This basic framework is a great resource to help you get to know your employees (or future employees) better.
Use it to find out what drives them as individuals, both on a personal level, as well as on a professional level. You can then compare the results of this framework with your company values and vision and see if there is a culture fit. See what drives their personal happiness and their workplace happiness.
Short, simple to use and very effective in assessing job-personality compatibility and, most importantly, in forming long term relationships!