DENTAL CEMENTS     INDIAN DENTAL ACADEMY  Leader in Continuing Dental Education     www.indiandentalacademy.com www.indian...
TERMINOLOGY    Cement – Substance that hardens to act as a    base, liner, filling material, or adhesive to bind    device...
Cavity Liner – Thin layer of cement, such as     a calcium hydroxide suspension in an aqueous orresin carrier (after evapo...
Intermediate restoration – Tooth filling orprosthesis that is placed for a limited period,    fromseveral days to months, ...
CEMENT BASESDEFINITION:      - A base is a layer of cement placed under thepermanent restoration to encourage recovery oft...
TYPES:      1. High strength bases: are used to provide thermalprotection for the pulp , as well as mechanical support for...
HIGH STRENGTH BASES                   LOW STRENGTH BASES- Zinc phosphate                       - Calcium hydroxide- Zinc p...
ZINC PHOSPHATE CEMENT:   It is the oldest of the luting cementsINDICATIONS :  - Luting of restorations  - High strength ba...
CLASSIFICATION:   Type I: Fine grained for luting.           Film thickness should be 25 um or less.    Type II: Medium gr...
MODE OF SUPPLY: I. Powder and liquid system. II. Capsules of preproportioned powder and liquid          www.indiandentalac...
COMPOSITION: POWDER:- Zinc oxide : 90.2%               Principal constituent- Magnesium oxide : 8.2%                Aids i...
LIQUID: - Phosphoric acid : 38%             Reacts with zinc oxide - Water : 36%            Controls rate of reaction - Al...
SETTING REACTION:  - When powder is mixed with liquid, the phosphoricacid attacks the surface of particles , dissolving th...
CONTROL OF SETTING TIME: a) Manufacturing process-  1. Sintering temperature: Higher the temperature ,more                ...
b) Factors under the control of operator:  1. Temperature: Higher temperature accelerates                    the reaction....
PROPERTIES:    1. COMPRESSIVE STRENGTH:            Maximum strength is attained in the first day                        10...
4. MODULUS OF ELASTICITY: 13 Gpa   5. SOLUBILITY AND DISINTEGRATION:         Shows relatively low solubility.      0.06% w...
8. BIOLOGICAL PROPERTIES:         - Due to the presence of phosphoric acid , theacidity of the cement is quite high at the...
MANIPULATION:  - A cool glass slab is used in order to delay the settingand allow more powder to be incorporated before th...
- Each increment is mixed for 15 to 20 sec before thenext increment is added.      Mixing time : 1 min 20 sec.   - The fie...
ZINC OXIDE EUGENOL           - Zinc oxide eugenol (ZOE) is the mostwidely used temporary restorative material.           -...
-   As an approximately neutral pH of7.0.           - Unfortunately its strength is notsufficient enough to resist forces ...
APPLICATIONS :1.   Base2.   Temporary cementation3.   Temporary restoration4.   Cavity liner5.   Endodontic sealer        ...
Classification :ADA specification No. 30 has listed 4 typesType I: Temporary cementation.Type II      :Permanent cementati...
COMPOSITIONPOWDER:•Zinc oxide – 69.0% - Principal ingredient•White rosin – 29.3% - To reduce brittleness of set           ...
LIQUID :Eugenol – 85.0 – Reacts with zinc oxideOlive oil – 15.0 – PlasticizeSETTING :               The setting reaction i...
Zn0 + H2O………………..Zn(OH)2  Zn(OH)2 + 2 HE ……………ZnE2 + 2H2O  Base            Acid                      the salt (Eugenol)   ...
- The water formed in the settingreaction aids in biding the individual chelate unitstogether in a chain or in an octahedr...
PROPERTIES :  1. Mechanical Properties:    a) Compressive strength:           -They are relatively weak cements. Thestreng...
- Cements intended forpermanent cementation (Type II) andintermediate restorations will be morestronger.           - The c...
b) Tensile strength:             Ranges from 0.32 to 5.8 Mpa.      c) Modulus of Elasticity:             Ranges from 0.22 ...
- The thermal conductivity of zincoxide-eugenol is in the range of insulators like corkand asbestos. 3.98 (Cal. Sec-1 cm-2...
- Solubility is reduced by increasingthe powder/liquid ratio.6. BIOLOGICAL PROPERTIES:         a) pH and effect on pulp: T...
Modified zinc oxide eugenol cements:         - To improve upon the working, handlingand setting characteristics, various m...
Resin reinforced zinc oxide eugenol cements :                    - The conventional zinc oxideeugenol cements have been mo...
- 20% polymethly methacrylate isusually added to zinc oxide as powder and is mixedwith eugenol along with accelerators lik...
The constituents of powder and liquid is as follows:POWDER              WEIGHT %Zinc oxide          80.0%Polymethyl-methac...
- Resin improves the strength,homogenicity and smoothness of the mix,decreases flow, brittleness and solubility.          ...
- Zinc stearate acts as a plasticizer and zincacetate improves the strength of the cement.         - Zinc stearate and zin...
GLASS IONOMER CEMENTS     www.indiandentalacademy.com
Definition (Akinmade & nicholson, 1993) :      - Water based cement where-in followingmixing, the glass powder & polyalken...
INDICATIONS:   - For eroded areas like erosion, abrasion and class Vrestorations.   - Anterior esthetic material for class...
Uses of GIC                   EROSION / ABRASION LESIONS                    CLASS V CARIOUS LESIONS                     CL...
Pits and fissures                     Primary Teeth restorations                    Bracket Bonding       www.indiandental...
Luting of crowns             Core Build-upwww.indiandentalacademy.com
CONTRAINDICATIONS:       Class IV carious lesions of fractured      incisors.       Lesions involving large areas of lab...
