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Sandstone Type Uranium Mineralisation in Gondwana
           Sediments of Central India:
         A case study from Satpura Basin




                         By
          Amit Majumdar, Scientific Officer-H
             Atomic Minerals Directorate
            Department of Atomic Energy
INTRODUCTION

 Gondwana sediments are deposited worldwide in dominantly
  Rift-related basins during Permo–Triassic, Jurassic and
  Cretaceous Period.

 These fluvio-deltaic sediments are known for Sandstone type
  Uranium Mineralisation and important among them are Karoo
  Basin, S. Africa and Parana Basin S. America.

 In India, Gondwana sediments are widespread and found in
  intracratonic rift related basins represented by a mosaic of
  graben, half graben and tilted blocks complicated by
  intersection and termination of normal faults .

 Among Indian Gondwana Basins, ~14700 sq km large and
  spindle shaped Satpura – Gondwana Basin (200km x 60km) in
  Central India - Potential for Uranium Mineralisation.
GLOBAL DISTRIBUTION OF URANIUM MINERALISATION IN
                  GONDWANA SEDIMENTS
                     Congo
           Gaban                  Rukwa
                                                               Satpura        Sonvalley
                                                     Tanzana
                                                                                           Damodar valley


                                                                                                                Carnarvin
                                                         Luano           Godavari
    Paraniba                                                                                         Perth
                                                                                                                        Canning



  Parana                                         Mocambique                                                          Ngalia
                                                     Limpopo
                                                Springbok Flats

  Peru Bolivia                                 Main Karoo
                                                                                          Victoria
                                  Botswana


                                              Central Patagonia
           Paganzo
                                                                                                                 Copper Galilee


  Callingasta
                                                                   Trans Antarctic                          Sydney
  Uspallata
                        Neuquen    South Patagonia




Location of uranium mineralization in Gondwana rocks of Gondwana land
GLOBAL CORRELATION OF GONDWANA FORMATIONS AND URANIUM DEPOSITS

Period           South Africa       South            Eastern             Narmada
                                    America          India               Valley, India
Jurassic         Elliot              Santamaria                          Jabalpur Fm.
                 Molteno                             Panchet
Lower Triassic                                       Formation
                                                                         Bagra
                 Beaufort           Estrata nova     Raniganj            Conglomerate
                 Group                               Formation
                                                     (Coal
                                                                         Denwa Fm.
                                                     Measures)

Permian                                                                  Pachmarhi
                 Ecca Series                                             Fm.
                                    Irati Shales
                 (CoalMeasu.)
                                                     Barakar             Bijori Fm
                                    Tarat Fm.,       Formation           (Up. Permian)
                 Dwyaka Shale       Itarare Series   (Coal
                                                     Measures)           Motur Fm.
Carboniferous    Dwyaka Tillite     Guezauman        Karharbari          Barakar Fm.
                                                     Fm                  (L. Permian)
                                    Tillite
                                    ~~~Unc~~~        Talchir Tillite     Talchir Tillite
                                    Tupe Tillite

                 ~~~Unc~~~~         ~~~Unc~~~        ~~~Unc~~~           ~~~~Unc~~~~
Archaean         Basement           Basement         Basement            Basement

                 Uranium Deposits                    Significant Anomalies
TYPES OF URANIUM MINERALIZATION IN
               GONDWANA BASINS
 Sand stone hosted Uranium Mineralisation
  e.g. Sierra Pintada, Argentina; Figueira, Brazil;
       Akouta, South Africa; Arlit, Niger etc.

 Coal hosted Uranium Mineralisation
  e.g. Springblock Basin, South Africa

 Pelite Hosted Uranium Mineralisation
  e.g. Gregorio Formation, Uruguay

 Vein type Uranium Mineralisation
  e.g. Rincon del Atuel, Argentina
DIAGONOSTIC CHARACTERISTICS OF SANDSTONE TYPE OF U DEPOSITS


1. Provenance            :       Granitic rocks / volcanic ash (tuffaceous)
2. Depositional Envn.    :       Fluvial / marginal marine
3. Host rock             :       Silurian or younger in age.
4. Host rock having porosity and permeability.
5. Host rock having low angle basin ward dip
6. Presence of carbonaceous / humic material.
7. Low temperature ground water and meteoric water are the mineralising
    solution.
8. Cover rocks.
METALLOGENETIC ASPECTS

The sedimentary uranium enrichment cycle consists of three stages
 A. Leaching of uranium from provenance/source.
        1. SOURCE
            - Granite / Volcanic ash
        2. WEATHERING

 B. Transportation of uranium to an accumulation site.
         1. TRANSPORTATION IN SURFACE WATER
             - As dissolved uranyl dicarbonate complex
             - Attached to dissolved or colloidal organic acids (humates)
             - In original mineral as bed-load
        2. IN GROUND WATER
            - In areas of tectonic activity, relief & dissection
            - Water expulsion from burial compaction

 C. Concentration of uranium.
        1. DIFFERENT DEPOSITIONAL ENVIRONMENTS
        2. PRECIPITATION
DEPOSITIONAL ENVIRONMENT
Most sandstone hosted epigenetic mineralisation occurs primarily within facies of
terrestrial system i.e in spectrum of fluvial and alluvial fans; while secondary but
                 important setting is marginal marine/Shore zone.
                                      SOURCE AREA

