• Like
Hazardous materials guide
Upcoming SlideShare
Loading in...5
×

Thanks for flagging this SlideShare!

Oops! An error has occurred.

Hazardous materials guide

  • 1,065 views
Published

Hazardous Materials Guide for First Responders

Hazardous Materials Guide for First Responders

  • Full Name Full Name Comment goes here.
    Are you sure you want to
    Your message goes here
No Downloads

Views

Total Views
1,065
On SlideShare
0
From Embeds
0
Number of Embeds
0

Actions

Shares
Downloads
68
Comments
1
Likes
1

Embeds 0

No embeds

Report content

Flagged as inappropriate Flag as inappropriate
Flag as inappropriate

Select your reason for flagging this presentation as inappropriate.

Cancel
    No notes for slide

Transcript

  • 1. Hazardous Materials Guide for First RespondersFederal Emergency Management Agency United States Fire Administration
  • 2. How to Use this GuideIf you know the Chemical/Material Name: 1. Go to the Specific Material Guides Ë locate the chemical in the alphabetical listing 2. If you are unable to locate the chemical in the Specific Material Guide: Ë Go the Alphabetical Material Name Index Ë locate the chemical in the alphabetical listing Ë go to the page listed for guidance information 3. If the chemical is not found in the index, go to the HAZMAT General Response SchemeIf you have only the UN Number for the Chemical/Material: 1. Go to the UN/NA Number Index Ë locate the UN/NA number in the numerical listing Ë go to the page listed for guidance information 2. If material UN number is not found in the index go to the HAZMAT General Response SchemeIf you have only NFPA Placard Information: 1. Go to the guidance information for using the NFPA 704 PlacardIf you have only DOT Placard information: 1. Go the HAZMAT General Response Scheme WARNING! The best time to learn how to use this book is BEFORE you need it. Train with this book the way you would train with any new piece of equipment - in advance!
  • 3. Hazardous Materials Guide for First RespondersThe information in this book was collected from a variety of sources which were reviewed by the Firefighters’ Safety Study Technical Commit-tee and are believed to be accurate. However, the Federal Emergency Management Agency makes no claim that these data and recommenda-tions are either correct or sufficient and assumes no liability for any adverse consequences arising from their use.The action recommendations in this book should be considered as suggestions only. Specific circumstances at the scene of an incident as well asthe number and training of first responders will dictate what actions are actually appropriate. Final decisions are the responsibility of the IncidentCommander.
  • 4. AcknowledgmentsThis document was prepared under a Cooperative Agreement (EMW-93-K-4351) between the Federal EmergencyManagement Agency/United States Fire Administration and the University of Louisville. The data was assembled andformatted by an active Writing Committee with direction and oversight by the Firefighters’ Safety Study Project Commit-tee. Technical content was also reviewed under a separate contract (EMW-3-4649) with Louisiana State University.Writing CommitteeGeorge C. Rodgers, Jr., Editor Steve Burton Gary M. HartMedical Director Assistant Chief, Fire/EMS/Hazmat PresidentKentucky Regional Poison Center Rohm and Haas Co., Louisville (Kentucky) Paragon Enterprises, Inc. Plant Louisville (Kentucky)Nancy J. Matyunas, Associate Editor Thomas L. Coomes, II Brad LearnClinical Assistant Professor of Pediatrics Environmental Health Coordinator/ Medical Training Coordinatorand Toxicology HazMat Response, Ret. City of Louisville (Kentucky)University of Louisville Louisville/Jefferson County (Kentucky) Division of Fire Health DepartmentClark Bledsoe A. J. “Bud” FeketeAssistant Director Deputy ChiefJefferson County (Kentucky) Louisville (Kentucky) Fire Department, Ret.Planning and Environmental Management Coordinator of Technical Hazards, Louisville/ Jefferson County Disaster and Emergency ServicesThis project could not have been undertaken without the expertise of the following individuals who providedinvaluable guidance and input by serving on the Firefighters’ Safety Study Project Committee.Steven C. Bailey (Chair) Patricia Frazier George C. Rodgers, Jr.Assistant Chief, Ret. Tri Data Corporation Medical DirectorSeattle (Washington) Fire Department Kentucky Regional Poison CenterJames Brizzell Richard L. Hartnett Jerry M. Schroy, P. E., DEEChief, Hazardous Materials Bureau Chief, Emergency Management Division Senior FellowNY Office of Fire Prevention & Control Boston (Massachusetts) Fire Department Solutia Inc.Gary E. Curmode Charles B. Henry, Jr. Alan L. SchneiderChief Institute for Environmental Studies Chemical EngineerSedgwick County (Kansas) Fire Department Louisiana State University US Coast GuardJohn Eversole Bradley S. PabodyChief, Hazardous Materials Fire Program SpecialistChicago (Illinois) Fire Department United States Fire AdministrationIn addition to the project committee members listed above, the following organizations and individuals provided invalu-able assistance in the field testing and evaluation of the Hazardous Material Guide for First RespondersNational Association of State Fire MarshalsRay E. Carnahan Michael Durst Donald BlissCommander, Fire Marshal’s Office State Fire Marshal State Fire MarshalArkansas State Police Nebraska State Fire Marshal’s Office New Hampshire Division of Fire Safety
  • 5. Table of ContentsHow to Use this Guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Inside Front CoverIntroduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1Alphabetical Material Name Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7UN/NA Number Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39Specific Material Guides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49Materials Summary Response Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481DOT Placards — Chart 10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 521Silhouettes of Rail Cars, Tank Trucks and Chemical Tanks . . . . . . . . . . 525General Approach to a Hazmat Incident . . . . . . . . . . . . . . . . . . . . . . . . . 547Glossary of Terms and Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . 557Important Telephone Numbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 562First Responder Strategy Using the NFPA 704 Placard . . . . . . . Inside Back CoverHazmat General Response Scheme . . . . . . . . . . . . . . . . . . . . . Outside Back Cover
  • 6. IntroductionI. Objectives (E) An understanding of the role of the first responder awareness individual in the employers emergency responseThis book is the result of an extensive study of available plan including site security and control and the U.S.hazardous materials response resources for first responders Department of Transportation’s Emergency Responseundertaken by the United States Fire Administration (USFA) Guidebook.as part of the Firefighters’ Safety Study Act of 1990 (P.L. 101-446). The study concluded that, while several excellent and (F) The ability to realize the need for additional resources,technically accurate resources are available, none are directed and to make appropriate notifications to the communicationto the specific needs of the first responder trained at the center.Awareness or Operational Levels of Training; the training levelsof most first responders. It is the hope and the intent of the First Responder Operations Level: First responders at theUSFA that this book will be that much needed resource. Operations Level are individuals who respond to releases or potential releases of hazardous substances as part of the initialThis book provides important information for the initial response response to the site for the purpose of protecting nearbyto both transportation and fixed facility incidents. It has been persons, property, or the environment from the effects of thedesigned to present the first responder with a maximum amount release. They are trained to respond in a defensive fashionof useful key information in a limited amount of space. As with without actually trying to stop the release. Their function is toany reference, it cannot include all information that might be contain the release from a safe distance, keep it from spreading,useful or discuss all situations which might occur; nor can it and prevent exposures. First responders at the Operationsreplace the training and experience of individual responders. Level shall have received at least eight hours of training orThe information contained in this book has been reviewed by have had sufficient experience to objectively demonstrateseveral sources and is as technically accurate as possible. competency in the following areas in addition to those listedFor major incidents it will be necessary to obtain more detailed for the Awareness Level and the employer shall so certify:information from other resources as well as more advancedexpertise from those with more extensive training. (A) Knowledge of the basic hazard and risk assessment techniques.It is assumed that those using this book will have hadsome training in hazardous materials response. Because (B) Know how to select and use proper personal protectivemost first responders are trained at the Awareness or equipment provided to the first responder operational level.Operational levels, this book is directed at appropriateresponses for these levels of training. These levels are defined (C) An understanding of basic hazardous materials terms.below as published by the National Fire Protection Association(NFPA 472, 1992) and the Occupational Safety and Health (D) Know how to perform basic control, containment, and/orAdministration (OSHA 1910.120). confinement operations within the capabilities of the resources and personal protective equipment available withOSHA 1910.120 their unit.First Responder At Awareness Level: First responders at (E) Know how to implement basic decontamination procedures.the Awareness Level are individuals who are likely to witnessor discover a hazardous substance release and who have been (F) An understanding of the relevant standard operatingtrained to initiate an emergency response sequence by notifying procedures and termination procedures.the authorities of the release. First responders at theAwareness Level shall have sufficient training or have had II. How The Book is Organizedsufficient experience to objectively demonstrate competencyin the following areas: The body of this book is divided into seven sections: • Indexes: ALPHABETICAL MATERIAL NAME INDEX followed by a UN/(A) An understanding of what hazardous substances are, and NA NUMBER INDEX. the risks associated with them in an incident. • SPECIFIC MATERIAL GUIDES: specific recommendations for 430(B) An understanding of the potential outcomes associated commonly encountered materials. with an emergency created when hazardous substances are present. • MATERIALS SUMMARY RESPONSE TABLE: summary information for 1,422 less commonly encountered materials.(C) The ability to recognize the presence of hazardous substances in an emergency. • DOT PLACARDS - CHART 10.(D) The ability to identify the hazardous substances, if • SILHOUETTES OF RAIL CARS, TANK TRUCKS AND CHEMICAL TANKS. possible. 1
