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IAEA
Technical Meeting on Origin of Sandstone Uranium Deposits: A Global Perspective
                     VIC, Vienna, May 29 - June 01, 2012




                           PERSISTENT SURVEILLANCE FOR
                   PIPELINE PROTECTION AND THREAT INTERDICTION




          Sedimentary Uranium Deposits
       in the Frome Basin, South Australia –
       Metallogeny and Recognition Criteria
                  for Exploration
H. Maerten1,2, A. Marsland-Smith1, M. Haschke2, A. Huddleston1, B. Packer1
            1
                Heathgate Resources Pty. Ltd., Adelaide, Australia
                        2
                          UIT GmbH Dresden, Germany
Overview


     • Introduction:
       Sedimentary uranium in Frome Basin
     • Metallogeny aspects:
         – Source: geological framework/source-term
         – Transport: primary groundwater vs. potential secondary flow
           paths
         – Trap: source/distribution of reductants, trap mechanisms in
           heterogeneous aquifers and varying deposit types/ages
     • Geophysical surveys:
         – Focus: shallow seismic → structural-stratigraphic model
           including regional fault structures and local discontinuities
     • Towards recognition criteria
         – Indications from structural-stratigraphic model
           (→ sandstone bodies): status and outlook
         – Deposit mapping and 3D modelling from delineation
           programs (roll-front geometry, characteristics)
     • Outlook:
       Methodology to assess ISR feasibility/optimization



2
Location




3
Frome Embayment – World Class Uranium Province




4
Known Deposits
                                    5 km                                                                  EL3934
              N
                                                                        Pepegoona
      Range Front 5km                                       Pepegoona West
    (deposits in Eyre/
      Cretaceous                                             Pannikan

      formations)
                                                              ML6387
                                                                                                          Main Beverley
                                                Four Mile
                                    Four Mile     East
                                                               ML6321
                                                                                    Tewalina               channels
                                      West                                          Channel                (Namba)
                       Paralana
                      Hot Springs                                 Beverley
                                                                                       Central
                                                                                       Channel
                                                                                          Beverley East


                                                                     South
                                                                    Channel      Beverley
                                                                                Deep South
                                                                                                              Tabular/
                                                                                                          paleochannel
                                                                                                           (flat mineral
                                EL3935                                                                        bodies)
             EL3666




5
Source and Mineralization Potential




                                               g es
                                            Ran
                                        s
                                    d er
                                l in
                            F
                       n
                     er
                 rth
               No           er
                         int
                       Pa
                  t.
                 M




                                                      Radiometrics

6
Frome Basin U Deposits – Systematic

                      Holocene       Frome Basin             [Ma]                   Age of host rock

            Neo-      Pleistocene     Willawortina
                                                                                    Uranium deposition
Cenozoic




                                       Formation
            gene       Pliocene                                                                                               3
                                        Namba               5.3
                       Miocene         Formation                  ~16   Beverley
                                                            23
                      Oligocene                                                        Pepegoona                              2
            Paleo-                       Eyre                                           Pep. West
                       Eocene          Formation                  ~43                                    Pannikan
             gene                                                                     Four Mile East
                      Paleocene
                                                            65

            Creta-       Late                                                                                                 1
            ceous        Early
                                        Bulldog Shale
                                    Cadna-owie Formation                                                 Four Mile
                                       Murta Formation           ~110




                                                                                                                      Basement uplift followed
                                    Algebuckina Sandstone                                                  West
                         Late
Mesocoic




                                                            145                          Multiple




                                                                                                                      by deep weathering
           Jurassic     Middle                                                          stacks of
                                                                         Paleo-         roll-fronts
                         Early                                                                         „Classical“
                                                                        channels/          (dis-
                                                                                                        roll-fronts
                         Late                                            tabular       continuous)

           Triassic     Middle
                         Early                              251                           Deposit type


