Crude Oil And Its Products
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- Slide 1: Science Interactive LTD Copyright 2005
Science Interactive LTD
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GCSE SCIENCE
Unit 1: The Digestive System Unit 20: Crude Oil and its Products
Unit 2: The Circulatory System Unit 21: Rock Cycle
OCR
Unit 3: Healthy Body and Immunity Unit 22: Elements, Molecules and Compounds
EDEXCEL
AQA
Unit 4: The Respiratory System Unit 23: Ionic and Covalent Compounds
Unit 5: Nervous System and the Senses Unit 24: The Halogens, their Uses and Compounds
Unit 6: Human Homeostasis Unit 25: The Noble Gases, their Properties and Uses
Unit 7: Hormones and the Endocrine System Unit 26: Rates of Reaction
Unit 8: Drugs and Bad Body Maintenance Unit 27: Energy
Unit 9: Photosynthesis in Green Plants Unit 28: Generating Electricity and its Domestic Use
Unit 10: Water Transport in Plants Unit 29: Electricity
Unit 11: Flow of Energy and Elements through the Environment Unit 30: Light and the Electromagnetic Spectrum
Unit 12: Mitosis and Meiosis Unit 31: Radioactivity
Unit 13: Inheritance and Selection Unit 32: Newton's Forces and the Effects of Forces
Unit 14: Evolution and Human Impact Unit 33: Earth and Space
Unit 15: Genetic Engineering Unit 34: The Earth and Plate Tectonics
Unit 16: The Periodic Table and its Elements Unit 35: The Alkaline Earth Metals
Unit 17: The Alkali Metals Unit 36: Sound and Hearing
Unit 18: Metals and their Properties Unit 37: Natural Forces
Unit 19: The Transitional Metals Unit 38: Cells, Tissue, Organs and Organs systems
- Slide 2: Science Interactive LTD Copyright 2005
Lesson number 20
Crude Oil and its Products
- Slide 3: Unit 20: Crude Oil and its Products Science Interactive LTD Copyright 2005
Understand: Keywords:
How crude oil and other fossil fuels rich in
1. Crude Oil, Formation, Fossil, Fuel,
carbon were formed. Hydrocarbons, Hydrogen, Carbon, Fractional,
That crude oil is a mixture of hydrocarbons.
2.
Distillation, Alkanes, Alkenes, Cracking,
That hydrocarbons contain only two elements:
3.
Ethene, Polymers, Plastics, Polymerisation,
hydrogen and carbon.
Greenhouse, Global, Warming & Pollution.
That different hydrocarbons have different uses
4.
and can be separated using fractional
distillation.
That the alkane family of hydrocarbons are used
5.
mainly as fuels by transport vehicles.
The chemical properties of the alkanes and the
6.
alkenes.
The use of ethene and other alkenes in the
7.
formation of polymers and plastics.
The benefits and costs of using crude oil as
8.
fuels and as a starting material for the
manufacture of plastics.
That the increases emissions of carbon dioxide
9.
in the atmosphere is causing the greenhouse
effect.
10. The likely impact of the greenhouse effect.
11. That there are many renewable alternative to
Click mouse to begin
using crude oil as an energy source.
Science Interactive LTD PO BOX 50764 LONDON NW6 9AT web: www.science-interactive.co.uk email: sales@science-interactive.co.uk
- Slide 4: Science Interactive LTD Copyright 2005
Oil and natural gas reserves
Underneath the bedrock of some countries of the World like Saudi Arabia, Iraq and Russia are
billions of barrels of c_______ oil. When extracted using drilling rigs, it can be used as a fuel,
and a raw material to manufacture plastics, paints and medicines. The biggest users of crude oil
are the United States followed by Europeans. The country with the greatest reserves of crude oil
is Saudi Arabia, who until the discovery of oil had a simple economy and little modern
infrastructure. Look at the map and find other countries with large reserves ?
World reserves of crude oil: Word bank: crude
World oil reserves Energy use in the modern World
Diagram
World oil reserves are finite. It estimated that This composite picture of the world at night shows us
Notes
we currently have around 60 – 80 years of the biggest energy users. North America, followed by
crude oil remaining. Saudi Arabia, Iraq and Europe and Japan are the largest users or energy. These
Russia have the largest reserves with over 50 countries depend most on the ‘cheap energy’ that crude
billions barrels of crude oil underground. oil provides us.
