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2012 02 08 Polyscope General Speciality Polymers V3


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General presentation on Styrene Maleic Anhydride Copolymers.

General presentation on Styrene Maleic Anhydride Copolymers.

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  • 1. PolyscopeXIRAN® styrene maleic anhydride co-polymers 1
  • 2. Polyscope: about us Polyscope is the world’s leading producer and supplier of styrene maleic anhydride co-polymers. Polyscope offers the broadest styrene maleic co-polymer product portfolio for Engineering Plastics and Specialty Polymer applications under it’s trade name XIRAN ®. XIRAN ® is commercially available in varying maleic anhydride content in broad molecular weight range. Polyscope was founded in 2006 and headquartered in Geleen, the Netherlands. Currently employing 40 fte’s and growing and is supported by marketing & sales organisations in the USA, Europe and Asia-Pacific. Polyscope operates a polymerization production plant in Geleen. The XIRAN ® based compounds are produced on in the US and in the Netherlands with dedicated production lines. Polyscope serves a wide range of industries globally whereby the functions XIRAN ® differs per application. 2
  • 3. Polyscope: about us Geleen, The Netherlands Production Facility &Head Office
  • 4. Industries we serve:Engineering Plastics & Specialty PolymersIndustries examples but not limited to this
  • 5. XIRAN key properties Amorphous co-polymer Crystal clear / Transparent Rigid High Tg 120 - 175 °C  heat and dimension stability Reactivity of maleic anhydride groups enables chemical modification Non water soluble but will hydrolyze in caustic solutions Ability to impact modify for extrusion and injection 5
  • 6. Specialty Polymers
  • 7. XIRAN® Commercial neat resin grades Mw x1000 XIRAN® grades 300 SZ08250 250 200 Engineering plastics SZ15170 150 Specialty Polymers SZ26120 SZ23110 100 SZ26080 50 SZ25010 SZ40005 0 0 5 10 15 20 25 30 35 40 45 50 %w Maleic Anhydride
  • 8. XIRAN® preferred commercial gradesfor water & solvent based formulations O O O XIRAN neat resin code CH2 CH n m Maleic Anhydride (MAnh) % Molecular weight (Mw) x 1000 styrene maleic anhydride S Z 2 5 0 1 0 co-polymer’s XIRAN® MaleicAnh. Styrene Mw PDI Tg SZ25010 25% 75% 10000 2 130°C SZ26080 26% 74% 80000 2 160°C SZ40005 42% 58% 5000 2 130°C ■Polyscope’s XIRAN grades for aqueous and solvent bases formulations ■ Below 25% maleic anhydride SMA cannot be made water soluble due to low reactivity
  • 9. XIRAN® truly random polymers 1.0 MSM SSS 0.8 SSM Only with a mole fraction of + 0.5 maleic anhydride SMA MSS triad fraction is a true alternating co- 0.6 polymer 0.4 Two maleic anhydride groups next to each other 0.2 within the polymer chain is almost non-existing 0.0 0.0 0.1 0.2 0.3 0.4 0.5 mole fraction maleic anhydride XIRAN® Maleic Anh. MSM SSM + MSS SSS SZ25010 0.25 10% 52% 38% SZ26080 0.26 10% 53% 37% SZ40005 0.42 46% 46% 8%
  • 10. Application areas of XIRAN®
  • 11. Market application segments Powder Coating Inks Pigments Paper matting agent binder dispersant surface sizing dispersant Leather Electronics Paraffin & Wax re-tanning binder surfactant & solder mask dispersant component water repellency
  • 12. Chemical modifications of XIRAN®“are endless and only limited by your imagination”
  • 13. Hydrolyzing XIRAN®: creating various anionic salts ammonium SMA most frequently used as dispersant, surfactant and + 2 NH3 binder in: O O O O - Wax & paraffin emulsions - O NH2 O - Pigments & inks dispersions + NH4 - Surface sizing - Specialty coatings - Adhesives formulations but also other salts can be + 2 NaOH used such as: O O O O sodium (or potassium) - - O O O Na+ Na+ SMA typically used for more hydrophilic systems