                                                      FAN
                                                      •Unconfined flow
                         Fan Delta                    • gravity mass transport
                                                      • confine flow
                                      Braid
                                      Delta
    LACUSTRINE                 Lacustrine
    Geochemical isolation        Delta    FLUVIAL               EOLIAN
    •Water mass stratification       •Channelized flow      •Unconfined flow
    •Instability


                                                            SHORE ZONE
                                                              •Waves
                                                              •Tides
                                                              •Storm processes
                                        DELTA               •    SHELF
                                     Transitional confine   •Unconfined flow
                                     To unconfined flow     •Strom processes
                                                            •waves
                                 SLOPE AND
                               BASE -OF-SLOPE                  The eight terrigenous clastic
                                                               depositional system and the
                             Gavity mass transport
                                                               sediment transport pathways
                            ± boundary confined flow
                                                               that commonly connect them.
TABULAR SANDSTONE TYPE URANIUM DEPOSIT

Provenance          : Granite / Basement gneises            When U+6 in ground water comes in contact with carb.
Host               : Sst. with reducing environment         matter in sediments, it is reduced to U +4 and gets
Transporting agent : Ground water                           precipitated to form uranium deposit

                           Cretaceous fluvial     Uranium deposit                       Tertiary sediments
                               sediments
                     U+6

  U+4
                             U+6
                                                                      Carb. matter
          U+4
                                                                U+6                         U+6
                                                           U+6 readily form soluble salts, gets dissolved and
                                                                moves downdip along with ground water
           U+4      O         U+6
                 oxidation                                                                        U+4
                                    U+6
  U+4                                           U+4    Granite gneiss with uranium
        Granite with labile uranium
FAVOURABILITY FACTORS FOR FORMATION OF SEDIMENTARY TYPE URANIUM
                             DEPOSITS, INDIA
      Favourability Criteria                Gondwana                  Siwalik            Mahadek (Meghalaya)

Palaeogeography: Stable platform                 P                       P                        P
or foreland interior basin; shelf
margin
Provenance: Crystalline of silicic              P                        P                        P
magmatic or tuffaceous                      (granites)          (Central Himalayan      (Precambrian gneises &
sediments                                                          Crystallines)        Neoproterozoic Granite)

Palaeoclimate: Humid followed by                 P                       P                        P
arid-semiarid
Sedimentation: Fluvial / lacustrine              P                       P                        P
/ marginal marine

Stratigraphic traps:Alteration of                P                       P                        P
coarse and fine grained                  (Intermittent clay    (Upp. & middle Siwalik    (Palaeo-topography)
continental fluvial sediments/                horizon)               boundary)
permeability barrier/topographic
depression

Chemical traps: Arkosic                          P                       P                        P
sediments with carbonaceous
matter/pyrite.
Protective cover                                 P             P (only in few cases)              P
Age: Mostly Carboniferous to          Upper carboniferous to      Middle Miocene-         Upper Cretaceous
Tertiary                                Lower Cretaceous             Pliocene


P- Present
68° 00’                  76° 00’                        84° 00’                  92° 00’

                                                             Distribution of Indian
                                                             Gondwana Sediments
                            ● Srinagar
32°                               ● Chamba                                                                    32°
00’                                                                    0    200    400 km                     00’

                                          ●
                                     Shimla

                                     Delhi
                                      ■                          ●              Lochi                                 Total Area of Indian Gondwanas
                                                            Gosainthan      ●●
                                                                   Mt. Everest ● Sikkim
                Mesozoic-Tertiary                                                                  ▲
                Sediment-Filled                                                          Gondwana rocks
                Cambey Graben
                                                             Damadar-Koel
                                                                                         In frontal zone of                Individual Basins Area
                                                             Gondwana                                         24°
32°                                               S. Rewa    Basin
                                                                                         E. Himalaya
                                                                                                              00’
                                                                                                                                        (Sq km)
00’     Bhuj          Late Gondwana
          ●           Continental
                                                  Basin
                                                                   ▲
                      Sediments                             ▲       Mahanadi Calcutta                               Pranhita-Godavari    = 29,000
                                        ▲●                                     ■
                               Satpura ▲                                                                            Satpura Basin       = 14,700
                                                                    Gondwana
                                                                    Basin                 Golsi-Malda
                               Basin      ▲                                               Rajmahal                  Bengal & Bihar       = 13,000
                                   Wardha ●
                                   Basin    ●
                                                                             Athgarh      Gondwana Basin            Upper Mahanadi = 8,771
                                                                             Trough
                  ■
                      Mumbai
                                                     Godawari                                                       Eastern Son Valley   = 5,002
                                                   ▲ Basin
                                                   ●
16°                                           ■                                                               16°
00’
                                      Hyderabad         ●    Godawari-Krishna                                 00’
                                                             Trough
                                                                           GONDWANA IN LESSER
                                          Palar                            HIMALAYA & TETHYAN DOMAIN
                                          Trough ■ Chennai
                                                                            EASTERN COASTAL TROUGH
                                                                            PENINSULAR GONDWANA BASIN
                                     Cauvery
                                     Trough                         ▲      URANIUM ANOMALIES
                                                                    ●      THORIUM ANOMALIES
8°                                                                                                            8°
00’                                                                                                           00’
                           76° 00’                              84° 00’                          92° 00’
SOME SALIANT POINTS
 The Satpura Basin, located in the central part of Indian subcontinent, is
  the westernmost exposed Gondwana basin.