- Slide 5: Science Interactive LTD Copyright 2005
Formation of crude oil
The formation of crude oil from the decayed remains of i________ and other organic material
has taken place over the last 65 million years. Crude oil forms when organic matter is buried
deep underground in an oxygen free environment. Over millions of years the carbon rich
compounds from the bodies of dead organism are subjected to h_____ and pressure which
changed them into hydrocarbons. Natural gas (mainly methane CH4), an important fossil fuel is
also found trapped with crude oil under rock sediments. Why do we call crude oil a fossil fuel ?
Formation of crude oil: Word bank: insects heat
Waters rich with life Dead matter falls Oils layers form
Surface water
Oxygen free layer
Sedimentary rock
The warm seas over areas When these animals died they Over many millions of years,
Notes
like Saudi Arabia of 65 sank to the sea bottom. Over heat and pressure over time
million years ago were time carbon rich sediments changes these compounds into
teeming with organisms rich containing many carbon rich carbon rich hydrocarbons now
in the element carbon. biological molecules formed. known as crude oil.
- Slide 6: Science Interactive LTD Copyright 2005
Fossils fuels and crude oil
A fossil fuel is a substance like o____ or coal that is rich in the element c_______, can be
combusted readily with oxygen and produces energy in the form of h____. They are fossil fuels
because they are formed from once living organisms with solar energy being the original
e_______ source. Fossil fuels are a non-renewable resource, because it takes millions of years
for them to form and we currently combust them faster than they are formed ! Fossil fuels are
also a finite energy resource, because they will eventually run out ! How will this change our way
of living ?
Types of fossil fuels: Word bank: oil carbon heat energy
Crude oil Coal Peat
Diagram
Remains of dead insects and Remains of dead plants More recent remains of dead
Source
other organic material plants
Life 60-70 years 300 years 10-15 years
expectancy
- Slide 7: Science Interactive LTD Copyright 2005
Extraction, transport and storage of crude oil
Crude oil, natural gas or coal can be extracted from under the sea or land, where they have
remained trapped for millions of years. Companies like Shell and BP have invested billions of
pounds exploiting oil r__________ under the North Sea, just off the coast of Scotland. The North
Sea has about 45 oil platforms producing up to four million barrels a day. England has sufficient
oil reserves meeting its current demand for the next forty years. Why is the price of oil likely to
increase over the next 10 years ?
Getting crude oil to the refinery: Word bank: reserves
Extraction Transport Storage
Diagram
Notes Oil is trapped under Oil is transported by ship or Oil is stored at refineries usually
sedimentary rock under the pipeline. This is the most by the coast. We use about 5
oceans and seas. Drilling is economic form of transport. million barrels a day. Oil will
from a floating platform. The Transportation by this method finally run out in around 60-80
North sea has about 45 oil does have its risks. Explain what years. Explain what consequences
platforms producing up to 4 these risks are and look for the this might have and what energy
million barrels a day. Exxon Oil Disaster. alternatives we can use ?
- Slide 8: Science Interactive LTD Copyright 2005
Processing of crude oil
Crude oil, once it has been extracted from underneath the bedrock, has to be processed to be
useful. Close to where it is stored, oil refineries process crude oil so that it can be more useful to
us. There is a great demand for fuels like petrol and d_________ and of course natural gas for
heating. There is less of a demand for the large hydrocarbons that make up the lubricating oils.
These refineries produce large amounts of p__________. Why is the demand for fuels and
natural gas very high in Europe and England ?
Processing crude oil: Word bank: diesel pollution
Oil refinery Distillation End Product
Diagram
Notes Oil refineries process millions Distillation by these huge Companies like Shell and BP
of barrels of crude oil every fractionating columns separates sell millions of litres of fuels
year to provide for the high out hydrocarbons based on their like petrol and diesel to over 40
demand for fuels like petrol boiling points. Natural gas has million drivers of cars, lorries
and diesel. the lowest boiling point. and vans in the UK.
- Slide 9: Science Interactive LTD Copyright 2005
Fractional distillation of crude oil
Crude oil is a mixture of different hydrocarbons. They can be separated by fractional distillation
according to their b_______ point which change according to their size (carbon atoms) The most
volatile fraction, i.e with the lowest boiling point evaporates off first and goes to the top of the
c________. The remaining, longer chain hydrocarbons also separate out according to their
boiling points. Word bank: boiling column lubricating
Carbon atoms Boiling points Use
Fractionating column
LPG gas C1 – C4 < 40oC Highly flammable gas fuel
Boiling points and viscosity.
Petrol C5 – C10 40oC – 200oC Car fuel
Naphtha C10 – C12 125oC – 175oC Valuable source of organic molecules
Paraffin 175oC – 275oC Less flammable than petrol, domestic
C12 – C16
heater fuel
Diesel 235oC – 300oC Larger vehicle fuels
C16 – C30
>300oC Not as flammable, used for central
C30 – C100
Fuel oil
heating oil and l_________ oils
Crude oil
C100 – C300 > 350oC
Bitumen Forms a thick, black, tough and
resistant adhesive layer on cooling.
