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10_CI4_SILICOAT_Eliseo Monfort

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  • 1. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Organizers: Supporters: Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 2. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Industrial implementation of processes to render RCS safer in manufacturing processes - SILICOAT Organizers: Funding programme: FP7 – Research for SME associations Call: 31025060 Budget: Supporters: 1 537 331,40 Total Length: Start 01/11/2011 - 1 043 500,11 UE Funding End 31/10/2014 Website of the project: www. silicoat.eu Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 3. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Consortium: – Co-ordinator: Organizers: – Partners and roles: Supporters: SMEs SME-AGs RTDs Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 4. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Background: RCS inhalation No direct relationship Organizers: demonstrated. Non-conclusive researches. Controversy among different authors. Conclusion: There are important “external factors” in the pathogenesis. Supporters: Demonstrated fact: high RCS dosis inhalation produces silicosis. Silicosis IARC suggests that silicosis enhances lung cancer risk Lung cancer Abstract: The present project is the industrial implementation of coating treatments in the ceramic manufacturing processes, transforming Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) the quartz-containing of Sustainability Area of intrinsically safe products. Head raw materials into ITC Cerámica Innova 4: From research to market
  • 5. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS • Certain substances can nullify RCS toxicity: Polivinilpiridine-N-oxide (PVPNO) (Schlipköter & Brockhaus, 1961) Organizers: Aluminium lactate (Bégin et al., 1986) Phospholipids (Wallace et al., 1986) Organosilanes (Castranova et al., 1996) Supporters: • These substances: Form a molecular coating on the RCS surface saturating silanol groups (SiOH). Dr. Eliseo Monfort been industrially implemented yet. They have not Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 6. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Organosilanes: Example: PTMO CH3 CH3 CH2 CH2 CH Organizers: 2 + H O 2 CH2 Hydrolysis Si Si OCH3 CH3O + CH3OH OCH3 CH3O OCH3 OH CH3 Supporters: CH2 CH3 CH2 CH2 H + H O O O CH2 H Silanization CH3O Si H OCH3 + H2O H Si Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Si Si Si Head of Sustainability Area of ITC OCH3 CH3O O O O OH Cerámica Innova 4: From research to market Si Si Si
  • 7. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Objectives:  Develop and implement respirable crystalline silica (RCS) coating technologies in the ceramic process, Organizers:  To render RCS-containing materials use intrinsically safe from the toxicological point of view. Supporters: Results: The technical viability of the implementation of the coating treatment in the ceramic process has been verified at laboratory scale, without negative effects on either the process parameters or the final product properties. The first toxicological tests confirm an inhibitory effect Chemical Engineering Professor (Universidad Jaume I) Dr. Eliseo Monfort Gimeno –of the selected coatings on the RCS toxicity. Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 8. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Results PTMO coating detection by thermogravimetry Organizers: 0 Pérdida de masa · 10 3 (%/ºC) -0,2 -0,4 0% PTMO -0,6 Supporters: 0.5% PTMO -0,8 -1 0.1% PTMO -1,2 1% PTMO -1,4 10% PTMO -1,6 Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) -1,8 Head of Sustainability Area of ITC 200 300 400 500 600 700 800 Temperatura (ºC) Cerámica Innova 4: From research to market
  • 9. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Results: Nano-alumina coating micrographs Organizers: Supporters: Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Original surface Cerámica Innova 4: From research to market Coated surface
  • 10. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Results: Toxicity tests results (including DQ12) Organizers: 60,0 25,0 20,0 Tail intensity (%) 40,0 30,0 20,0 Supporters: 15,0 10,0 SI VO F1 Co nt ro l DQ 12 0,0 SI VO 0,0 F1 Co nt ro l DQ 12 5,0 0, 4 SI VO PT 0,2 M O PT 1,4 M O PT 0,5 M O Na 0, no 1 -a lu m in a 10,0 0, 4 SI VO PT 0,2 M O PT 1,4 M O PT 0,5 M O Na 0, no 1 -a lu m in a Citotoxicity (%) 50,0 Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 11. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Results: Toxicity tests results Organizers: 10,0 Tail intensity (%) 12,0 12,0 10,0 8,0 6,0 Supporters: 4,0 8,0 6,0 4,0 Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market Co nt ro l SI VO SI VO F1 0,0 Co nt ro l 0,0 F1 2,0 0, 4 SI VO 0, 2 PT M O 1, 4 PT M O 0, 5 PT M O Na 0, no 1 -a lu m in a 2,0 0, 4 SI VO 0, 2 PT M O 1, 4 PT M O 0, 5 PT M O Na 0, 1 no -a lu m in a Citotoxicity (%) 14,0
  • 12. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Obtained experience  A coating process has been developed to render RCS Organizers: safer.  Several coating agents have demonstrated their efficiency from a toxicological viewpoint. Supporters:  Some industrial trials are in progress to implement this process at industrial scale in different ceramic manufacturing companies.  The developed process is a promising candidate to be Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) included in the “NEPSI Good practices Guide” Head of Sustainability Area of ITC Cerámica Innova 4: From research to market
  • 13. 4th Technology-Business Networking Event HABITAT, CONSTRUCTION, ARCHITECTURE & CERAMICS Organizers: Supporters: Dr. Eliseo Monfort Gimeno – Chemical Engineering Professor (Universidad Jaume I) Head of Sustainability Area of ITC Cerámica Innova 4: From research to market