What can Materials Science tell us about Solar Energy of the Future?

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  • 1. What can Materials Science tell us about Solar Energy of the Future?
    Professor Stuart Irvine
    Centre for Solar Energy Research
    Glyndŵr University
  • 2. Climate change
  • 3. Were the conditions in the Pacific in March 2010 exceptional?
    During the winter of 2009-2010 a rare combination of known factors in earth’s climate variability systems ................(AccuWeather.com).
    According to records going back to 1950, this winter saw one of the strongestEl Nino events, combined with the most negative Arctic Oscillation(and also with a negative North Atlantic Oscillation) yet seen during a winter.
  • 4. Can we link this to climate change?
    Yes and no
    Individual weather events cannot be directly attributable to climate change – but
    With the warming of the ocean temperatures we can expect a greater occurrence of extreme weather (Hadley Centre)
    Forecast for 2nd April 2010
  • 5. Evidence for anthropogenic climate change
  • 6. What can we do to limit carbon dioxide emissions?
    The world is heavily dependent on energy from fossil fuels: coal, gas, oil
    Approximately 80% of the UK electricity grid is still powered by fossil fuel http://www.ecotricity.co.uk/our-green-energy/energy-independence/uk-grid-live
    UK government target to reduce carbon emissions by 80% by 2050 to limit temperature rise to 2o C
    How can we achieve this?
  • 7. Moving towards a low carbon economy
    More efficient use of energy: transport, heating, electricity
    Replace fossil fuel energy with renewable energy sources: Solar, wind, bio-energy, tidal, wave, hydro
    Build a new generation of nuclear power stations
    Fusion power
    The task is huge so all of the above have a part to play!
  • 8. The sun radiates more than enough energy onto the Earth in just one day to provide enough energy for the population of 5.9 billion people for 27 years
    In Wales enough solar energy radiates onto just 1 square kilometre over a year to supply 10% of our electricity needs
  • 9. This X-ray image of the Sun, taken by the SOHO satellite, shows numerous active regions in the Sun's atmosphere.
    The Sun is by far the largest object in our solar system, containing more than 99% of the total mass.
    The sun is composed of 75% hydrogen and 25% helium
    The sun’s energy comes from a thermo-nuclear reaction where the nuclei of hydrogen are converted into helium releasing huge amounts of energy
    atmospheric temperature of 5500 oC and a luminosity of 4x1020 megawatts
  • 10. When solar radiation arrives at the Earth it can be converted to heat
    heat
    Solar radiation
  • 11. But how can we generate electricity from solar radiation?
  • 12. Our modern understanding of light and colour begins with Isaac Newton (1642-1726) and a series of experiments that he published in 1672.
  • 13. It wasn’t until 1901 with the publication of Planck’s black body theory that we started to understand how light interacts with matter
    Low energy photons
    High energy photons
    Planck had to assume that light carried “quanta” of energy that we now call “photons”
  • 14. To make electricity we need a flow of electrons. Einstein was the first to explain how electrons could be released from a metal in a vacuum by light (photons) beamed at the surface
    People are also aware of his theories of relativity:  the Special Theory of Relativity (published in 1905) and the General Theory of Relativity (published in 1915).  What many people do not know is that Einstein was the second person to make a major contribution to the quantum revolution, in a paper also published in 1905 .  In fact, this paper won him a Nobel prize.
    Only blue light would release electrons and not red light, no matter how intense the red light.
  • 15. How are photons absorbed in a semiconductor?
    photon
    Conduction band
    electron
    Band gap energy
    Valence band
    energy
    For absorption
    Ep > Eg
    Silicon cells can now convert up to 20% of the sun’s radiation into electrical energy
  • 16. For the electron to become an electric current it must pass across a junction from electron depleted to electron rich semiconductor materials
    Unlike metals where electricity can only be conducted by electrons, semiconductors can conduct electricity with negatively charged electrons and positively charged “holes”
  • 17. The Sharp silicon PV module factory in Llay is producing around 300 MW of PV panels a year (increasing to 500 MW) this year
    CIS tower, Manchester
  • 18. What are the components of a grid-connected PV system?
    Inverter
    Export Meter
    Import Meter
    PV Modules
    On-site Load
    To Grid
  • 19. Examples of grid connected silicon PV modules installed by Dulas Ltd
  • 20. Market price and predicted capacity for PV solar modules
    Potential to drive down cost with thin film PV
    Solar Buzz September ‘10 minimum prices
    Thin film PV (a-Si, CdTe and CIGS) will be a quarter of the market by 2013
    Materials cost becomes the major cost factor for high volume manufacture
    EPIA Report
  • 21. Semiconductor elements
  • 22. The structure of a CdTe thin film solar cell
    Glass substrate
    Front contact
    TCO
    n- CdS
    junction
    p- CdTe
    Back contact
  • 23. PV modules can be made much cheaper if the semiconductor was just a thin film on a sheet of glass
    First Solar Inc
    Wurth Solar
  • 24. First solar is leading the way with high volume thin film CdTe PV manufacture
  • 25. The PV façade at OpTICGlyndwr Campus, StAsaphdemonstrates novel thin film CIGS technology
    1000 m2 generating up to 85 kWp of completely clean energy.