Used to lay roads.
Heat (400oC)
- Slide 10: Science Interactive LTD Copyright 2005
Separating hydrocarbons
Fractional distillation of crude oil, a mixture of hydrocarbons is able to separate different
‘fractions’ based on their boiling points. The l_______ the chain, the higher the boiling
point. Methane, ethane and propane, all short chained hydrocarbons have very low boiling
points, whereas hydrocarbons containing a hundred of more carbon atoms have relatively
h_____ boiling points. How can differences in boiling points be used to separate different
alkanes ?
Distillation and fractional distillation: Word bank: longer high
Distillation Crude oil distillation Hydrocarbons
CH4
Diagram
C2H6
C3H8
C4H10
C5H12
C6H14
C8H18
C10H22
Notes In the laboratory we can An industrial fractionating Hydrocarbons are separated
separate different liquids from a column separating different into their fractions. Methane
‘mixture’ based on their hydrocarbons based on their with the lowest boiling point
different boiling points. What is boiling points and number is separated first at a
the role of the condenser ? of carbon atoms. temperature of around 40oC.
- Slide 11: Science Interactive LTD Copyright 2005
Hydrocarbons in crude oil
Crude oil contains two families of hydrocarbon compounds: The alkanes and alkenes. The
alkanes have a general formula of CnH2n + 2 and are used mainly as fuels for combustion with
o______. They include methane (natural gas), the simplest alkane with the formula CH4. Alkanes
can have up to 200 carbon atoms in a long carbon chain, but their general formula does not
change. Longer chains are used for diesel engines, lubricating oils and domestic h________
fuels. Alkanes with more than 100 carbon atoms are found in bitumen or tar.
The alkanes: Word bank: oxygen heating
Name Formula Diagram Name Formula Diagram
CH4 C5H12
Methane Pentane
C2H6 C6H14
Ethane Hexane
C3H8 C8H18
Propane Octane
C10H22
C4H10
Butane Decane
- Slide 12: Science Interactive LTD Copyright 2005
Combustion of methane
Useful alkanes include natural gas, petrol and diesel. When we combust these fuels with
o________, energy in the form of h____ and light is released. The products of complete
combustion are water and carbon dioxide. If insufficient oxygen from the atmosphere is supplied
during combustion, what might form instead of carbon dioxide ?
CH4 + 2O2 CO2 + 2H2O
Methane Oxygen Carbon dioxide Water
Combustion of methane: Word bank: oxygen heat
Natural gas Substrates Reaction mixture Products
Diagram
O
CH4 H H
C02
O
O H
O2
H
C
O
O2 H2O H2O
Natural gas is extracted Methane is rich in carbon During combustion, The products of methane
Notes
from underneath the and is a store of ancient new products are combustion with oxygen
bedrock, It is often chemical energy. During formed. The methane are water (H2O) and
found with crude oil its combustion with (CH4) molecules breaks carbon dioxide. (C02) If
deposits. The UK oxygen, it releases its apart and forms new there is not enough
obtains its gas from the energy in the form of bonds with the oxygen oxygen carbon monoxide
North Sea. heat and light. atoms. can form.
- Slide 13: Science Interactive LTD Copyright 2005
Combustion of the alkanes
Most vehicles use petrol or diesel as a fuel. When we combust these hydrocarbon fuels
with o_______, energy in the form of h____ and motion is released. New substances are
also produced including carbon dioxide and water.
Equation:
2C8H18 + 25O2 CO2 + 18H2O
Octane Oxygen Carbon dioxide Water
Combustion of octane in the car engine: Word bank: oxygen heat
Car engine Octane & Oxygen Engine Products
Diagram
With over 30 million In the engine, huge The engine is designed to The waste products are
Notes
cars in the UK, petrol amounts of oxygen are converted the chemical carbon dioxide and water.
rich in octane (C8H18) combined with octane. engine contained in However, un-combusted
This releases all the octane to forward carbon and carbon mon-
is used as a source of
stored chemical energy motion. It is highly oxide are also released
chemical energy. Find
contained in carbon inefficient releasing only into the environment as
out the current cost of
rich petrol. 13% of the energy. polluting gases.
litre of petrol ?
- Slide 14: Science Interactive LTD Copyright 2005
Supply and demand of crude oil fractions
There is a greater demand by those who use fossil fuels for the low carbon, more volatile
hydrocarbons which are used for f____ in cars, p_____ and lorries. However, there is a
greater supply of the high carbon, less volatile hydrocarbons. By breaking up the surplus
large fractions to form small volatile fractions, companies like Shell and BP can balance
s______ and demand. This is called cracking.
