . K4] x [Kelvin]
Basic Laws of Radiation/ Black Body Radiation

Consider the earth to be a blackbody with average surface temperature
15°C and area equal to 5.1 x 1014 m2. Find the rate at which energy is
radiated by the earth and the wavelength at which maximum power is
radiated. Compare this peak wavelength with that for a 5800 K
blackbody (the sun).
The earth radiates:

                       σ                  A                 T   4

 E (W ) = (5 64 x 10 -8 W −2 K −4 ) (5 1 x 1014 m 2 ) [(15 + 273)K]4 = 2 0 x 1017 W
   (Watt) (5.64       8
                        Wm          (5.1                               2.0        Watt

The wavelength at which the maximum power is emitted



                      2898 2898                                     2898
     λmax (earth) =        =     = 10.1μm               λ (sun) =        = 0.5μ.
                      T(K)   288                                    5800
Basic Laws of Radiation/ Black Body Radiation
                                            Copyrighted Material, from internet


                            Sun (visible)
                          λMAX = 0.5 μm
                        FT = 64 million W m-2

                                     Earth (infrared)
                                      λMAX = 10 μm
                                      FT = 390 W m-2
                                                   2
Basic Laws of Radiation/ Black Body Radiation
                                     Copyrighted Material, from internet




      Replicate this experience in your lab.
Black Body Radiation
is the amount of incoming solar radiation per unit area that would be incident on a plane
perpendicular to the rays, at a the mean distance from the Sun to the Earth.

  Solar constant
                                    2
                    ⎛R⎞    4
              E=σ T ⎜ ⎟
                    ⎝D⎠
   σ = 5,67 . 10-8 W/(m2.K4), T = 5800 K
   R = 6 96 108 m D = 1,49.1011 m
       6,96.10 m,     1 49 10
                                                                   For more detail
   E = 1402 W/m2                                      See PVSEC1:Solar flux intercepted by the Earth

                       2                                                                           2
                                                 4 ⎛ 6,96.10 m ⎞
                                                                                           8
             ⎛R⎞
     E = σ T ⎜ ⎟ = 5,67 . 10 W/(m .K ) x (5800 K) x ⎜
               4            -8   2  4
                                                    ⎜ 1,49.10 11 m ⎟
                                                                   ⎟
             ⎝D⎠                                    ⎝              ⎠
   The atmosphere will transmit a fraction (75%) of solar radiation
                           τ E = 0,75 E = 1052 W/m2
Altitude angle at solar noon

                        L
                                            Example 1: Tilt Angle of a PV Module. Find the
               P              δ             optimum tilt angle for a south-facing
                       βNoon = 90 + L- δ    photovoltaic module in Rabat (latitude 34° at
               L
  Equation
  E    i
                         Local
                                            solar noon on M h 1
                                              l           March 1st.
                       horizontal


March 1st. is the 60th. day of the year so the solar declination is:

                 ⎡ 360          ⎤             ⎡ 360           ⎤
   δ = 23.45 sin ⎢     (n − 81) ⎥ = 23.45 sin ⎢
                       (      )                     (60 − 81) ⎥ = −8.3°
                                                    (       )
                 ⎣ 365          ⎦             ⎣ 365           ⎦

The tilt angle that would make the sun’s rays perpendicular
to the module at noon would therefore be                                  Altitude
                                                                          Altit d angle
                                                                                      l
 βnoon = 90° − L + δ = 90− 34− 8.3 = 47.7                                   βnoon=47.7


Tilt = 90 − β noon = 90 − 47.7 = 42.3°          Tilt = 42.3°
                                                                                     S
Altitude angle and azimuth angle
Find altitude angle β and azimuth angle S at 3 PM solar time in Boulder, CO (L = 40˚)
                                                                 Boulder          40 )
on the summer solstice:.At the solstice, we know the solar declination δ = 23.45°
     ⎛ 15 ° ⎞                              ⎛ 15 ° ⎞
HA = ⎜      ⎟ x (hours before solarnoon) = ⎜
                ( ou s be o e so a oo )           ⎟ x (-3h) = -45 °
                                                      (3 )      5
     ⎝  h ⎠                                ⎝  h ⎠
sin β = sin(40)sin (23.45) + cos(40)cos (23.45)cos (-45) = 0.7527 β = sin -1 (0.7527) = 48.8 °
            cos(23.45) sin(-45)
sin(Az) =                       = −0 9848
                                   0.9848   φ S = sin -1 ( 0 9848) = −80 °
                                                   i 1 (-0.9848)
                cos(48.8)
                                                       A.M.
                                                                             P.M.


                                                                                    β = 48.8 °



                                                          φ S = −80 °
Solar angles
Sunrise and sunset can be found from a simple use of:
    sin(h) = sin(L)sin( δ) + cos(L)cos( δ)cos(ω) = 0




 Find the time at which sunrise (geometric and conventional) will occur in
 Boston (latitude 42.3°) on July 1 (n = 182). Also find conventional sunset.
Example 1: Solar Time vs. Clock Time
  Find Eastern Daylight Time for solar noon in Boston (longitude 71.1 W)
                                                                  71.1°
  on July 1st.
  Answer: July 1st. is day number n = 182. to adjust for local time,
  we obtain:
      360            360
  B=      (n − 81) =     (182 − 81) = 99.89°
      364            364
 E = 9.87sin2B − 7.53cosB - 1.5sinB = 9.87sin2[2 (99.89)] − 7.53cos(99.89) - 1.5sin(99.89) = -3.5
                                                 (     )           (     )         (     )
  For Boston at longitude 71.7° W in the Eastern Time Zone with local time meridian 75°
                                       4min
  Solar Time (ST) = Clock Time (CT) +        (Local Time Meridian - Local Longitude)° + E(min)
                                      degree
  To adjust for Daylight Savings Time add 1 h, so solar noon will be at about 12:48 P.M.
  CT = 12 − 4(75 - 71.1)° − ( −3.5) = 12 : 00 − 12.1min = 11 : 47.9A.M. East

                                Origine
                                For Eastern
                                zone

Time Belts of the U.S : Eastern Standard Time - E.S.T. is calculated to the 75th meridian west longitude. Central Standard Time - C.S.T. is calculated to the 90th
meridian west. Mountain Standard Time - M.S.T. is calculated to the 105th meridian west. Pacific Standard Time - P.S.T. is calculated to the 120th meridian
west. Alaska was standardized in 1918 on 150th Meridian west, but in actual practice, other zones are and have been in use: 120° 150°, 165°
Example 2: Solar Time vs. Clock Time
For the “Green community village” near Dubai (latitude angle = 25° N, local longitude angle = 55°12’ E,
standard time zone = UTC +4, no daylight saving ti ) on February 3 at 14.00. Determine:
 t d d ti                   4    d li ht        i time) F b             t 14 00 D t   i
a. the apparent solar time.
b. solar declination and hour angle , solar altitude and solar azimuth angles.
                                                                        UTC = Universal Time and GMT = Greenwich Mean Time.
                                               Atlantic Standard Time (AST) is 4 hours behind of Coordinated Universal Time(UTC)
                                                                     http://www.timeanddate.com/worldclock/search.html
                                                     http://www.timeanddate.com/worldclock/results.html?query=Morocco
 a) The apparent solar time                                              360            360
                                     February 3th ⇒ n = 34 B =
                                            y                                (n − 81) =
                                                                             (      )       (34 − 81) = - 46,48°
                                                                                            (       )       ,
                                                                         364            364
     ET = 9.87 sin2B − 7.53B - 1.5 sinB = 9.87 sin2(-46.48) − 7.53(-46.48) - 1.5 sin(-46.48) = -13.95 min
 Local longitude angle = 55°12’ E = -55.2° (conversion in °, and negative since location is in East
 Standard time zone UTC+4 Local Time meridian (LTM)= -60° (negative since location is in East)
                                                     (    )       ( g                               )
 No daylight saving time February LST = 14:00
                          4min
  AST = LST + E(min) +          (LT M - Local Longitudinal angle ) = 14 : 00 + (−13.95°) + [− 60° − (−55.2°)]. 4min = 13 : 27
                         degree                                                                               degree
   Hour angle ω and solar d li ti δ
b) H         l      d l declination δ.
                                                                           360 °(284 + n)              360 °(284 + 34)
AST = 13:27 = 13.45 h (conversion of time in hours)        δ = 23.45 ° sin                = 23.45 °sin                 = − 16.97
                                                                                365                          365
ω =15° (hours from local solar noon) = 15° (ST-12)
ω = 15°.( 13.45-12) = 21.75°
sin(h) = sin(L)sin(δ) + cos(L)cos(δ) ( ) ⇒ h = sin-1 [sin(25°) i (−16 97) + cos(25°)
  i (h) i (L) i (          (L) (δ)cos(ω)        i      i (25 ).sin( 16.97)                      (21 75).cos(−16 97)] = 42 98°
                                                                                     (25 ).cos(21.75)         ( 16.97) 42.98
                                                                         cosδ . sinω               ⎡ cos(−16.97).sin(21.75) ⎤
                                                             sin(Az) =               ⇒ Az = sin −1 ⎢                        ⎥ = 28.98°
                                                                           cos(h)                  ⎣      cos(42.98)        ⎦
Attenuation and air mass