CLASSIFICATION:   According to skinners:                    Type I – Luting                    Type II- Restorative       ...
According to clinical use as:  Type I- Luting  TYPE II- Restorative  Type III- Liner/ Base  Type IV- Pit & Fissure Sealant...
COMPOSITION OF CALCIUM FLUROALUMINOSILICATEGLASS POWDER:  COMPONENT               WEIGHT%  SiO2 [quartz]           29  Al2...
POWDER:             - The composition of the glass is an acid solublecalcium aluminosilicate glass.               - Formed...
LIQUID :  - POLYACRYLIC ACID(45%)                 Polyacrylic : Itaconic  2:1 - ITACONIC ACID - MALEIC ACID - TRICARBOXYL...
LIQUID:        - The liquid was an aqueous solution of polyacrylicacid in a concentration of about 50%.          - The liq...
SETTING REACTION :        The setting reaction of glass Ionomer  cements involves three overlapping stages.Stage1: Dissolu...
www.indiandentalacademy.com
ADHESION:          - Glass ionomer cements have the important propertyof adhering to untreated enamel and dentin.         ...
ADHESION OF GIC:         - Polyalkenoic acid attacks the dentine andenamel and displaces phosphate and calcium (orstrontiu...
Comparative properties of glass ionomer cement Property          TYPE- I         TYPE- II TYPE- III P:L ratio          1.5...
PROPERTIES:PHYSICAL PROPERTIES –    EFFECT ON PULP AND CELLS:      - The glass Ionomer causes greater inflammatory respons...
- Although the glass ionomers are acidic they are lessirritant than silicates  - The acid used in glass Ionomer cement i.e...
Fluoride Release:       - Fluoride ions released from the restorative  materials become incorporated in hydroxyapatite  cr...
ASTHETICS:          - The glass ionomer cement is an aesthetic fillingmaterial because it has a degree of translucency whi...
DIMENSIONAL STABILITY:               A correctly manipulated and protected glass  ionomer material shows a volumetric sett...
Thermal Properties:                The thermal diffusivity value of glass Ionomer cement ions is close to that for dentin....
www.indiandentalacademy.com
DISPENSING AND MIXING      Glass ionomers are available commercially in two forms:-          Powder and liquid supplied   ...
DISPENSING                STANDARDIZE POWDER IN SPOON               DISPENSE LIQUID TO AVOID AIR BUBBLES     www.indianden...
MIXING    MIXING POWDER AND LIQUID USING PLASTIC SPATULA      FOLDING TECHNIQUE FOR MIXINGwww.indiandentalacademy.com
FINISHING & POLISHING     - No finishing for 24 hours.     - If essential, sharp blade to reduce gross contour     - After...
www.indiandentalacademy.com
RECENT ADVANCES IN GLASS IONOMER CEMENTS•   METAL – MODIFIED GLASS IONOMERS      -   MIRACLE MIX      -   CERMET•   RESIN ...
METAL – MODIFIED GLASS IONOMER CEMENTS        - Glass ionomer cements lack toughness and hence,cannot withstand high-stres...
SILVER ALLOY ADMIX or MIRACLE MIX           - Sced and wilson (1980) found that amalgamalloys could be incorporated into g...
- These systems have been used clinically bySimmons(1983). However, their esthetics are poor –theytend to impart a gray to...
CERMET – IONOMER CEMENTS:            - In an attempt to improve the abrasion resistance and strength of GIC, McLean and Ga...
RESIN – MODIFIED GLASS IONOMER CEMENT:    -Low early strength and moisture sensitivity of thetraditional glass ionomer was...
POLYACID – MODIFIED COMPOSITE RESINS              “COMPOMERS”            A new variety of the usual composite resinscompri...
The compomer - combination of “comp” form composite and“omer” from glass ionomer was introduced as a type of glassionomer,...
Zinc polycarboxylate:INDICATIONS:    1. Primarily for luting permanent restorations.    2. As bases and liners.    3. Used...
COMPOSITION:        POWDER - Zinc oxide                Basic ingredient - Magnesium oxide           Principle modifier and...
LIQUID:     - Liqueous solution of polyacrylic acid                      OR     - Copolymer of acrylic acid with other uns...
SETTING TIME: 7 to 9 minutes.PROPERTIES:1. MECHANICAL PROPERTIES:        - Compressive strength: 5.5 Mpa (80000Psi)       ...
4. ADHESION:     - Cement bond chemically with tooth structure.The bond strength to enamel is 3.4 to 13.1Mpa & that ofdent...
MANIPULATION:    - Proportioning 1.5 parts of powder to 1 part of liquid by wt.     - The powder and liquid are taken on g...
CALCIUM HYDROXIDE     CEMENT    www.indiandentalacademy.com
DEFINITION:     - Calcium hydroxide cements are relatively weakcements commonly employed as direct or indirect pulpcapping...
INDICATIONS:     - For direct and indirect pulp capping.     - As low strength bases beneath silicate andcomposite restora...
MODE OF SUPPLY:      1. Two paste system containing base and catalystpastes in collpsible tubes .      2. In powder form. ...
BASE PASTE  - Glycol salicylate 40%              Reacts with calcium                                     hydroxide & zinco...
CATALYST PASTE- Calcium hydroxide 50%              Principal reactive                                          ingredients...
MANIPULATION:           Traditionally, it is formulated by dispersing calcium hydroxide in aqueous or resin carrier soluti...
It can be carried in various ways:   - The powder can be mixed with distilled water orsterile saline to form a thick paste...
SETTING TIME: 2.5 TO 5.5 minutes.   Factors affecting the setting time:       - The setting of cement can be accelerated b...