  • 14. Cationic XIRAN® with DMAPA H2N 80°C > 100°C +O O O O O O H3C N O OH HN N CH3 + Acetic acid H3C N H3C N CH3 CH3Cationic XIRAN is of importance in the paper industry.It can be used as co-softener in laundry. It has anti-bacterial effect and therefore has a fit as binder in O O Nanti-fouling coatings O H3CAcetic acid is used in this example as counter ion. Other acids can be -used as well. O + HN H3C CH3In this example DMAPA is used:Dimethylaminepropylamine is a clear and colorless liquid, with a typicalamine smell, fully miscible with water, heptane and benzene and has aboiling point of 135°C.
  • 15. Imidization of XIRAN® SMA imide is insoluble in Altering the water and will form nano hydrophobicity particles with size of 40 – 140 nm. O O in between O insoluble in water If done in a wax or silicon + ammonia oil “dispersion” the oil will get encapsulated. non-ionicamic acid form & “hydrophilic” Lotus effect O O soluble in water NH2 HO temperature >100°C more hydrophobic O O N insoluble in water H
  • 16. Solubility profile of XIRAN®
  • 17. Solubility of XIRAN® grades in waterin relation to the molecular weight ■ This graph roughly depicts the solubility of the ammonium salt of the various XIRAN grades in water 50 SZ40005 40 maleic anhydride cont. 50% % solids 30 38% 25% 20 SZ25010 10 SZ26080 0 1 10 Mw x1000100 1000
  • 18. Solubility as function of the pHfor XIRAN® SZ40005 in water ■ Graph indicates a solid content level at various pH levels for liquid solutions with a viscosity below 500 mPa·s ■ Solubility of the anionic salts are in the order K+> Na+ > NH4+ 50 45 NH…+ NH4 40 Na+ Na+ 35 % solid 30 25 20 15 10 5 0 3 5 7 9 11 pH
  • 19. Solubility as function of the pHfor XIRAN® SZ25010 in water ■Graph indicates a solid content level at various pH levels for liquid solutions with a viscosity below 500 mPa·s ■ Theammonium & sodium salt of XIRAN SZ25010 shows similar behavior as the SZ40005 but has a substantial lower solid content 35 30 NH4 NH… + ■ Advice: keep Na+ Na+ values clearly above 25 pH 9 for anionic % solid 20 XIRAN solutions for 15 best optimal stability 10 5 0 3 5 7 9 11 pH
  • 20. Solubility profile of XIRAN® in organic solvents 10 Propylene glycol Isopropanol Ethanol Ethylene Glycol 2-Ethylhexanol Methanol Hydrogen bonding index (γ) 8 2-Ethoxyethanol Diethyl ether Diisopropyl ether Dimethyl acetamide 6 Acetone Diisobutyl ether MEK DMSO Acetonitrile 4 Propylene carbonate Toluene Nitromethane n-Pentane Carbon disulfide 2 SZ25010 SZ40005 0 6 8 10 12 14 16 18 Hildebrand (δ)
  • 21. HLB values of XIRAN®as function of the maleic anhydride content 35 ■The HLB value XIRAN co-polymers depends on 30 the maleic anhydride content 25 HLB value SZ40005 ■ No relation with molecular 20 weight other than that the solubility drops with 15 increasing Mw SZ25010 10 5 0 25 30 35 40 45 50 %w, Maleic Anhydride
  • 22. Contact us Polyscope Polymers BV Prins de Lignestraat 28 6161CZ Geleen The Netherlands PO BOX 1073 6160BB Geleen Tel. +31 46 75 000 10 Fax. +31 46 75 000 19
  • 23. Polyscope building partnership Our global presence & supply, constantly close,serving your needs in the best way possibleFORWARD - LOOKING STATEMENTSAll information supplied by or on behalf of the Polyscope in relation to its products, whether in the nature of data, recommendations or otherwise, issupported by research and believed reliable, but Polyscope assumes no liability whatsoever in respect of application, processing or use made of the aforementioned information or products, or any consequence thereof. The user undertakes all liability in respect to the application, processing or use of theafore-mentioned information or product, whose quality and other properties he shall verify, or any consequence thereof. No liability whatsoever shallattach to Polyscope for any infringement of the rights owned or controlled by a third party in intellectual, industrial or property by reason of the 23application, processing or use of the afore-mentioned information or products by the user.