Direct B
Di t Beam Radiation at th Surface of the Earth –
          R di ti    t the S f     f th E th
Find the direct beam solar radiation normal to the sun’s rays at solar
noon on a clear day in Atlanta (latitude 33.7°C) on May 21.
                   y           (               )      y
                                             May 21 is day number 141

                            ⎡ 360           ⎤
         A = 1160 + 75sin . ⎢     (n − 275) ⎥ (W/m 2 ) = 1104 W/m 2
                            ⎣ 365           ⎦
                              ⎡ 360           ⎤
         k = 0.175 + 0.035sin ⎢     (n − 100)⎥ = 0.197
                                    (       )
                              ⎣ 365           ⎦
                       Optical Depth k and the apparent Extraterrestrial Flux A.
                    The Sky Diffuse Factor C can be used later for diffuse radiation




            Measurements for the 21st Day of Each Month after ; Source: ASHRAE (1993).
Insolation on a Collector




Use the the following equation to evaluate δ
                           ⎡ 360         ⎤
             δ = 23.45 sin ⎢     (n − 81)⎥
                           ⎣ 365         ⎦
The altitude angle of the sun at solar noon is


 The air mass ratio:


 The value of clear sky beam radiation at the earth’s surface:
Insolation on a Collector
 Direct-Beam Radiation, IBC
  The translation of direct-beam radiation IB (normal to the rays) into beam
insolation striking a collector face IBC is a simple function of the angle of incidence



                                              θ = incidence angle between a normal
                                              to the collector face and the incoming
                                              beam.

                                     Panel Tilt
            n



Special
S i l case of beam insolation on a horizontal surface
            fb     i l ti          h i t l       f                       IBH
Insolation on a Collector
  At any particular time θ will be a function of the collector orientation
                    time,                                      orientation,
the altitude and azimuth angles of the sun at any particular time

                  The incidence angle is given by



                                           β: altitude
                                           φS solar azimuth
                                           φC P
                                              Panel azimuth
                                                     l i   h




                                                  Panel Tilt
Insolation on a Collector
 Beam Insolation on a Collector at solar noon
 in Atlanta (latitude 33.7°) on May 21 the altitude angle of the sun was found to
 be 76.4° and the clear-sky beam insolation was found to be 902 W/m2.
 Find the beam insolation at that time on a collector that faces 20° toward the
 southeast if it is tipped up at a 52° angle.
     th    t      i ti   d     t          l
       The cosine of the incidence angle




The beam radiation on the collector                             β: altitude
                                                                φS solar azimuth
                                                                φC Panel azimuth

                                          76.4°
                  Solar noon ΦS = 0

                 collector that                                      Panel Tilt
                 faces 20◦ toward                                      52°
                 the southeast                           East
Insolation on a Collector
 Diffuse Radiation on a Collector - find the diffuse radiation on the same panel.
 Solar noon in Atlanta on May 21 (n = 141), a
 Collector faces 20° toward the southeast
 Tipped up at a 52° angle.
 Insolation
 I l ti was f    found to be 902 W/ 2.
                     dt b        W/m
 Diffuse insolation on a horizontal surface IDH is proportional to the direct beam radiation IB no
 matter where in the sky the sun happens to be: IDH = C x IB where C is a sky diffuse factor.




                                                 The diffuse energy striking the collector


                            52°




Added to the total beam insolation of 697 W/m2, this gives a total beam of 785 W/m2.
Insolation on a Collector
Reflected Radiation Onto a Collector.
Reflectance of the surfaces in front of the panel is 0.2 (20%)
Solar noon in Atlanta on May 21,
Altitude angle of the sun β =76.4°,
Collector faces 20° toward the southeast
Tipped up at a 52° angle
Diffuse sky factor C is 0.121
Clear-sky beam i
Cl      k b      insolation i 902 W/ 2.
                      l i is      W/m                            52°

The clear-sky reflected insolation on the collector is
            y




The total insolation on the collector
Insolation on a Collector
You can use this equation, combining the equations for the three
                  q      ,         g      q
components of radiation:




                         Diffuse radiation
               Direct-beam



                                                      collector, C



                               Reflected radiation

                                                     Tilt angle
Insolation on a Collector using obstruction diagram



                                 Figure below




  The sun path diagram with superimposed obstructions makes it easy to
                  estimate periods of shading at a site.
Insolation on a Collector using obstruction diagram
Insolation on a Collector using obstruction diagram
Physics of semiconductor devices
Continuity equations:
         y q
• Derived from Maxwell’s equations:
                                           ∂
              ∇ ⋅ (∇ × H ) = ∇ ⋅ J cond   + ∇⋅D = 0
                                           ∂t
              ∇⋅ (J n + J p ) + ∂ρ = 0,
                                ∂t
                                          ρ = q( p − n + N D − N A )
                ⎧ ∂n = 1 ∇ ⋅ J + G − R
                ⎪ ∂t q        n   n   n
              ⇒ ⎨
                  ∂p     1
                ⎪ = − ∇ ⋅ J p + Gp − Rp
                ⎩ ∂t     q
• Low-level injection (SRH lifetime dominated by the minority
  carrier lifetime):      n p − n p0       p − pn 0
                     Rn =            , Rp = n
                              τn              τp
Physics of semiconductor devices
  Poisson’s equation:
              q
  • Derived from the Maxwell’s equations (electrostatics case):
                      ∇ × E = 0 → E = −∇ϕ
                                                          ρ
                      ∇ ⋅ D = ∇ ⋅ (εE) = − ε∇ ϕ → ∇ ϕ = −
                                            2      2
                                                          ε
   Quasi-Fermi levels:
   • In non-equilibrium conditions, one needs to define separate
     Fermi levels for n and p:

                         ⎛ E Fn − Ei ⎞
               n = ni exp⎜
                         ⎜ k T ⎟     ⎟
                         ⎝     B     ⎠ a J n = nμ n ∇E Fn
                         ⎛ Ei − E Fp ⎞   J p = pμ p ∇E Fp
               p = ni exp⎜
                         ⎜ k T ⎟     ⎟
                         ⎝     B     ⎠
Source: Arizona State University
Physics of semiconductor devices
  Sample problems:

    • Decay of the photo-excited carriers
    • Steady-state injection from one side
    • Surface-recombination
  (1) Decay of photo-excited carriers:
  Consider a sample illuminated with light source until t≤0. The
  generation rate equals to G At t=0 the light source is turned off
                            G.                                  off.
  Calculate pn(t) for t>0 .
                                             hf


                                   n type
                                   n-type sample

                     x=0                             x
Source: Arizona State University
Physics of semiconductor devices
     Solution
     • Boundary conditions:          ∂p
                                                E = 0,       n   =0
     • Minority hole continuity equation: ∂x
     ∂pn    1               pn − pn 0     pn − pn 0
         = − ∇ ⋅ J p + Gp −           =G−                               Have this set up in your lab,.All
                                                                        what you need a diode,
      ∂t    q                  τp            τp                         oscilloscope, )




     • General form of the solution:                                    −t / τ p
                                                         pn (t ) = Ae              +B
     • Boundary conditions:                                             pn ( t )
                                                  pn 0 + τ p G
            p n ( t ≤ 0 ) = p n 0 + Gτ p
            pn ( ∞ ) = p n 0                                                        Light turned off


                                     −t / τ p
                                                 pn 0
            pn (t ) = pn0 + τ pGe
Source: Arizona State University                                                                            t
Physics of semiconductor devices
     ( )
     (2) Steady-state injection from one side:
              y         j
    Consider a sample under constant illumination by a light sour-ce. Calculate
    pn(x).