 This basin is limited to the north by Son-Narmada geo fractures, while the
  southern limit is marked by the faulted contact with Betul–Chhindwara
  plateau.

 It is an intra cratonic basin occurring at the junction of two tectonic trends
  namely sub latitudinal ENE-WSW Satpura trend and NW-SE Godavari
  grain.

 Structurally, basin can be divided into Denwa sub-basin in the north and
  Pench Kanhan sub basin in the south. Malni–Tamia high separates these
  two basins.

 The Betul–Chhindwara Crystallines form basement for Gondwanas and
  represent a conspicuous lithotectonic unit of the Central Indian Tectonic
  Zone (CITZ). These are traversed by several ENE –WSW trending ductile
  shear zones.
GEOLOGY AND PALAEOCURRENT MAP OF SATPURA GONDWANA BASIN
                                                                                                    NORTH
                                                 0       15 km



                                                                  KHARATORIA
                                               MATKULI
                                      NANNER         JHIRPA   BANDHI



                                                 PACHMARHI
                                    RAMPUR


                            POLAPATHAR

                                                                 TAMIYA
                      GHORADONGRI



INDEX                                                                  PARASIA

DECCAN TRAPS
JABALPUR FORMATION
                               UPPER
DENWA FORMATION                GONDWANA
PACHMARHI FORMATION                                           RADIOACTIVITY OCCURRENCE
                                                              MAJOR FAULT
BIJORI FORMATION
MOTUR FORMATION               LOWER                           MINOR FAULT
BARAKAR FORMATION             GONDWANA                        PALAEOCURRENT DIRECTION
TALCHIR FORMATION

BASEMENT
                                                              (Geology after Peter et. al., 2001)
GENERALISED STRATIGRAPHIC SUCCESSION
                                                    Thickness
          Age                     Formation                               Litho-unit
                                                       (m)
                           Trap                                 Basalt
Eocene to                  Lameta (Infratrappean)               Calcareous Sandstone,
                                                    --          Mudstone & Conglomerate
Up. Cretaceous

                             ~~~~~~~~~~ Unconformity ~~~~~~~~~~
Early to Middle                                                 Calcareous Sandstone and
                            G         Jabalpur      ~250
Cretaceous                                                      Limestone
Late Jurassic to Early      O     U
                            N                                   Coarse grained sandstone and
Cretaceous                        P   Bagra         250 - 500
                            D                                   conglomerates
                                  P
                            W     E                           Sandstone – Mudstone
Early to Middle Triassic    A         Denwa         300-600
                                  R                           alternations
                            N                                 Coarse grained and pebbly
Early Triassic              A         Pachmarhi  500 - 800
                                                              sandstones
                                      ~~~~~~~~~~ Disconformity ~~~~~~~~~~
                            S
                            U                                 Sandstones and Carbonaceous
Late Permian                          Bijori     450- 2000
                            P                                 Shale
Middle Permian              E    L    Motur         400-750     Sandstone and Red Clay
                            R    O
                            G    W                              Sandstones, Carbonaceous
Early Permian               R         Barakar       120-500
                                 E                              shale and Coal beds
                            O    R
                            U                                   Polymictic boulder
Late Carboniferous to
                            P         Talchir       120 - 700   conglomerate, sandstones and
Early Permian
                                                                olive green shale
                             ~~~~~~~~~~ Unconformity ~~~~~~~~~~
Precambrian                        Betul–Chhindwara Crystalline Complex (Basement)
Basement Characteristics
 Presence of granite gneiss, intrusive granites
 Presence of recycled metasediments, tuffs
 Average Radioelement content
       Metasediments : U3O8 3.2, ThO2 17 ppm (n=30)
       Granite        : U3O8 7.9, ThO2 50 ppm (n=47)
 Uranium Anomalies within Basement
 Associated with ENE-WSW trending fractures containing
  Cherty cataclasites
 Radioactive phases: Collophane, allanite, zircon.
 Host Rock Characteristics: Rich in P2O5 and CaO with
  positive correlation with U content.
 U3O8 values upto 0.31% without ThO2 (n=98)
MOTUR FORMATION
GEOLOGICAL MAP OF POLAPATHAR-BHOUNRA AREA
       SHOWING URANIUM OCCURENCES AND PALAEOCURRENT TRENDS

                                                                        0                     10km
78°45’10”                                                                          5

                                                                                 Scale

                               Suktawa R

                                  ▲                            78°00’               LEGEND
                                            ▲
                          ■Jamundol
                                                                                       Palaeocurrent Direction
                            ▲                ■ Mulwarpura
                                           ▲          ▲
                                                                             •         Uranium Occurrences

                                                                             ▲         Thorium Anomalies
                   Mansingpura    •
            ••   •• ■ Keolari ■
                   •
                  ••               • •
                                ■ Bodipani •
                                                                                    Pachmarhi Clay Facies
                       •     •
                                      ■Polapathar
                        ■ Chirmatekri        •                                      Bijori Formation
                                        ■
78°45’10”                             Bhawra                   78°00’                  Motur Formation

Uranium Minerals Pitchblende, Brannerite, coffinite Hosted by Arenite

Mansingpura                  : U3O8 0.01-0.34%, ThO2 0.002-0.04%. (n=11)
Polapathar                   : U3O8 0.01-0.084%, ThO2 <0.005-0.022%.(n=7).
Chirmatekri                  : U3O8 0.007%, ThO2 nil. (n=2).
Variation in Paleocurrent direction in Motur Formation
DEPOSITIONAL ENVIRONMENT (MOTURS)
                                      Claystone     Sandstone           PASS
     90