Meeting demand from crude oil: Word bank: fuels planes supply
LPG gas Petrol fuel Paraffin Diesel Tar or Bitumen
-100%
% of total crude oil
-80%
-60%
supply
demand supply demand
-40%
demand
supply supply
-20%
demand
demand
-0% supply
LPG Gas Petrol Paraffin Diesel Residue
- Slide 15: Science Interactive LTD Copyright 2005
Cracking long chain hydrocarbons
Crude oil contains far too many long chained h_________ with more than 15 carbon atoms in
them. Longer hydrocarbons do not make efficient fuels. Cracking is also used to form ethene, the
starting product for most plastics and other polymers. We can s_____ long chain molecules into
short chained molecules. Cracking these hydrocarbons requires heat, a catalyst and an o________
free atmosphere. Why do you need to exclude oxygen from the cracker ?
Producing short chained hydrocarbons: Word bank: split oxygen
Industrial cracking of crude oil Closer look at cracking
C10H22 Decane
Useful products
Short chained
Alkanes & alkenes
Crude oil and catalyst
are recycled at 400oC
Ethene
C2H4
C3H6 Propene
Crude oil
C5H12 Pentane
Heat (400oC) Cracker
- Slide 16: Science Interactive LTD Copyright 2005
The alkenes
The alkenes have a general formula of CnH2n and are used mainly for the manufacture of
polymers. Each alkene has a carbon-carbon double bond (C=C) which can be broken by
other atoms like h________ or chlorine added across the double bond. Polymers, made
from simple alkenes are extremely long chained hydrocarbon molecules. The simplest
alkene is ethene with the formula C2H4.
Word bank: hydrogen
The alkenes:
Name Formula Diagram Structural Diagram
Ethene C2H4 H H
C=C
H H
Propene C3H6 H H
C=C C H
H HH
Butene C4H8 H H
H C C=C C H
HH HH
Pentene C5H10 H HH
H C C=C C C H
HH HHH
- Slide 17: Science Interactive LTD Copyright 2005
Producing ethane from ethene
Unsaturated e_______ (C2H4) can also react with the gas h________ to form the alkane
ethane (C2H6) In this case, ethene in changing to ethane, becomes fully saturated. This
reaction requires h________, a nickel catalyst and an oxygen free atmosphere. The ethene
molecule is much more reactive then the ethane molecule because it has the carbon-carbon
double bond. Why do we call ethene and the alkenes unsaturated and ethane and the
alkanes saturated ?
Addition of hydrogen to ethene: Word bank: ethene hydrogen
Ethene (Alkene) Hydrogen (from water) Ethane (Alkane)
Diagram
Equation C2H4 + H2 C2H6
The two hydrogen atoms join the ethene molecule across the double bond forming
the saturated alkane, ethane.
- Slide 18: Science Interactive LTD Copyright 2005
Chemical test for the alkenes
Hydrocarbons like the alkenes with a double carbon-carbon bond are called unsaturated. Alkenes
with their double bond are much more r________ that the alkanes. Other elements like hydrogen
and chlorine can be added to alkenes by breaking the double bond. Testing for alkenes: If you
shake up an alkene with a solution of brown bromine water, then the bromine water appears to
lose it’s colour. The double bond in the alkene breaks open and forms new bonds with the
b_______ atoms. This type of reaction is called an addition reaction. Olive oil but not butter
decolourises bromine water what does this tell you about the two types of fat ?
Testing for alkenes: Word bank: reactive bromine
Ethene Bromine (in water) di-Bromoethene
Diagram
Equation C2H4 + Br2 C2H4Br2
The ethene molecule contains a carbon-carbon double bond which accepts both bromine atoms.
When the bromine atoms join the ethene molecule the bromine water loses its brown colour.
- Slide 19: Science Interactive LTD Copyright 2005
Using ethene to form plastics
Ethene (C2H4) monomers can be joined together to make a polymer called polythene.
Polythene contains huge molecules that act like fibres that can be used as alternatives to
natural materials like w____, paper and metals. Polythene is also very cheap to
manufacture whilst crude oil remains plentiful and the quality is always the same after its
manufacture. Explain why it is beneficial to the environment to use plastics rather than
natural materials like wood, paper and metals ?