  • 7. • GENERAL APPROACH TO A HAZMAT INCIDENT. found in the top center of each page. Underneath the primary• GLOSSARY OF TERMS AND ABBREVIATIONS used in the book. name is the UN (United Nations) number or the NA (North American) number. The UN number is commonly used forThe main body of the book provides information on about 1750 materials in commerce and can be found on shipping papers.different materials. The materials included in these sections A few materials in this section do not have an assigned UNinclude most of those which have been reported to have been number. This may mean either that the material is notinvolved in hazardous materials incidents. Most drugs have considered a hazard, or that it is not found in transport in abeen excluded. Materials were assigned to the SPECIFIC MATERIAL sizeable amount. The shipping name of the material appearsGUIDE section or the MATERIALS SUMMARY RESPONSE TABLE based directly under the chemical name. Finally, other less commonlyupon the likelihood that they would be encountered and the used names for the material are listed.magnitude of the hazards they represent, using a formuladesigned for this project. The information in these two sections In the upper right hand corner of the page are the DOTis intended to be used during an actual incident. placard(s)/label(s) assigned to the material when transported within the United States. A complete list of current DOTThe GENERAL APPROACH TO A HAZMAT INCIDENT section provides placards is found in Chart 10 on page 521. For a few materials,specific information about a number of different response no specific DOT placard designation has been made in 49CFRscenarios. It also provides useful information and techniques and this area is left blank.for assisting in the identification of materials. This sectionshould be studied as part of training for Hazmat response. It is In the upper left corner of the page is the NFPA 704 placardnot intended for use during an actual incident. providing summary information on acute health, fire and reactivity hazards plus any special concerns such as waterFollowing the General Approach section is a Glossary of the reactivity which apply to the material. An explanation of thetechnical terms and abbreviations used throughout the book. number designations used in the NFPA placard taken from /While the authors have tried to use simple and straightforward NFPA 704 is found on page 550. The placard is commonlylanguage, some terms may not be familiar to all users. Also found on storage containers or is posted at fixed facilities.included in this last section are several Appendices providing When posted on fixed facilities each designation representsreference information mentioned in the text. the worst hazard in that category within the building or facility. The placard is not found on materials in transport.This book has been extensively indexed using all of the materialnames and synonyms (other names for the same chemical) NFPA 704 designations were taken, when available, from thefound in the book. There is a separate index for UN and NA 1994 editions of NFPA 49 and NFPA 325. If the material wasnumbers which are commonly found on shipping papers when not rated in these references, values were determined andmaterials are in transport. While the SPECIFIC MATERIAL GUIDES assigned from published data, where available, or were basedsection is arranged in alphabetical order by the most widely on reasonable estimation from data published on structurallyused name of the material, the index should be used as the similar materials, using the definitions for these designationsmost rapid way of locating information about a specific from NFPA 49. If the information in the placard is from thematerial. NFPA 49 or NFPA 325, the designation “NFPA” appears along the right edge of the placard. If there is no such designation,This book does not contain specific recommendations about the content of the NFPA 704 placard was determined by theisolation or evacuation distances. Because this book is authors.designed to be used in a wide range of scenarios involvingdifferent container sizes, it was felt that the calculation of such Below the list of synonyms may appear a section printed in reddistances could be misleading and perhaps dangerous. entitled WARNING. This section is vitally important. It providesIsolation distances are best determined by those trained above crucial information about hazards that are immediately lifethe operations level, taking into account the amount of material threatening to the first responder. A WARNING indicates ainvolved, the weather conditions and the specific very dangerous material because of the health risk or becausecircumstances of the release. of the extreme fire, explosion or reactivity risk(s). Most materials will not have a WARNING section. This does not mean thatIII. How to Use The Specific Material Guides (Chemical they are not dangerous and cannot injure or kill, only that they Specific) Pages are not likely to do so if they are handled properly.The SPECIFIC MATERIAL GUIDES (RED TAB) provides detailed Below the WARNING section is a section entitled HAZARDS.response information for 430 materials. These materials were This section describes the physical, chemical, or toxicsystematically selected based on their likelihood of being properties of the material which create risks for the firstencountered and the magnitude of the hazard they pose to responder. This section includes such things as explosionthe first responder. An example of a specific material guide hazard, flammability risk and acute health hazards. Hazardsis shown in Figure 1 on page 4. are arranged in the approximate order of their importance to the first responder.The most widely accepted chemical name for the material is2
  • 8. Next to the Hazards is a section entitled Description. This more detailed references as an indexing number. It is providedsection describes what the material looks and smells like, as another positive identifier and to allow quick reference toalong with some important information about the physical other data bases.properties of the material, such as whether it floats or sinksin water or whether it is heavier or lighter than air (if it is a IV. How to Use the Materials Summary Response Tablegas). The information in this section may be useful in verifyingthe identity of a hazardous material and in anticipating some The MATERIALS SUMMARY RESPONSE TABLE (YELLOW TAB)of its actions. provides summary information on 1,422 additional materials. These materials are either less likely to be encountered byIn the middle of the page are sections entitled Awareness the first responder. This table is arranged in alphabetic orderand Operational Level Training Response and using the most common chemical name of the material. ForOperational Level Training Response. These sections list each material the UN number and DOT placard designationthe appropriate actions for the first responder trained to each are provided, if available. NFPA designations are provided forof these two levels of expertise. Not all of the statements all materials. In the case where NFPA designations were notlisted may be appropriate for every situation, but actions should available from NFPA 49 or 325, values were assigned by thenot be more aggressive than those listed. The most important authors using NFPA 49 definitions along with available datarecommendations are given first. Remember that these are on the material or on structurally similar materials. NFPA 704initial recommendations for the first responder. They may be designations taken from NFPA sources are shown in greenmodified by the on-scene Hazmat Incident Commander. while the those assigned by the authors are in black.Awareness Level Response actions are all defensive innature. Operational Level Response actions are divided intotwo general situations, those involving releases of materialwithout an accompanying fire and those where a fire is involved,whether or not the material itself is burning. OperationalLevel Responders must remember that actions listed underAwareness and Operational Level Response should becompleted before beginning the more definitive OperationalLevel Response actions.At the bottom of the page is a First Aid section. Theserecommendations should be used in caring for victims whoare out of the Hot zone. Rescue of victims from within a Hotzone should only be performed by trained personnel wearingappropriate chemical resistant gear and is not generally a firstresponder action.Removal of hazardous material from the skin, eyes or clothingof a victim (decontamination) is usually the most importantfirst aid action that can be initiated. It should be performedonly by appropriately trained and equipped individuals. Rapidremoval of the material may be the difference between a minorinjury and a serious injury. The details of decontaminationtechniques are beyond the scope of this book. In general,using large quantities of water to rinse off materials is almostalways the first choice for decontamination in the field.Materials which are so toxic that first aid should not beperformed on contaminated victims because of the risk ofserious injury to the responder are clearly labeled. There arevery few antidotes for treating victims exposed to chemicalsand they are listed in this section for the benefit of hospitalpersonnel who may care for these victims. Other First Aidinformation is also provided.Finally, at the middle of the page below the first aid section isa CHEMICAL ABSTRACTS SERVICE REGISTRY NUMBER(CAS: _ _ _-_ _-_). This is a specific identifying number givento each chemical by the Chemical Abstract Service. Mixturesare usually not assigned CAS numbers. While not commonlyused in shipping, the CAS number may be found on containersand Material Safety Data Sheets (MSDS) and is used by many 3