PROPERTIES: 1. MECHANICAL PROPERTIES-       a) Compressive strength: It has a low compressive strength ,however it increas...
3. SOLUBILITY AND DISINTEGRATION:          Solubility is high in water – 0.4 to 7.8%    Solubility is more when exposed to...
CAVITY VARNISHDEFINITION:        Is a solution of one or more resins whichwhen applied onto the cavity walls, evaporatesle...
APPLICATIONS:1.It reduces the microleakage around the margins of newly placed amalgam restorations, thereby reducing post...
4. May be used as a surface coating over certainrestorations to prevent them from dehydration orcontact with oral fluids; ...
COMPOSITION:- Natural gum : Copal , rosin or synthetic resin.- Organic solvent : alcohol , acetone or ether.- Medicinal ag...
CONTRAINDICATIONS:  a) Composite resins – The solvent in varnish may react with or soften the resin.  b) Glass ionomer – V...
PROPERTIES: - Varnishes neither possess a mechanical strength norprovide thermal insulation , because of the thin filmthic...
MANIPULATION:   - The varnish may be applied by using a brush , wire loop on a small pledget of cotton.  - Several thin la...
PRECAUTIONS:   - Varnish solutions should be tightly closed to prevent loss of solvent by evaporation.   - Should be appli...
THANK YOU FOR WATCHING     www.indiandentalacademy.com
Upcoming SlideShare
Loading in …5
×

Dental cements /certified fixed orthodontic courses by Indian dental academy

7,544 views
7,363 views

Published on

Welcome to Indian Dental Academy
The Indian Dental Academy is the Leader in continuing dental education , training dentists in all aspects of dentistry and offering a wide range of dental certified courses in different formats.


Indian dental academy has a unique training program & curriculum that provides students with exceptional clinical skills and enabling them to return to their office with high level confidence and start treating patients

State of the art comprehensive training-Faculty of world wide repute &Very affordable.

Published in: Education
0 Comments
44 Likes
Statistics
Notes
  • Be the first to comment

No Downloads
Views
Total views
7,544
On SlideShare
0
From Embeds
0
Number of Embeds
4
Actions
Shares
0
Downloads
0
Comments
0
Likes
44
Embeds 0
No embeds

No notes for slide

Dental cements /certified fixed orthodontic courses by Indian dental academy

  1. 1. DENTAL CEMENTS INDIAN DENTAL ACADEMY Leader in Continuing Dental Education www.indiandentalacademy.com www.indiandentalacademy.com
  2. 2. TERMINOLOGY Cement – Substance that hardens to act as a base, liner, filling material, or adhesive to bind devices and prostheses to tooth structure or to each other. Base – Layer of insulating, sometimesmedicated, cement, placed in the deep portion of the preparation to protect pulpal tissue from thermal and chemical injury. www.indiandentalacademy.com
  3. 3. Cavity Liner – Thin layer of cement, such as a calcium hydroxide suspension in an aqueous orresin carrier (after evaporation), used forprotection of the pulp; Varnish – A solution of natural gum, synthetic resins, or resins dissolved in a volatile solvent, such as acetone, ether, or chloroform. www.indiandentalacademy.com
  4. 4. Intermediate restoration – Tooth filling orprosthesis that is placed for a limited period, fromseveral days to months, and is designed to sealteeth and maintain their position until a long-term restoration is placed; Luting agent – A Viscous material placedbetween tooth structure and a prosthesis thathardens through chemical reactions to firmlyattach the prosthesis to the tooth structure. www.indiandentalacademy.com
  5. 5. CEMENT BASESDEFINITION: - A base is a layer of cement placed under thepermanent restoration to encourage recovery ofthe injured pulp and to protect it againstnumerous types of insult [thermal, chemical orgalvanic] to which it may be subjected. www.indiandentalacademy.com
  6. 6. TYPES: 1. High strength bases: are used to provide thermalprotection for the pulp , as well as mechanical support forthe restoration. 2. Low strength bases: have minimum strength and lowrigidity . Their main function is to act as a barrier toirritating and to provide therapeutic benefit to the pulp. www.indiandentalacademy.com
  7. 7. HIGH STRENGTH BASES LOW STRENGTH BASES- Zinc phosphate - Calcium hydroxide- Zinc polycarboxylate - Zinc oxide Eugenol- Glass ionomer cement [type III]- Reinforced Zinc oxide Eugenol www.indiandentalacademy.com
  8. 8. ZINC PHOSPHATE CEMENT: It is the oldest of the luting cementsINDICATIONS : - Luting of restorations - High strength bases - Temporary restorations - Luting of orthodontic bands and brackets www.indiandentalacademy.com
  9. 9. CLASSIFICATION: Type I: Fine grained for luting. Film thickness should be 25 um or less. Type II: Medium grain for luting and filling. Film thickness should not be more than40 um. www.indiandentalacademy.com
  10. 10. MODE OF SUPPLY: I. Powder and liquid system. II. Capsules of preproportioned powder and liquid www.indiandentalacademy.com
  11. 11. COMPOSITION: POWDER:- Zinc oxide : 90.2% Principal constituent- Magnesium oxide : 8.2% Aids in sintering- Other oxides : 0.2% Improves smoothness of mix [ like bismuth trioxide, calcium hydroxide, barium oxide]- Silica : 1.4% Filler, aids in sintering. www.indiandentalacademy.com
  12. 12. LIQUID: - Phosphoric acid : 38% Reacts with zinc oxide - Water : 36% Controls rate of reaction - Aluminium phosphate : 16.2% Buffers, to reduce or zinc phosphate rate of reaction - Aluminium : 2.5% - Zinc : 7.1% www.indiandentalacademy.com
