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Purification of Substances
[object Object],[object Object],Objectives: ,[object Object],[object Object],[object Object],Know their principles, procedures and application
The NEED for pure substance ,[object Object],Chemist need pure substances to study their  properties. Pure substances are used in industry to make  useful  products such as  food  and  drugs .
The NEED for pure substance In  pharmaceutical  industry, medicines must be tested for purity before they are sold. Impurities in drugs and food may produce  undesirable  side effects.
[object Object],The NEED for pure substance
The NEED for pure substance In  food  and  beverage  industry, the types of chemicals which can be added into our food are  controlled  by certain  governmental  guidelines to ensure that our food and drinks contain chemicals that are  safe  for consumption.
Criteria for purity ,[object Object],In nature, many substances are not pure. Most are found impure as  mixtures .
[object Object],The need for pure substance They can be  easily separated  into pure substances by  purification  techniques. The substances  do not react  with one another  chemically . (Physical method)
Criteria for purity Mixtures Pure Substances Properties  Boiling Point Melting Point Exact and Fixed Not Fixed (Higher) Not Fixed (Lower) Definite Not Definite Exact and Fixed
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Criteria for purity
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Criteria for purity
A pure substance contains only one type of substance (that is, one type of molecule or atom) Melting point of pure water = 0 ºC Boiling point of pure water = 100 ºC So, do you think the temperature for sea water is also 100 ºC?
[object Object],[object Object],Criteria for purity To find out if the substance is pure: Melt at its true melting point Boil at its true boiling point Measure its melting point Measure its boiling point
[object Object],Criteria for purity When impure: Melting point decreases further, Boiling point increases 0 o C 100 o C -2 o C 102 o C Liquid Solid Gas
WEBSITE TO VISIT:http://environmentalchemistry.com/ ,[object Object],[object Object],[object Object],[object Object],[object Object]
Some important terms Some terms that you should know: A  solute  is a  dissolved substance  (e.g. salt in salt solution). A  solvent  is a substance which  dissolve a solute  (e.g. water in salt solution. Miscible  liquids are liquids that are  completely soluble  in each other.
Mixtures Solutions and suspensions ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
How do we obtain Pure substances from a mixture? ,[object Object]
Possible scenarios of mixtures! ,[object Object],[object Object]
[object Object],[object Object],[object Object],Possible scenarios of mixtures!
Types of separation techniques Suitable method of purification: Filtration Aim:  To separate a soluble and insoluble solid (E.g. Salt and sand)/ To separate insoluble solids from  a solution (E.g. Sand from water)
Filtration 1. Glass rod 2. Retort stand 3. Mixture 4. Filter paper 5. Filter funnel 6. Beaker 7. Filtrate Filtration is usual method of separating solid from a liquid. Solid-Solid mixture Solid-Liquid mixture
A Glimpse of our First mini Practical on   FILTRATION !!
Do you remember how to do filtration?
Filtration – How it works ,[object Object],[object Object],[object Object],[object Object],-  Residue ,[object Object],-  Filtrate Solid-Solid mixture Solid-Liquid mixture Filter paper with small holes Small particles of liquid Large particles of solid
Filtration – How it works Applications: Solid-Solid mixture Solid-Liquid mixture
A little extra: Buchner funnel ,[object Object],[object Object],[object Object]
Buchner funnel ,[object Object]
What happens to the filtrate? Can filtration be done to separate solids dissolved in solution? Filtration Solid-Solid mixture Solid-Liquid mixture
Notes ,[object Object],[object Object],Dyes in ink go through the filter As dye molecules are smaller than the pores in the filter paper and go straight through them. Salt in sea water cannot be separated from water by filtration, as the sodium chloride molecules are much smaller than the pores in the paper.
Possible Scenario Suitable method of purification: Which should we use? Crystallisation Evaporate  ? ?
