Perstorp - Plasticizer for Sensitive PVC Applications

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"New Unique Plasticizer for Sensitive PVC Applications" was presented at PVC 2014 in Brighton,

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Perstorp - Plasticizer for Sensitive PVC Applications

  1. 1. New Unique Plasticiser for Sensitive PVC Applications PVC 2014, Brighton Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions
  2. 2. Table of Contents Introduction to Perstorp Perstorp in the PVC industry Perstorp plasticisers New Unique plasticiser – Pevalen™ Summary
  3. 3. Perstorp in brief  World leader in several sectors of the specialty chemicals market  Pioneer in formalin chemistry, plastics and surface materials  Perstorp was formed in 1881, over 130 years of winning formulas  Since December 2005 controlled by PAI partners, a leading European private equity company  Annual turnover of more than 10 billion SEK in 2013  About 1,400 employees in 22 countries  Production plants in Europe, Asia and North America  Sales offices in all major markets
  4. 4. Perstorp in the PVC industry  Perstorp is a fully integrated plasticiser producer based on the west coast of Sweden since 1980’s  Perstorp exited the DOP business in 2012  Storage facilities in UK, Belgium, Germany and Portugal to serve Europe  Focus on European market and sustainable growth  Member of ECPI, VinylPlus and founding member of PlasticiserPlus
  5. 5. Perstorp believes in plasticisers  Perstorp is making its largest investment in history  Based on our own technology and backwardly integrated in raw materials  It will be on stream in Q1 2015  Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM  This investment will increase the production by 150 000 MT
  6. 6. EmolteneTM 100 PevalenTM Investment for a more sustainable future Versatile general PVC plasticiser  Established C10 (DPHP) GP plasticiser  Excellent versatility and flexibility  Expands lifespan of end products  High technical performance, with tough outdoor resistance High performance polyolester plasticiser  Highly efficient in providing softness  Easy to process and use  Low volatility ensuring no VOC and consistent properties  New capacity for Valeraldehyde and its derivatives  Strengthen our production platform  Fully integrated an secure supply chain  Ability to offer competitive and safe products Innovative plasticiser for sensitive applications Flexible, versatile & safe
  7. 7. Emoltene™ 100 and Pevalen™ focus on different markets Emoltene™ 100 - Durable applications – Wire and cables – Films & sheets e.g. roofing membranes, pool and pond liners – Coated fabrics; e.g. tarpaulins – Automotive interiors Pevalen™ - Sensitive applications – Coated fabrics; e.g. table cloths, protective clothing – Films & sheets; e.g. office materials, furniture foils – Flooring; e.g. public buildings, hospitals, domestic – Plastisols; e.g. wall paper, toys – Moulded parts; e.g. grips, hoses
  8. 8. Pevalen ™ shows low intial viscosity Pevalen ™ has excellent viscosity stability Plastisol Viscosity resin P15 0 2 4 6 8 10 12 14 2.5 20 2 hours 100 2.5 20 24 hours 100 2.5 20 5 days 100 Pas DINP Pevalen™
  9. 9. Plastisol Viscosity resin P2170 0 2 4 6 8 10 12 2.5 20 2 hours 100 2.5 20 24 hours 100 2.5 20 5 days 100 Pas DINP Pevalen™ Pevalen ™ shows low intial viscosity Pevalen ™ has excellent viscosity stability
  10. 10. Pevalen ™ has faster gelation than other plasticiser Rheology 1 10 100 1000 10000 100000 1000000 25 75 125 175 ElasticModulusG',Pa Temperature, C° Pevalen™ DINP DOTP DINCH
  11. 11. Pevalen ™ yields PVC with lower hardness values Pevalen ™ is a very efficient plasticiser Hardness 68 70 72 74 76 78 80 82 P15- Pevalen™ P15- DINP P2170 - Pevalen™ P2170 - DINP ShoreA
  12. 12. Pevalen ™ yields softer films Strain is at high level with Pevalen ™ Tensile measurement PevalenTM PVC quality Stress at 100% strain (N/mm2) Stress at 200% strain (N/mm2) Stress at 300% strain (N/mm2) Max stress (N/mm2) Strain at break (%) Pevikon P2170 8.0 (0.5) 13 (0.8) 17 (1.2) 24 (2.8) 440 (47) Pevikon P1412 7.3 (0.3) 11 (0.6) 15 (0.8) 21 (2.2) 430 (37) Vinnolit P70 7.1 (0.4) 11 (0.5) 15 (0.7) 21 (1.5) 440 (13) Solvin 367 NF 8.2 (1.0) 13 (1.6) 18 (2.4) 23 (4.8) 400 (79) DINP PVC quality Stress at 100% strain (N/mm2) Stress at 200% strain (N/mm2) Stress at 300% strain (N/mm2) Max stress (N/mm2) Strain at break (%) Pevikon P2170 7.3 (0.2) 11 (0.3) 15 (0.5) 20 (2.3) 430 (69) Pevikon P1412 8.1 (0.5) 12 (0.8) 16 (1.1) 21 (2.3) 430 (37) Vinnolit P70 7.7 (0.3) 12 (0.4) 15 (0.6) 20 (0.9) 420 (28) Solvin 367 NF 8.8 (0.4) 13 (0.7) 18 (0.8) 26 (1.5) 480 (29)
  13. 13. Both plasticisers gives full transparency in resin P15 In resin P2170 Pevalen ™ has better compatibility Clarity DINP PevalenTM P15P2170
  14. 14. Pevalen ™ yields film with less initial colour In P15 Pevalen ™ is equal in heat stability to DINP In P2170 Pevalen ™ is more sensitive to heat Thermal stability DINP PevalenTM P2170P15 DINP PevalenTM
  15. 15.  Pevalen™ is unaffected in the QUV environment QUV 0 10 20 30 40 50 60 70 80 0 h 500 h 1000 h 1500 h Yellowindex,Yi DINP DINCH DOTP Pevalen™
  16. 16.  Pevalen ™ gives an unique combination of high plasticising efficiency and low volatility Unique property combination 66 67 68 69 70 71 72 73 74 75 76 77 0 0,5 1 1,5 2 2,5 Hardness,ShoreA Volatility, % DUP PEVALEN™ DINCH DOTP TOTM
  17. 17.  Pevalen ™ gives good fogging properties Fogging 0 0,5 1 1,5 2 2,5 3 0 10 20 30 40 50 60 70 80 90 TOTM PEVALEN™ DINCH DOTP Reflectometric,% Gravimetric,mg
  18. 18. Summary  Perstorp is a reliable supplier of Emoltene™ 100, the major type of plasticiser for wire & cable, film & sheets and automotive interior  Perstorp is an innovative company developing a polyol ester plasticiser - Pevalen™  Pevalen™ has a good compromise on shelf life and ease of fusion  Pevalen™ retains the visual appearance by improved clarity and low yellowing  Pevalen™ has a unique combination of high efficiency and low volatility  The low volatility is reflected in the good fogging values Pevalen™ brings
  19. 19. Acknowledgement My very special thanks to INEOS Chlor Vinyls Vulcaflex S.p.A
  20. 20. Thank You for your attention! Anders Magnusson Market Development Manager Don’t hesitate to contact me if you have any questions! anders.magnusson@perstorp.com Perstorp Group

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