  13. 13. SETTING REACTION: - When powder is mixed with liquid, the phosphoricacid attacks the surface of particles , dissolving thezinc oxide forming acid zinc phosphate. - The aluminium of the liquid is essential for cementformation. The aluminium complexes with thephosphoric acid to form a zinc aluminophosphate gel .SETTING TIME: 5 to 9 minutes. www.indiandentalacademy.com
  14. 14. CONTROL OF SETTING TIME: a) Manufacturing process- 1. Sintering temperature: Higher the temperature ,more slowly the cement sets. 2. Particle size : Finer particles react more quickly as a greater surface area is exposed to the liquid. 3. Water content of the liquid: excess water acceleratesthe reaction whereas less water retards the reaction. 4. Buffering agents : slow down the reaction. www.indiandentalacademy.com
  15. 15. b) Factors under the control of operator: 1. Temperature: Higher temperature accelerates the reaction. 2. Powder/liquid ratio: More liquid employed ,slower the reaction. 3. Rate of addition of powder to liquid: The reaction is slower if the powder is incorporated into the liquid slowly. 4. Mixing time: Longer the mixing time, slower is the rate of reaction. www.indiandentalacademy.com
  16. 16. PROPERTIES: 1. COMPRESSIVE STRENGTH: Maximum strength is attained in the first day 103.5Mpa(15000Psi) Factors affecting strength are: a) Powder/ Liquid ratio: More the powder added into liquid, greater is the strength. b) Water content: A change in the water content of the liquid, either loss or gain, reduces the strength. 2. TENSILE STRENGTH: This cement is weaker in tension, thus making it brittle. 5.5Mpa(800Psi) www.indiandentalacademy.com
  17. 17. 4. MODULUS OF ELASTICITY: 13 Gpa 5. SOLUBILITY AND DISINTEGRATION: Shows relatively low solubility. 0.06% wt 6. FILM THICKNESS: The smaller the particle size,less is the film thickness. 7. THERMAL PROPERTIES: Are good thermalinsulators and may be effective in reducing galvanic effects. 8. ADHESIVE PROPERTIES: The retention is bymechanical interlocking of the set cement with the surfaceroughness of www.indiandentalacademy.com the cavity and restoration.
  18. 18. 8. BIOLOGICAL PROPERTIES: - Due to the presence of phosphoric acid , theacidity of the cement is quite high at the time they areinserted in the tooth. - 3 min after start of mixing Ph is 3.5 and laterrapidly approaches neutrality in 24 to 48 hours. Therefore damage to the pulp by acid occursduring the first few hours after insertion. www.indiandentalacademy.com
  19. 19. MANIPULATION: - A cool glass slab is used in order to delay the settingand allow more powder to be incorporated before thematrix formation occurs. - The liquid should be dispensed just before mixing. - The powder is added in small increments. Recommended ratio is 1.4gm/ 0.5ml - Mixing is initiated by addition of a small amount ofpowder at a time into the liquid. A large area is covered during mixing in order todissipate the exothermic heat. - Spatulation is carried out with a brisk, circular motionof the spatula. www.indiandentalacademy.com
  20. 20. - Each increment is mixed for 15 to 20 sec before thenext increment is added. Mixing time : 1 min 20 sec. - The field of operation should be kept dry during theentire procedure. www.indiandentalacademy.com
  21. 21. ZINC OXIDE EUGENOL - Zinc oxide eugenol (ZOE) is the mostwidely used temporary restorative material. - It seems to have been developed fromzinc oxy-chloride cements, which consisted of a powder: 75% zinc oxide and 25%pulverized glass or silica and liquid: zinc chloride and a little borax. - They were slow setting, and anotable shrinkage was generally observed. www.indiandentalacademy.com
  22. 22. - As an approximately neutral pH of7.0. - Unfortunately its strength is notsufficient enough to resist forces ofmastication, lacks resistance to wear and hasrelatively high solubility in the oral cavity. www.indiandentalacademy.com
  23. 23. APPLICATIONS :1. Base2. Temporary cementation3. Temporary restoration4. Cavity liner5. Endodontic sealer www.indiandentalacademy.com
  24. 24. Classification :ADA specification No. 30 has listed 4 typesType I: Temporary cementation.Type II :Permanent cementation.Type III :Temporary filling material and thermal insulation.Type IV : Cavity liners. www.indiandentalacademy.com
  25. 25. COMPOSITIONPOWDER:•Zinc oxide – 69.0% - Principal ingredient•White rosin – 29.3% - To reduce brittleness of set cement•Zinc Stearate – 1.0% - Accelerator, Plasticizer•Zinc Acetate – 0.7% - Accelerator, improvesstrength•Magnesium Oxide – Is added in some powders, it acts with eugenol in a similar www.indiandentalacademy.com
  26. 26. LIQUID :Eugenol – 85.0 – Reacts with zinc oxideOlive oil – 15.0 – PlasticizeSETTING : The setting reaction is a typical acid-basereaction to from a chelate. The reaction is also known asCHELATION and the product is called ZINC EUGENOLATE. www.indiandentalacademy.com
  27. 27. Zn0 + H2O………………..Zn(OH)2 Zn(OH)2 + 2 HE ……………ZnE2 + 2H2O Base Acid the salt (Eugenol) (Zinc Eugenolate) The chelate (Zinc Eugenolate) formed is a matrixsurrounding free zinc oxide particles. The chelate thoughtto form as an amorphous gel that tends to crystallize www.indiandentalacademy.com
