ANDESCO 2012
Working with MIOX: A Safe Partnership  Safest advanced technology  Safest investment: save customers money  Safest for emp...
The leader in On-Demand Disinfection Chemistry  ►   18 years history   continuous innovation in electrolytic cell design  ...
What is on-site generation (OSG)?                  +                    +         Salt             Water             Power...
OSG is Environmentally BenignOSG reduces carbon emissions12% bleach is 88% water. It takes almost 5 deliveries of bulk ble...
MIOX® On-site Generation System
Superior Chemistry from Electrolysis Expert        Input Salts                                        Output Chemistries  ...
Mixed Oxidants ChemistryDiscovered serendipitously in 1992, optimized systematically                                      ...
What is in Mixed Oxidant Solution (MOS)? ►   Traditional measurements of the additional oxidant(s) in MOS has not been    ...
Mixed Oxidant Solution (MOS)Visible Effect of Trace Hydrogen Peroxide with Hypo   CDC Study - Inactivating Bacillus globig...
Mixed Oxidant Solution (MOS)Benefits and Advantages                          ►   Superior Disinfection                    ...
Mixed Oxidant Solution (MOS)Destroys biofilm more effectively than standard hypochlorite                  Mixed Oxidants D...
Mixed Oxidants Reduce Biofilm and Algae FoulingVisible Effect of Trace Hydrogen Peroxide with Hypo                        ...
MIOX® Wide Range of Generators & Applications                                                            1 to 2000 lbs./da...
MIOX®: World Class Manufacturing                            Albuquerque, NM  18+ years in technology  15+ years in assembl...
Mixed oxidants formunicipal drinking water treatment  Superior microorganism inactivation  Elimination of biofilm  Reduced...
Distribution System                                                  MF/UF                                                ...
Distribution System                                                            MF/UF                                      ...
What is Microflocculation?Microflocculation is a pretreatment mechanism resulting in:  A reduction in coagulant demand for...
Pretreatment with MIOX Mixed Oxidants mayinduce the microflocculation effect, which improves:   Coagulation   Flocculation...
MIOX Customers Report:                 Larger floc that forms more rapidly, even at                 colder temperatures   ...
Turbidity reduced using less Aqualumwhen used with Mixed Oxidant                             McAllan, TX Mixed Oxidant Mic...
Biofilm:  Communities of microorganisms encased within an  extracellular polymeric slime (EPS) matrix living on  surfaces....
Field Evidence - MOS Removes Biofilmsfrom Distribution Systems  Direct (visual)  − Diana WSC in TX, 2 line breaks    occur...
Mixed Oxidant Solution (MOS)Destroys biofilm more effectively than standard hypochlorite                  Mixed Oxidants D...
Installation Profiles
E.A.A.B. Wiesner - Bogota, Colombia • Largest water treatment plant in Colombia • Total plant capacity of 10.3 cubic meter...
E.A.A.B. El Dorado - Bogota, Colombia                     • Water treatment plant in the south of                       Bo...
EPM Plant in Caldas, Antioquia                         • Plant capacity of 150 liters per                           second...
Sopo, Cundinamarca                     • Rural installation donated by a foundation                       to improve acces...
Cali, Colombia:Bottling Plant Replaces Cal-hypo                          Calcium hypochlorite replaced in                 ...
West Columbia, South Carolina:Biofilm removal in municipal application                         Gradual reduction in biofil...
Emerald Coast Utilities, Pensacola, FL:Treating up to 22 MGD wastewater for industrial reuse                            Fi...
Santa Ana Pueblo, New Mexico:Mixed Oxidant Solution for Wastewater Reuse                                             Influ...
Tamaya Hyatt® Regency, New Mexico:MIOX Treating Pools, Spas, Cooling Tower                                       AAA Top 1...
Power Generation Station, Puerto RicoBiofilm removal in power plant & cooling tower         Before MIOX                 Af...
THANK YOU!Diana Lorena Gomez ZUSA Global Market S.A.Office: 212 0144E-mail: dlgomez@usagmsa.com
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El Futuro del agua está claro.

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Raichel Zuback, Experta MIOX

Congreso Andesco de Servicios Públicos y TIC 14º Nacional y 5º Internacional, Cartagena Colombia, Junio 27, 28 y 29 de 2012

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El Futuro del agua está claro.