                        hf
                                             n-type sample


                                   x=0                          x
    Solution
    • Minority carrier continuity equation:

                ∂pn    1                      1 ∂J p pn − pn 0
                    = − ∇ ⋅ J p + Gp − Rp ⇒ −       −
                 ∂t    q                      q ∂x      τp
                                         2
                ∂pn      d pn pn − pn 0
                    = Dp       −
                 ∂t       dx 2   τp
Source: Arizona State University
Physics of semiconductor devices
                                                    ∂pn
                                                     p
     • Steady state situation:
       Steady-state                                     =0
                                                     ∂t
                 d 2 pn       pn − pn 0     d 2 Δpn Δpn
          Dp            2
                            −           =0→      2
                                                   − 2 = 0,                           Lp = τ p Dp
                   dx            τp           dx     Lp
                                                    − x / Lp           x / Lp
                                   Δpn ( x ) = Ae               + Be
     • Boundary conditions for a long sample:                                             Diffusion length

                                   Δpn ( ∞) = 0 → B = 0
                                   Δpn (0) = pn (0) − pn 0 = A                  pn (x )
     • Final solution:                                           p n ( 0)
                                                     − x / Lp
       pn ( x ) = pn 0 + [ pn (0) − pn 0 ]e
                  qD p                    − x / Lp
       J p ( x) =       [ pn (0) − pn0 ]e                           pn 0
                   Lp                                                                                        x
Source: Arizona State University
                                                                                   Lp
Physics of semiconductor devices
     (3) Surface recombination:
    Consider a sample under constant illumination by a light sour-ce. There is a
    finite surface recombination at x=0. Calculate pn(x).
                                                                       Gp



            Surface recombination:
            S f          bi ti                                                   n-type
                                                                                 n type sample

      dpn
   Dp                    = S r [ p n ( 0) − p n 0 ]                                                                       x
       dx         x =0
                                                              x 0
                                                              x=0                                            x L
                                                                                                             x=L

    Solution
    • Minority carrier continuity equation at steady state:
                                              steady-state:
                           d 2 pn      pn − p n 0            d 2 Δpn Δpn   Gp
                     Dp              −            + Gp = 0 ⇒        − 2 =−
                             dx 2         τp                   dx 2
                                                                     Lp    Dp
Source: Arizona State University

Surface Recombination Velocity from Photocurrent Measurements in Journal of The Electrochemical Society, 146 (12) 4640-
4646 (1999)
Physics of semiconductor devices
     • General form of the solution:
                                         − x / Lp          x / Lp
                       Δpn ( x ) = Ae               + Be            +C
                                                       B=0 (asymptotic condition)

     • Boundary conditions for a long sample:
                                   Δp n ( ∞ ) = C = τ p G p
                                   Δp n ( 0 ) = A + C = A + τ p G p
     • Use boundary condition at the surface to determine Δpn(0):
               dpn                                          τ p D pG p
            Dp           = S r [ pn (0) − pn0 ] → Δpn (0) =
                dx x = 0                                    D p + Sr L p
     • Final solution:                                    ⎡       Sr τ p      −x / Lp ⎤
                                        Δpn ( x) = τ pG p ⎢1 −              e         ⎥
                                                          ⎣    L p + Sr τ p           ⎦
Source: Arizona State University
Physics of semiconductor devices

     • Graphical representation of the solution:

                         Δpn ( )
                             (x


                                   Sr = 0
                    τ pG p


                                      Sr increasing

                                   Sr → ∞

                                                      x

Source: Arizona State University
Solar cell and Modules

    1:
Solar cell and Modules
Solar cell and Modules

    2
Solar cell and Modules
Solar cell and Modules

  3
Solar cell and Modules




         The voltage produced by the 36-cells module
Solar cell and Modules
Solar cell and Modules

          4




The NOCT is cell temperature in a module when ambient is
20°C, solar irradiation is 0.8 kW/m2, and windspeed is 1 m/s.
The following expression may be used:
             g p              y
Solar cell and Modules
    PV Module Performance Data Under Standard Test
   Conditions (1 kW/m2, AM 1.5, 25°C Cell Temperature)
Solar cell and Modules




 See table
Effect of Shading
To help understand shading phenomenon consider Figure (a) in which an n-cell module
                              phenomenon,
with current I and output voltage V shows one cell separated from the others (shown as
the top cell, though it can be any cell in the string). The equivalent circuit of the top cell
has been drawn, while the other (n − 1) cells in the string are shown as just a module with
current I and output voltage Vn-1.




                                           all cells are in the sun and since they are in
                                           series,
                                           series the same current , I flows through
                                           each of them.
Effect of Shading
Now , the top cell in figure (b) is shaded and its current source ISC has been reduced to
zero. The voltage drop across RP as current flows through it causes the diode to be
reverse biased, so the diode current is also (essentially) zero. That means the entire
current flowing through the module must travel through both RP and RS in the shaded
cell on its way to the load. That means the top cell, instead of adding to the output
voltage, actually reduces it.
                                   We consider the bottom n − 1 cells still have full sun and
                                   still some how carry their original current I so they will
                                   still produce their original voltage Vn−1.
                                   This means that the output voltage of the entire module
                                                             p        g
                                   VSH with one cell shaded will drop to:
Effect of Shading
 With all n cells in the sun and carrying I , the output voltage was V so the voltage
 of the bottom n − 1 cells will be




 The drop in voltage ΔV at any given current I , caused by the shaded cell, is given by




Since the parallel resistance RP is so much greater than the series resistance RS
Effect of Shading
At any given current, the I –V curve for the module with one shaded cell drops
             current         V
by V. The huge impact this can have is illustrated in the figure below:
Effect of Shading
Example 5 : The 36-cell PV module described in Example 3 had a parallel resistance per cell of
of RP = 6.6 Ω. In full sun and at current I = 2.14 A the output voltage was found there to be V =
19.41 V. If one cell is shaded and this current some how stays the same, then:
a. What would be the new module output voltage and power?
b. What would be the voltage drop across the shaded cell?
c. How much power would be dissipated in the shaded cell?
(a) The drop in module voltage will be



 The new output voltage will be 19.41 − 14.66 = 4.75 V.
 Power delivered by the module with one cell shaded would be


 For
 F comparison, i f ll sun the module was producing 41 5 W
              i      in full    th    d l          d i 41.5 W.
 (b) All of that 2.14 A of current goes through the parallel plus series resistance (0.005Ω ) of
 the shaded cell, so the drop across the shaded cell will be


(normally a cell in the sun will add about 0.5 V to the module; this shaded cell subtracts over 14
V from the module).
Effect of Shading
  The power dissipated in the shaded cell is voltage drop times current, which is
      p          p                                g     p              ,



All of that power dissipated in the shaded cell is converted to heat, which can cause a local hot
spot that may permanently damage the plastic laminates enclosing the cell.

Final remarks:
The proced res demonstrated in this e ample can be e tended to de elop I –V c r es under
     procedures                        example            extended develop V curves nder
various conditions of shading. The following figures shows such curves for the example
module under full-sun conditions and with one cell 50% shaded, one cell completely shaded,
and two cells completely shaded. Also shown on the graph is a dashed vertical line at 13 V,
                   p     y                                g p
which is a typical operating voltage for a module charging a 12-V battery. The reduction in
charging current for even modest amounts of shading is severe. With just one cell shaded out
of 36 in the module, the power delivered to the battery is decreased by about two-thirds!
Effect of Shading




       Effects of shading on the I –V curves for a PV module. The dashed line
shows a typical voltage that the module would operate at when charging a 12-V battery;
                  the impact on charging current is obviously severe.
Exercice: Spectral efficiency of photovoltaic (PV) cells

This exercise will enable you to determine the theoretical maximum spectral efficiency of a
photovoltaic cell, and to determine the effect of concentration on cell efficiency.
Exercice: Spectral efficiency of photovoltaic (PV) cells
Table 2: Fractional function F0−λΤ
Solution: Spectral efficiency of photovoltaic (PV) cells
Solution: Spectral efficiency of photovoltaic (PV) cells
Solution: Spectral efficiency of photovoltaic (PV) cells
Solution: Spectral efficiency of photovoltaic (PV) cells
PROBLEMS
1) For the following materials determine the maximum wavelength of solar
                     materials,
energy capable of creating hole-electron pairs:
a. Gallium arsenide, GaAs, band gap 1.42 eV.
b. Copper indium diselenide, CuInSe2, band gap 1.01 eV
     pp                                      g p
c. Cadmium sulfide, CdS, band gap 2.42 eV.