Evaporation ,[object Object],To obtain a  solute  from its solution by vaporising  ALL  the solvent.  (E.g. To obtain salt from salt solution.) How it works? When a solution is  heated,  only the  solvent  boils away while the  solute  remains. Evaporation is a process where  ALL  the liquid has been  vaporised . Solid-Liquid mixture
[object Object],[object Object],Evaporation Solid-Liquid mixture salt solution evaporating dish Salt solution heat
[object Object],Solid-Liquid mixture Evaporation Boiling to dryness Evaporation using water bath (slower)
[object Object],Evaporation ,[object Object],[object Object],There is Always conditions involved!!! Solid-Liquid mixture
Crystallisation Aim:  To obtain PURE solids from a solution (solid will decompose upon strong heating). E.g. To obtain  sugar  from  sugar solution ,  Copper (II) Sulphate  from  Copper (II) Sulphate solution . Do you know others? Solid-Liquid mixture solution
CRYSTALLISATION
Crystallisation Glass Rod Solvent Impure Solid 1. 2. Solution Evaporating dish Crystals 3. Pure crystals appear when the hot solution cools. 4. Filter paper Crystals Crystals are then collected and dried between filter papers. ,[object Object],[object Object],saturated. Heat the solution until  MOST  of the solvent  evaporate  off. Allow it to cool. (Steps to make solution  saturated ) Dissolved solid appears as  pure crystals  as the solution cools.  Impurities  remain  dissolved  in the solution . Solid-Liquid mixture
Crystals Salt crystals Sugar crystals Copper(II) sulphate crystals Solid-Liquid mixture
Have you noticed the difference of evaporation from Crystallisation? In a  Solid-Liquid mixture ,  both Evaporation and Crystallisation   is used  to obtained solid from its solution. Most All How much solvent have to be vaporised? Yes No Does solid decompose upon strong heating? Crystallisation Evaporation
Summary: Evaporation & Crystallization To obtain a   soluble   solid   from a   liquid  in solid-liquid mixture Evaporation Crystallization If solid   does not decompose   on heating If solid   decomposes   on heating
[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],Questions
Questions   ,[object Object],[object Object],[object Object],[object Object],[object Object]
Questions   4.  Which of the following is the correct order for purifying potassium nitrate from impure saltpetre (naturally occuring potassium nitrate) using water as a solvent? A) dissolve – filter – evaporate -crystallise B) dissolve – evaporate – crystallise - filter C) filter – dissolve – evaporate - crystallise D) evaporate – crystallise – dissolve - filter

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Purification Of Substances 1

  • 2.
  • 3.
  • 4. The NEED for pure substance In pharmaceutical industry, medicines must be tested for purity before they are sold. Impurities in drugs and food may produce undesirable side effects.
  • 5.
  • 6. The NEED for pure substance In food and beverage industry, the types of chemicals which can be added into our food are controlled by certain governmental guidelines to ensure that our food and drinks contain chemicals that are safe for consumption.
  • 7.
  • 8.
  • 9. Criteria for purity Mixtures Pure Substances Properties Boiling Point Melting Point Exact and Fixed Not Fixed (Higher) Not Fixed (Lower) Definite Not Definite Exact and Fixed
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  • 12. A pure substance contains only one type of substance (that is, one type of molecule or atom) Melting point of pure water = 0 ºC Boiling point of pure water = 100 ºC So, do you think the temperature for sea water is also 100 ºC?
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  • 16. Some important terms Some terms that you should know: A solute is a dissolved substance (e.g. salt in salt solution). A solvent is a substance which dissolve a solute (e.g. water in salt solution. Miscible liquids are liquids that are completely soluble in each other.
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  • 21. Types of separation techniques Suitable method of purification: Filtration Aim: To separate a soluble and insoluble solid (E.g. Salt and sand)/ To separate insoluble solids from a solution (E.g. Sand from water)
  • 22. Filtration 1. Glass rod 2. Retort stand 3. Mixture 4. Filter paper 5. Filter funnel 6. Beaker 7. Filtrate Filtration is usual method of separating solid from a liquid. Solid-Solid mixture Solid-Liquid mixture
  • 23. A Glimpse of our First mini Practical on FILTRATION !!
  • 24. Do you remember how to do filtration?
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  • 26. Filtration – How it works Applications: Solid-Solid mixture Solid-Liquid mixture
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  • 29. What happens to the filtrate? Can filtration be done to separate solids dissolved in solution? Filtration Solid-Solid mixture Solid-Liquid mixture
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  • 31. Possible Scenario Suitable method of purification: Which should we use? Crystallisation Evaporate ? ?
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  • 36. Crystallisation Aim: To obtain PURE solids from a solution (solid will decompose upon strong heating). E.g. To obtain sugar from sugar solution , Copper (II) Sulphate from Copper (II) Sulphate solution . Do you know others? Solid-Liquid mixture solution
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  • 39. Crystals Salt crystals Sugar crystals Copper(II) sulphate crystals Solid-Liquid mixture
  • 40. Have you noticed the difference of evaporation from Crystallisation? In a Solid-Liquid mixture , both Evaporation and Crystallisation is used to obtained solid from its solution. Most All How much solvent have to be vaporised? Yes No Does solid decompose upon strong heating? Crystallisation Evaporation
  • 41. Summary: Evaporation & Crystallization To obtain a soluble solid from a liquid in solid-liquid mixture Evaporation Crystallization If solid does not decompose on heating If solid decomposes on heating
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  • 44. Questions 4. Which of the following is the correct order for purifying potassium nitrate from impure saltpetre (naturally occuring potassium nitrate) using water as a solvent? A) dissolve – filter – evaporate -crystallise B) dissolve – evaporate – crystallise - filter C) filter – dissolve – evaporate - crystallise D) evaporate – crystallise – dissolve - filter