  • 9. Figure 1. HYDROGEN CYANIDE 4 (STABILIZED) 4 2 UN 1051 Shipping Name: Hydrogen cyanide, stabilized with less than 3 percent water PA Other Names: AC Hydrocyanic acid solution NF HCN Prussic acid Hydrocyanic acid WARNING! POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU! Firefighting gear (including SCBA) provides NO protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel EXTREMELY FLAMMABLE! Hazards: Description: Odor is not a reliable indicator of the presence of toxic Colorless liquid that boils at 78˚ F amounts of vapor Sweet odor like bitter almonds; many people cannot smell it May react with itself without warning with explosive Dissolves slowly in water but is soluble in water violence Extremely flammable Container may BLEVE or explode when exposed to fire Vapors are slightly lighter than air but will collect and stay Vapors may travel long distances to ignition sources and in low areas flashback Transported in red and white candy striped containers Vapors in confined areas (e.g., tanks, sewers, buildings) Produces large amounts of vapor may explode when exposed to fire Freezes at 8˚ F Vapors are slightly lighter than air but will collect and stay Operational Level Training Response: in low areas RELEASE, NO FIRE: Combustion products are less toxic than the material itself Stop the release if it can be done safely from a distance Awareness and Operational Level Training Use large amounts of water well away from the material to Response: disperse vapors - contain runoff DO NOT ATTEMPT RESCUE! Ventilate confined area if it can be done without placing Stay upwind and uphill personnel at risk Determine the extent of the problem FIRE: BACK OFF! - Isolate a wide area around the release or If material is on fire and conditions permit, DO NOT fire, deny entry and call for expert help EXTINGUISH; combustion products are less toxic then the Remove all ignition sources original material. Cool exposures using unattended monitors. For container exposed to fire evacuate the area in all Specially trained personnel operating from a safe distance directions because of the risk of BLEVE or explosion can fight fires using alcohol resistant (AFFF) foam or dry Evacuate the immediate area and downwind for a large chemical if available in sufficient amounts. Under favorable release conditions, experienced crews can use coordinated fog Notify local health and fire officials and pollution control streams to sweep the flames off the surface of the burning agencies liquid. Do not direct straight streams into the liquid. If material or contaminated runoff enters waterways, notify Cool exposed containers with large quantities of water downstream users of potentially contaminated water from unattended equipment or remove intact containers if it can be done safely If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid: DO NOT ATTEMPT RESCUE! The contaminated victim poses a health risk to the responder Decontaminate the victim from a safe distance with a stream of water; have the victim remove clothing if possible; provide Basic Life Support/CPR as needed Decontaminate the victim as follows: Inhalation - remove the victim to fresh air and give oxygen if available Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes Eye - rinse eyes with large volumes of water or saline for 15 minutes Swallowed - do not make the victim vomit Victims should be examined by a physician as soon as possible Toxic effects may be delayed Do NOT perform direct mouth to mouth resuscitation; use a bag/mask apparatus Note to physician: can produce cyanide toxicity; if symptoms indicate, initial treatment includes the cyanide antidote kit CAS: 74-90-84
  • 10. References1. North American Emergency Response Guide, 1996 16. R.J. Lewis, SAX’s Dangerous Properties of Industrial Edition, U.S. Department of Transportation, Washington, Materials, 8th Edition (1992), Van Nostrand Reinhold, DC. New York, NY.2. The Merck Index, 12th Edition (1996), Merck and Co., 17. R.J. Lewis, Hazardous Chemicals Desk Reference, 3rd Inc., Rahway, NJ. Edition (1993), Van Nostrand Reinhold, New York, NY.3. Emergency Handling of Hazardous Materials in Surface 18. A Guide to Fire Hazard Properties of Flammable Liquids, Transportation (1992), American Association of Gases and Volatile Solids, ANSI/NFPA 325 (1994), Railroads, Washington, DC. National Fire Protective Association, Quincy, MA.4. Emergency Action Guide (1995), American Association 19. Hazardous Chemicals Data, ANSI/NFPA 49 (1994), of Railroads, Washington, DC. National Fire Protective Association, Quincy, MA.5. Chemical Hazards Response Information System, 20. Code of Federal Regulations 49 Transportation (1996), Hazardous Chemical Data Manual, Vol. II (1993), U.S. Office of Federal Register National Archives and Records Department of Transportation, U.S. Coast Guard, Administration, Washington, DC. Washington, DC. 21. Chemical/Biological Incident Handbook, (1995), The6. NIOSH Pocket Guide to Chemical Hazards (1990), U.S. Director of Central Intelligence Committee on Terrorism/ Department of Health and Human Services, Community Counterterrorism Board. Washington, DC.7. L. Bretherick, Bretherick’s Handbook of Reactive Chemical Hazards, 4th Edition (1990), Butterworth- Heinemann, Ltd., Boston, MA.8. Tomes Plus (1995), Micromedex, Denver, CO.9. CAMEO (1990), U.S. Environmental Protection Agency, National Oceanic and Atmospheric Administration, National Safety Council, Washington, DC.10. Fire Protection Guide to Hazardous Materials; 10th Edition (1991), National Fire Protection Association, Quincy, MA.11. Responding to Hazardous Materials Incidents, ANSI/ NFPA 473 (1992), National Fire Protective Association, Quincy, MA.12. Responders to Hazardous Materials Incidents, ANSI/ NFPA 472 (1992), National Fire Protective Association, Quincy, MA.13. Identification of the Fire Hazards of Materials, ANSI/ NFPA 704 (1990), National Fire Protective Association, Quincy, MA.14. Field Guide to Tank Care Identification (1992), Association of American Railroads, Washington, D.C.15. Hazardous Materials Response Handbook, 2nd Edition (1993), National Fire Protective Association, Quincy, MA. 5
  • 11. Alphabetical Material Name IndexA J SB K TC L UD M VE N WF O XG P YH Q ZI R Click on letter to go to section
  • 12. Alphabetical Material IndexA-150 .......................................................................... 476 Acrylic acid .................................................................. 62AA ................................................................................ 67 Acrylic acid chloride ..................................................... 64AC .............................................................................. 285 Acrylic acid, butyl ester .............................................. 114Acetaldehyde ................................................................ 51 Acrylic acid, ethyl ester .............................................. 231Acetaldehyde cyanohydrin ......................................... 305 Acrylic acid, methyl ester ........................................... 321Acetaldehyde ethylacetal .............................................. 50 Acrylic amide ................................................................ 61Acetamide ................................................................... 482 Acrylonitrile ................................................................... 63Acetene ...................................................................... 243 Acryloyl chloride ........................................................... 64Acetic acid .................................................................... 52 Acrylyl chloride ............................................................. 64Acetic acid anhydride ................................................... 53 Actidione ..................................................................... 171Acetic acid bromide ...................................................... 57 Actidone ..................................................................... 171Acetic acid chloride ...................................................... 58 Adipic acid .................................................................. 482Acetic acid dimethylamide .......................................... 206 Adipic acid dinitrile ....................................................... 