7
Ultimate U Source and Mineralization Potential

Cosmogenic 10Be erosion rate                  Ultimate U source:
estimates suggest that Northern Flinders      - geochronological
                                              - geochemical
formed over 4 Ma (Quigley et al., 2007).      - mass-balance
If granites contain >30 ppm U, then           - sedimentologic
yearly erosion ~2,400 lbs U.                  arguments

                                              Possible chemical
                                              weathering of
                                              U-rich granites
                                              before uplift
                                er            (preconditioning)
                             int
                           Pa
                      t.
                     M




      >9 Blbs U eroded into Frome Basin in the past 4 Ma

8
Conceptual Geological Section: Beverley




                                     Beverley
                                     Alpha
                                     Beta
                                     Gamma




9
Four Mile Schematic




10
Transport

     • Channelized flow of U-bearing groundwater from
       weathering granite blocks into Frome Basin
        – Meteoric → groundwater
        – Sandstone layers/lenses and paleochannels
     • Time-dependence of hydrogeological flow regime in
       geological scale
        – Active tectonics
        – Stress system according to orientation of Flinders Ranges
          and known faults
        – Seismicity/seismic surveys → transpressive tectonic regime/
          tectonic constraints
     • Primary groundwater flow versus secondary flowpaths
        – Role of faults


11
Trap: Single-fluid versus Two-fluid Models

     • Single-fluid model
        – In-situ reductants immobilize U in aquifer
        – In-situ reductants from microbial, anaerobic decomposition
          of organic matter
     • Two-fluid model
        – Upflow of reductants into aquifer from underlying organic-
          rich formations, thus, immobilizing U from the groundwater




                            Jaireth et al., 2008


12
Reduction Processes – Organic Matter Decomposition under
  Anaerobic Conditions (Schematic)

                                     Fe-oxide reducing bacteria


                                                         Fe2+
                                    FeOOH
     Organic
     material

                                     Sulfate reducing bacteria
                          Acetate
                          Formate
                                                         H2S
                              H2
                                     SO42-
                              CO2



                                     Methanogenic bacteria
     Fermenting
      bacteria
                                                      CH4 + CO2

                                                      CH4 + H2O
Re-drawn from Appelo/Postma


13
Reference: Sediment REDOX – GA Study EL 5/6




GA18232


14
In-situ reductants or reductant
  REDOX Mapping – EL 5/6                    transport via faults?




  Long transport
 pathways from
   source rock
   to trapping
 (Beverley within
    Namba)



  Short transport
    pathways
 (→ Range Front
                       Same patterns observed
    deposits)
                         at Beverley/Four Mile



GA18232


15
Towards Recognition Criteria (Programmatic)

     • Conventional geophysical surveying
        – Including gravimetrics, magnetics, airborne electromagnetics,
          induced polarization, magnetotellurics, and radiometrics
        – From data it is hard/impossible to identify recognition criteria in
          a regional scale
     • New high-resolution seismic surveys (2D):
        – Throughout Paralana Lease (Beverley) and in the Range Front area
          (including Four Mile) – total of ~500 line km
        – Targets: sandy formations (including paleachannels) and faults

     • In progress:
        – Improved migration procedures for higher resolution/ significance
        – Joint inversion (seismic + CSAMT/gravimetrics)
        – Advanced seismic analysis including attribute analysis and AVO
          (towards rock physics)
     • Outlook: 3D seismic surveying:
        – Much better significance for (bending) channel structures


16
3D Paralana Model with Beverley Deposit (2D Seismic)

                                 Flinders Ranges




                             t
                          ul
                       Fa
                       na
                     ta
                   on
                 Po




                                                   Top
                                                   of:
                                                   Namba
                                                   Eyre
                                                   Bulldog Shale
                                                   Cadna-owie
                                                   Basement




17
3D Paralana Model with Beverley Deposit (2D Seismic)




18
3D Beverley (2D Seismic – Line 2500)




                               Beverley Central




19
3D Beverley (2D Seismic Line 2500 + Drill Logs)