                  Semi- humid

     80

                                                           Semi- arid

              H U M I D
     70                                                                  Arid
SiO2 %




                                    A R I D

     60


                                              (After Suttner et al. 1986)

     50
          0         5           10      15      20               25             30
                                Al2O3+K2O+Na2O (%)

         Semi-arid to Semi-humid depositional palaeo-climate indicates
                  low to moderate order of Chemical Maturity
PROVENANCE STUDY (MOTURS)
                                           8
                                                                          PASS           Claystone         Sandstone
                                           6                                                 Quartzose
                                                                                             sedimentary
           Discriminant Function 2 ( f2)   4                                                 provenance

                                           2
                                                       Mafic
                                           0
                                                       Igneous
                                                       provenance                                      Felsic
                                           -2                                                          Igneous
                                                                                                       provenance
                                           -4                       Intermediate
                                                                    Igneous
                                                                    provenance
                                           -6
                                                                                     (After Roser and Krosch
                                                                                     1988)
                                           -8
                                                -8.0     -6.0   -4.0    -2.0       0.0     2.0       4.0     6.0       8.0
                                                                    Discriminant Function 1 (f1)

Discriminant function coefficients using TiO2, Al2O3, FeO(t), MgO, Na2O and
K2O i. e., F1 and F2 scores exhibit predominance of felsic igneous provenance,
along with little contribution from Quartzose Sedimentary and intermediate
igneous Provenance is supported by the presence of Granites, Metasediments in
Betul Complex. This is further substantiated by Al2O3/TiO2 ratio (8.49 to 70.11).
BH No:PM-22          BH No:PM-28        BH No: PM-29



                                                             INDEX
                                                                     Altered brown
                                                                     sandstone

                                                                     Violet clay stone


                                                                     Grey clayey sandstone


       0.029%eU3O8                                                   Light grey bleached
       X2.30m                                                        sandstone
                                                                     Sandstone with black
                                                                     carb.(?) shale & pyrite

                                                                     Grey sandstone with
                                                                     shale fragments
                          0.041%eU3O8
                          X2.70m


                                               0.011%eU3O8
                                               X0.40m




                                               0.045%eU3O8
                                               X3.00m
Lithology Colour   Grainsize
Depth                       S F M C G
  0m                                          Lithology Index
                                                    Overburden
                                                                                         Depth vs. Ra eU3O8 & ThO2
                                                    Sandstone                                 for core sample
                                                    Claystone/mudstone
  20m
                                              Colour Index
                                                                                                                Values in ppm
                                                    Brownish Yellow                                         0      100      200            300
                                                    Buff                                              175
  40m                                               Brown/Chocolate brown
                                                                                                                        Ra eU3O8
                                                    Dark Grey
                                                    Grey
                                                                                                      176               ThO2
                                                    Light Grey/Dirty white
  60m                                                                                                 177
                                              Grainsize Index
                                                S   Silt/Clay                                                    Porosity 15%
                                                F
                                                    Fine                                              178        by volume
                                                M   Medium
  80m
                                                C   Coarse
                                                                                                      179
                                                G   Very Coarse/Grit


  100m
                                                                                                      180




                                                                                          Depth (m)
                                                                                                      181

  120m
                                                                                                      182                       Porosity
                                                                                                                                11% by
                                             LITHOLOG OF BOREHOLE PM-69                               183                       volume
  140m                                   Polapathar-Mansingpur Area, Betul Dist., M.P.

                                                                                                      184

  160m
                                                                                                                   Porosity
                                                                                                      185
                                                                                                                   13% volume

                                                                                                      186
  180m
                                        U-Mineralisation (1.90m x 0.014%)
                                                                                                      187


  200m                                                                                                188
SOURCE OF URANIUM FOR SATPURA GONDWANA SEDIMENTS

 Satpura Gondwana Basin is surrounded by Granites and
  Metasediments of Betul – Chhindwara Crystalline Complex and
  acted as provenance for the supply of detritus material to the
  basin.

 Fertile basement - Metasediments of Betul crystalline complex
  contains an average content of 3.2 ppm U3O8 and 17 ppm ThO2 17
  ppm and granite and gneisses contain 7.9 ppm U3O8 and 50ppm
  ThO2.

 Uraninite, Brannerite, Davidite, Monazite, Zircon, Apatite, Sphene,
  Pyrochlore and Betafite are present in the basement.

 Presence of Acid Volcanics in the Provenance and Volcaniclastic
  Material in Gondwana Sediments are also one of the important
  source of Uranium in the system.

 Sediment of Lower Gondwana contains higher intrinsic uranium
  content
CONTROLS OF URANIUM MINERALISATION

 Eh-pH condition of the depositional environment.

 Change in the Palaeocurrent direction.

 Alternate sequence of sandstone and claystone/shale with
  shallow dip of Formation.

 Porosity and permeability of host rock.

 Presence of basic dykes/sills leading to compaction of
  sediments and expulsion of connate water rich in dissolved
  uranium, as well as act as barrier for the flow of uraniferous
  groundwater.