65Acetic acid, ethinyl ester ............................................. 468 Adiponitrile .................................................................... 65Acetic acid, methyl ester ............................................. 319 Agent T ....................................................................... 482Acetic acid, n-butyl ester ............................................ 113 Alachlor ...................................................................... 482Acetic acid, n-propyl ester .......................................... 408 Alcide ......................................................................... 140Acetic acid, vinyl ester ................................................ 468 Aldicarb ........................................................................ 66Acetic aldehyde ............................................................ 51 Aldifen ........................................................................ 223Acetic anhydride ........................................................... 53 Aldrin .......................................................................... 482Acetic chloride .............................................................. 58 Algrain ........................................................................ 232Acetic ester ................................................................ 230 Alkyl benzene sulfonic acids ....................................... 482Acetic ether ................................................................ 230 Allene .......................................................................... 482Acetoacetone .............................................................. 381 Allene-methyl acetylene mixture .................................. 320Acetocyanohydrin ......................................................... 55 Allethrin ....................................................................... 482Acetocyanohydrin ....................................................... 305 Allyl acetate ................................................................ 482Acetol ........................................................................... 50 Allyl al ........................................................................... 67Acetone ........................................................................ 54 Allyl alcohol ................................................................... 67Acetone cyanohydrin .................................................... 55 Allyl aldehyde ................................................................ 60Acetone thiosemicarbazide ......................................... 482 Allyl bromide ................................................................. 69Acetonitrile .................................................................... 56 Allyl chloride ................................................................. 70 Allyl chlorocarbonate ..................................................... 71Acetophenone ............................................................. 482 Ally chloroformate ......................................................... 711-Acetoxyethylene ...................................................... 468 Allyl ether .................................................................... 4821-Acetoxypropane ....................................................... 408 Allyl ethyl ether ............................................................ 482Acetyl acetone ............................................................ 381 Allyl iodide .................................................................. 482Acetyl anhydride ........................................................... 53 Allyl isothiocyanate ..................................................... 482Acetyl bromide .............................................................. 57 Allylamine ..................................................................... 68Acetyl chloride .............................................................. 58 Allylic alcohol ................................................................ 67Acetyl ether .................................................................. 53 Allyltrichlorosilane ......................................................... 72Acetyl ketene .............................................................. 204 alpha-Bromotoluene ...................................................... 95Acetyl oxide .................................................................. 53 alpha-Chlorobenzaldehyde ............................................ 94Acetyl peroxide solution .............................................. 482 alpha-Chloropropionic ................................................. 1552-Acetylaminofluorene ................................................ 482 alpha-Chlorotoluene ...................................................... 96Acetylene ...................................................................... 59 alpha-Cumene hydroperoxide ..................................... 161Acetylene dichloride ................................................... 186 alpha-Endosulfan ........................................................ 497Acetylene tetrachloride ............................................... 438 alpha-Methacrylic acid ................................................ 313Acetylene trichloride ................................................... 454 alpha-Methyl benzyl alcohol ........................................ 505Acetylenogen .............................................................. 128 alpha-Methyl styrene ................................................... 299Acetylsilicon trichloride ................................................. 72 alpha-Naphthylamine ................................................... 507Acid ............................................................................ 155 alpha-Pinene ............................................................... 398Acridine ...................................................................... 482 alpha-Tolunitrile ........................................................... 385Acroleic acid ................................................................. 62 Aluminum (dust) .......................................................... 482Acrolein ........................................................................ 60 Aluminum borohydride ................................................ 482Acrylaldehyde .............................................................. 60 Aluminum chloride ...................................................... 482Acrylamide .................................................................... 61 Aluminum fluoride ....................................................... 4828
  • 13. Alphabetical Material IndexAluminum nitrate ......................................................... 482 Ammonium fluoborate ................................................. 483Aluminum oxide ........................................................... 482 Ammonium fluoride ..................................................... 483Aluminum phosphide ................................................... 482 Ammonium formate ..................................................... 483Aluminum sulfate ......................................................... 482 Ammonium gluconate .................................................. 483Aluminum, triisobutyl ................................................... 459 Ammonium hydroxide ................................................... 77AMFO ........................................................................... 84 Ammonium hypophosphite .......................................... 483Am-fol ........................................................................... 74 Ammonium iodide ....................................................... 483Aminic acid ................................................................. 269 Ammonium lactate ....................................................... 4831-Amino-2,4-dinitrobenzene ........................................ 220 Ammonium lauryl sulfate ............................................. 4832-Amino-2-methyl-1-propanol ..................................... 482 Ammonium molybdate ................................................. 4831-Amino-2-propanol .................................................... 298 Ammonium monosulfide ................................................ 794-Aminoazobenzene ................................................... 482 Ammonium nitrate ....................................................... 483Aminobenzene .............................................................. 85 Ammonium nitrate fertilizers ........................................ 4831-Aminobutane ............................................................ 116 Ammonium nitrate: fuel oil ............................................. 844-Aminobutyl diethoxymethyl silane ............................. 482 Ammonium nitrate-phosphate mixture ......................... 483Aminocyclohexane ...................................................... 172 Ammonium nitrate-sulfate mixture ............................... 483Aminoethane ............................................................... 233 Ammonium nitrate-urea solution .................................. 4832-Aminoethanol ........................................................... 229 Ammonium oleate ....................................................... 4832-(2-Aminoethoxy)ethanol ........................................... 482 Ammonium oxalate ...................................................... 483Aminoethyl ethanol amine ........................................... 482 Ammonium pentaborate .............................................. 483Aminoethylethandiamine ............................................. 