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Chapter 5 Thermochemistry John D. Bookstaver St. Charles Community College Cottleville, MO Chemistry, The Central Science , 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Energy ,[object Object],[object Object],[object Object]
Potential Energy ,[object Object]
Kinetic Energy ,[object Object],1 2 KE  =     mv 2
Units of Energy ,[object Object],[object Object],[object Object],1 J = 1   kg m 2 s 2
Definitions: System and Surroundings ,[object Object],[object Object]
Definitions: Work ,[object Object],[object Object],[object Object]
Heat ,[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object]
First Law of Thermodynamics ,[object Object],[object Object]
Internal Energy ,[object Object]
Internal Energy ,[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object]
 E ,  q ,  w , and Their Signs
Exchange of Heat between System and Surroundings ,[object Object]
Exchange of Heat between System and Surroundings ,[object Object],[object Object]
State Functions ,[object Object]
State Functions ,[object Object],[object Object]
State Functions ,[object Object],[object Object],[object Object]
State Functions ,[object Object],[object Object],[object Object]
Work ,[object Object]
Work ,[object Object],[object Object]
Enthalpy ,[object Object],[object Object],H  =  E  +  PV
Enthalpy ,[object Object],[object Object],[object Object],[object Object]
Enthalpy ,[object Object],[object Object],[object Object],[object Object],[object Object]
Endothermicity and Exothermicity ,[object Object]
Endothermicity and Exothermicity ,[object Object],[object Object]
Enthalpy of Reaction ,[object Object],[object Object]
Enthalpy of Reaction ,[object Object]
The Truth about Enthalpy ,[object Object],[object Object],[object Object]
Calorimetry ,[object Object]
Heat Capacity and Specific Heat ,[object Object]
Heat Capacity and Specific Heat ,[object Object]
Heat Capacity and Specific Heat ,[object Object],Specific heat = heat transferred mass    temperature change s  = q m       T
Constant Pressure Calorimetry ,[object Object]
Constant Pressure Calorimetry ,[object Object],[object Object]
Bomb Calorimetry ,[object Object],[object Object]
Bomb Calorimetry ,[object Object],[object Object]
Hess’s Law ,[object Object],[object Object]
Hess’s Law ,[object Object]
Hess’s Law ,[object Object]
Enthalpies of Formation ,[object Object]
Standard Enthalpies of Formation ,[object Object]
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l ) C 3 H 8 ( g )  + 5 O 2 ( g )     3 CO 2 ( g )  + 4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Calculation of   H C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l )
Energy in Foods ,[object Object]
Energy in Fuels ,[object Object]

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Ch05 outline

  • 1. Chapter 5 Thermochemistry John D. Bookstaver St. Charles Community College Cottleville, MO Chemistry, The Central Science , 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
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  • 17.  E , q , w , and Their Signs
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