  1. 1. ANDESCO 2012
  2. 2. Working with MIOX: A Safe Partnership Safest advanced technology Safest investment: save customers money Safest for employees and surrounding community Safest for the environment
  3. 3. The leader in On-Demand Disinfection Chemistry ► 18 years history continuous innovation in electrolytic cell design ► Only company able to produce multiple oxidant based products ► Technology company 18 patents issued; 25 patents pending ► 2,000+ units installed across 30+ countries treating 6 billion gallons/day Municipal Water Food & Industrial & Oil and Gas Treatment Beverage Commercial
  4. 4. What is on-site generation (OSG)? + + Salt Water Power Chlorine OSG gives power to the userThe amount you need, when you need it, and where you need it.Eliminates storage and handling of hazardous chemicals.
  5. 5. OSG is Environmentally BenignOSG reduces carbon emissions12% bleach is 88% water. It takes almost 5 deliveries of bulk bleachto equal the same amount of disinfectant generated by a singledelivery of salt vs. OSG Bulk BleachStorage footprint reduction VSNo disposal of empty chemical containers
  6. 6. MIOX® On-site Generation System
  7. 7. Superior Chemistry from Electrolysis Expert Input Salts Output Chemistries Unique Cell technology Reliable, Self-cleaning Disinfection Chemistries Efficacy Sodium Chloride Salt Hypochlorite Mixed Oxidant Sodium Chloride Salt Hypochlorite with Hydrogen PeroxideQuaternary Ammonium Salt Activated Quaternary Ammonium Hypochlorite Organic & Hydrocarbon Destruction UV Activated + = Hypochlorite UV Light
  8. 8. Mixed Oxidants ChemistryDiscovered serendipitously in 1992, optimized systematically "Log-Kill" Data (geometry, power) Power A Concentration & duration of 5 mg/L mixed oxidant dose as FAC Power B other oxidants depends on: Cryptosporidium inactivation, "log kill" 3.5 Power C 3.0 Power D ► Cell Configuration Power E ► Power 2.5 ► Fluid Flow 2.0 ► Fluid Concentration 1.5 ► Time in Cell ► Temperature 1.0 ► Cell Coating 0.5 ► and more . . . 0.0 The combination of factors leading to optimal oxidant efficacy and Geom etry duration is a key trade secret
  9. 9. What is in Mixed Oxidant Solution (MOS)? ► Traditional measurements of the additional oxidant(s) in MOS has not been successful • Chlorine is a strong oxidant and interferes with measurement ► There are a small number of known compounds formed from reactions of NaCl and H2O HOCl NaOCl ClO2 NaOH Anode (+) O3 H2 Cathode (-) Cl2 H2O2 Products Products O2 OH0, OH+ Through partnership with academia and internal research, hydrogen peroxide (H2O2 ) is the additional oxidant in MOS
  10. 10. Mixed Oxidant Solution (MOS)Visible Effect of Trace Hydrogen Peroxide with Hypo CDC Study - Inactivating Bacillus globigii (B.g.) Hypochlorite Mixed Oxidant Solution 0 min (untreated) 15 min 30 min 45 min 60 min Bajszar, 2009; Validated in 3rd party studies at the Centers for Disease Control and Prevention
  11. 11. Mixed Oxidant Solution (MOS)Benefits and Advantages ► Superior Disinfection ► Superior Biofilm Removal ► Superior Residual Maintenance ► Superior (lower) Disinfection By-Product Formation ► Potential Microflocculation Effect • Can reduce chemical costs and improve water quality BEFORE MIOX AFTER MIOX
  12. 12. Mixed Oxidant Solution (MOS)Destroys biofilm more effectively than standard hypochlorite Mixed Oxidants Destroy Biofilm better than Sodium Hypo Sodium Hypo Extensive biofilm growth Sodium Hypo Coliform and Legionella hits 1.5 mg/L FAC dose 0.2 mg/L FAC residual Mixed Oxidant Solution Biofilm eliminated No bacterial hits MOS 0.6 mg/L FAC dose 0.4 mg/L FAC residual
  13. 13. Mixed Oxidants Reduce Biofilm and Algae FoulingVisible Effect of Trace Hydrogen Peroxide with Hypo BEFORE MIOX Condenser Tube Sheet after extended run at a large industrial cooling tower. AFTER MIOX Condenser Tube Sheet after 2.5 months of using MIOX. BEFORE MIOX Algae is rampant with conventional biocide program at power gen plant. AFTER MIOX Condenser Tube Sheet after 2.5 months of using MIOX.