198 Ammonium perchlorate .................................................. 78Aminohexahydrobenzene ............................................ 172 Ammonium perchlorate high explosive .......................... 782-Aminoisobutane ....................................................... 117 Ammonium perchlorate oxidizer .................................... 78Aminomethane ............................................................ 323 Ammonium permanganate .......................................... 483Aminomethane ............................................................ 324 Ammonium persulfate ................................................. 4834-Amino-N,N-dimethylaniline ....................................... 215 Ammonium phosphate ................................................. 4832-Aminopentane .......................................................... 195 Ammonium picrate (wet) ............................................. 483Aminophen .................................................................... 85 Ammonium rhodanate ................................................... 812-Aminopropane ......................................................... 300 Ammonium silicofluoride ............................................. 4833-Aminopropene ........................................................... 68 Ammonium stearate .................................................... 4834-Aminopropiophenone ............................................... 482 Ammonium sulfamate .................................................. 4833-Aminopropylene ......................................................... 68 Ammonium sulfate ....................................................... 4834-Aminopyridine ........................................................... 73 Ammonium sulfide ......................................................... 79Aminopyridines ............................................................. 73 Ammonium sulfite .......................................................... 80Aminotoluene .............................................................. 451 Ammonium sulfocyanide ............................................... 81Amiton ........................................................................ 482 Ammonium sulphite ....................................................... 80Amiton oxalate ............................................................. 482 Ammonium tartrate ...................................................... 483Amitrole ...................................................................... 482 Ammonium thiocyanate ................................................. 81Ammonia ....................................................................... 74 Ammonium thiosulfate ................................................. 483Ammonia monohydrate ................................................. 77 AMS ............................................................................ 299Ammonia solution .......................................................... 77 Amthio .......................................................................... 81Ammonia water ............................................................. 77 Amyl alcohol ................................................................. 82Ammonia, anhydrous .................................................... 74 Amyl methyl ketone ..................................................... 325Ammonium acetate ..................................................... 483 Amyl phthalate ............................................................ 484Ammonium aminoformate ............................................. 76 Amylol ........................................................................... 82Ammonium benzoate ..................................................... 75 Amyltricholorsilane ........................................................ 83Ammonium bicarbonate .............................................. 483 AN/FO ........................................................................... 84Ammonium bifluoride .................................................. 483 Anhydrol ..................................................................... 232Ammonium bisulfite ..................................................... 483 Anhydrous ammonia ..................................................... 74Ammonium bromide .................................................... 483 Anhydrous ethanol ...................................................... 232Ammonium carbamate .................................................. 76 Anhydrous hydrobromic acid ...................................... 283Ammonium carbonate ................................................. 483 Anhydrous hydrofluoric acid ....................................... 286Ammonium chloride .................................................... 483 Aniline ........................................................................... 85Ammonium chromate .................................................. 483 Aniline oil ...................................................................... 85Ammonium citrate ....................................................... 483 Anisole ........................................................................ 484Ammonium dichromate ............................................... 483 Anisoyl chloride .......................................................... 484 9
  • 14. Alphabetical Material IndexAnone ......................................................................... 170 Barium peroxide .......................................................... 485Ansul ether 121 ........................................................... 205 BCME ......................................................................... 188Anthion ....................................................................... 401 BD .............................................................................. 111Anthracene ................................................................. 484 Benomyl ...................................................................... 485Antimony (powder) ...................................................... 484 Bentazon ..................................................................... 485Antimony pentachloride .............................................. 484 Benzal chloride ............................................................. 98Antimony pentafluoride ............................................... 484 Benzaldehyde ............................................................... 88Antimony potassium tartrate ........................................ 484 Benzalmalonoitrile ....................................................... 145Antimony tribromide .................................................... 484 Benzamide .................................................................... 89Antimony trichloride .................................................... 484 Benzenamine ................................................................ 85Antimony trifluoride ..................................................... 484 Benzene ....................................................................... 90Antimony trioxide ........................................................ 484 Benzene arsonic acid ................................................. 485ANTU .......................................................................... 484 Benzene chloride ........................................................ 147Aqua fortis .................................................................. 361 Benzene fluoride ......................................................... 264Aqueous ammonia ........................................................ 77 Benzene hexachloride ................................................. 485Aramite ....................................................................... 484 Benzene methylal .......................................................... 88Arctic .......................................................................... 331 Benzene nitro ............................................................. 263Argon .......................................................................... 484 Benzene phosphorous dichloride ................................ 388Arsenic ....................................................................... 484 Benzene sulfonyl chloride ........................................... 485Arsenic acid ............................................................... 484 Benzeneacetonitrile .................................................... 385Arsenic butter ............................................................... 86 Benzenecarbonal .......................................................... 88Arsenic chloride ............................................................ 86 Benzenecarbonyl chloride ............................................ 94Arsenic dichloroethane ............................................... 241 Benzenehexahydride .................................................. 169Arsenic disulfide ......................................................... 484 Benzenenitrile ............................................................... 91Arsenic hydride ............................................................ 87 Benzenethiol ............................................................... 387Arsenic pentoxide ....................................................... 484 Benzenol ..................................................................... 384Arsenic trichloride ......................................................... 86 Benzidine .................................................................... 485Arsenic trihydride ......................................................... 87 Benzin ........................................................................ 