                                Beverley Central
                                sand channel




20
3D Beverley (2D Seismic Line 2500 + Drill Logs + Ore)




                                Beverley Central
                                ore body




21
3D Beverley (from 2D Seismic) + Ore Bodies

Top of Bulldog Shale                                       Top of Eyre Formation




         Line 2500                      Beverley deposit
                       Poontana Fault




22
Range Front Deposit Example: Four Mile East




                                                Top of:
                                                Basement




23
Range Front Deposit Example: Four Mile East

                               View from Flinders Ranges into the Basin


             Silcrete on top
             of sand body in
             Eyre Formation
                (chemical
              wheathering
              during high-T
             climate period)

                                                         Sandy
                                                         Eyre
                                                         Formation



                                            Top of basement
                   Faults



24
Range Front Deposit Example: Four Mile East

                               View from Flinders Ranges into the Basin


             Silcrete on top
             of sand body in
             Eyre Formation
                (chemical
              wheathering
              during high-T
             climate period


                                                    U mineralization
                                                    in Eyre
                                                    Formation



                                            Top of basement
                   Faults



25
Ranges Front Stratigraphy (Example: Four Mile East)




                                   Extending to Beverley North




26
Ranges Front Stratigraphy (Example: Four Mile East)
                                                         Max.
                                             Boun-
                                                        thick-                                                                                                      System
                               Strata        ding
                                                         ness                                 Lithofacies                                                           tracks
                                                                                                                                                                                Age
                                             surface
                                                          [m]
                                                                 Alluvial fan-braided channel conglomerates with fine floodplain/
                                                         50
                               Willwortina   Will                lacustrine muds; several coarsening upwards cycles; incised base;                                  Tectonic    Pliocene
                                                                 hematitic
                                                                 Alluvial fan-fluvial conglomerates and sands/multiples fine upward                                             Late
                                                         125
                               Namba         Namb                cycles; disrupted floodplain muds (‘injection flames’); highly incised                             Tectonic    Oligocene –




                                                                                                                                          + aeolian contributions
                                                                 base; kaolinitic                                                                                               Late Miocene
                                                                 Fluvio-lacustrine; channel sands/conglomerates, fine-grained ‘glass’
Basin




                                             Eyre 4/5            sands, thicker lucustrine muds with turbiditic sands, abundant mud                                 Late HST
                                                                 ‘rip up’ clasts; minor lignitic debris
                                                                 Multi-storey (amalgamated) braided channel sands/conglomerates;
                                             Eyre 3      12                                                                                                         Early HST
                                                                 floodplain muds; minor lignitic debris                                                                         Early – Middle
                               Eyre
                                                                 Meandering channel sands with minor conglomerates; floodplain                                                  Eocene
Lake Eyre (Frome Embayment)




                                             Eyre 2      20      sands/silt/muds; abundant lignitic debris/some thin coals (zone of                                 TST
                                                                 maximum flooding/accomodation)
                                                                 Multi-storey (amalgamated) braided channel sands/conglomerates;
                                             Eyre 1       8                                                                                                         LST
                                                                 minor lignitic debris; highly incised base
                                                                 ‘Bulldog shale facies’: carbonaceous shales/silts, fine sands and
                                             Bull 4       5                                                                                                         TST         Early Albian*
                                                                 ‘pebbly mudstone’; abundant bioturbation

                                             Bull 3       0      Grain flow sands/turbidites (present at Four Mile West only)                                                   Late Aptian*

                                             Bull 2       5      Sandy diamictite with dropstones                                                                   Glacial     *Microplanctonic
                                                                                                                                                                                age extrapolated
                                                                                                                                                                                from Four Mile
                                             Bull 1      20      Basal conglomerates (clast-supported ‘cabblestones’)                                                           West




27
Rollfront Morphology at Four Mile East (Area 1)

                   UB

     LB                                                     UB
                                                   LB

                                                50m

                              Uranium deposition controlled by both
                            REDOX and (heterogeneous) permeability
                                  within host formation (aquifer)
                         → recognition criteria on local scale to follow up
                                rollfronts within drilling programs




