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Worksheet 1.1Chapter 1: Quantitative chemistry – glossaryAmount The number of moles of a substance present in a sample.Aqueous solution A solution with water as the solvent.Atmosphere The unit atmosphere is used to measure pressure. 1 atm. = 101 325 Pa. It is not an SIunit.Atmospheric pressure The pressure exerted by the atmosphere on the surface of the Earth due tothe weight of the gases in the atmosphere.Avogadro constant, L The Avogadro constant (6.02 × 1023) is the number of atoms in exactly 12grams of carbon-12. It has units of mol–1.Avogadro’s hypothesis This states that at a specified temperature and pressure, equal volumes of(ideal) gases contain equal numbers of moles of particles. There is a direct relationship between thevolume of gas, V, and the amount of particles, n: V n.Back titration An experimental procedure which typically consists of two consecutive acid-basetitrations performed when an insoluble and slowly reacting reagent is treated with an excess of anacid or base. The excess acid or base is then titrated and neutralised with a primary standard. It canbe used, for example, to analyse the amount of calcium carbonate in a shell or the amount of aspirinin a tablet.Balanced equation A summary of a chemical reaction using chemical formulae. The totalnumber of any of the atoms and charges is the same on the reactant and product sides of theequation.Boiling The conversion of a liquid into a gas at constant temperature when the vapour pressure ofthe liquid is equal to the external pressure. It is characterised by the appearance of bubbles ofvapour throughout the liquid.Boiling point The temperature at which a liquid is converted to a gas. A liquid boils when thevapour pressure of the liquid equals the surrounding pressure.Boyle’s law This states that the pressure of a fixed mass of ideal gas is inversely proportional tothe volume at constant temperature. P 1/V.By-products Unwanted products of a chemical synthesis or manufacturing process.Celsius scale (of temperature) This scale of temperature is based on a 100-degree range betweenthe normal melting point of pure ice (0°C) and the normal boiling point of pure water (100°C).Change of state The inter-conversions of a substance between the solid, liquid and gaseousstates.Charles’ law This states that the volume of a fixed mass of an ideal gas at constant pressure isdirectly proportional to its absolute temperature. V T. 1
Chemical element A substance which cannot be decomposed or broken down into simplersubstances by chemical methods. All atoms of an element contain the same number of protons.Chemical reaction A change in which a new substance or substances are formed.Chemical symbol This consists of one or two letters used to represent each element. The first (oronly) letter is always a capital letter, the second is lower case.Coefficient (in a chemical equation) The coefficients in a chemical equation are the numbersthat appear on the left of chemical formulae.Combined gas law This relates the pressure, absolute temperature and volume, under two sets ofconditions for a fixed mass of gas. P1V1/T1 = P2V2/T2.Completion Complete consumption of at least one of the reactants in a chemical reaction. Areaction goes to completion if its limiting reactant or reagent is consumed.Compound A substance formed by the chemical combination of two or more chemical elementsin fixed proportions.Concentrated A concentrated solution contains a relatively high concentration of solute.Concentration This is the amount of solute in a known volume of solution. It can be expressedeither in g dm–3 or mol dm–3. Concentration in mol dm–3 is often represented by square bracketsaround the substance: [solute] (mol dm–3) = nsolute (mol) / Vsolution (dm3)Condensing The change of a vapour into a liquid at constant temperature. Latent heat is releasedto the surroundings during this process, as bonds between the particles in the liquid are formed.Dalton’s law of partial pressures The total pressure of a mixture of ideal gases is the sum of thepartial pressures of all the component gases.Density Density is defined as mass per unit volume. Density ( ) = mass (m) / volume (V).Diffusion The spontaneous movement of gas or liquid particles from a region of highconcentration of the particles to a region of low concentration.Dilute A dilute solution contains a relatively low concentration of solute.Dilution The process of adding more solvent, usually water, to a solution to decrease theconcentration.Empirical formula This gives the ratio of the atoms of different elements in a compound. It is themolecular formula expressed as its simplest ratio. The molecular formula is a whole-numbermultiple of the empirical formula.Evaporation Evaporation occurs at the surface of the liquid and involves a liquid changing into agas at a temperature below the boiling point of the liquid.Excess A reactant is in excess when, after the reaction is complete, some of that reactant remainsunreacted.Formula mass This is the sum of the atomic masses of the elements in the formula of an ioniccompound. 2