258Arsenic trioxide ........................................................... 484 Benzo (A) anthracene ................................................. 485Arsenic trisulfide ......................................................... 484 Benzo (A) pyrene ....................................................... 485Arsenous chloride ......................................................... 86 Benzo (B) fluoranthene ............................................... 485Arsenous trichloride ...................................................... 86 Benzo (GHI) perylene ................................................. 485Arsine ........................................................................... 87 Benzoic acid ............................................................... 485Asbestos ..................................................................... 484 Benzoic acid amide ...................................................... 89Asphalt ........................................................................ 484 Benzoic aldehyde ......................................................... 88Asphalt blending stocks: roofers flux ........................... 484 Benzoic trichloride ........................................................ 93Asphalt blending stocks: straight run residue .............. 484 Benzol ........................................................................... 90asym-Dimethylhydrazine ............................................. 214 Benzonitrile ................................................................... 91Atrazine ...................................................................... 484 Benzophenone ............................................................ 485Auramine .................................................................... 484 Benzoquinone ............................................................... 92Avitrol ............................................................................ 73 1,4-Benzoquinone ......................................................... 92Azabenzene ................................................................ 415 Benzotrichloride ............................................................ 93Azacyclohexane .......................................................... 399 Benzoyl chloride ........................................................... 94Azacyclopropane ........................................................ 253 Benzoyl peroxide ........................................................ 485Azide .......................................................................... 419 Benzoylamide ............................................................... 89Azine .......................................................................... 415 Benzyl acetate ............................................................ 485Azirane ....................................................................... 253 Benzyl alcohol ............................................................. 485Aziridine ..................................................................... 253 Benzyl amine .............................................................. 485Azophos ...................................................................... 349 Benzyl bromide ............................................................. 95Barium ........................................................................ 485 Benzyl carbonyl chloride ............................................... 97Barium carbonate ....................................................... 485 Benzyl chloride ............................................................. 96Barium chlorate .......................................................... 485 Benzyl chlorocarbonate ................................................ 97Barium cyanide .......................................................... 485 Benzyl chloroformate .................................................... 97Barium nitrate ............................................................. 485 Benzyl cyanide ........................................................... 385Barium perchlorate ..................................................... 485 Benzyl dichloride .......................................................... 98Barium permanganate ................................................. 485 Benzyl dimethyl amine ................................................ 48510
  • 15. Alphabetical Material IndexBenzyl dimethyl octadecyl ammonium chloride ........... 485 Black powder, pellets .................................................. 486Benzyl ether ................................................................ 178 Bladan ........................................................................ 377Benzyl iodide .............................................................. 485 Bladan-M .................................................................... 349Benzyl nitrile ............................................................... 385 Blasting oil .................................................................. 366Benzyl oxide ............................................................... 178 Bleach ........................................................................ 422Benzyl trichloride .......................................................... 93 Blue oil .......................................................................... 85Benzyl trimethyl ammonium chloride ........................... 485 Bolero ......................................................................... 486Benzyl violet ................................................................ 485 Bondolane A ............................................................... 427Benzylene chloride ....................................................... 98 Bonoform .................................................................... 438Benzylidene chloride ..................................................... 98 Boric acid ................................................................... 486Beryllium ..................................................................... 485 Borneol ....................................................................... 486Beryllium chloride ....................................................... 485 Boroethane ................................................................. 179Beryllium fluoride ........................................................ 485 Boron bromide ............................................................ 100Beryllium nitrate .......................................................... 485 Boron chloride ............................................................ 101Beryllium oxide ............................................................ 485 Boron fluoride ............................................................. 102Beryllium sulfate .......................................................... 485 Boron hydride ............................................................. 177beta-Butyrolactone ...................................................... 487 Boron hydride ............................................................. 179beta-Chloroprene ........................................................ 154 Boron hydride ............................................................. 378beta-Endosulfan .......................................................... 497 Boron tribromide ......................................................... 100beta-Methyl acrolein .................................................... 160 Boron trichloride ......................................................... 101beta-Propiolactone ...................................................... 405 Boron trifluoride .......................................................... 102BHA ............................................................................ 485 Boron trifluoride: dimethyl etherate ............................. 486BHC, alpha- ................................................................ 485 Bottled gas .................................................................. 308BHC, beta- .................................................................. 485 BPL ............................................................................ 405BHC, delta- ................................................................. 486 Brimstone ................................................................... 428BHC, gamma- ............................................................. 486 Brom ........................................................................... 103BIC ............................................................................. 121 Bromacil ..................................................................... 486Bicylcopentadiene ...................................................... 192 Bromadiolone .............................................................. 486Biethylene ................................................................... 111 Bromide fluoride ......................................................... 104Bimethyl ...................................................................... 228 Bromine ...................................................................... 103Biocide ......................................................................... 60 Bromine chloride ......................................................... 486Biogas ........................................................................ 315 Bromine cyanide ......................................................... 164Bioxirane ..................................................................... 193 Bromine fluoride ......................................................... 105Biphenyl ...................................................................... 486 Bromine pentafluoride ................................................. 