2) A p-n junction diode at 25°C carries a current of 100 mA when the diode
voltage is 0 5 V What is the reverse saturation current, I0?
           0.5 V.                               current

3) For the simple equivalent circuit for a 0.005 m2 photovoltaic cell shown
below, the reverse saturation current is I0 = 10−9 A and at an insolation of
1-sun the short-circuit current is ISC = 1 A,. At 25°C, find the following:
PROBLEMS
a.
a The open-circuit voltage
       open circuit voltage.
b. The load current when the output voltage is V = 0.5 V.
c. The power delivered to the load when the output voltage is 0.5 V.
d. The efficiency of the cell at V = 0.5 V.

4) The equivalent circuit for a PV cell includes a parallel resistance of RP =
10 . The cell has area 0.005 m2, reverse saturation current of I0 = 10−9 A
and at an insolation of 1-sun the short-circuit current is ISC = 1 A, At 25 C,
                        1 sun      short circuit                         25◦C,
with an output voltage of 0.5 V, find the following:
PROBLEMS
a.
a The load current
             current.
b. The power delivered to the load.
c. The efficiency of the cell.

5) The following figure shows two I-V curves. One is for a PV cell with an equivalent
circuit having an infinite parallel resistance (and no series resistance).
What is the parallel resistance in the equivalent circuit of the other cell?
PROBLEMS
6) The following figure shows two I-V curves. One is for a PV cell with an
                                   IV
equivalent circuit having no series resistance (and infinite parallel resistance).
What is the series resistance in the equivalent circuit of the other cell?
PROBLEMS
7) Estimate the cell temperature and power delivered by a 100-W PV module
with the following conditions. Assume 0.5%/°C power loss.
a. NOCT = 50°C, ambient temperature of 25°C, insolation of 1-sun.
b. NOCT = 45°C, ambient temperature of 0°C, insolation of 500 W/m2.
c. NOCT = 45°C, ambient temperature of 30°C, insolation of 800 W/m2.

8) A module with 40 cells has an idealized, rectangular I-V curve with ISC = 4 A and
VOC = 20 V. If a single cell has a parallel resistance of 5 and negligible series
resistance, draw the I-V curve if one cell is completely shaded. What current would it
deliver to a 12-V battery (vertical I-V load at 12 V)?
PROBLEMS
9) Suppose a PV module has the 1 sun I V curve shown below Within the module
                                  1-sun I-V              below.
itself, the manufacturer has provided a pair of bypass diodes to help the panel
deliver some power even when many of the cells are shaded. Each diode bypasses
half of the cells, as shown. You may consider the diodes to be “ideal;” that is, they
have no voltage drop across them when conducting.




 Suppose there is enough shading on the bottom cells to cause the lower diode
 to start conducting. Draw the new “shaded” I-V curve for the module.
Tracking system for photovoltaics
Tracker systems are either: 2 axis trackers which track the sun both in azimuth and
                             2-axis trackers,
altitude angles so the collectors are always pointing directly at the sun, or 1-axis
trackers, which track only one angle or the other.




                     Two-axis tracking angular relationships
Tracking system for photovoltaics




A single-axis tracking for photovoltaic consists of a mount having a manually
     g               g     p                                       g        y
         adjustable tilt angle along a north-south axis, and a tracking
        mechanism that rotates the collector array from east-to-west
Tracking system for photovoltaics
 When the tilt angle of the mount is set equal to the local latitude (called a polar
 mount), not only is that an optimum angle for annual collection, but the collector
 geometry and resulting insolation are fairly easy to evaluate as well.




If a polar mount rotates about its axis at the same rate as the earth turns, 15°/h, then
the centerline of the collector will always face directly into the sun.
Tracking system for photovoltaics
Under these conditions the incidence angle θ between a normal to the collector and the
             conditions,
sun’s rays will be equal to the solar declination δ. That makes the direct-beam insolation
on the collector just egal to IB cos δ. To evaluate diffuse and reflected radiation, we need
to know the tilt angle of the collector.
                   g
The axis of rotation has a fixed tilt Σ = L, unless it is solar noon, the collector itself is
cocked at an odd angle with respect to the horizontal plane. The effective tilt, which is
the angle between a normal to the collector and the horizontal plane, is given by



The beam, diff
Th b      diffuse, and reflected radiation on a polar mount, one-axis tracker are given
                     d fl t d di ti               l       t        i t k           i
by



 One-Axis, Polar Mount:
Tracking system for photovoltaics
Example: Compare the 40° latitude clear-sky insolation on a collector at solar noon
                           40 latitude,
on the summer solstice for a two-axis tracking mount versus a single-axis polar
mount. Ignore ground reflectance.
1) Solution: For two-Axis Tracker, the beam insolation from IB = Aexp (−km), we need
  )                               ,                                    p(     ),
the air mass ratio m, the apparent extraterrestrial flux A, and the optical depth k. To
find m, we need the altitude angle of the sun. Using:



with a solstice declination of 23.45°,
Tracking system for photovoltaics




You can use the above relation to find A = 1088 W/m2, k = 0.205, and C = 0.134.
The direct beam insolation on the collector is therefore
Tracking system for photovoltaics
The diffuse radiation on the collector is




2) One-Axis Polar Tracker: The beam portion of insolation is given by



The diffuse portion




The total is

               The two-axis tracker provides 994 W/m2, which is only 9% higher
                                  than the single-axis mount.
Physics of semiconductor devices
Sources:
Internet Materials: Arizona State University

Solar cells: operating principles, technology, and system applications by Martin Green (You have a sample of this book)

Practical photovoltaics: electricity from solar cells by Richard J. Komp.
Solar cells: What they are and how they work ; How solar cells are made ; Solar cells and modules ; Using photovoltaics ; Batteries and
other storage systems ; New developments in photovoltaic technology ; The future of photovoltaics ; Assembling your own modules.

The Physics of Solar Cells by Jenny Nelson.
Provides
P id a comprehensive introduction to the physics of the photovoltaic cell. It is suitable for undergraduates, graduate students, and
                   h i i t d ti t th h i                  f th h t lt i      ll i     it bl f     d      d t        d t t d t          d
researchers new to the field. It covers: basic physics of semiconductors in photovoltaic devices; physical models of solar cell operation;
characteristics and design of common types of solar cell; and approaches to increasing solar cell efficiency. The text explains the terms
and concepts of solar cell device physics and shows the reader how to formulate and solve relevant physical problems. Exercises and
worked solutions are included.