 Presence of pyrite and carbonaceous matter as reductant in the
  system.
FAVOURABILITY FACTORS FOR URANIUM MINERALISATION IN MOTUR
           FORMATION OF SATPURA GONDWANA BASIN

 Highly Fertile Palaeoproterozoic Basement–cum-Provenance with Labile
  Uranium
 Presence of Acid Effusives in the Provenance
 Thick pile of Gondwana Sediments with alternating sequence of arenaceous
  and argillaceous beds in Rift related Basin
 Porous and Permeable Feldspathic to Sub-feldspathic Arenites with
  volcaniclastic material as well as presence of Oxidised and Reduced
  Arenites
 Pre- and Post-depositional reactivations and tectonic deformations
  providing channel ways for hydrothermal solution movements
 Enhanced Thermal Gradient by Profuse Mafic/Basic intrusives
 Presence of suitable reductants such as Carbonaceous Matter, Pyrite and
  Iron in sediments etc. to Fix & Precipitate U
 Availability of suitable environment and locales such as Redox interfaces in
  Unconformity Planes and Fracture Zones for Fixation of Uranium
            INDICATES HIGH POTENTIAL OF SATPURA GONDWANA BASIN FOR
                   SANDSTONE-HOSTED D URANIUM MINERALISATION
CONCLUSIONS
GEOLOGY OF THE SATPURA GONDWANA BASIN
 Satpura Gondwana basin (14700 sq km) is located in the environs of Son
  – Narmada Rift Zone, which is an important Structural Domain in Central
  India and known for Base Metal, Precious Metal, Radioelement and REE
  mineralisation associated with various lithounits located in its vicinity.
 Exposes a thick pile of Gondwana Sediments in this Rift related Basin
  over Palaeoproterozoic Basement Rocks.
 Gondwana sediments exhibit large facies variation right from Glacial
  Tillites (Talchir) to alternate sequences of Arenaceous and Argillaceous
  rocks signifying the change in depositional and tectonic environment.
 Satpura Gondwana Basin has various signatures of Pre- and Post-
  depositional Tectonic activity and Reactivation viz. Faults/ Fractures,
  profuse emplacement of Basic Intrusives and Effusives etc.
 Out of all the Formation of Lower and Upper Gondwana; Motur Formation
  of Lower Gondwana seems to be the most promising horizon.
Thank You