  28. 28. - The water formed in the settingreaction aids in biding the individual chelate unitstogether in a chain or in an octahedral structure,or the water may be merely absorbed by the excessZinc Oxide. - The free eugenol content of the setcement is probably very low. www.indiandentalacademy.com
  29. 29. PROPERTIES : 1. Mechanical Properties: a) Compressive strength: -They are relatively weak cements. Thestrength depends on the intended use of thematerials. -For example, cements intended fortemporary purposes like temporary restorationsand cementation (Type I), and cavity lining (TypeIV), will have a lower strength. www.indiandentalacademy.com
  30. 30. - Cements intended forpermanent cementation (Type II) andintermediate restorations will be morestronger. - The compressive strength rangesfrom a low of 3-4 Mpa upto 50-55Mpa. - The smaller the particle size, thestronger the cement. The strength can also www.indiandentalacademy.combe increased by reinforcing with alumina –
  31. 31. b) Tensile strength: Ranges from 0.32 to 5.8 Mpa. c) Modulus of Elasticity: Ranges from 0.22 to 5.4 Gpa.2.THERMAL PROPERTIES: a) Thermal conductivity: Their thermal insulting properties areexcellent and are approximately the same as for humandentin. www.indiandentalacademy.com
  32. 32. - The thermal conductivity of zincoxide-eugenol is in the range of insulators like corkand asbestos. 3.98 (Cal. Sec-1 cm-2 (°C/cm)-1 x 10-4. b) Co-efficient of thermal expansion: 35 x 10-6/°C.3. SOLUBILITY AND DISINTEGRATION: - The solubility of the set cement is high,the highest among the dental cements. - They disintegrate in oral fluids. This breakdown is due to hydrolysis of the zinc eugenolatematrix to from zinc hydroxides and eugenol. www.indiandentalacademy.com
  33. 33. - Solubility is reduced by increasingthe powder/liquid ratio.6. BIOLOGICAL PROPERTIES: a) pH and effect on pulp: They are the leastirritating of all dental cements. In terms of pulpal response they are classifiedas mild. pH is 6.6 to 8.0 b) Bacteriostatic and obtuandantproperties: They inhibit the growth of bacteria andhave an anodyne or soothing effect on the pulp indeep cavities, reducing pain when it is present. www.indiandentalacademy.com
  34. 34. Modified zinc oxide eugenol cements: - To improve upon the working, handlingand setting characteristics, various modificationswere tried and are still being tried. Improvedproperties have been achieved by two approaches:Partial substitution of eugenol by –ethoxy-benzoic acid (EBA) Addition of fused quartz or aluminium oxide or resin polymer to the powder component www.indiandentalacademy.com
  35. 35. Resin reinforced zinc oxide eugenol cements : - The conventional zinc oxideeugenol cements have been modified by theaddition of polymeric substances like polymethylmethacrylate to the powder component. - The degree of reinforcementappears to be dependent to a great extent upon theparticle size and on uniformity of distribution ofthe resinous and inorganic phases of the powdercomponents. www.indiandentalacademy.com
  36. 36. - 20% polymethly methacrylate isusually added to zinc oxide as powder and is mixedwith eugenol along with accelerators like zincacetate and zinc stearate. - Thymol or hydroxyquinoline asantimicrobial agents are added in traces. www.indiandentalacademy.com
  37. 37. The constituents of powder and liquid is as follows:POWDER WEIGHT %Zinc oxide 80.0%Polymethyl-methacrylate 20.0%Zinc stearate tracesZinc accetate tracesThymol tracesLIQUID:Eugenol 85 %Olive oil www.indiandentalacademy.com 15%
  38. 38. - Resin improves the strength,homogenicity and smoothness of the mix,decreases flow, brittleness and solubility. - Resin may physically bond to theother components or react chemically with theeugenol. www.indiandentalacademy.com
  39. 39. - Zinc stearate acts as a plasticizer and zincacetate improves the strength of the cement. - Zinc stearate and zinc acetate also acts asaccelerators. - Olive oil acts as a plasticizer and masksthe irritating effects of eugenol. www.indiandentalacademy.com
  40. 40. GLASS IONOMER CEMENTS www.indiandentalacademy.com
  41. 41. Definition (Akinmade & nicholson, 1993) : - Water based cement where-in followingmixing, the glass powder & polyalkenoic acidundergo an acid/base setting reaction. - The acid attacks the surface of powderparticles, releasing calcium & aluminium ions, thusdeveloping a diffusion-based adhesion betweenpowder & liquid. www.indiandentalacademy.com
  42. 42. INDICATIONS: - For eroded areas like erosion, abrasion and class Vrestorations. - Anterior esthetic material for class III cavities. - As luting agent - As liners and bases - For core build-up - To a limited extend pit and fissure sealants. www.indiandentalacademy.com
  43. 43. Uses of GIC EROSION / ABRASION LESIONS CLASS V CARIOUS LESIONS CLASS III CARIES MNIMAL CAVITY PREPARATIONSwww.indiandentalacademy.com
  44. 44. Pits and fissures Primary Teeth restorations Bracket Bonding www.indiandentalacademy.com
  45. 45. Luting of crowns Core Build-upwww.indiandentalacademy.com
  46. 46. CONTRAINDICATIONS: Class IV carious lesions of fractured incisors. Lesions involving large areas of labial enamelwhere esthetics is of major importance Class II carious lesions where conventional cavitiesare prepared; replacement of existing amalgamrestorations. Lost cusp areas. www.indiandentalacademy.com
  47. 47. CLASSIFICATION: According to skinners: Type I – Luting Type II- Restorative Type III- Liner and base According to Sturdevent:1. Traditional or conventional2. Metal modified GIC a. Cermets b. Miracle mix3. Light cured GIC4. Hybrid (Resin modified GIC)5. Polyacid modified resin composite or Compomer www.indiandentalacademy.com