Manufacturing plastic or polythene from ethene: Word bank: wood
Ethene (C2H4) Polymerisation reaction Polythene (nC2H4)
Diagram +
+
+
+
Notes Ethene (C2H4) is produced in In the presence of a metal Polythene has the general
catalyst, molecules of ethene formula nC2H4. Molecules
large amounts by cracking
add to one another forming
long chain hydrocarbons can contain up to 50,000
long chained polymers with the
found in crude oil. carbon atoms. These chains
formula nC2H4 behave like fibres.
- Slide 20: Science Interactive LTD Copyright 2005
Using plastics in everyday life
Polymers like polythene, polyvinylchloride (PVC) and nylon have replaced natural materials like
paper, wood, glass and ceramic. Plastics are c_______, readily available, tough, waterproof and
flexible. They are produced in huge quantities and are used in everyday life from the humble
plastic bag to replacement h____ and bone joints. Although using plastics instead of glass, paper
and wood actually saves energy and rainforests, they are not biodegradable so their use adds
many thousands of tonnes of rubbish per year to landfill sites.
Using plastics: Word bank: cheap hip
Making polythene The plastic bag Saving energy
Diagram
Here we see polythene made from the The plastic shopping bag
Notes Recycle
polymerisation of the alkene ethene. made from polythene has Reduce
Huge sheets of polythene like the one saved thousands of trees Replace
pictured above are manufactured from which would have been used
We can all make less of an
combining alkene monomers. for making paper. Plastic
impact on the environment in
Polythene is used for food wrapping, takes a long time to decay
our daily lives.
packaging and plastic bags. once thrown away.
- Slide 21: Science Interactive LTD Copyright 2005
The carbon cycle
All living organisms require the element c_________ to make carbohydrates, proteins and other
important molecules which make up living organisms. Cellular respiration and decomposition by
bacteria releases carbon dioxide into the atmosphere. Plants use this during p____________ at
the same rate. The amount of carbon dioxide in the atmosphere should stay the same but it is
increasing rapidly because of the use of fossil fuels and deforestation.
The carbon cycle: Word bank: carbon photosynthesis
Atmosphere Respiration
CO2 Atmosphere
There is 750 billion tonnes of CO2 trapped in the
atmosphere. This is rising by 3 billion tonnes a
year because of fossil fuel use and deforestation.
Fossil fuel combustion Land deforestation Photosynthesis
Plant biomass
Ocean
Soil
Buried fossil fuels Marine biomass
There is 3300 billion tonnes of carbon trapped in oil, coal There is 1020 billion tonnes of carbon trapped in living
and natural gas deposits found under rock sediments. organisms like algae. CO2 is also dissolved in the oceans.
- Slide 22: Science Interactive LTD Copyright 2005
Pollution using crude oil
The oil industry, including companies like Shell and Exxon have a responsibility to make
sure that their company and staff do not p_______ the environment. Occasionally, either
during extraction, transport or s_______ of crude oil, these companies can pollute the
environment with devastating consequences. An oil tanker spilling its load at sea or near to
populated coastlines can destroy the local ecosystems and peoples’ livelihoods. These
effects can sometimes last for many decades. Go to google.co.uk and type in and search
for ‘Exxon Valdize’
Impacting on the environment: Word bank: pollute storage
Tanker spills Oil depot fires Oil spills on land
Diagram
Releasing millions of barrels Fires involving crude oil Crude oil coats every living
Notes
of thick poisonous crude oil releases thick black toxic smoke organisms that it comes in
into the oceans means death to into the environment causing contact with. Birds are
many species in the ocean’s widespread pollution and especially vulnerable with their
food chains and webs. damage over a large area. delicate feathers.
- Slide 23: Science Interactive LTD Copyright 2005
Fossil fuels greenhouse effect
Over the last century, our use of fossil fuels has released huge amounts of carbon dioxide into our
atmosphere. This has disrupted the b_________ between carbon in the form of carbon dioxide
and carbon found tied up under rock in crude oil, natural gas and coal. Currently we are adding
an extra 3 billion tonnes of carbon each year into the atmosphere. The carbon dioxide molecule
traps infra red h_____ from the sun. Slowly our planet is warming because of the rising carbon
dioxide levels. How can you reduce your dependence on fossil fuels like petrol and natural gas ?
The greenhouse effect:
Word bank: balance heat
World’s crude oil use Rising levels of carbon dioxide The greenhouse effect
So
l
l
ar
rra
ad
Absorbed in atmosphere
i
ati
by greenhouse gases
o
on
ce
pa
os
tt
ou
ted
dia
Ra
15 50
15 50
Altitude (km)
(km)
The World’s energy demand and There are over 500 million cars, Carbon dioxides traps heat
the use of crude oil is increasing. all pumping out carbon dioxide energy from the sun. The amount
China in the next two decades from the combustion of octane or of carbon dioxide in the
will use more than the USA. petrol. Car use is set to double atmosphere is increasing by 3
over 20 years. billion tonnes a year.