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02 iaea 2012- a majumdar

  • 1. Sandstone Type Uranium Mineralisation in Gondwana Sediments of Central India: A case study from Satpura Basin By Amit Majumdar, Scientific Officer-H Atomic Minerals Directorate Department of Atomic Energy
  • 2. INTRODUCTION  Gondwana sediments are deposited worldwide in dominantly Rift-related basins during Permo–Triassic, Jurassic and Cretaceous Period.  These fluvio-deltaic sediments are known for Sandstone type Uranium Mineralisation and important among them are Karoo Basin, S. Africa and Parana Basin S. America.  In India, Gondwana sediments are widespread and found in intracratonic rift related basins represented by a mosaic of graben, half graben and tilted blocks complicated by intersection and termination of normal faults .  Among Indian Gondwana Basins, ~14700 sq km large and spindle shaped Satpura – Gondwana Basin (200km x 60km) in Central India - Potential for Uranium Mineralisation.
  • 3. GLOBAL DISTRIBUTION OF URANIUM MINERALISATION IN GONDWANA SEDIMENTS Congo Gaban Rukwa Satpura Sonvalley Tanzana Damodar valley Carnarvin Luano Godavari Paraniba Perth Canning Parana Mocambique Ngalia Limpopo Springbok Flats Peru Bolivia Main Karoo Victoria Botswana Central Patagonia Paganzo Copper Galilee Callingasta Trans Antarctic Sydney Uspallata Neuquen South Patagonia Location of uranium mineralization in Gondwana rocks of Gondwana land
  • 4. GLOBAL CORRELATION OF GONDWANA FORMATIONS AND URANIUM DEPOSITS Period South Africa South Eastern Narmada America India Valley, India Jurassic Elliot Santamaria Jabalpur Fm. Molteno Panchet Lower Triassic Formation Bagra Beaufort Estrata nova Raniganj Conglomerate Group Formation (Coal Denwa Fm. Measures) Permian Pachmarhi Ecca Series Fm. Irati Shales (CoalMeasu.) Barakar Bijori Fm Tarat Fm., Formation (Up. Permian) Dwyaka Shale Itarare Series (Coal Measures) Motur Fm. Carboniferous Dwyaka Tillite Guezauman Karharbari Barakar Fm. Fm (L. Permian) Tillite ~~~Unc~~~ Talchir Tillite Talchir Tillite Tupe Tillite ~~~Unc~~~~ ~~~Unc~~~ ~~~Unc~~~ ~~~~Unc~~~~ Archaean Basement Basement Basement Basement Uranium Deposits Significant Anomalies
  • 5. TYPES OF URANIUM MINERALIZATION IN GONDWANA BASINS  Sand stone hosted Uranium Mineralisation e.g. Sierra Pintada, Argentina; Figueira, Brazil; Akouta, South Africa; Arlit, Niger etc.  Coal hosted Uranium Mineralisation e.g. Springblock Basin, South Africa  Pelite Hosted Uranium Mineralisation e.g. Gregorio Formation, Uruguay  Vein type Uranium Mineralisation e.g. Rincon del Atuel, Argentina
  • 6. DIAGONOSTIC CHARACTERISTICS OF SANDSTONE TYPE OF U DEPOSITS 1. Provenance : Granitic rocks / volcanic ash (tuffaceous) 2. Depositional Envn. : Fluvial / marginal marine 3. Host rock : Silurian or younger in age. 4. Host rock having porosity and permeability. 5. Host rock having low angle basin ward dip 6. Presence of carbonaceous / humic material. 7. Low temperature ground water and meteoric water are the mineralising solution. 8. Cover rocks.
  • 7. METALLOGENETIC ASPECTS The sedimentary uranium enrichment cycle consists of three stages A. Leaching of uranium from provenance/source. 1. SOURCE - Granite / Volcanic ash 2. WEATHERING B. Transportation of uranium to an accumulation site. 1. TRANSPORTATION IN SURFACE WATER - As dissolved uranyl dicarbonate complex - Attached to dissolved or colloidal organic acids (humates) - In original mineral as bed-load 2. IN GROUND WATER - In areas of tectonic activity, relief & dissection - Water expulsion from burial compaction C. Concentration of uranium. 1. DIFFERENT DEPOSITIONAL ENVIRONMENTS 2. PRECIPITATION
  • 8. DEPOSITIONAL ENVIRONMENT Most sandstone hosted epigenetic mineralisation occurs primarily within facies of terrestrial system i.e in spectrum of fluvial and alluvial fans; while secondary but important setting is marginal marine/Shore zone. SOURCE AREA FAN •Unconfined flow Fan Delta • gravity mass transport • confine flow Braid Delta LACUSTRINE Lacustrine Geochemical isolation Delta FLUVIAL EOLIAN •Water mass stratification •Channelized flow •Unconfined flow •Instability SHORE ZONE •Waves •Tides •Storm processes DELTA • SHELF Transitional confine •Unconfined flow To unconfined flow •Strom processes •waves SLOPE AND BASE -OF-SLOPE The eight terrigenous clastic depositional system and the Gavity mass transport sediment transport pathways ± boundary confined flow that commonly connect them.
  • 9. TABULAR SANDSTONE TYPE URANIUM DEPOSIT Provenance : Granite / Basement gneises When U+6 in ground water comes in contact with carb. Host : Sst. with reducing environment matter in sediments, it is reduced to U +4 and gets Transporting agent : Ground water precipitated to form uranium deposit Cretaceous fluvial Uranium deposit Tertiary sediments sediments U+6 U+4 U+6 Carb. matter U+4 U+6 U+6 U+6 readily form soluble salts, gets dissolved and moves downdip along with ground water U+4 O U+6 oxidation U+4 U+6 U+4 U+4 Granite gneiss with uranium Granite with labile uranium
  • 10.