    Largest of its kind outside US
    In the first 12 months of operation a total of 65,000 kWh of clean electricity was generated, saving 28 tonnes of carbon emissions from fossil fuelled power stations
  • 26. Variation of energy output from OpTIC PV facade through the year
  • 27. What are the limits to efficiency of PV solar cells?
    The optimum efficiency is a compromise between the proportion of the solar spectrum that can be absorbed and the amount of energy captured per photon absorbed
    Potential for 30% efficient cells based on single junction PV
  • 28. For greater than 30% efficiency need to go to multi-junction cells
  • 29.
  • 30. The cost/ performance trade-off
    The highest performance solar cells (triple junction gallium arsenide are over 30% efficient) are too expensive for building integrated PV but used for powering satellites.
    Very low cost dye-sensitised solar cells (DSC) may be suitable for large areas such as industrial roofs (Tata- Dyesol piloting DSC onto sheet steel (approx 5% efficient)
    Crystalline silicon is still a good compromise between efficiency and cost (15-20% efficient)
    Thin film silicon, cadmium telluride and CIGS are moving towards crystalline silicon but with inherently lower cost.
  • 31. Concentrators might just prove to be a winner for terrestrial triple junction cells
    Whitfield Solar – trough type concentrators
    • concentration up to 500x the amount of expensive solar cell material can be reduced
    • 32. but the array has to track the sun so not suitable for building facades
    Circadian Solar – plastic Fesnel lens concentrators
  • 33. The opportunity for the UK to generate substantial amounts of solar electricity is by incorporating into the fabric of buildings (BIPV)
    Thin film PV offers the cost advantage but how can we get higher efficiency without the cost going through the roof?
    Thin film can be either on rigid surfaces such as glass or on flexible surfaces such as steel or even on plastic.
    Opportunity for designing or even disguising PV in buildings.
  • 34. Solar glazing
    Polysolar partially transmitting thin film silicon modules
  • 35. Solar tiles
    Solar Century solar tiles to replace roof slates and tiles
  • 36. Solar facades
    Examples of PV facades from Green Coast Solar
  • 37. What do we know from our current knowledge of materials science that can improve on these solar energy materials?
    Improve light capture – if it reflects we are losing energy!
    Need to work with a wider range of materials to integrate PV into buildings
    Improve the efficiency of low cost PV such as thin film and organic
    Photon management to capture more of the spectrum
    Hybrid solar cells
  • 38. Crystalline silicon cells – textured surface improves light capture
    Poly-c Si(x1.0k) grain boundary
    Mono-c Si(x2.0k) mounted at 45 degrees
  • 39. Research in the CSER lab at the OpTIC campus of Glyndwr University, applying materials science to develop new thin film PV technology
  • 40. Development of a research thin film deposition process to be compatible with production processes
    • From single batch to continuous process
    • 41. Batch process flows chemical vapour over the substrate
    • 42. In-line process flows the chemical vapours onto the surface that moves underneath the injector
  • SPARC inline process outline (15×15 cm2 ) for experimental PV modules
    Buffer
    TCO
    CdS
    CdTe
    CdTe p+
    CdCl2
    Exhaust
    Loading &
    pre-heating
    zone
    Annealing &
    Cooling zone
  • 43. Thin film PV materials are complex and uniformity is everything!
    Scanning electron microscope (SEM) image of plan view of cadmium telluride thin film PV cell
    Scanning electron microscope (SEM) image of a cross section of the cell
  • 44. New laser scanning method to understand defects in PV cells - Micro-LBIC
    Areas of thin CdZnS window layer
    Blue
    red
    infrared
  • 45. Plasmonic down conversion to enhance short wavelength response
    CSER in collaboration with Markvart and Lefteris, Southampton University
    Comparison of external quantum efficiency plot (EQE) of CdTe cell (Glyndwr) with a PMMA blank luminescence down shifting (LDS) layer, a single dye and a two dye mixture LDS layer. An inset of a simplified structure of the LDS + cell structure is shown. Observed increased EQE efficiencies are for the single dye ~9.8% and two dye ~ 12.5%
  • 46. Nano-materials for down conversion
    Blue laser on nano-material film
    Blue laser on polymer
    Polymer + nano-material
    Polymer film
  • 47. Conclusions
    Solar energy has enormous potential but we have to improve ways of capturing it
    Capturing more of the solar spectrum can be very challenging and expensive!
    Solar electric modules in the future will become part of the fabric of a building – so you might not even recognise them
    Materials Innovation needed at all levels of PV module manufacture – improve efficiency and reduce cost.
    Will we be able to reduce our carbon emissions in time?
    What will the climatic conditions be like in 2050?
  • 48. Acknowledgements
    Members of the CSER team
    Pilkington Group for supply of NSG TEC glass
    Financial support from the EPSRC energy programme, funding through PV21 –SUPERGEN consortium.
    Financial support from the Low Carbon Research Institute (LCRI) EU Convergence programme
    http://www.cser.org.uk
  • 49. CSER Team
    Dr Vincent Barrioz
    Dr Dan Lamb
    Dr Louise Jones
    Dr Andy Clayton
    Dr GirayKartopu
    Dr Sarah Rugen-Hankey
    Dr Graham Sparey-Taylor
    Garth Lautenbach
    Eurig Jones
    William Brooks
    Steve Jones
    Simon Hodgson
    Peter Siderfin
    Fraser Hogg
    Emma Dawson