- Slide 24: Science Interactive LTD Copyright 2005
Effects of global warming one
Scientists have many theories as to what may happen over the next century because of rising
carbon dioxide levels in the a__________, as a result of combusting fossil fossils and the
subsequent rising global temperatures. There is now increasing agreement amongst scientists that
atmospheric carbon dioxide levels need to be controlled. Many countries have signed ‘The Kyoto
Agreement’ which aims to reduce carbon emissions over the next 20 years. This will perhaps
s____ global warming. Only one country, America has not signed up, she is the biggest carbon
polluter. Why do you think that America has not signed up ?
Effects of global warming: Word bank: atmosphere slow
Global warming Drought Ozone layer Flooding
Diagram
Average world or More extremes of The destruction of the Flooding will increase
Notes
global temperatures are temperatures are now Ozone by CFCs from over the next decade. In
set to increase by expected with lower aerosols will also add to England (summer 2004),
between 0.5 and 1oC rainfall in areas which global warming by we had some of the worst
per decade for the next already see little rain reflecting less infra red flash floods on record,
fifty years. over the year. heat given out by the including Boscastle.
- Slide 25: Science Interactive LTD Copyright 2005
Effects of global warming two
The greenhouse effect is a natural process where the 750 billions tonnes of c________
dioxide in the atmosphere maintains the Earth’s atmosphere at hospitable temperatures,
which are supportive of life, here on Earth. Combusting fossil fuels is adding to this
‘warming effect’ causing average global t___________ to rise over the last fifty years.
Global warming will continue, whilst we continue to combust fossil fuels like coal and oil.
The World’s weather, habitats and temperature are set to change over the next century.
Effects of global warming: Word bank: carbon temperatures
Weather Waves Biodiversity Melting ice caps
Diagram
The World’s weather Damage due to strong Animals and plants may The ice caps have shrunk
Notes
will become more tides and wave action undergo mass extinction in size over the last 30
dynamic. In summer along the coast will in the next one hundred years. This may rise sea
2004, Florida in also increase over the years if global warming levels and also reduce
America was hit by next decade. Parts of continues. The Malarial the amount of the Sun’s
three hurricanes causing the England's coastline Mosquito is spreading infra red heat reflected
immense damage. are now being eroded. north into Europe. back into space.
- Slide 26: Science Interactive LTD Copyright 2005
Acid rain and fossil fuels
Carbon dioxide is not the only pollutant that is released into the environment during the
combustion of fossil fuels. Sulphur and nitrogen, in small quantities are also present in
crude oil. During combustion, both s_______ and nitrogen combine with oxygen to form
sulphur dioxide and nitrogen oxides. These gases form weak acids when they react with
water present in the atmosphere. Acid rain can damage f________ and plant life. It can
also acidify lakes and ponds disrupting natures balance.
Acid rain: Word bank: sulphur forest
Polluting the Earth’s atmosphere pH of precipitation across America
Diagram
With 280 million Americans each using on The pH of rainfall is lowest where you find the highest
Notes
average a staggering 3kw per hour every day population across the East Coast of America. Almost 150
of the year, the amount of Sulphur dioxide million Americans live, work, drive and pollute in this
gas emitted per year for ever square area. The pH of rain water in some areas of the Eastern
kilometre of land is around 0.4 of a tonne. USA seaboard has a very acidic pH of 4.2.
- Slide 27: Science Interactive LTD Copyright 2005
Acid rain and the atmosphere
In addition to releasing carbon dioxide, small amounts of sulphur and nitrogen, present as impurities in
crude oil cause other polluting gases to be released into the atmosphere. During combustion, both
sulphur and nitrogen combine with o________ to form sulphur dioxide and nitrogen oxides. These
gases form weak acids when they react with water in the atmosphere. Acid rain can damage forests
and plant life. It can also acidify lakes and ponds disrupting natures balance.
Acid rain cycle: Word bank: oxygen
Diagram
Rain cloud
S02 & NOx react with
water to form acid rain.
SO2 NOx H SO HNO3
2 4
Sulphuric acid Nitric acid
Acid Rain Acid Rain Acid Rain
Power station Acidified soil Acidified lake Damaged forests
Combustion engines
The combustion of fossils fuels releases SO2 and NOx into the atmosphere. These gases on contact
Notes
with water vapour form sulphuric and nitric acid. Acid rain can damage forests, acidify the soil and
reduce the pH of lakes, ponds and rivers. Rain clouds containing low pH rain water can travel
many kilometres. Due to England's westerly winds, our acid rain travels to our European
neighbours including Sweden and Denmark.