                                                         Open pit (Texas)


28
Beverley North Roll Fronts – Morphology




                              29
29
Core Samples Four Mile East (Area 1)




30
Four Mile East Details – Area 1 (Upper Rollfront)

      % of ore zone in pyrite (organic carbon – more scattered)




31
Four Mile East Details – Area 1 (Upper Rollfront)

     Disequilibrium DEF – pU3O8/eU3O8 (U grade/γ activity)




32
Four Mile East Details – Area 1 (Upper Rollfront)

     % of ore zone in clays




33
Four Mile East Details – Area 1 (Upper Rollfront)

      Host formation flow rates




34
Conclusion: ISR Feasibility

     • Data matrix for assessment on the basis of
        – (Real) Uranium GT (grade/thickness)
        – Permeability (flow rates)
        – Mineralogy/geochemistry (in particular, abundance of
          reductants including organics and pyrite)


     • Reactive-transport model simulation of ISR performance
        – Forecast of wellfield performance + experience
        – Adjustment of ISR chemistry/optimization

        → To be presented at the IAEA Technical Meeting/
         Consultants’ Meeting on ISL Technology, Nov 19-23, 2012



35

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02 iaea tm-u-may-jun2012_maerten

  • 1. IAEA Technical Meeting on Origin of Sandstone Uranium Deposits: A Global Perspective VIC, Vienna, May 29 - June 01, 2012 PERSISTENT SURVEILLANCE FOR PIPELINE PROTECTION AND THREAT INTERDICTION Sedimentary Uranium Deposits in the Frome Basin, South Australia – Metallogeny and Recognition Criteria for Exploration H. Maerten1,2, A. Marsland-Smith1, M. Haschke2, A. Huddleston1, B. Packer1 1 Heathgate Resources Pty. Ltd., Adelaide, Australia 2 UIT GmbH Dresden, Germany
  • 2. Overview • Introduction: Sedimentary uranium in Frome Basin • Metallogeny aspects: – Source: geological framework/source-term – Transport: primary groundwater vs. potential secondary flow paths – Trap: source/distribution of reductants, trap mechanisms in heterogeneous aquifers and varying deposit types/ages • Geophysical surveys: – Focus: shallow seismic → structural-stratigraphic model including regional fault structures and local discontinuities • Towards recognition criteria – Indications from structural-stratigraphic model (→ sandstone bodies): status and outlook – Deposit mapping and 3D modelling from delineation programs (roll-front geometry, characteristics) • Outlook: Methodology to assess ISR feasibility/optimization 2
  • 4. Frome Embayment – World Class Uranium Province 4
  • 5. Known Deposits 5 km EL3934 N Pepegoona Range Front 5km Pepegoona West (deposits in Eyre/ Cretaceous Pannikan formations) ML6387 Main Beverley Four Mile Four Mile East ML6321 Tewalina channels West Channel (Namba) Paralana Hot Springs Beverley Central Channel Beverley East South Channel Beverley Deep South Tabular/ paleochannel (flat mineral EL3935 bodies) EL3666 5
  • 6. Source and Mineralization Potential g es Ran s d er l in F n er rth No er int Pa t. M Radiometrics 6
  • 7. Frome Basin U Deposits – Systematic Holocene Frome Basin [Ma] Age of host rock Neo- Pleistocene Willawortina Uranium deposition Cenozoic Formation gene Pliocene 3 Namba 5.3 Miocene Formation ~16 Beverley 23 Oligocene Pepegoona 2 Paleo- Eyre Pep. West Eocene Formation ~43 Pannikan gene Four Mile East Paleocene 65 Creta- Late 1 ceous Early Bulldog Shale Cadna-owie Formation Four Mile Murta Formation ~110 Basement uplift followed Algebuckina Sandstone West Late Mesocoic 145 Multiple by deep weathering Jurassic Middle stacks of Paleo- roll-fronts Early „Classical“ channels/ (dis- roll-fronts Late tabular continuous) Triassic Middle Early 251 Deposit type 7