Formula unit The symbols used in equations and calculations to represent elements andcompounds with giant structures.Freezing The change of a liquid into a solid at constant temperature.Freezing point The temperature at which a liquid turns to a solid. Latent heat is released to thesurroundings during this process, as bonds between the particles in the solid are formed.Gas A state of matter in which there are little attractive forces operating between the particles.The individual particles move at high speed and collide with each other and the walls of thecontainer.Gas laws The various laws that describe the physical behaviour of gases.Gay–Lussac’s law of combining gas volumes The volume of gases taking part in a chemicalreaction show simple whole number ratios to one another when measured at the same temperatureand pressure.Graham’s law of diffusion Gases diffuse at a rate that is inversely proportional to the square rootof their density or molar mass at constant temperature and pressure. The result follows from therelation between kinetic energy and temperature. Two different gases at the same temperature havethe same average kinetic:½mxvx2 = ½mYvY2vx2 / vY2 = mY/ mxvx / vY = mY/ mxvx 1/ mxGravimetric analysis A method of quantitative analysis for finding the composition andformulae of compounds based on accurate weighing of reactants and products.Heating curve A plot of temperature against time for a substance when heated at a constant rate.Hydrate A salt associated with a definite number of molecules of water.Hydrated ion An ion which has a definite number of water molecules associated with it.Hydration A process where an unsaturated molecule adds a water molecule or water moleculesinteract with ions in aqueous solution.Ideal gas An ideal gas is a hypothetical substance that consists of molecules or atoms that occupyalmost no space and have no intermolecular forces. All collisions between the molecules or atomsare perfectly elastic. An ideal gas obeys the gas laws exactly under all conditions.Ideal gas constant (R) The ideal gas constant (R) is the constant that appears in the ideal gasequation (PV = nRT).Ideal gas equation This is an equation relating to the temperature, pressure, volume and amountof an ideal gas. It is frequently used in experimental work to determine the molar masses of gases. 3
Kelvin scale A temperature scale starting from absolute zero (–273°C) using degrees the samesize or magnitude as degrees Celsius. The temperature in kelvin is proportional to the averagekinetic energy of the particles.Kinetic energy (of particles in a gas) The energy due to the motion; it depends on the mass ofthe gas particle (atom or molecule) and the square of their speed. Kinetic energy = ½mv2.Kinetic theory This explains the physical properties of solids, liquids and gases in terms of themovement of particles (atoms, ions or molecules). The theory also accounts for changes of state.Lattice A regular, repeating three-dimensional arrangement of atoms, molecules or ions within acrystal.Law of conservation of mass Mass is not lost or gained during a chemical reaction. The totalmass of the reactants equals the total mass of the products.Limiting reactant This determines the theoretical yield of product. The reactant that iscompletely consumed, or used up, when the reaction goes to completion. The other reagents are inexcess.Liquid A state of matter in which particles are loosely attracted by intermolecular forces. A liquidtakes up the shape of the walls of its container and has a fixed volume. The particles have anirregular arrangement.Melting The change of a solid into a liquid at constant temperature. Latent heat is needed to breakthe bonds between the particles in the solid state.Melting point The temperature at which a solid is converted to a liquid. It can be used to test theidentity or the purity of a sample.Molar gas volume One mole of an ideal gas occupies 22.4 dm3 at 0ºC (273 K) and oneatmosphere pressure.Molarity A measure of the concentration of a solution: the amount in moles of solute in 1 dm3 ofsolution. Units are mol dm–3 or sometimes simply M.Molar mass The mass in grams of one mole of molecules or the formula units of an ioniccompound. It is numerically equal to the relative molecular, atomic or formula mass of a substancein units of g mol–1.Mole The unit of amount of a substance. One mole of a substance has a mass equal to its formulamass in grams. One mole of a substance contains 6.02 × 1023 (Avogadro’s constant) of atoms, ionsor molecules.Molecular formula This shows the number of atoms of each element present in a molecule.Molecular mass The molecular mass is the sum of the atomic masses of the elements in theformula of a covalent compound.Molecule A group of atoms held together by covalent bonds.Particle (in kinetic theory) The term particle refers to atoms, molecules or ions. 4