  48. 48. According to clinical use as: Type I- Luting TYPE II- Restorative Type III- Liner/ Base Type IV- Pit & Fissure Sealant Type V- Luting for Orthodontic Purpose Type VI- Core build up material Type VII- High fluoride releasing GIC Type VIII- ART Type IX- Geriatric & Paediatric GIC www.indiandentalacademy.com
  49. 49. COMPOSITION OF CALCIUM FLUROALUMINOSILICATEGLASS POWDER: COMPONENT WEIGHT% SiO2 [quartz] 29 Al2O3 [alumina] 16.6 CaF2[fluorite] 34.2 Na3AlF6[cryolite] 5 AlF3 5.3 AlPO4 9.9 www.indiandentalacademy.com
  50. 50. POWDER: - The composition of the glass is an acid solublecalcium aluminosilicate glass. - Formed by fusing silica[Sio2], alumina [Al2O3],calcium fluoride / fluorite(CaF2), at 11000C to 15000Ctemperature. - The glass is crushed, milled and then ground to afine powder {20u – 50u) www.indiandentalacademy.com
  51. 51. LIQUID : - POLYACRYLIC ACID(45%) Polyacrylic : Itaconic  2:1 - ITACONIC ACID - MALEIC ACID - TRICARBOXYLIC ACID - TARTARIC ACID(5-15%) - POLYPHOSPHATES - METAL OXIDES - WATER www.indiandentalacademy.com
  52. 52. LIQUID: - The liquid was an aqueous solution of polyacrylicacid in a concentration of about 50%. - The liquid was quite viscous and tended to gel overtime. Hence, acrylic acid was copolymerised with other acidssuch as iticonic ,maleic,and tricarboxylic acid. www.indiandentalacademy.com
  53. 53. SETTING REACTION : The setting reaction of glass Ionomer cements involves three overlapping stages.Stage1: DissolutionStage2: Precipitation of salt, gelation and hardeningStage3: Hydration of salts. www.indiandentalacademy.com
  54. 54. www.indiandentalacademy.com
  55. 55. ADHESION: - Glass ionomer cements have the important propertyof adhering to untreated enamel and dentin. - It reacts with the smear layer on cut dentin and alsobonds to other reactive polar substrates such as the basemetals. www.indiandentalacademy.com
  56. 56. ADHESION OF GIC: - Polyalkenoic acid attacks the dentine andenamel and displaces phosphate and calcium (orstrontium) ions. - These migrate into the cement and developan ion enriched layer firmly attached to the toothstructure. - Dentinal tubules will remain sealed andmicroleakage can only occur into the cement. www.indiandentalacademy.com
  57. 57. Comparative properties of glass ionomer cement Property TYPE- I TYPE- II TYPE- III P:L ratio 1.5:1 3:1 3:1 Working time 3.5 2.0 2.0 Setting time 7.0 5.0 4.0 Compressive 120 150-200 120 strength(Mpa) Tensile 9-12 15-20 6-10 sterngth(Mpa) Flexural strength 12-15 18-20 13-16 Surface hardness 160 200 120 Film thikness(uM) 20 - - Coeff.thermal - -6 -6 expansion 13x10 8x10 Solubility 0.1 0.1 0.1 www.indiandentalacademy.com
  58. 58. PROPERTIES:PHYSICAL PROPERTIES – EFFECT ON PULP AND CELLS: - The glass Ionomer causes greater inflammatory response than zinc-oxide eugenol cement but less than zinc phosphate cement and the silicates - Freshly mixed materials is very acidic between (0.9 and 1.6) which causes mild inflammatory response of pulpal tissues but it resolves within 30 days and there is no enhancement of reparative or secondary dentin formation. www.indiandentalacademy.com
  59. 59. - Although the glass ionomers are acidic they are lessirritant than silicates - The acid used in glass Ionomer cement i.e. thepolyacrylic acid is weaker than phosphoric acid. - The polyacid chains are large and immobile beingfurther restricted by their affinity for calcium ions in thetooth on which the material is applied. www.indiandentalacademy.com
  60. 60. Fluoride Release: - Fluoride ions released from the restorative materials become incorporated in hydroxyapatite crystals of adjacent tooth structure to from structure such as fluorapatite that is more resistant to acid mediated decalcification. - The fluoride originates from that used in preparing the alumino silicate glass, which can contain upto 23% fluoride www.indiandentalacademy.com
  61. 61. ASTHETICS: - The glass ionomer cement is an aesthetic fillingmaterial because it has a degree of translucency which arisesbecause it’s filler is a glass. - The colour of glass ionomer remains unaffectedby oral fluids as compared to composites which tend tostain. Translucency increases as they age and is reflected by adecrease in opacity. www.indiandentalacademy.com
  62. 62. DIMENSIONAL STABILITY: A correctly manipulated and protected glass ionomer material shows a volumetric setting contraction of approximately 3% which develops slowly through the setting process. www.indiandentalacademy.com
  63. 63. Thermal Properties: The thermal diffusivity value of glass Ionomer cement ions is close to that for dentin. Hence the material has an adequate thermal insulating effect on the pulp and helps to protect it from thermal trauma. www.indiandentalacademy.com
  64. 64. www.indiandentalacademy.com
  65. 65. DISPENSING AND MIXING Glass ionomers are available commercially in two forms:- Powder and liquid supplied separately, or handmixing. Encapsulated, or mechanical mixing. www.indiandentalacademy.com
  66. 66. DISPENSING STANDARDIZE POWDER IN SPOON DISPENSE LIQUID TO AVOID AIR BUBBLES www.indiandentalacademy.com
  67. 67. MIXING MIXING POWDER AND LIQUID USING PLASTIC SPATULA FOLDING TECHNIQUE FOR MIXINGwww.indiandentalacademy.com
