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Fish Analytical
Chemistry
Prepared by:
RODNEY L.
PEÑAFIEL
Why we need to analyzed the fish?
 To set quantitave standards.
 To establish tolerance level of Chemical.
 To eliminate the need to base decisions
regarding product quality on PERSONAL
OPENIONS.
FOOD SAFETY AND
QUALITY CONTROL
Food Safety
Hazards
-Biological
-Chemical
- Physical
Hazards
- A biological, chemical or
physical agent that is reasonably
likely to cause illness or injury in
the absence of its control.
Hazards
- In HACCP, “hazards” refer to
conditions of contaminants in foods that can
cause illness or injury. It does not refer to
undesirable conditions or contaminants such
as:
Insects
Hair
Filth
Spoilage
Economic fraud
Violations of regulatory food
standards directly to safety
Chemical Hazards
• Naturally Occurring
• Intentionally added
• Unintentionally added
Types of Naturally Occurring
Chemicals Hazards
 Mycotoxins (e.g., aflatoxin)
 Scombrotoxin (histamine)
 Ciguatera fish poisoning ( algae toxins)
 Shellfish toxins
- Paralytic shellfish poisoning (PSP)
- Diarrhetic shellfish poisoning (DSP)
- Neurotoxic shellfish poisoning (NSP)
- Amnesic shellfish poisoning (ASP)/
Domoic Acid
 Food Additives
- Direct (allowable limits under
GMPs)
 Preservatives (e.g., nitrite and sulfiting
agents
Nutritional additives (e.g., niacin and
vitamin A )
 Color additives e.g., FD&C Yellow No.5
(tatrazine)
Intentionally Added Chemicals
Allergens
o Naturally occurring proteins
o Minute amounts can cause allergic
reaction
o Fatal reactions are known from :
peanuts, tree nuts, seafood
Composition of a Fish
Water 65-80 %
Fat 1-20 %
Protein 14-20 %
Vitamins
Minerals
Quality changes during preservation
METHOD PROTEINS LIPIDS
Salted No effects Might rancid
Smoked No effects Might rancid
Airdried Might deteriorate Rancid
Fermented Proteins
peptides = bitter
taste
Might get rancid
Some Chemical Indices of
Seafood Quality and Safety
• Total Volatile Base-Nitrogen
• Ammonia
• Trimethyl-Ammonia
• Nitrogen
• Dimethyl-Ammonia
Biogenic Amines
• Indole
• K-value
• Peroxide value
• Free fatty Acid test
• Heavy metals
• Marine Biotoxins
FIN…

Thank You
****

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Fish analytical chemistry

  • 2. Why we need to analyzed the fish?  To set quantitave standards.  To establish tolerance level of Chemical.  To eliminate the need to base decisions regarding product quality on PERSONAL OPENIONS.
  • 5. Hazards - A biological, chemical or physical agent that is reasonably likely to cause illness or injury in the absence of its control.
  • 6. Hazards - In HACCP, “hazards” refer to conditions of contaminants in foods that can cause illness or injury. It does not refer to undesirable conditions or contaminants such as: Insects Hair Filth Spoilage Economic fraud Violations of regulatory food standards directly to safety
  • 7. Chemical Hazards • Naturally Occurring • Intentionally added • Unintentionally added
  • 8. Types of Naturally Occurring Chemicals Hazards  Mycotoxins (e.g., aflatoxin)  Scombrotoxin (histamine)  Ciguatera fish poisoning ( algae toxins)  Shellfish toxins - Paralytic shellfish poisoning (PSP) - Diarrhetic shellfish poisoning (DSP) - Neurotoxic shellfish poisoning (NSP) - Amnesic shellfish poisoning (ASP)/ Domoic Acid
  • 9.  Food Additives - Direct (allowable limits under GMPs)  Preservatives (e.g., nitrite and sulfiting agents Nutritional additives (e.g., niacin and vitamin A )  Color additives e.g., FD&C Yellow No.5 (tatrazine) Intentionally Added Chemicals
  • 10. Allergens o Naturally occurring proteins o Minute amounts can cause allergic reaction o Fatal reactions are known from : peanuts, tree nuts, seafood
  • 11. Composition of a Fish Water 65-80 % Fat 1-20 % Protein 14-20 % Vitamins Minerals
  • 12. Quality changes during preservation METHOD PROTEINS LIPIDS Salted No effects Might rancid Smoked No effects Might rancid Airdried Might deteriorate Rancid Fermented Proteins peptides = bitter taste Might get rancid
  • 13. Some Chemical Indices of Seafood Quality and Safety • Total Volatile Base-Nitrogen • Ammonia • Trimethyl-Ammonia • Nitrogen • Dimethyl-Ammonia
  • 14. Biogenic Amines • Indole • K-value • Peroxide value • Free fatty Acid test • Heavy metals • Marine Biotoxins