  14. 14. MIOX® Wide Range of Generators & Applications 1 to 2000 lbs./day per generator Pen RIO Zuni AE Series Puerco VAULT RIO RIO Grande Potable Water 2-3 People ------------------------ to --------------------------- 2-3 Million Pools & Spas 10,000 ------- to -------- 1 Million Gallons Dairy Farms 100 -------- to --------- 5000 Milk Cows Waste Water 1,000 Gallons Day -------- to --------- 100 MGD Produced Water 0.5 ------ to ------- 5 MGD Frack/Flood Water 10 to 100 Barrels / Minute Cooling Tower 50 Tons ------- to -------- 200,000 GPM
  15. 15. MIOX®: World Class Manufacturing Albuquerque, NM 18+ years in technology 15+ years in assembly EPA Approved NSF Certified ISO Compliant Lean Six Sigma High Quality & Testing UL Approved CE Certified Japan WWA Approved
  16. 16. Mixed oxidants formunicipal drinking water treatment Superior microorganism inactivation Elimination of biofilm Reduced formation of DBPs A longer-lasting disinfectant residual Improved taste and odor Microflocculation Iron bacteria control Oxidation of iron, manganese, sulfides, ammonia Chlorine breakpoint reaction at low chlorine-to-nitrogen ratios
  17. 17. Distribution System MF/UF Hollow Fiber Solids Contact Membrane System ClarifierSurface Water Clearwell CIP System RO System (optional) To Process
  18. 18. Distribution System MF/UF Hollow Fiber Solids Contact Membrane SystemSurface Water Clarifier 1. 2. 4. Clearwell 3. CIP System RO System (optional) To Process 1. Microflocculation 2. MF/UF Pre-feed 3. Clean in Place (CIP) 4. Final Disinfection
  19. 19. What is Microflocculation?Microflocculation is a pretreatment mechanism resulting in: A reduction in coagulant demand for the same final (filtered water) turbidity OR a reduction in final turbidity at the same coagulant demand.
  20. 20. Pretreatment with MIOX Mixed Oxidants mayinduce the microflocculation effect, which improves: Coagulation Flocculation Settling-clarification FiltrationThese process improvements may: Reduce chemical costs Reduce system downtime Improve system performance
  21. 21. MIOX Customers Report: Larger floc that forms more rapidly, even at colder temperatures Heavier floc that is conducive to good settling compared to chlorine dioxide and chlorine in pretreatment Reductions of up to 40% in required coagulant and flocculent Reductions of disinfection by-product (DBP) formation due to better organic precursor removal Improved filter run time; reduced down time
  22. 22. Turbidity reduced using less Aqualumwhen used with Mixed Oxidant McAllan, TX Mixed Oxidant Microflocculation Jar Test 3 2,5 Turbidity (NTU) 2 aqualum 1,5 MOS/aqualum 1 0,5 0 35 40 45 50 55 60 Aqualum Dose (ppm)
  23. 23. Biofilm: Communities of microorganisms encased within an extracellular polymeric slime (EPS) matrix living on surfaces. Typically composed of many species of microorganisms, including bacteria fungi, algae and protozoa. Difficult to remove once initial adhesion occurs. Found in aqueous environments and are often resistant to disinfection. Can shelter disease-causing microorganisms, such as Top Menu Legionella, Listeria, and temperature resistant bacterial spores.