- Slide 28: Science Interactive LTD Copyright 2005
Acid rain and fossil fuels
Carbon dioxide is not the only pollutant that is released into the environment during the
combustion of fossil fuels. Sulphur and nitrogen are also present in crude oil. During combustion,
both sulphur and nitrogen combine with oxygen to form sulphur dioxide and nitrogen oxides.
These gases form weak a_____ when they react with water in the atmosphere. Acid rain can
damage forests and plant life. It can also acidify l______ and pond disrupting natures balance.
Look at this statue and notice the chemical weathering !
Acid rain and its effects: Word bank: acids lakes
Acid rain damage to forests Acid rain damage to waterways Acid rain damage to marble
Diagram
Forests and all plant life are Rivers, ponds and lakes can Acid rain also destroys buildings
Notes
sensitive to acid rain even over become acidic in areas with high and statues made from limestone
short periods of time. The rainfall levels. Low pH of the or marble. Dissolved acid in
delicate leaves are damaged by water can lead to the disruption of raindrops reacts with the calcium
the low pH rainfall. When a the ecosystem, therefore killing carbonate in the marble or
tree loses its leaves due to acid many species. How can scientists limestone making a soluble
rain, it can no longer produce neutralise acidic lakes, what product calcium oxide. This is
its own food during chemical would they use ? slowly dissolved away by
- Slide 29: Science Interactive LTD Copyright 2005
Renewable energy sources
Renewable alternatives to using crude oil for generating electricity are now being
developed. These reduce our dependence on crude oil, as well as reducing carbon dioxide
emissions. Many sources of e_______ that we currently use every day are now renewable.
This means that unlike coal, natural gas and crude oil they are not used up. Many
scientists are working to develop the technology to use these renewable sources of energy
to generate e__________.
Overview of renewable energy: Word bank: energy electricity
Wind Solar Biogas Hydroelectric
Wind farms could supply Solar cells using solar Converting animal waste like Using moving water, hydro-
up to 15% of the energy energy could power traffic manure from farms and electric dams are able to
we use every year. Why lights and street lamps. farming into methane using generate clean electricity.
do people in the They are only useful in bacteria is a way of replacing The only problem is that you
countryside object to countries with high rates fossil fuels like gas. Give the need lots of space and high
these wind farms ? of sunshine. formula of methane ? yearly rainfall.
- Slide 30: Science Interactive LTD Copyright 2005
Generating electricity using wind power
Wind power stations makes use of the k_______ energy of moving air currents. Kinetic
energy directly drives small generators that produce electricity. Wind farms are usually
found in windy unpopulated areas. Several w_____ turbines can supply, on a windy day
enough energy for a small town. This is a clean, renewable form of energy with limited
drawbacks. Some people object to the ‘visual pollution’ that many wind turbines cause and
believe they spoil the landscape. Why do you need large areas of land to generate
electricity using wind power ?
Wind power supplying electricity: Word bank: kinetic wind
Diagram
Captured kinetic energy of the wind drives the generator, producing electricity. Using wind
Notes
turbines is still expensive and is only viable in countries with large amounts of free land and of
course windy weather. The energy is totally renewable and does not increase the levels of polluting
gases which add to either global warming or acid rain. The map shows the average wind speed in
America. Where are the best places for a wind farm....Explain your answer ?
- Slide 31: Science Interactive LTD Copyright 2005
Generating electricity using solar power
Solar power can be used directly to generate small amounts of electricity using photovoltic cells.
These produce a low c________ and are only useful for producing electricity in remote areas or
for devices that only require a low current, for example calculators. Using solar power to heat
water creating steam which then drives a turbine generator is another way the sun’s energy can
be used to generate electricity. E_________ regions that receive plenty of sunshine are ideal. The
only problem is that the technology is still relatively expensive. Why is the UK not an ideal
location for solar panels or cells ?
Solar power supplying electricity: Word bank: current equatorial
Diagram
Steam produced from the heat energy collected by solar reflectors drives the turbine and generator.
Notes
A current is induced in the cables. Electricity is transported to commercial and domestic users.
Using solar cells is expensive and is only viable in countries with good weather. Solar cells can be
used to directly generate electricity. These are very useful where there is demand for energy in very
remote areas like the desert or away from major towns and cities.
- Slide 32: Science Interactive LTD Copyright 2005
Generating electricity using biogas
Electricity can be generated on a small scale using biogas. Biogas is exactly the same as methane,
the fossil fuel extracted from underneath the rock, but it is produced by b________ respiring
animal wastes like manure. This is therefore a renewable supply of methane gas which can be
used in the same way as fossil fuels, with the h_____ energy used to produce steam which in turn
drives a turbine generator. Why is the amount of electricity generated using this method very
small at present ?