  • 11. FAVOURABILITY FACTORS FOR FORMATION OF SEDIMENTARY TYPE URANIUM DEPOSITS, INDIA Favourability Criteria Gondwana Siwalik Mahadek (Meghalaya) Palaeogeography: Stable platform P P P or foreland interior basin; shelf margin Provenance: Crystalline of silicic P P P magmatic or tuffaceous (granites) (Central Himalayan (Precambrian gneises & sediments Crystallines) Neoproterozoic Granite) Palaeoclimate: Humid followed by P P P arid-semiarid Sedimentation: Fluvial / lacustrine P P P / marginal marine Stratigraphic traps:Alteration of P P P coarse and fine grained (Intermittent clay (Upp. & middle Siwalik (Palaeo-topography) continental fluvial sediments/ horizon) boundary) permeability barrier/topographic depression Chemical traps: Arkosic P P P sediments with carbonaceous matter/pyrite. Protective cover P P (only in few cases) P Age: Mostly Carboniferous to Upper carboniferous to Middle Miocene- Upper Cretaceous Tertiary Lower Cretaceous Pliocene P- Present
  • 12. 68° 00’ 76° 00’ 84° 00’ 92° 00’ Distribution of Indian Gondwana Sediments ● Srinagar 32° ● Chamba 32° 00’ 0 200 400 km 00’ ● Shimla Delhi ■ ● Lochi Total Area of Indian Gondwanas Gosainthan ●● Mt. Everest ● Sikkim Mesozoic-Tertiary ▲ Sediment-Filled Gondwana rocks Cambey Graben Damadar-Koel In frontal zone of Individual Basins Area Gondwana 24° 32° S. Rewa Basin E. Himalaya 00’ (Sq km) 00’ Bhuj Late Gondwana ● Continental Basin ▲ Sediments ▲ Mahanadi Calcutta Pranhita-Godavari = 29,000 ▲● ■ Satpura ▲ Satpura Basin = 14,700 Gondwana Basin Golsi-Malda Basin ▲ Rajmahal Bengal & Bihar = 13,000 Wardha ● Basin ● Athgarh Gondwana Basin Upper Mahanadi = 8,771 Trough ■ Mumbai Godawari Eastern Son Valley = 5,002 ▲ Basin ● 16° ■ 16° 00’ Hyderabad ● Godawari-Krishna 00’ Trough GONDWANA IN LESSER Palar HIMALAYA & TETHYAN DOMAIN Trough ■ Chennai EASTERN COASTAL TROUGH PENINSULAR GONDWANA BASIN Cauvery Trough ▲ URANIUM ANOMALIES ● THORIUM ANOMALIES 8° 8° 00’ 00’ 76° 00’ 84° 00’ 92° 00’
  • 13.
  • 14. SOME SALIANT POINTS  The Satpura Basin, located in the central part of Indian subcontinent, is the westernmost exposed Gondwana basin.  This basin is limited to the north by Son-Narmada geo fractures, while the southern limit is marked by the faulted contact with Betul–Chhindwara plateau.  It is an intra cratonic basin occurring at the junction of two tectonic trends namely sub latitudinal ENE-WSW Satpura trend and NW-SE Godavari grain.  Structurally, basin can be divided into Denwa sub-basin in the north and Pench Kanhan sub basin in the south. Malni–Tamia high separates these two basins.  The Betul–Chhindwara Crystallines form basement for Gondwanas and represent a conspicuous lithotectonic unit of the Central Indian Tectonic Zone (CITZ). These are traversed by several ENE –WSW trending ductile shear zones.
  • 15. GEOLOGY AND PALAEOCURRENT MAP OF SATPURA GONDWANA BASIN NORTH 0 15 km KHARATORIA MATKULI NANNER JHIRPA BANDHI PACHMARHI RAMPUR POLAPATHAR TAMIYA GHORADONGRI INDEX PARASIA DECCAN TRAPS JABALPUR FORMATION UPPER DENWA FORMATION GONDWANA PACHMARHI FORMATION RADIOACTIVITY OCCURRENCE MAJOR FAULT BIJORI FORMATION MOTUR FORMATION LOWER MINOR FAULT BARAKAR FORMATION GONDWANA PALAEOCURRENT DIRECTION TALCHIR FORMATION BASEMENT (Geology after Peter et. al., 2001)
  • 16. GENERALISED STRATIGRAPHIC SUCCESSION Thickness Age Formation Litho-unit (m) Trap Basalt Eocene to Lameta (Infratrappean) Calcareous Sandstone, -- Mudstone & Conglomerate Up. Cretaceous ~~~~~~~~~~ Unconformity ~~~~~~~~~~ Early to Middle Calcareous Sandstone and G Jabalpur ~250 Cretaceous Limestone Late Jurassic to Early O U N Coarse grained sandstone and Cretaceous P Bagra 250 - 500 D conglomerates P W E Sandstone – Mudstone Early to Middle Triassic A Denwa 300-600 R alternations N Coarse grained and pebbly Early Triassic A Pachmarhi 500 - 800 sandstones ~~~~~~~~~~ Disconformity ~~~~~~~~~~ S U Sandstones and Carbonaceous Late Permian Bijori 450- 2000 P Shale Middle Permian E L Motur 400-750 Sandstone and Red Clay R O G W Sandstones, Carbonaceous Early Permian R Barakar 120-500 E shale and Coal beds O R U Polymictic boulder Late Carboniferous to P Talchir 120 - 700 conglomerate, sandstones and Early Permian olive green shale ~~~~~~~~~~ Unconformity ~~~~~~~~~~ Precambrian Betul–Chhindwara Crystalline Complex (Basement)
  • 17. Basement Characteristics  Presence of granite gneiss, intrusive granites  Presence of recycled metasediments, tuffs  Average Radioelement content Metasediments : U3O8 3.2, ThO2 17 ppm (n=30) Granite : U3O8 7.9, ThO2 50 ppm (n=47)  Uranium Anomalies within Basement  Associated with ENE-WSW trending fractures containing Cherty cataclasites  Radioactive phases: Collophane, allanite, zircon.  Host Rock Characteristics: Rich in P2O5 and CaO with positive correlation with U content.  U3O8 values upto 0.31% without ThO2 (n=98)
  • 19. GEOLOGICAL MAP OF POLAPATHAR-BHOUNRA AREA SHOWING URANIUM OCCURENCES AND PALAEOCURRENT TRENDS 0 10km 78°45’10” 5 Scale Suktawa R ▲ 78°00’ LEGEND ▲ ■Jamundol Palaeocurrent Direction ▲ ■ Mulwarpura ▲ ▲ • Uranium Occurrences ▲ Thorium Anomalies Mansingpura • •• •• ■ Keolari ■ • •• • • ■ Bodipani • Pachmarhi Clay Facies • • ■Polapathar ■ Chirmatekri • Bijori Formation ■ 78°45’10” Bhawra 78°00’ Motur Formation Uranium Minerals Pitchblende, Brannerite, coffinite Hosted by Arenite Mansingpura : U3O8 0.01-0.34%, ThO2 0.002-0.04%. (n=11) Polapathar : U3O8 0.01-0.084%, ThO2 <0.005-0.022%.(n=7). Chirmatekri : U3O8 0.007%, ThO2 nil. (n=2).
  • 20. Variation in Paleocurrent direction in Motur Formation