  • 8. Ultimate U Source and Mineralization Potential Cosmogenic 10Be erosion rate Ultimate U source: estimates suggest that Northern Flinders - geochronological - geochemical formed over 4 Ma (Quigley et al., 2007). - mass-balance If granites contain >30 ppm U, then - sedimentologic yearly erosion ~2,400 lbs U. arguments Possible chemical weathering of U-rich granites before uplift er (preconditioning) int Pa t. M >9 Blbs U eroded into Frome Basin in the past 4 Ma 8
  • 9. Conceptual Geological Section: Beverley Beverley Alpha Beta Gamma 9
  • 11. Transport • Channelized flow of U-bearing groundwater from weathering granite blocks into Frome Basin – Meteoric → groundwater – Sandstone layers/lenses and paleochannels • Time-dependence of hydrogeological flow regime in geological scale – Active tectonics – Stress system according to orientation of Flinders Ranges and known faults – Seismicity/seismic surveys → transpressive tectonic regime/ tectonic constraints • Primary groundwater flow versus secondary flowpaths – Role of faults 11
  • 12. Trap: Single-fluid versus Two-fluid Models • Single-fluid model – In-situ reductants immobilize U in aquifer – In-situ reductants from microbial, anaerobic decomposition of organic matter • Two-fluid model – Upflow of reductants into aquifer from underlying organic- rich formations, thus, immobilizing U from the groundwater Jaireth et al., 2008 12
  • 13. Reduction Processes – Organic Matter Decomposition under Anaerobic Conditions (Schematic) Fe-oxide reducing bacteria Fe2+ FeOOH Organic material Sulfate reducing bacteria Acetate Formate H2S H2 SO42- CO2 Methanogenic bacteria Fermenting bacteria CH4 + CO2 CH4 + H2O Re-drawn from Appelo/Postma 13
  • 14. Reference: Sediment REDOX – GA Study EL 5/6 GA18232 14
  • 15. In-situ reductants or reductant REDOX Mapping – EL 5/6 transport via faults? Long transport pathways from source rock to trapping (Beverley within Namba) Short transport pathways (→ Range Front Same patterns observed deposits) at Beverley/Four Mile GA18232 15
  • 16. Towards Recognition Criteria (Programmatic) • Conventional geophysical surveying – Including gravimetrics, magnetics, airborne electromagnetics, induced polarization, magnetotellurics, and radiometrics – From data it is hard/impossible to identify recognition criteria in a regional scale • New high-resolution seismic surveys (2D): – Throughout Paralana Lease (Beverley) and in the Range Front area (including Four Mile) – total of ~500 line km – Targets: sandy formations (including paleachannels) and faults • In progress: – Improved migration procedures for higher resolution/ significance – Joint inversion (seismic + CSAMT/gravimetrics) – Advanced seismic analysis including attribute analysis and AVO (towards rock physics) • Outlook: 3D seismic surveying: – Much better significance for (bending) channel structures 16
  • 17. 3D Paralana Model with Beverley Deposit (2D Seismic) Flinders Ranges t ul Fa na ta on Po Top of: Namba Eyre Bulldog Shale Cadna-owie Basement 17
  • 18. 3D Paralana Model with Beverley Deposit (2D Seismic) 18
  • 19. 3D Beverley (2D Seismic – Line 2500) Beverley Central 19
  • 20. 3D Beverley (2D Seismic Line 2500 + Drill Logs) Beverley Central sand channel 20
  • 21. 3D Beverley (2D Seismic Line 2500 + Drill Logs + Ore) Beverley Central ore body 21
  • 22. 3D Beverley (from 2D Seismic) + Ore Bodies Top of Bulldog Shale Top of Eyre Formation Line 2500 Beverley deposit Poontana Fault 22