104Bis (chloromethyl) ketone ........................................... 181 Bromine trifluoride ...................................................... 105Bis-(2-aminoethyl) amine ............................................ 198 3-Bromo-1-propene ...................................................... 69Bis-(2-chloro-1-methyl ethyl) ether .............................. 486 1-Bromo-3-methylbutane ............................................. 486Bis-(2-chloroethoxy) methane ..................................... 486 Bromoacetic acid ........................................................ 486Bis-(2-chloroethyl) ether ............................................. 184 Bromoacetone ............................................................ 486Bis-(2-chloroethyl) methylamine .................................. 311 Bromoacetyl bromide .................................................. 106Bis-(2-chloroethyl) sulfide ............................................ 99 Bromoallylene ............................................................... 69Bis-(2-chloroisopropyl) ether ...................................... 486 Bromobenzene ............................................................ 107Bis-(2-ethyl hexyl) adipate .......................................... 486 1-Bromobutane ........................................................... 108Bis-(2-ethyl hexyl) phthalate ........................................ 486 2-Bromobutane ........................................................... 486Bis-(chloromethyl) ether ............................................. 188 Bromochloromethane .................................................. 486Bismuth oxychloride .................................................... 486 Bromocyan ................................................................. 164Bis-O,O-diethylpyrophosphoric anhydride .................. 441 Bromoethanoyl bromide .............................................. 106Bisphenol A ................................................................ 486 Bromoethene .............................................................. 469Bisphenol A diglycidyl ether ........................................ 486 2-Bromoethyl ethyl ether ............................................. 486Bisulfite ....................................................................... 430 Bromoethylene ............................................................ 469Bithionol ...................................................................... 486 Bromoform .................................................................. 486Bitoscanate ................................................................. 486 Bromofume ................................................................. 247Bivinyl ......................................................................... 111 Brom-O-Gas ............................................................... 326B-K Liquid ................................................................... 422 Bromomethane ............................................................ 326Black powder, compressed ......................................... 486 2-Bromopentane ......................................................... 486Black powder, granular ............................................... 486 4-Bromophenyl phenyl ether ....................................... 486 11
  • 16. Alphabetical Material IndexBromophenylmethane ................................................... 95 2,3-Butylene oxide ...................................................... 4871-Bromopropane ......................................................... 486 Butylethylamine ........................................................... 2362-Bromopropane ......................................................... 109 Butylsilicon trichloride ................................................. 1233-Bromopropylene ........................................................ 69 Butyltrichlorosilane ...................................................... 123Bromopropyne ............................................................ 110 2-Butyne-1,4-diol ........................................................ 1243-Bromopropyne ......................................................... 110 Butynediol ................................................................... 124Bromotrifluoroethylene ................................................ 486 1,4-Butynediol ............................................................. 124Bromotrifluoromethane ................................................ 486 2-Butynediol ................................................................ 124Brucine ....................................................................... 487 Butyral ........................................................................ 125Butadiene ................................................................... 111 Butyraldehyde ............................................................. 1251,3-Butadiene ............................................................. 111 Butyric acid chloride ................................................... 127Butadiene diepoxide .................................................... 193 Butyric acid nitrile ....................................................... 126Butadiene dioxide ....................................................... 193 Butyric acid, ethyl ester .............................................. 237Butal ........................................................................... 125 Butyric acid, methyl ester ........................................... 330Butaldehyde ................................................................ 125 Butyric aldehyde ......................................................... 125Butanal ........................................................................ 125 Butyric chloride .......................................................... 127Butane ........................................................................ 112 Butyronitrile ................................................................ 126Butane nitrile ............................................................... 126 Butyryl chloride ........................................................... 127Butanedione ................................................................ 487 BZCF ............................................................................ 97Butanethiol .................................................................. 122 C.I. acid blue 9, diammonium salt ............................... 4901-Butanethiol ............................................................... 122 C.I. acid blue 9, disodium salt ..................................... 4902-Butanone ................................................................. 338 C.I. acid green 3 ......................................................... 490Butanoyl chloride ........................................................ 127 C.I. basic green 4 ....................................................... 4903-Buten-2-one ............................................................. 356 C.I. basic red 1 ........................................................... 4902-Butenal .................................................................... 160 C.I. disperse yellow 3 ................................................. 490Butene ........................................................................ 118 C.I. food red 15 .......................................................... 4901-Butene oxide ............................................................ 119 C.I. food red 5 ............................................................ 4901,4-Butenediol ............................................................. 487 C.I. solvent orange 7 ................................................... 4903-Buteno-beta-lactone ................................................. 204 C.I. solvent yellow 14 .................................................. 4901-Butyl acetate ............................................................ 113 C.I. solvent yellow 3 .................................................... 490Butyl acid phosphate ................................................... 487 C.I. vat yellow 4 .......................................................... 490Butyl acrylate .............................................................. 114 Cacodylic acid ............................................................ 487Butyl alcohol ............................................................... 115 Cadmium acetate ........................................................ 487Butyl aldehyde ............................................................ 125 Cadmium bromide ....................................................... 487Butyl benzyl phthalate ................................................. 487 Cadmium chloride ....................................................... 487Butyl bromide .............................................................. 108 Cadmium fluoroborate ................................................. 487Butyl butyrate .............................................................. 487 Cadmium nitrate .......................................................... 487Butyl chloride .............................................................. 148 Cadmium oxide ........................................................... 487Butyl ethanoate ........................................................... 113 Cadmium stearate ....................................................... 487Butyl ether .................................................................. 487 Cadmium sulfate ......................................................... 487Butyl ethylene ............................................................. 277 Cadmium(powder) ...................................................... 