  • 21. DEPOSITIONAL ENVIRONMENT (MOTURS) Claystone Sandstone PASS 90 Semi- humid 80 Semi- arid H U M I D 70 Arid SiO2 % A R I D 60 (After Suttner et al. 1986) 50 0 5 10 15 20 25 30 Al2O3+K2O+Na2O (%) Semi-arid to Semi-humid depositional palaeo-climate indicates low to moderate order of Chemical Maturity
  • 22. PROVENANCE STUDY (MOTURS) 8 PASS Claystone Sandstone 6 Quartzose sedimentary Discriminant Function 2 ( f2) 4 provenance 2 Mafic 0 Igneous provenance Felsic -2 Igneous provenance -4 Intermediate Igneous provenance -6 (After Roser and Krosch 1988) -8 -8.0 -6.0 -4.0 -2.0 0.0 2.0 4.0 6.0 8.0 Discriminant Function 1 (f1) Discriminant function coefficients using TiO2, Al2O3, FeO(t), MgO, Na2O and K2O i. e., F1 and F2 scores exhibit predominance of felsic igneous provenance, along with little contribution from Quartzose Sedimentary and intermediate igneous Provenance is supported by the presence of Granites, Metasediments in Betul Complex. This is further substantiated by Al2O3/TiO2 ratio (8.49 to 70.11).
  • 23. BH No:PM-22 BH No:PM-28 BH No: PM-29 INDEX Altered brown sandstone Violet clay stone Grey clayey sandstone 0.029%eU3O8 Light grey bleached X2.30m sandstone Sandstone with black carb.(?) shale & pyrite Grey sandstone with shale fragments 0.041%eU3O8 X2.70m 0.011%eU3O8 X0.40m 0.045%eU3O8 X3.00m
  • 24. Lithology Colour Grainsize Depth S F M C G 0m Lithology Index Overburden Depth vs. Ra eU3O8 & ThO2 Sandstone for core sample Claystone/mudstone 20m Colour Index Values in ppm Brownish Yellow 0 100 200 300 Buff 175 40m Brown/Chocolate brown Ra eU3O8 Dark Grey Grey 176 ThO2 Light Grey/Dirty white 60m 177 Grainsize Index S Silt/Clay Porosity 15% F Fine 178 by volume M Medium 80m C Coarse 179 G Very Coarse/Grit 100m 180 Depth (m) 181 120m 182 Porosity 11% by LITHOLOG OF BOREHOLE PM-69 183 volume 140m Polapathar-Mansingpur Area, Betul Dist., M.P. 184 160m Porosity 185 13% volume 186 180m U-Mineralisation (1.90m x 0.014%) 187 200m 188
  • 25.
  • 26. SOURCE OF URANIUM FOR SATPURA GONDWANA SEDIMENTS  Satpura Gondwana Basin is surrounded by Granites and Metasediments of Betul – Chhindwara Crystalline Complex and acted as provenance for the supply of detritus material to the basin.  Fertile basement - Metasediments of Betul crystalline complex contains an average content of 3.2 ppm U3O8 and 17 ppm ThO2 17 ppm and granite and gneisses contain 7.9 ppm U3O8 and 50ppm ThO2.  Uraninite, Brannerite, Davidite, Monazite, Zircon, Apatite, Sphene, Pyrochlore and Betafite are present in the basement.  Presence of Acid Volcanics in the Provenance and Volcaniclastic Material in Gondwana Sediments are also one of the important source of Uranium in the system.  Sediment of Lower Gondwana contains higher intrinsic uranium content
  • 27. CONTROLS OF URANIUM MINERALISATION  Eh-pH condition of the depositional environment.  Change in the Palaeocurrent direction.  Alternate sequence of sandstone and claystone/shale with shallow dip of Formation.  Porosity and permeability of host rock.  Presence of basic dykes/sills leading to compaction of sediments and expulsion of connate water rich in dissolved uranium, as well as act as barrier for the flow of uraniferous groundwater.  Presence of pyrite and carbonaceous matter as reductant in the system.
  • 28. FAVOURABILITY FACTORS FOR URANIUM MINERALISATION IN MOTUR FORMATION OF SATPURA GONDWANA BASIN  Highly Fertile Palaeoproterozoic Basement–cum-Provenance with Labile Uranium  Presence of Acid Effusives in the Provenance  Thick pile of Gondwana Sediments with alternating sequence of arenaceous and argillaceous beds in Rift related Basin  Porous and Permeable Feldspathic to Sub-feldspathic Arenites with volcaniclastic material as well as presence of Oxidised and Reduced Arenites  Pre- and Post-depositional reactivations and tectonic deformations providing channel ways for hydrothermal solution movements  Enhanced Thermal Gradient by Profuse Mafic/Basic intrusives  Presence of suitable reductants such as Carbonaceous Matter, Pyrite and Iron in sediments etc. to Fix & Precipitate U  Availability of suitable environment and locales such as Redox interfaces in Unconformity Planes and Fracture Zones for Fixation of Uranium INDICATES HIGH POTENTIAL OF SATPURA GONDWANA BASIN FOR SANDSTONE-HOSTED D URANIUM MINERALISATION
  • 29. CONCLUSIONS GEOLOGY OF THE SATPURA GONDWANA BASIN  Satpura Gondwana basin (14700 sq km) is located in the environs of Son – Narmada Rift Zone, which is an important Structural Domain in Central India and known for Base Metal, Precious Metal, Radioelement and REE mineralisation associated with various lithounits located in its vicinity.  Exposes a thick pile of Gondwana Sediments in this Rift related Basin over Palaeoproterozoic Basement Rocks.  Gondwana sediments exhibit large facies variation right from Glacial Tillites (Talchir) to alternate sequences of Arenaceous and Argillaceous rocks signifying the change in depositional and tectonic environment.  Satpura Gondwana Basin has various signatures of Pre- and Post- depositional Tectonic activity and Reactivation viz. Faults/ Fractures, profuse emplacement of Basic Intrusives and Effusives etc.  Out of all the Formation of Lower and Upper Gondwana; Motur Formation of Lower Gondwana seems to be the most promising horizon.