Physics of Semiconductor Devices
Classic book has set the standard for advanced study and reference in the semiconductor device field.
Designed for graduate textbook adoptions and reference needs, this new edition includes: New devices such as three-dimensional
MOSFETs, MODFETs, resonant-tunneling diodes, semiconductor sensors, quantum-cascade lasers, single-electron transistors, real-
space transfer devices, Problem sets at the end of each chapter

Photovoltaic Design & Installation For Dummies by Ryan Mayfield.
Gives you a comprehensive overview of the history, physics, design, installation, and operation of home-scale solar-panel systems. You'll
also get an introduction to the foundational mathematic and electrical concepts you need to understand and work with photovoltaic
syste s Covers all
systems. Co e s a aspects o home-scale solar-power systems , Viable resource for p o ess o a s, stude ts, a d tec ca laymen
                              of o e sca e so a po e syste s ab e esou ce o professionals, students, and technical ay e
Can be used to study for the NABCEP exam (the North American Board of Certified Energy Practitioners, NABCEP)
http://www.nabcep.org/about-us

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Workshop problems solving

  • 1. Photovoltaic Solar Energy Conversion (PVSEC) ‫إﻧﺘﺎج اﻟﻜﻬﺮﺑﺎء ﻣﻦ اﻟﻄﺎﻗﺔ اﻟﺸﻤﺴﻴﺔ‬ Courses on photovoltaic for Moroccan academic staff; 23-27 April, ENIM / Rabat 23 27 Workshop d W k h and problem solving activities bl l i ti iti Ahmed Ennaoui Helmholtz-Zentrum Berlin für Materialien und Energie ennaoui@helmholtz-berlin.de This material is intended for use in lectures, presentations and as handouts to students, it can be provided in Powerpoint format to allow customization for the individual needs of course instructors. Permission of the author and publisher is required for any other usage. Sources: Stanford University/JOHN WILEY & SONS, INC., PUBLICATION Sources: Arizona State University
  • 2. Aims of Classroom Workshop To clarify and illustrate the concepts of the theoretical courses To sharpen the communicative skills of the students, this includes communication in other languages than the native tongue . To develop a global quality reflex and to accomplish a reality sense: through critical observation, in learning the applicability and limits of the theoretical concepts and experimental techniques To gain experience in working in groups and communicate towards group members. To develop the analytical mind and the sense for synthesis To be able to report orally and by writing
  • 3. Basic Laws of Radiation/ Black Body Radiation - The following issues should be discussed: - A photon is determined by the magnitude and the direction of its momentum - direction of the associated electric field: p = ħ k - Distinguish between: wave vector k with the Boltzmann constant kB. - 2 states for photons corresponding to the two possibilities of polarization of the electric field perpendicular to the direction of propagation. - N b of possible states of th photons i a volume V i given by: Number f ibl t t f the h t in l is i b 1 V 3 β= 1 ns = 2 3 dk k BT eβ S − 1 βε (2π) ) Average number of photons per unit volume having their wave vector between k and k + dk = the n mber of states x probabilit of each state number probability
  • 4. Basic Laws of Radiation/ Black Body Radiation 2hc2 1 E(λ, T) = 5 λ ⎡ ⎛ hc ⎞ ⎤ ⎢exp⎜ ⎜ λk T ⎟ − 1⎥ ⎟ ⎣ ⎝ B ⎠ ⎦ c = 3 0 × 108 ms-1 ; h = 6 63 × 10-34 J ; k =1.38 × 10-23 JK-1 3.0 1 6.63 34 J.s 1 38 23 1
  • 5. Basic Laws of Radiation/ Black Body Radiation Total area under the curve is the total radiant power emitted. This area in (W/m2) is the power emitted between λ1 and λ2
  • 6. Basic Laws of Radiation/ Black Body Radiation Total area under the curve is the total radiant power emitted.
  • 7. Basic Laws of Radiation/ Black Body Radiation [Watt] = [m] x [W/m2 . K4] x [Kelvin]
  • 8. Basic Laws of Radiation/ Black Body Radiation Consider the earth to be a blackbody with average surface temperature 15°C and area equal to 5.1 x 1014 m2. Find the rate at which energy is radiated by the earth and the wavelength at which maximum power is radiated. Compare this peak wavelength with that for a 5800 K blackbody (the sun). The earth radiates: σ A T 4 E (W ) = (5 64 x 10 -8 W −2 K −4 ) (5 1 x 1014 m 2 ) [(15 + 273)K]4 = 2 0 x 1017 W (Watt) (5.64 8 Wm (5.1 2.0 Watt The wavelength at which the maximum power is emitted 2898 2898 2898 λmax (earth) = = = 10.1μm λ (sun) = = 0.5μ. T(K) 288 5800
  • 9. Basic Laws of Radiation/ Black Body Radiation Copyrighted Material, from internet Sun (visible) λMAX = 0.5 μm FT = 64 million W m-2 Earth (infrared) λMAX = 10 μm FT = 390 W m-2 2
  • 10. Basic Laws of Radiation/ Black Body Radiation Copyrighted Material, from internet Replicate this experience in your lab.
  • 11. Black Body Radiation is the amount of incoming solar radiation per unit area that would be incident on a plane perpendicular to the rays, at a the mean distance from the Sun to the Earth. Solar constant 2 ⎛R⎞ 4 E=σ T ⎜ ⎟ ⎝D⎠ σ = 5,67 . 10-8 W/(m2.K4), T = 5800 K R = 6 96 108 m D = 1,49.1011 m 6,96.10 m, 1 49 10 For more detail E = 1402 W/m2 See PVSEC1:Solar flux intercepted by the Earth 2 2 4 ⎛ 6,96.10 m ⎞ 8 ⎛R⎞ E = σ T ⎜ ⎟ = 5,67 . 10 W/(m .K ) x (5800 K) x ⎜ 4 -8 2 4 ⎜ 1,49.10 11 m ⎟ ⎟ ⎝D⎠ ⎝ ⎠ The atmosphere will transmit a fraction (75%) of solar radiation τ E = 0,75 E = 1052 W/m2
  • 12. Altitude angle at solar noon L Example 1: Tilt Angle of a PV Module. Find the P δ optimum tilt angle for a south-facing βNoon = 90 + L- δ photovoltaic module in Rabat (latitude 34° at L Equation E i Local solar noon on M h 1 l March 1st. horizontal March 1st. is the 60th. day of the year so the solar declination is: ⎡ 360 ⎤ ⎡ 360 ⎤ δ = 23.45 sin ⎢ (n − 81) ⎥ = 23.45 sin ⎢ ( ) (60 − 81) ⎥ = −8.3° ( ) ⎣ 365 ⎦ ⎣ 365 ⎦ The tilt angle that would make the sun’s rays perpendicular to the module at noon would therefore be Altitude Altit d angle l βnoon = 90° − L + δ = 90− 34− 8.3 = 47.7 βnoon=47.7 Tilt = 90 − β noon = 90 − 47.7 = 42.3° Tilt = 42.3° S
  • 13. Altitude angle and azimuth angle Find altitude angle β and azimuth angle S at 3 PM solar time in Boulder, CO (L = 40˚) Boulder 40 ) on the summer solstice:.At the solstice, we know the solar declination δ = 23.45° ⎛ 15 ° ⎞ ⎛ 15 ° ⎞ HA = ⎜ ⎟ x (hours before solarnoon) = ⎜ ( ou s be o e so a oo ) ⎟ x (-3h) = -45 ° (3 ) 5 ⎝ h ⎠ ⎝ h ⎠ sin β = sin(40)sin (23.45) + cos(40)cos (23.45)cos (-45) = 0.7527 β = sin -1 (0.7527) = 48.8 ° cos(23.45) sin(-45) sin(Az) = = −0 9848 0.9848 φ S = sin -1 ( 0 9848) = −80 ° i 1 (-0.9848) cos(48.8) A.M. P.M. β = 48.8 ° φ S = −80 °
  • 14. Solar angles Sunrise and sunset can be found from a simple use of: sin(h) = sin(L)sin( δ) + cos(L)cos( δ)cos(ω) = 0 Find the time at which sunrise (geometric and conventional) will occur in Boston (latitude 42.3°) on July 1 (n = 182). Also find conventional sunset.
  • 15. Example 1: Solar Time vs. Clock Time Find Eastern Daylight Time for solar noon in Boston (longitude 71.1 W) 71.1° on July 1st. Answer: July 1st. is day number n = 182. to adjust for local time, we obtain: 360 360 B= (n − 81) = (182 − 81) = 99.89° 364 364 E = 9.87sin2B − 7.53cosB - 1.5sinB = 9.87sin2[2 (99.89)] − 7.53cos(99.89) - 1.5sin(99.89) = -3.5 ( ) ( ) ( ) For Boston at longitude 71.7° W in the Eastern Time Zone with local time meridian 75° 4min Solar Time (ST) = Clock Time (CT) + (Local Time Meridian - Local Longitude)° + E(min) degree To adjust for Daylight Savings Time add 1 h, so solar noon will be at about 12:48 P.M. CT = 12 − 4(75 - 71.1)° − ( −3.5) = 12 : 00 − 12.1min = 11 : 47.9A.M. East Origine For Eastern zone Time Belts of the U.S : Eastern Standard Time - E.S.T. is calculated to the 75th meridian west longitude. Central Standard Time - C.S.T. is calculated to the 90th meridian west. Mountain Standard Time - M.S.T. is calculated to the 105th meridian west. Pacific Standard Time - P.S.T. is calculated to the 120th meridian west. Alaska was standardized in 1918 on 150th Meridian west, but in actual practice, other zones are and have been in use: 120° 150°, 165°