Biogas supplying electricity: Word bank: bacteria heat
Biogas
Biogas mini power station
Diagram Waste
Waste
Gases
Gases
Turbine
Turbine
Boiler Generator
Boiler Generator
33,000V
Steam 240V
Steam 33,000V 240V
Manure Fermentor Fermentor Furnace Transformer 1 Transformer 2 Customer
Manure Fermentor Fermentor Furnace Transformer 1 Transformer 2 Customer
Steam produced from the heat energy given out when natural gas (CH4) is combusted with oxygen
Notes
drives the turbine and generator. A current is induced in the cables. Electricity is transported to
commercial and domestic uses only. Using biogas, although expensive and still producing
greenhouse gases recycles animal waste like manure.
- Slide 33: Science Interactive LTD Copyright 2005
Generating electricity using gravitational potential energy
Water held behind a dam, stores huge amount of gravitational potential energy. When the stored
water is allowed to flow downhill, its kinetic energy is used to drive turbine generators, which in
turn produces electricity. Hydroelectric dams are usually constructed in mountainous areas with
high yearly rainfall levels. The three gorges dam is the largest r__________ and is currently
under construction in China. When finished, it will generate millions of kilowatts everyday.
Although this is renewable e_______ up to ten million people will be displaced when the valley
is flooded. Why is this technology used only in wet mountainous areas ?
Moving water supplying electricity: Word bank: reservoir energy
Diagram
Notes Large amounts of land and rainfall are required for any hydroelectric dam. The main
advantages of hydroelectricity is that it is a renewable form of energy and the start up time
from allowing the water drop to generating electricity is less than a second. Electrical energy
generated in this way is used to supply electrical power during peak demands.
- Slide 34: Science Interactive LTD Copyright 2005
Extension questions and homework
1: Define the following terms: Cracking, Distillation, Separation, Alkene, Alkane, Saturated and Unsaturated.
2: Look at the three pictures below. Complete the table.
Picture Fuel type (alkane) Formula
Car
Plane
Cooker
3: Answer the following:
a) Give 5 uses of oil in the modern industrial world.
b) How does the volatility and flammability of the alkanes change as the carbon chain increases its length.
c) Which fractions will ignite most easily and why.
d) Cracking large molecules of alkanes is very important. Give two reasons why and give an example of a large
molecule being cracked and its subsequent products. (e.g. C12H26)
e) Describe the conditions for cracking and explain why large molecules are heated in the absence of oxygen.
f) Explain what is meant by the following sentence: Oil is a finite source what does this mean.
- Slide 35: Science Interactive LTD Copyright 2005
4: In table 1 the information shows the demand for different fractions of North Seal Oil.
a) Why is the demand for diesel oil and residue greater in the winter than the summer.
b) Why is the demand for petrol fairly constant all year round.
c) What would an oil company do to cope with the changing demand between summer and winter.
d) What is bitumen used for and how does its properties fit in with this use.
Fraction Percentage demand Percentage demand Fraction Percentage demand in Percentage demand in
in summer in winter summer winter
Refinery gas 3.6 3 Diesel oil 17 23
Gasoline 32 29 Residue 20 22
Kerosene 12 6 Bitumen 15.4 17
5: Answer the following questions:
a) Explain what is meant by the following words: Monomer, polymer, polymerization, plastic and polymer.
b) What is the polymer of the following monomers: (i) Ethene (ii) Vinyl chloride (iii) Ester.
c) Each of the following materials contain fibres or polymers. For each material say whether it is natural or
synthetic, being made from crude oil.
Wood PVC Linen Polyester Perspex Rayon Lycra Rubber Leather
6: Answer the following questions:
a) You often hear chemists say crude oil is too valuable just to burn for heating and transport. Explain why this
could be true.
b) Give the balanced equation for the complete combustion of a) methane (CH4) and nonane (C9H20). What are
the bonds broken and formed during the reaction.
c) Why does plastic present a problem for disposal. What solutions can you think of.
d) Some manufactures are making biodegradable plastics. One type used for making shopping bags consists of
tiny grains of polythene stuck together with cellulose. Why does this make it biodegradable. Will it degrade
completely.
e) The price of virtually all plastics depends on the price of crude oil. Explain why this is true.
Internet:
Go to google.co.uk and find out about the manufacture of nylon. Also visit the website of British Petroleum
(bp.com). Where do they extract their crude oil from and which use of crude oil forms their biggest market.