  • 23. Range Front Deposit Example: Four Mile East Top of: Basement 23
  • 24. Range Front Deposit Example: Four Mile East View from Flinders Ranges into the Basin Silcrete on top of sand body in Eyre Formation (chemical wheathering during high-T climate period) Sandy Eyre Formation Top of basement Faults 24
  • 25. Range Front Deposit Example: Four Mile East View from Flinders Ranges into the Basin Silcrete on top of sand body in Eyre Formation (chemical wheathering during high-T climate period U mineralization in Eyre Formation Top of basement Faults 25
  • 26. Ranges Front Stratigraphy (Example: Four Mile East) Extending to Beverley North 26
  • 27. Ranges Front Stratigraphy (Example: Four Mile East) Max. Boun- thick- System Strata ding ness Lithofacies tracks Age surface [m] Alluvial fan-braided channel conglomerates with fine floodplain/ 50 Willwortina Will lacustrine muds; several coarsening upwards cycles; incised base; Tectonic Pliocene hematitic Alluvial fan-fluvial conglomerates and sands/multiples fine upward Late 125 Namba Namb cycles; disrupted floodplain muds (‘injection flames’); highly incised Tectonic Oligocene – + aeolian contributions base; kaolinitic Late Miocene Fluvio-lacustrine; channel sands/conglomerates, fine-grained ‘glass’ Basin Eyre 4/5 sands, thicker lucustrine muds with turbiditic sands, abundant mud Late HST ‘rip up’ clasts; minor lignitic debris Multi-storey (amalgamated) braided channel sands/conglomerates; Eyre 3 12 Early HST floodplain muds; minor lignitic debris Early – Middle Eyre Meandering channel sands with minor conglomerates; floodplain Eocene Lake Eyre (Frome Embayment) Eyre 2 20 sands/silt/muds; abundant lignitic debris/some thin coals (zone of TST maximum flooding/accomodation) Multi-storey (amalgamated) braided channel sands/conglomerates; Eyre 1 8 LST minor lignitic debris; highly incised base ‘Bulldog shale facies’: carbonaceous shales/silts, fine sands and Bull 4 5 TST Early Albian* ‘pebbly mudstone’; abundant bioturbation Bull 3 0 Grain flow sands/turbidites (present at Four Mile West only) Late Aptian* Bull 2 5 Sandy diamictite with dropstones Glacial *Microplanctonic age extrapolated from Four Mile Bull 1 20 Basal conglomerates (clast-supported ‘cabblestones’) West 27
  • 28. Rollfront Morphology at Four Mile East (Area 1) UB LB UB LB 50m Uranium deposition controlled by both REDOX and (heterogeneous) permeability within host formation (aquifer) → recognition criteria on local scale to follow up rollfronts within drilling programs Open pit (Texas) 28
  • 29. Beverley North Roll Fronts – Morphology 29 29
  • 30. Core Samples Four Mile East (Area 1) 30
  • 31. Four Mile East Details – Area 1 (Upper Rollfront) % of ore zone in pyrite (organic carbon – more scattered) 31
  • 32. Four Mile East Details – Area 1 (Upper Rollfront) Disequilibrium DEF – pU3O8/eU3O8 (U grade/γ activity) 32
  • 33. Four Mile East Details – Area 1 (Upper Rollfront) % of ore zone in clays 33
  • 34. Four Mile East Details – Area 1 (Upper Rollfront) Host formation flow rates 34
  • 35. Conclusion: ISR Feasibility • Data matrix for assessment on the basis of – (Real) Uranium GT (grade/thickness) – Permeability (flow rates) – Mineralogy/geochemistry (in particular, abundance of reductants including organics and pyrite) • Reactive-transport model simulation of ISR performance – Forecast of wellfield performance + experience – Adjustment of ISR chemistry/optimization → To be presented at the IAEA Technical Meeting/ Consultants’ Meeting on ISL Technology, Nov 19-23, 2012 35