  • 16. Example 2: Solar Time vs. Clock Time For the “Green community village” near Dubai (latitude angle = 25° N, local longitude angle = 55°12’ E, standard time zone = UTC +4, no daylight saving ti ) on February 3 at 14.00. Determine: t d d ti 4 d li ht i time) F b t 14 00 D t i a. the apparent solar time. b. solar declination and hour angle , solar altitude and solar azimuth angles. UTC = Universal Time and GMT = Greenwich Mean Time. Atlantic Standard Time (AST) is 4 hours behind of Coordinated Universal Time(UTC) http://www.timeanddate.com/worldclock/search.html http://www.timeanddate.com/worldclock/results.html?query=Morocco a) The apparent solar time 360 360 February 3th ⇒ n = 34 B = y (n − 81) = ( ) (34 − 81) = - 46,48° ( ) , 364 364 ET = 9.87 sin2B − 7.53B - 1.5 sinB = 9.87 sin2(-46.48) − 7.53(-46.48) - 1.5 sin(-46.48) = -13.95 min Local longitude angle = 55°12’ E = -55.2° (conversion in °, and negative since location is in East Standard time zone UTC+4 Local Time meridian (LTM)= -60° (negative since location is in East) ( ) ( g ) No daylight saving time February LST = 14:00 4min AST = LST + E(min) + (LT M - Local Longitudinal angle ) = 14 : 00 + (−13.95°) + [− 60° − (−55.2°)]. 4min = 13 : 27 degree degree Hour angle ω and solar d li ti δ b) H l d l declination δ. 360 °(284 + n) 360 °(284 + 34) AST = 13:27 = 13.45 h (conversion of time in hours) δ = 23.45 ° sin = 23.45 °sin = − 16.97 365 365 ω =15° (hours from local solar noon) = 15° (ST-12) ω = 15°.( 13.45-12) = 21.75° sin(h) = sin(L)sin(δ) + cos(L)cos(δ) ( ) ⇒ h = sin-1 [sin(25°) i (−16 97) + cos(25°) i (h) i (L) i ( (L) (δ)cos(ω) i i (25 ).sin( 16.97) (21 75).cos(−16 97)] = 42 98° (25 ).cos(21.75) ( 16.97) 42.98 cosδ . sinω ⎡ cos(−16.97).sin(21.75) ⎤ sin(Az) = ⇒ Az = sin −1 ⎢ ⎥ = 28.98° cos(h) ⎣ cos(42.98) ⎦
  • 17. Attenuation and air mass Direct B Di t Beam Radiation at th Surface of the Earth – R di ti t the S f f th E th Find the direct beam solar radiation normal to the sun’s rays at solar noon on a clear day in Atlanta (latitude 33.7°C) on May 21. y ( ) y May 21 is day number 141 ⎡ 360 ⎤ A = 1160 + 75sin . ⎢ (n − 275) ⎥ (W/m 2 ) = 1104 W/m 2 ⎣ 365 ⎦ ⎡ 360 ⎤ k = 0.175 + 0.035sin ⎢ (n − 100)⎥ = 0.197 ( ) ⎣ 365 ⎦ Optical Depth k and the apparent Extraterrestrial Flux A. The Sky Diffuse Factor C can be used later for diffuse radiation Measurements for the 21st Day of Each Month after ; Source: ASHRAE (1993).
  • 18. Insolation on a Collector Use the the following equation to evaluate δ ⎡ 360 ⎤ δ = 23.45 sin ⎢ (n − 81)⎥ ⎣ 365 ⎦ The altitude angle of the sun at solar noon is The air mass ratio: The value of clear sky beam radiation at the earth’s surface:
  • 19. Insolation on a Collector Direct-Beam Radiation, IBC The translation of direct-beam radiation IB (normal to the rays) into beam insolation striking a collector face IBC is a simple function of the angle of incidence θ = incidence angle between a normal to the collector face and the incoming beam. Panel Tilt n Special S i l case of beam insolation on a horizontal surface fb i l ti h i t l f IBH
  • 20. Insolation on a Collector At any particular time θ will be a function of the collector orientation time, orientation, the altitude and azimuth angles of the sun at any particular time The incidence angle is given by β: altitude φS solar azimuth φC P Panel azimuth l i h Panel Tilt
  • 21. Insolation on a Collector Beam Insolation on a Collector at solar noon in Atlanta (latitude 33.7°) on May 21 the altitude angle of the sun was found to be 76.4° and the clear-sky beam insolation was found to be 902 W/m2. Find the beam insolation at that time on a collector that faces 20° toward the southeast if it is tipped up at a 52° angle. th t i ti d t l The cosine of the incidence angle The beam radiation on the collector β: altitude φS solar azimuth φC Panel azimuth 76.4° Solar noon ΦS = 0 collector that Panel Tilt faces 20◦ toward 52° the southeast East
  • 22. Insolation on a Collector Diffuse Radiation on a Collector - find the diffuse radiation on the same panel. Solar noon in Atlanta on May 21 (n = 141), a Collector faces 20° toward the southeast Tipped up at a 52° angle. Insolation I l ti was f found to be 902 W/ 2. dt b W/m Diffuse insolation on a horizontal surface IDH is proportional to the direct beam radiation IB no matter where in the sky the sun happens to be: IDH = C x IB where C is a sky diffuse factor. The diffuse energy striking the collector 52° Added to the total beam insolation of 697 W/m2, this gives a total beam of 785 W/m2.
  • 23. Insolation on a Collector Reflected Radiation Onto a Collector. Reflectance of the surfaces in front of the panel is 0.2 (20%) Solar noon in Atlanta on May 21, Altitude angle of the sun β =76.4°, Collector faces 20° toward the southeast Tipped up at a 52° angle Diffuse sky factor C is 0.121 Clear-sky beam i Cl k b insolation i 902 W/ 2. l i is W/m 52° The clear-sky reflected insolation on the collector is y The total insolation on the collector
  • 24. Insolation on a Collector You can use this equation, combining the equations for the three q , g q components of radiation: Diffuse radiation Direct-beam collector, C Reflected radiation Tilt angle
  • 25. Insolation on a Collector using obstruction diagram Figure below The sun path diagram with superimposed obstructions makes it easy to estimate periods of shading at a site.
  • 26. Insolation on a Collector using obstruction diagram
  • 27. Insolation on a Collector using obstruction diagram
  • 28. Physics of semiconductor devices Continuity equations: y q • Derived from Maxwell’s equations: ∂ ∇ ⋅ (∇ × H ) = ∇ ⋅ J cond + ∇⋅D = 0 ∂t ∇⋅ (J n + J p ) + ∂ρ = 0, ∂t ρ = q( p − n + N D − N A ) ⎧ ∂n = 1 ∇ ⋅ J + G − R ⎪ ∂t q n n n ⇒ ⎨ ∂p 1 ⎪ = − ∇ ⋅ J p + Gp − Rp ⎩ ∂t q • Low-level injection (SRH lifetime dominated by the minority carrier lifetime): n p − n p0 p − pn 0 Rn = , Rp = n τn τp
  • 29. Physics of semiconductor devices Poisson’s equation: q • Derived from the Maxwell’s equations (electrostatics case): ∇ × E = 0 → E = −∇ϕ ρ ∇ ⋅ D = ∇ ⋅ (εE) = − ε∇ ϕ → ∇ ϕ = − 2 2 ε Quasi-Fermi levels: • In non-equilibrium conditions, one needs to define separate Fermi levels for n and p: ⎛ E Fn − Ei ⎞ n = ni exp⎜ ⎜ k T ⎟ ⎟ ⎝ B ⎠ a J n = nμ n ∇E Fn ⎛ Ei − E Fp ⎞ J p = pμ p ∇E Fp p = ni exp⎜ ⎜ k T ⎟ ⎟ ⎝ B ⎠ Source: Arizona State University
  • 30. Physics of semiconductor devices Sample problems: • Decay of the photo-excited carriers • Steady-state injection from one side • Surface-recombination (1) Decay of photo-excited carriers: Consider a sample illuminated with light source until t≤0. The generation rate equals to G At t=0 the light source is turned off G. off. Calculate pn(t) for t>0 . hf n type n-type sample x=0 x Source: Arizona State University
  • 31. Physics of semiconductor devices Solution • Boundary conditions: ∂p E = 0, n =0 • Minority hole continuity equation: ∂x ∂pn 1 pn − pn 0 pn − pn 0 = − ∇ ⋅ J p + Gp − =G− Have this set up in your lab,.All what you need a diode, ∂t q τp τp oscilloscope, ) • General form of the solution: −t / τ p pn (t ) = Ae +B • Boundary conditions: pn ( t ) pn 0 + τ p G p n ( t ≤ 0 ) = p n 0 + Gτ p pn ( ∞ ) = p n 0 Light turned off −t / τ p pn 0 pn (t ) = pn0 + τ pGe Source: Arizona State University t