  68. 68. FINISHING & POLISHING - No finishing for 24 hours. - If essential, sharp blade to reduce gross contour - After 24 hours, fine diamond with air/ water spray for gross contour. - Rubber polishing points for refining - Polishing discs for glossy finish - sealing with resin sealant or vaseline. www.indiandentalacademy.com
  69. 69. www.indiandentalacademy.com
  70. 70. RECENT ADVANCES IN GLASS IONOMER CEMENTS• METAL – MODIFIED GLASS IONOMERS - MIRACLE MIX - CERMET• RESIN MODIFIED GLASS IONOMERS• POLY ACID- MODIFIED COMPOSITE RESINS /COMPOMERS www.indiandentalacademy.com
  71. 71. METAL – MODIFIED GLASS IONOMER CEMENTS - Glass ionomer cements lack toughness and hence,cannot withstand high-stress concentrations. - GIC have been modified by the inclusion of metalfiller particles in an attempt to improve toughnessTwo methods of modifications have been employed. www.indiandentalacademy.com
  72. 72. SILVER ALLOY ADMIX or MIRACLE MIX - Sced and wilson (1980) found that amalgamalloys could be incorporated into glass ionomer cementsand that these served to increase the flexure strength. - Spherical silver amalgam alloy powder is mixedwith Type II glass ionomer powder in the ratio 7:1. www.indiandentalacademy.com
  73. 73. - These systems have been used clinically bySimmons(1983). However, their esthetics are poor –theytend to impart a gray to blackish colour to the cementand they do not take burnish. www.indiandentalacademy.com
  74. 74. CERMET – IONOMER CEMENTS: - In an attempt to improve the abrasion resistance and strength of GIC, McLean and Gasser(1985) developed the “cermet”-ionomer. - These cements, unlike simple mixtures of alloy particles or metal fibres, contain glass-metal powders sintered to high density that can be made to react with polyacids to form a cement. www.indiandentalacademy.com
  75. 75. RESIN – MODIFIED GLASS IONOMER CEMENT: -Low early strength and moisture sensitivity of thetraditional glass ionomer was the result of slow acid-basereactions. - Hence to overcome these two inherent drawbacks, somepolymerizable resin functional groups have been added to GICto impart additional curing process and allow the bulk of the www.indiandentalacademy.com
  76. 76. POLYACID – MODIFIED COMPOSITE RESINS “COMPOMERS” A new variety of the usual composite resinscomprising resins and inorganic filler particles is thepolyacid-modified composite resin or “compomer” whichwas introduced in the early 1990s. www.indiandentalacademy.com
  77. 77. The compomer - combination of “comp” form composite and“omer” from glass ionomer was introduced as a type of glassionomer, with claims that it offered some fluoride release aswell as improved physical properties and clinicalcharacteristics. www.indiandentalacademy.com
  78. 78. Zinc polycarboxylate:INDICATIONS: 1. Primarily for luting permanent restorations. 2. As bases and liners. 3. Used in orthodontics for cementation of bands. MODE OF SUPPLY: 1. Powder and liquid in bottles. 2. Powder mixed with water (water settable cements) www.indiandentalacademy.com
  79. 79. COMPOSITION: POWDER - Zinc oxide Basic ingredient - Magnesium oxide Principle modifier and also aids in sintering. - Other oxides like Small amounts Bismuth and aluminium - Stannous fluoride Increases strength , modifies setting time and imparts anticariogenic properties. www.indiandentalacademy.com
  80. 80. LIQUID: - Liqueous solution of polyacrylic acid OR - Copolymer of acrylic acid with other unsaturated carboxylic acids i .e; iticoni c, maleic, tricarboxylic acid. SETTING REACTION: - When the powder and liquids are mixed, the surface of powder particles are attacked by the acid, releasing zinc magnesium and tin ions. - These ions bond to the polymer chain via cross – linked salts. www.indiandentalacademy.com
  81. 81. SETTING TIME: 7 to 9 minutes.PROPERTIES:1. MECHANICAL PROPERTIES: - Compressive strength: 5.5 Mpa (80000Psi) - Tensile strength : 6.2 Mpa (900 Psi)2. SOLUBILITY AND DISINTEGRATION: - More soluble than zinc phosphate 0.06% 3. BIOCOMPATIBILITY: - Pulpal response is mild. pH of liquid is 1.0 to 1.7 & the freshly mixedcement is 3.0 to 4.0.www.indiandentalacademy.com5.0 to 6.0 After 24 hrs pH of cement is
  82. 82. 4. ADHESION: - Cement bond chemically with tooth structure.The bond strength to enamel is 3.4 to 13.1Mpa & that ofdentin is 2.07Mpa. 5. THERMAL PROPERTIES: - They are good thermal insulators. www.indiandentalacademy.com
  83. 83. MANIPULATION: - Proportioning 1.5 parts of powder to 1 part of liquid by wt. - The powder and liquid are taken on glass slab. - The powder is incorporated into the liquid in large quantities (90%) MIXING TIME : 30 to 40 sec. - The cement should be used while the surface is still glossy. - When placed in the cavity do not remove the excess, as it passesthrough the rubbery stage it tends to get lifted from the cavity . Remove the excess cement only when it has hardened www.indiandentalacademy.com
  84. 84. CALCIUM HYDROXIDE CEMENT www.indiandentalacademy.com
  85. 85. DEFINITION: - Calcium hydroxide cements are relatively weakcements commonly employed as direct or indirect pulpcapping agents. - Due to their alkaline nature they also serve as aprotective barrier against irritants from certainrestorations. www.indiandentalacademy.com
  86. 86. INDICATIONS: - For direct and indirect pulp capping. - As low strength bases beneath silicate andcomposite restorations for pulp protection. - Root canal sealer. - In wheeping canals for exudation control. CONTRAINDICATIONS: - It cannot be used in a teeth with a degeneratingpulp tissues as this can lead to calcific type ofdegeneration. www.indiandentalacademy.com