Pascal The SI unit of pressure. One Pascal, abbreviated to Pa., is equivalent to a force of one 1 Mon 1 m2.Percentage composition The percentage by mass of each of the elements in a compound.Percentage yield The experimental yield as a percentage of the theoretical yield:Percentage yield = (experimental yield/ theoretical yield) × 100%Phase A physically or chemically distinct part of a system. A phase is homogenous throughoutand is separated from other phases by a phase boundary.Pressure A measure of the force pressing on a surface. The pressure that a gas exerts upon itscontainer is caused by the particles colliding with the walls of the container. Pressure is defined asforce per unit area. Pressure = force / areaPressure law The gas law stating that the pressure of a fixed mass of an ideal gas, at constantvolume, is directly proportional to its absolute temperature. P T.Primary standard A substance which can be used to prepare a standard solution with a preciseconcentration for volumetric analysis.Product A substance produced during a chemical reaction.Reactant A substance that is consumed during a chemical reaction.Reacting masses The masses of elements and compounds which take part in a chemical reaction.Real gas A real gas does not obey the gas laws and exhibits non ideal behaviour. Its moleculeshave a finite size and there are intermolecular forces of attraction.Recrystallisation A technique for the purification of solid crystalline substances. The procedureis based on the significant increase of solubility of the solutes with increasing temperature.Redox titration A titration used to determine the concentration of a solution of an oxidising agentor of a reducing agent in a redox reaction.Relative atomic mass The average mass of an atom of an element, according to relativeabundances of its isotopes in a naturally occurring sample, on a scale where the mass of one atom of is 12 exactly.Saturated solution A solution which contains the maximum amount of dissolved solute in asolvent at a particular temperature.Side reactions Unwanted reactions which reduce the yield of the product being formed from themain reaction.Solid A state of matter with particles in fixed positions and not able to move from one location toanother. The particles are held in a lattice by chemical bonds or intermolecular forces. 5
Solubility The amount of solute required to form a saturated solution in a given volume (e.g.1 dm3) of solvent.Solute A solute is the solid, liquid or gas that has been dissolved to form a solution.Solution A solution is a homogeneous mixture of a liquid (the solvent) with another substance(the solute). The solute can be solid, liquid or gas but the solvent is generally a liquid.Solvation The process of the solute particles dissolving in a solvent as they spread out and aresurrounded by solvent molecules.Solvent A solvent is a liquid that dissolves a solute to form a solution.Standard solution A solution with an accurately known concentration made by dissolving aknown amount of a primary standard in water.Standard state The most stable state for a specific element (in a particular allotropic form, whereappropriate) under standard conditions of temperature and pressure.State symbols Symbols used in equations to describe the physical state of the substances that areparticipate in a reaction. Solid (s), liquid (l), gas (g) or dissolved in water, that is aqueous, (aq).Stoichiometry The ratio in which the elements combine in a compound or the ratio in whichcompounds react in a reaction.Sublimation The direct change of state from solid to gas without melting or freezing occurring.Temperature A measure of the average kinetic energy of the particles in a substance. Theabsolute temperature, measured in K, is proportional to the average kinetic energy of the particles.Theoretical yield The theoretical yield is the mass or amount of product produced according tothe chemical equation assuming 100% reaction of the limiting reagent.Titration A chemical technique in which one solution is used to analyse another solution to findthe concentration or amount of solute.Volatility A qualitative measure of how readily a liquid or solid is vaporised upon heating orevaporation.Water of crystallisation Water molecules that are incorporated into the crystal lattice of manyinorganic salts when they crystallise from aqueous solution.Word equation A summary of a chemical reaction using the chemical names of the reactant andproducts. They are not appropriate at IB level. 6