  • 32. Physics of semiconductor devices ( ) (2) Steady-state injection from one side: y j Consider a sample under constant illumination by a light sour-ce. Calculate pn(x). hf n-type sample x=0 x Solution • Minority carrier continuity equation: ∂pn 1 1 ∂J p pn − pn 0 = − ∇ ⋅ J p + Gp − Rp ⇒ − − ∂t q q ∂x τp 2 ∂pn d pn pn − pn 0 = Dp − ∂t dx 2 τp Source: Arizona State University
  • 33. Physics of semiconductor devices ∂pn p • Steady state situation: Steady-state =0 ∂t d 2 pn pn − pn 0 d 2 Δpn Δpn Dp 2 − =0→ 2 − 2 = 0, Lp = τ p Dp dx τp dx Lp − x / Lp x / Lp Δpn ( x ) = Ae + Be • Boundary conditions for a long sample: Diffusion length Δpn ( ∞) = 0 → B = 0 Δpn (0) = pn (0) − pn 0 = A pn (x ) • Final solution: p n ( 0) − x / Lp pn ( x ) = pn 0 + [ pn (0) − pn 0 ]e qD p − x / Lp J p ( x) = [ pn (0) − pn0 ]e pn 0 Lp x Source: Arizona State University Lp
  • 34. Physics of semiconductor devices (3) Surface recombination: Consider a sample under constant illumination by a light sour-ce. There is a finite surface recombination at x=0. Calculate pn(x). Gp Surface recombination: S f bi ti n-type n type sample dpn Dp = S r [ p n ( 0) − p n 0 ] x dx x =0 x 0 x=0 x L x=L Solution • Minority carrier continuity equation at steady state: steady-state: d 2 pn pn − p n 0 d 2 Δpn Δpn Gp Dp − + Gp = 0 ⇒ − 2 =− dx 2 τp dx 2 Lp Dp Source: Arizona State University Surface Recombination Velocity from Photocurrent Measurements in Journal of The Electrochemical Society, 146 (12) 4640- 4646 (1999)
  • 35. Physics of semiconductor devices • General form of the solution: − x / Lp x / Lp Δpn ( x ) = Ae + Be +C B=0 (asymptotic condition) • Boundary conditions for a long sample: Δp n ( ∞ ) = C = τ p G p Δp n ( 0 ) = A + C = A + τ p G p • Use boundary condition at the surface to determine Δpn(0): dpn τ p D pG p Dp = S r [ pn (0) − pn0 ] → Δpn (0) = dx x = 0 D p + Sr L p • Final solution: ⎡ Sr τ p −x / Lp ⎤ Δpn ( x) = τ pG p ⎢1 − e ⎥ ⎣ L p + Sr τ p ⎦ Source: Arizona State University
  • 36. Physics of semiconductor devices • Graphical representation of the solution: Δpn ( ) (x Sr = 0 τ pG p Sr increasing Sr → ∞ x Source: Arizona State University
  • 37. Solar cell and Modules 1:
  • 38. Solar cell and Modules
  • 39. Solar cell and Modules 2
  • 40. Solar cell and Modules
  • 41. Solar cell and Modules 3
  • 42. Solar cell and Modules The voltage produced by the 36-cells module
  • 43. Solar cell and Modules
  • 44. Solar cell and Modules 4 The NOCT is cell temperature in a module when ambient is 20°C, solar irradiation is 0.8 kW/m2, and windspeed is 1 m/s. The following expression may be used: g p y
  • 45. Solar cell and Modules PV Module Performance Data Under Standard Test Conditions (1 kW/m2, AM 1.5, 25°C Cell Temperature)
  • 46. Solar cell and Modules See table
  • 47. Effect of Shading To help understand shading phenomenon consider Figure (a) in which an n-cell module phenomenon, with current I and output voltage V shows one cell separated from the others (shown as the top cell, though it can be any cell in the string). The equivalent circuit of the top cell has been drawn, while the other (n − 1) cells in the string are shown as just a module with current I and output voltage Vn-1. all cells are in the sun and since they are in series, series the same current , I flows through each of them.
  • 48. Effect of Shading Now , the top cell in figure (b) is shaded and its current source ISC has been reduced to zero. The voltage drop across RP as current flows through it causes the diode to be reverse biased, so the diode current is also (essentially) zero. That means the entire current flowing through the module must travel through both RP and RS in the shaded cell on its way to the load. That means the top cell, instead of adding to the output voltage, actually reduces it. We consider the bottom n − 1 cells still have full sun and still some how carry their original current I so they will still produce their original voltage Vn−1. This means that the output voltage of the entire module p g VSH with one cell shaded will drop to:
  • 49. Effect of Shading With all n cells in the sun and carrying I , the output voltage was V so the voltage of the bottom n − 1 cells will be The drop in voltage ΔV at any given current I , caused by the shaded cell, is given by Since the parallel resistance RP is so much greater than the series resistance RS
  • 50. Effect of Shading At any given current, the I –V curve for the module with one shaded cell drops current V by V. The huge impact this can have is illustrated in the figure below:
  • 51. Effect of Shading Example 5 : The 36-cell PV module described in Example 3 had a parallel resistance per cell of of RP = 6.6 Ω. In full sun and at current I = 2.14 A the output voltage was found there to be V = 19.41 V. If one cell is shaded and this current some how stays the same, then: a. What would be the new module output voltage and power? b. What would be the voltage drop across the shaded cell? c. How much power would be dissipated in the shaded cell? (a) The drop in module voltage will be The new output voltage will be 19.41 − 14.66 = 4.75 V. Power delivered by the module with one cell shaded would be For F comparison, i f ll sun the module was producing 41 5 W i in full th d l d i 41.5 W. (b) All of that 2.14 A of current goes through the parallel plus series resistance (0.005Ω ) of the shaded cell, so the drop across the shaded cell will be (normally a cell in the sun will add about 0.5 V to the module; this shaded cell subtracts over 14 V from the module).
  • 52. Effect of Shading The power dissipated in the shaded cell is voltage drop times current, which is p p g p , All of that power dissipated in the shaded cell is converted to heat, which can cause a local hot spot that may permanently damage the plastic laminates enclosing the cell. Final remarks: The proced res demonstrated in this e ample can be e tended to de elop I –V c r es under procedures example extended develop V curves nder various conditions of shading. The following figures shows such curves for the example module under full-sun conditions and with one cell 50% shaded, one cell completely shaded, and two cells completely shaded. Also shown on the graph is a dashed vertical line at 13 V, p y g p which is a typical operating voltage for a module charging a 12-V battery. The reduction in charging current for even modest amounts of shading is severe. With just one cell shaded out of 36 in the module, the power delivered to the battery is decreased by about two-thirds!
  • 53. Effect of Shading Effects of shading on the I –V curves for a PV module. The dashed line shows a typical voltage that the module would operate at when charging a 12-V battery; the impact on charging current is obviously severe.
  • 54. Exercice: Spectral efficiency of photovoltaic (PV) cells This exercise will enable you to determine the theoretical maximum spectral efficiency of a photovoltaic cell, and to determine the effect of concentration on cell efficiency.
  • 55. Exercice: Spectral efficiency of photovoltaic (PV) cells
  • 56. Table 2: Fractional function F0−λΤ
  • 57. Solution: Spectral efficiency of photovoltaic (PV) cells
  • 58. Solution: Spectral efficiency of photovoltaic (PV) cells
  • 59. Solution: Spectral efficiency of photovoltaic (PV) cells
  • 60. Solution: Spectral efficiency of photovoltaic (PV) cells
  • 61.
  • 62. PROBLEMS 1) For the following materials determine the maximum wavelength of solar materials, energy capable of creating hole-electron pairs: a. Gallium arsenide, GaAs, band gap 1.42 eV. b. Copper indium diselenide, CuInSe2, band gap 1.01 eV pp g p c. Cadmium sulfide, CdS, band gap 2.42 eV. 2) A p-n junction diode at 25°C carries a current of 100 mA when the diode voltage is 0 5 V What is the reverse saturation current, I0? 0.5 V. current 3) For the simple equivalent circuit for a 0.005 m2 photovoltaic cell shown below, the reverse saturation current is I0 = 10−9 A and at an insolation of 1-sun the short-circuit current is ISC = 1 A,. At 25°C, find the following:
  • 63. PROBLEMS a. a The open-circuit voltage open circuit voltage. b. The load current when the output voltage is V = 0.5 V. c. The power delivered to the load when the output voltage is 0.5 V. d. The efficiency of the cell at V = 0.5 V. 4) The equivalent circuit for a PV cell includes a parallel resistance of RP = 10 . The cell has area 0.005 m2, reverse saturation current of I0 = 10−9 A and at an insolation of 1-sun the short-circuit current is ISC = 1 A, At 25 C, 1 sun short circuit 25◦C, with an output voltage of 0.5 V, find the following:
  • 64. PROBLEMS a. a The load current current. b. The power delivered to the load. c. The efficiency of the cell. 5) The following figure shows two I-V curves. One is for a PV cell with an equivalent circuit having an infinite parallel resistance (and no series resistance). What is the parallel resistance in the equivalent circuit of the other cell?
  • 65. PROBLEMS 6) The following figure shows two I-V curves. One is for a PV cell with an IV equivalent circuit having no series resistance (and infinite parallel resistance). What is the series resistance in the equivalent circuit of the other cell?
  • 66. PROBLEMS 7) Estimate the cell temperature and power delivered by a 100-W PV module with the following conditions. Assume 0.5%/°C power loss. a. NOCT = 50°C, ambient temperature of 25°C, insolation of 1-sun. b. NOCT = 45°C, ambient temperature of 0°C, insolation of 500 W/m2. c. NOCT = 45°C, ambient temperature of 30°C, insolation of 800 W/m2. 8) A module with 40 cells has an idealized, rectangular I-V curve with ISC = 4 A and VOC = 20 V. If a single cell has a parallel resistance of 5 and negligible series resistance, draw the I-V curve if one cell is completely shaded. What current would it deliver to a 12-V battery (vertical I-V load at 12 V)?
  • 67. PROBLEMS 9) Suppose a PV module has the 1 sun I V curve shown below Within the module 1-sun I-V below. itself, the manufacturer has provided a pair of bypass diodes to help the panel deliver some power even when many of the cells are shaded. Each diode bypasses half of the cells, as shown. You may consider the diodes to be “ideal;” that is, they have no voltage drop across them when conducting. Suppose there is enough shading on the bottom cells to cause the lower diode to start conducting. Draw the new “shaded” I-V curve for the module.
  • 68. Tracking system for photovoltaics Tracker systems are either: 2 axis trackers which track the sun both in azimuth and 2-axis trackers, altitude angles so the collectors are always pointing directly at the sun, or 1-axis trackers, which track only one angle or the other. Two-axis tracking angular relationships
  • 69. Tracking system for photovoltaics A single-axis tracking for photovoltaic consists of a mount having a manually g g p g y adjustable tilt angle along a north-south axis, and a tracking mechanism that rotates the collector array from east-to-west
  • 70. Tracking system for photovoltaics When the tilt angle of the mount is set equal to the local latitude (called a polar mount), not only is that an optimum angle for annual collection, but the collector geometry and resulting insolation are fairly easy to evaluate as well. If a polar mount rotates about its axis at the same rate as the earth turns, 15°/h, then the centerline of the collector will always face directly into the sun.
  • 71. Tracking system for photovoltaics Under these conditions the incidence angle θ between a normal to the collector and the conditions, sun’s rays will be equal to the solar declination δ. That makes the direct-beam insolation on the collector just egal to IB cos δ. To evaluate diffuse and reflected radiation, we need to know the tilt angle of the collector. g The axis of rotation has a fixed tilt Σ = L, unless it is solar noon, the collector itself is cocked at an odd angle with respect to the horizontal plane. The effective tilt, which is the angle between a normal to the collector and the horizontal plane, is given by The beam, diff Th b diffuse, and reflected radiation on a polar mount, one-axis tracker are given d fl t d di ti l t i t k i by One-Axis, Polar Mount:
  • 72. Tracking system for photovoltaics Example: Compare the 40° latitude clear-sky insolation on a collector at solar noon 40 latitude, on the summer solstice for a two-axis tracking mount versus a single-axis polar mount. Ignore ground reflectance. 1) Solution: For two-Axis Tracker, the beam insolation from IB = Aexp (−km), we need ) , p( ), the air mass ratio m, the apparent extraterrestrial flux A, and the optical depth k. To find m, we need the altitude angle of the sun. Using: with a solstice declination of 23.45°,
  • 73. Tracking system for photovoltaics You can use the above relation to find A = 1088 W/m2, k = 0.205, and C = 0.134. The direct beam insolation on the collector is therefore
  • 74. Tracking system for photovoltaics The diffuse radiation on the collector is 2) One-Axis Polar Tracker: The beam portion of insolation is given by The diffuse portion The total is The two-axis tracker provides 994 W/m2, which is only 9% higher than the single-axis mount.
  • 75. Physics of semiconductor devices Sources: Internet Materials: Arizona State University Solar cells: operating principles, technology, and system applications by Martin Green (You have a sample of this book) Practical photovoltaics: electricity from solar cells by Richard J. Komp. Solar cells: What they are and how they work ; How solar cells are made ; Solar cells and modules ; Using photovoltaics ; Batteries and other storage systems ; New developments in photovoltaic technology ; The future of photovoltaics ; Assembling your own modules. The Physics of Solar Cells by Jenny Nelson. Provides P id a comprehensive introduction to the physics of the photovoltaic cell. It is suitable for undergraduates, graduate students, and h i i t d ti t th h i f th h t lt i ll i it bl f d d t d t t d t d researchers new to the field. It covers: basic physics of semiconductors in photovoltaic devices; physical models of solar cell operation; characteristics and design of common types of solar cell; and approaches to increasing solar cell efficiency. The text explains the terms and concepts of solar cell device physics and shows the reader how to formulate and solve relevant physical problems. Exercises and worked solutions are included. Physics of Semiconductor Devices Classic book has set the standard for advanced study and reference in the semiconductor device field. Designed for graduate textbook adoptions and reference needs, this new edition includes: New devices such as three-dimensional MOSFETs, MODFETs, resonant-tunneling diodes, semiconductor sensors, quantum-cascade lasers, single-electron transistors, real- space transfer devices, Problem sets at the end of each chapter Photovoltaic Design & Installation For Dummies by Ryan Mayfield. Gives you a comprehensive overview of the history, physics, design, installation, and operation of home-scale solar-panel systems. You'll also get an introduction to the foundational mathematic and electrical concepts you need to understand and work with photovoltaic syste s Covers all systems. Co e s a aspects o home-scale solar-power systems , Viable resource for p o ess o a s, stude ts, a d tec ca laymen of o e sca e so a po e syste s ab e esou ce o professionals, students, and technical ay e Can be used to study for the NABCEP exam (the North American Board of Certified Energy Practitioners, NABCEP) http://www.nabcep.org/about-us