  24. 24. Field Evidence - MOS Removes Biofilmsfrom Distribution Systems Direct (visual) − Diana WSC in TX, 2 line breaks occurred simultaneously − At a KOA campground in Great Falls, MT, mixed oxidant solution removed heavy biofilm in 2 weeks and eliminated coliform hits Indirect − More consistent, lower residual at Left: Pipe treated with chlorine alone – same dose a biofilm slime is visible; only 200 feet − Lower TTHMs in the distribution from disinfection station. system Right: Pipe treated with MOS 0.5 miles from disinfection station
  25. 25. Mixed Oxidant Solution (MOS)Destroys biofilm more effectively than standard hypochlorite Mixed Oxidants Destroy Biofilm better than Sodium Hypo Sodium Hypo Extensive biofilm growth Sodium Hypo Coliform and Legionella hits 1.5 mg/L FAC dose 0.2 mg/L FAC residual Mixed Oxidant Solution Biofilm eliminated No bacterial hits MOS 0.6 mg/L FAC dose 0.4 mg/L FAC residual
  26. 26. Installation Profiles
  27. 27. E.A.A.B. Wiesner - Bogota, Colombia • Largest water treatment plant in Colombia • Total plant capacity of 10.3 cubic meters per second • MIOX units treating approximately 40% of plant capacity with 2000 ppd FAC to provide water for roughly 1.8 million people in Top Menu Bogota • Wiesner will ultimately replace all gas chlorine with MIOX equipment
  28. 28. E.A.A.B. El Dorado - Bogota, Colombia • Water treatment plant in the south of Bogota • Used in pretreatment for microflocculation and final disinfection • 100% replacement of chlorine gas • Treats water for 420,000 people Top Menu
  29. 29. EPM Plant in Caldas, Antioquia • Plant capacity of 150 liters per second in a conventional treatment plant • 60 ppd FAC as mixed oxidant to provide water for roughly 80,000 people in Caldas, Antioquia • Benefits include: improved plant safety after replacing chlorine gas and improved residual stability in system distribution Top Menu
  30. 30. Sopo, Cundinamarca • Rural installation donated by a foundation to improve access to safe water • Replaced chlorine gas, improving safety for the community Top Menu
  31. 31. Cali, Colombia:Bottling Plant Replaces Cal-hypo Calcium hypochlorite replaced in 2007 with MIOX Disinfection is for: Beverages (dechlorinate afterwards) − JuiceBefore MIOX − Carbonated beverage − Bottled water Filter backwash Cooling towersAfter MIOX
  32. 32. West Columbia, South Carolina:Biofilm removal in municipal application Gradual reduction in biofilms in the clearwells and distribution Chlorine residual stability allowed lower mixed oxidant solution dosing at the plant TTHM and HAA5 concentrations steadily declined Conversion from chloramination using chlorine gas and anhydrous ammonia (gas) to FAC as MOS resulted in improved plant safety and chemical cost savings
  33. 33. Emerald Coast Utilities, Pensacola, FL:Treating up to 22 MGD wastewater for industrial reuse Five RIO H5 (500 lbs/day) went live in 2010 Largest public works project in Escambia County history. Replaces odorous Main Street Wastewater Treatment Plant in downtown Pensacola after Hurricane Ivan in 2006. 2,500 lbs/day total installed capacity Reclaimed water transmission & reuse system 100% Beneficial reuse: – 17MGD goes to Gulf Power Plant Crist Cooling Tower – 6 MGD goes to International Paper process water. Up to 22 million gallons a day.
  34. 34. Santa Ana Pueblo, New Mexico:Mixed Oxidant Solution for Wastewater Reuse Influent from residential and business districts, the Hyatt Regency Tamaya, and the Star Casino WWTP supplies 50,000 gallons at a time to golf course, with remaining irrigation needs met by groundwater Disinfection converted in 2007 from competitor’s hypochlorite to MIOX mixed oxidant solution“MIOX played an important role in helping the Pueblo meet our environmental goals.” Glenn Tenorio, Chairman of Tribal Utilities Authority
  35. 35. Tamaya Hyatt® Regency, New Mexico:MIOX Treating Pools, Spas, Cooling Tower AAA Top 10 Getaway – one of the nations top family getaways (swimming pools) 2008: RIO installed to treat outside pools, whirlpool, indoor spas 2011: AE-4 installed to treat cooling tower water“Safety issues were our biggest motivator. We eliminated the need to manuallytransfer 55-gal barrels of chemicals (liquid bleach) each day, which creates asafer environment all around – it’s a win-win-win.” – Chris Dillon, Director of Engineering
  36. 36. Power Generation Station, Puerto RicoBiofilm removal in power plant & cooling tower Before MIOX After MIOX Biofilm with conventional Biofilm eliminated with biocide program mixed oxidant solution
  37. 37. THANK YOU!Diana Lorena Gomez ZUSA Global Market S.A.Office: 212 0144E-mail: dlgomez@usagmsa.com
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