  87. 87. MODE OF SUPPLY: 1. Two paste system containing base and catalystpastes in collpsible tubes . 2. In powder form. 3. Light cured system www.indiandentalacademy.com
  88. 88. BASE PASTE - Glycol salicylate 40% Reacts with calcium hydroxide & zincoxide - Calcium sulphate - Titanium dioxide Inert fillers,pigments - Calcium tungstate Provides radio-opacity www.indiandentalacademy.com
  89. 89. CATALYST PASTE- Calcium hydroxide 50% Principal reactive ingredients.- Zinc oxide 10%- Zinc stearate 0.5% Accelerator- Ethylene toluene- Sulfonamide 39.5% Oily compound, acts as carrier www.indiandentalacademy.com
  90. 90. MANIPULATION: Traditionally, it is formulated by dispersing calcium hydroxide in aqueous or resin carrier solutions to facilitate application to the walls of cavity preperation. The carrier evaporates and leaves a thin layer of calcium hydroxide on the cavity walls. www.indiandentalacademy.com
  91. 91. It can be carried in various ways: - The powder can be mixed with distilled water orsterile saline to form a thick paste. - It can also be suspended in chloroform or plasmaand can be applied with the help syringe. - It may be applied in pure powder form also. www.indiandentalacademy.com
  92. 92. SETTING TIME: 2.5 TO 5.5 minutes. Factors affecting the setting time: - The setting of cement can be accelerated bymoisture and heat. Conversely, the setting time will be retarded bydryness and cold. www.indiandentalacademy.com
  93. 93. PROPERTIES: 1. MECHANICAL PROPERTIES- a) Compressive strength: It has a low compressive strength ,however it increases with time after setting. The strength after 24 hrs ranges from 10 to 27 Mpa. b) Tensile strength: has low tensile strength – 1.0 Mpa c) Modulus of elasticity: 0.37Gpa. 2. THERMAL PROPERTIES: If used in sufficiently thick layers they provide some thermalinsulation. Thickness should not exceed 0.5 mm www.indiandentalacademy.com
  94. 94. 3. SOLUBILITY AND DISINTEGRATION: Solubility is high in water – 0.4 to 7.8% Solubility is more when exposed to phosphoric acid andether. So care should be taken during acid etching andduring application of varnish in present of this cement. 4. BIOLOGICAL PROPERTIES: a) Effect on pulp: It is alkaline in nature due to presence of freecalcium hydroxide in set cement. Ph 9.2- 11.7 b) Helps in formation of secondary dentin. www.indiandentalacademy.com
  95. 95. CAVITY VARNISHDEFINITION: Is a solution of one or more resins whichwhen applied onto the cavity walls, evaporatesleaving a thin resin film, that serves as a barrierbetween the restoration and the dentinal tubules. www.indiandentalacademy.com
  96. 96. APPLICATIONS:1.It reduces the microleakage around the margins of newly placed amalgam restorations, thereby reducing post operative sensitivity.2. It reduces passage of irritants into the dentinal tubules from the overlying restoration or base.Eg: silicate,zinc phosphate etc..3 In case of amalgam restorations it prevent the penetration of corrosion products into the dentinal tubules, thus www.indiandentalacademy.comdiscoloration. minimizing the tooth
  97. 97. 4. May be used as a surface coating over certainrestorations to prevent them from dehydration orcontact with oral fluids; eg; Silicate and GIC. 5. May be applied on the surface of metallicrestorations as a temporary protection in case ofgalvanic shock. 6. In cases where electrosurgery is to be doneadjacent to metallic restorations, varnish applied overthe metallic restorations serves as a temporaryelectrical insulator. www.indiandentalacademy.com
  98. 98. COMPOSITION:- Natural gum : Copal , rosin or synthetic resin.- Organic solvent : alcohol , acetone or ether.- Medicinal agents : Chlorbutanol , thymol or eugenol Some varnishes contains fluorides. www.indiandentalacademy.com
  99. 99. CONTRAINDICATIONS: a) Composite resins – The solvent in varnish may react with or soften the resin. b) Glass ionomer – Varnish eliminate the potential for adhesion and the biocompatibility of the cement. c) When therapeutic action is expected from the overlying cement. Eg: Zinc oxide eugenol and calcium hydroxide. www.indiandentalacademy.com
  100. 100. PROPERTIES: - Varnishes neither possess a mechanical strength norprovide thermal insulation , because of the thin filmthickness. Film thickness ranges between 2 to 40microns. - The solubility of dental varnishes is low , they arevirtually insoluble in distilled water. www.indiandentalacademy.com
  101. 101. MANIPULATION: - The varnish may be applied by using a brush , wire loop on a small pledget of cotton. - Several thin layers are applied. Each layer is allowed to dry before applying the next one. - When the first layer dries , small pinholes develop.These voids are filled in by the succeding varnish applications. The main objective is to attain a uniform and continuous coating. www.indiandentalacademy.com
  102. 102. PRECAUTIONS: - Varnish solutions should be tightly closed to prevent loss of solvent by evaporation. - Should be applied in a thin consistency. Viscous varnish does not wet the cavity walls properly. - Excess varnish should not be left on the margins of the restorations as it prevents proper finishing of the margins of the restorations. www.indiandentalacademy.com - Varnish should be confined to the dentin.
  103. 103. THANK YOU FOR WATCHING www.indiandentalacademy.com

×