Paint spread onto a surface will dry into a hard film that can best be described as consisting of pigments and additives suspended in the binder. One of the most common types of paint examined in the crime laboratory involves finishes emanating from automobiles. Automobile manufacturers normally apply a variety of coatings to the body of an automobile. These coatings may include electrocoat primer, primer surfacer, basecoat, and clearcoat.
The wide diversity of automotive paint contributes to the forensic significance of an automobile paint comparison. Questioned and known specimens are best compared side by side under a stereoscopic microscope for color, surface texture, and color layer sequence. Pyrolysis gas chromatography and infrared spectrophotometry are invaluable techniques for distinguishing most paint binder formulations, adding further significance to a forensic paint comparison.
Solid materials, such as paint, may be heated or pryolyzed to high temperatures so that they will decompose into numerous gaseous products to flow through the GC column. Crime laboratories are often asked to identify the make and model of a car from a small amount of paint and will make use of color charts for automobile finishes or the PDQ database.
Paint chips are most likely found on or near persons or objects involved in hit-and-run incidents. Paper druggist folds and glass or plastic vials make excellent containers for paint. Paint smeared or embedded in garments or objects require the whole item to be packaged and sent to the laboratory. Uncontaminated standard/reference paint must always be collected. Tools used to gain entry into buildings or safes often contain traces of paint, requiring the tool be collected, along with reference paint samples
Glass is a hard, brittle, amorphous substance that is composed of silicon oxides mixed with various metal oxides. Amorphous solids have their atoms arranged randomly, unlike crystals. Tempered glass is stronger than normal glass due to rapid heating and cooling. Laminated glass found in car windshields has a layer of plastic between two pieces of ordinary window glass.
For the forensic scientist, the problem of glass comparison is one that depends on the need to find and measure those properties that will associate one glass fragment with another while minimizing or eliminating other sources. To compare glass fragments, a forensic scientist evaluates two important physical properties: density and refractive index.
The flotation method is a rather precise and rapid method for comparing glass densities. In the flotation method, a glass particle is immersed in a liquid. The density of the liquid is carefully adjusted by the addition of small amounts of an appropriate liquid until the glass chip remains suspended in the liquid medium. At this point, the glass will have the same density as the liquid medium and can be compared to other relevant pieces of glass which will remain suspended, sink, or float.
The immersion method is best used to determine a glass fragment’s refractive index. This method involves immersing a glass particle in a liquid medium whose refractive index is varied until it is equal to that of the glass particle. At this point, known as the match point, the Becke line disappears and minimum contrast between liquid and particle is observed. The Becke line is a bright halo near the border of a particle that is immersed in a liquid of a different refractive index.
The penetration of window glass by a projectile, whether it is a bullet or a stone, produces cracks which radiate outward (radial fractures) and encircle the hole (concentric fractures). By analyzing the radial and concentric fracture patterns in glass, the forensic scientist can determine the direction of impact.
A high-velocity projectile such as a bullet often leaves a hole that is wider at the exit side, and hence its examination is important in determining the direction of impact. The direction of impact can also be accomplished by applying the 3R Rule: R adial cracks form a R ight angle on the R everse side of the force. The sequence of impacts when there have been successive penetrations of glass, is frequently possible to determine because a fracture always terminates at an existing line of fracture.
If even the remotest possibility exists that glass fragments may be pieced together, every effort must be made to collect all the glass found. When an individual fit is thought improbable, the evidence collector must submit all glass evidence found in the possession of the suspect along with a representative sample of broken glass remaining at the crime scene. The glass fragments should be packaged in solid containers to avoid further breakage. If the suspect’s shoes and/or clothing are to be examined for the presence of glass fragments, they should be individually wrapped in paper and transmitted to the laboratory.
The value of soil as evidence rests with its prevalence at crime scenes and its transferability between the scene and the criminal. Most soils can be differentiated by their gross appearance. A side-by-side visual comparison of the color and texture of soil specimens is easy to perform and provides a sensitive property for distinguishing soils that originate from different locations.
Standard /reference soils are to be collected at various intervals within a 100-yard radius of the crime scene, as well as the site of the crime, for comparison to the questioned soil. Soil found on the suspect, such as adhering to a shoe or garments, must not be removed. Instead, each object should be individually wrapped in paper, and transmitted to the laboratory.
Fs Ch 13
Chapter 13 Trace Evidence II: Paint, Glass, and Soil
Methods for Paint Comparison <ul><li>Diversity: </li></ul><ul><li>-forensic significance </li></ul><ul><li>-questioned and known specimens </li></ul><ul><li>-stereoscopic microscope: </li></ul><ul><li>color/surface texture/color layer sequence </li></ul><ul><li>-pyrolysis gas chromatography/infrared spectrophotometry: </li></ul><ul><li>paint binder formulations </li></ul>
Methods for Paint Comparison <ul><li>Solid: </li></ul><ul><li>-heated (pryolyzed) </li></ul><ul><li>-decompose into gases </li></ul><ul><li>-GC column </li></ul><ul><li>-small amounts of paint </li></ul><ul><li>-ID make/model of car </li></ul><ul><li>-PDQ data base </li></ul>
Flotation Method <ul><li>Glass densities: </li></ul><ul><li>-immersed in liquid </li></ul><ul><li>-density adjusted by </li></ul><ul><li>-chip remains suspended </li></ul><ul><li>-same density as liquid </li></ul><ul><li>-compared to other glass </li></ul><ul><li>-suspended/sink/float </li></ul>
Immersion Method <ul><li>Refractive index: </li></ul><ul><li>-glass particle in a liquid </li></ul><ul><li>-refractive index is varied </li></ul><ul><li>-equal to particle </li></ul><ul><li>-match point </li></ul><ul><li>-Becke line: bright halo near the border of particle </li></ul><ul><li>-Becke Line disappears </li></ul>
<ul><li>Looking at end of broken pane of glass </li></ul>
<ul><li>End of broken piece of glass </li></ul>
Analyzing Cracks <ul><li>Directionality: </li></ul><ul><li>High-velocity: </li></ul><ul><li>-wider at the exit side </li></ul><ul><li>-3 R rule: R adial cracks form a R ight angle on the R everse side of the force </li></ul><ul><li>-terminates at existing line of fractures </li></ul>
Collection of Glass <ul><li>Find all the pieces </li></ul><ul><li>On suspect </li></ul><ul><li>Representative known sample </li></ul><ul><li>solid containers </li></ul><ul><li>individually wrapped in paper </li></ul>
<ul><li>Homeless camp in the desert with multiple victims </li></ul>
<ul><li>Does crime scene processing still seem as glamorous as CSI? </li></ul>
Comparison of Soil <ul><li>Forensic geologists: </li></ul><ul><li>- Compare mineral content </li></ul><ul><li>-vast variety of minerals/rocks </li></ul><ul><li>-artificial debris </li></ul><ul><li>-points of comparison </li></ul>
Collection of Soil <ul><li>Standard /reference: </li></ul><ul><li>-various intervals </li></ul><ul><li>-100-yard radius </li></ul><ul><li>-site of the crime </li></ul><ul><li>on suspect: </li></ul><ul><li>-shoe/garments </li></ul><ul><li>-must not be removed </li></ul><ul><li>-wrap individually in paper </li></ul><ul><li>-lab </li></ul>