487Butyl isocyanate ......................................................... 121 CADOXTHB................................................................. 120Butyl isovalerate .......................................................... 487 CAF ............................................................................ 144Butyl mercaptan .......................................................... 122 Calcium ...................................................................... 488Butyl methyl ether ....................................................... 487 Calcium acetylide ....................................................... 128Butyl nitrite .................................................................. 487 Calcium arsenite ......................................................... 488Butyl toluene ............................................................... 487 Calcium carbide .......................................................... 128Butyl, decyl, cetyl-eicosyl methacrylate ...................... 487 Calcium chlorate ......................................................... 488Butyl-2-propenoate ..................................................... 114 Calcium chloride ......................................................... 488Butylacetic acid .......................................................... 129 Calcium chromate ....................................................... 488Butylacetone ............................................................... 325 Calcium cyanide ......................................................... 488Butylamine .................................................................. 116 Calcium fluoride .......................................................... 488Butylated hydroxyanisole ............................................ 487 Calcium hydride .......................................................... 489Butylene ...................................................................... 118 Calcium hydroxide ...................................................... 4881,2-Butylene oxide ...................................................... 119 Calcium hypochlorite .................................................. 4881-Butylene oxide ......................................................... 119 Calcium nitrate ............................................................ 48812
  • 17. Alphabetical Material IndexCalcium oxide ............................................................. 488 Carbonic oxide ............................................................ 134Calcium peroxide ........................................................ 488 Carbonochloride acid, ethyl ester ............................... 240Calcium phosphate ..................................................... 488 Carbonyl chloride ....................................................... 390Calcium phosphide ..................................................... 489 Carbonyl fluoride ........................................................ 136Calcium resinate ......................................................... 488 Carbonyl sulfide .......................................................... 137Camphene .................................................................. 488 Carene ........................................................................ 488Camphor oil ................................................................ 488 Casing head gasoline ................................................. 272Cantharidin ................................................................. 488 Castor oil, edible ......................................................... 488CAP ............................................................................ 144 Caswell No 805 ........................................................... 424Caproic acid ............................................................... 129 Catechol ..................................................................... 488Caprolactam ............................................................... 488 Caustic potash solution ............................................... 488Capronic acid ............................................................. 129 Caustic soda ............................................................... 421Caprylene ................................................................... 373 Caustic soda, solution ................................................. 421Capsicum ................................................................... 488 Cellon ......................................................................... 438Capsine ...................................................................... 222 Certox ......................................................................... 424Captan ........................................................................ 488 Cesium ....................................................................... 489Carbachol ................................................................... 130 CHA ............................................................................ 172Carbachol chloride ...................................................... 130 Chloral ........................................................................ 138Carbacholin ................................................................ 130 Chlorallylene ................................................................. 70Carbacholine dichloride .............................................. 130 Chloramben ................................................................ 488Carbacryl ...................................................................... 63 Chlorbisan .................................................................. 488Carbamic acid, ammonium salt ..................................... 76 Chlordane, flammable liquid ........................................ 488Carbamide peroxide .................................................... 466 Chlordecone ............................................................... 488Carbamiotin ................................................................ 130 Chlorex ....................................................................... 184Carbamoyl dimethyl chloride ....................................... 209 Chlorfenvinfos ............................................................. 488Carbamyl ...................................................................... 66 Chloride of phosphorus ............................................... 396Carbaryl (solid) ........................................................... 488 Chlorine ...................................................................... 139Carbide ....................................................................... 128 Chlorine cyanide ......................................................... 165Carbinol ...................................................................... 318 Chlorine dioxide .......................................................... 140Carbofuran ................................................................. 131 Chlorine dioxide hydrate ............................................. 140Carbolic acid .............................................................. 384 Chlorine dioxide hydrate (frozen) ................................ 140Carbolic oil .................................................................. 488 Chlorine fluoride ......................................................... 141Carbon bisulfide .......................................................... 133 Chlorine monoxide ...................................................... 489Carbon chloride .......................................................... 135 Chlorine pentafluoride ................................................. 489Carbon dichloride oxide .............................................. 390 Chlorine peroxide ........................................................ 140Carbon difluoride ........................................................ 136 Chlorine sulfide ........................................................... 429Carbon dioxide ............................................................ 132 Chlorine trifluoride ...................................................... 141Carbon disulfide .......................................................... 133 Chlormephos ............................................................... 489Carbon disulphide ....................................................... 133 Chlormequat chloride .................................................. 489Carbon monoxide ........................................................ 134Carbon nitride ............................................................. 163 2-Chlorobenzylidine malononitrile............................... 145Carbon oxide .............................................................. 134 Chloro methyl sulfane ................................................. 316Carbon oxide sulfide ................................................... 137 Chloro(chloromethoxy) methane ................................. 188Carbon oxychloride ..................................................... 390 2-Chloro-1,3-butadiene ............................................... 154Carbon oxyfluoride ...................................................... 136 2-Chloro-1-ethanol ...................................................... 244Carbon oxysulfide ....................................................... 137 4-Chloro-1-methylbenzene .......................................... 158Carbon sulfide ............................................................ 133 1-Chloro-1-propene .................................................... 489Carbon tet ................................................................... 135 1-Chloro-2,3-epoxypropane ........................................ 227Carbon tetrachloride ................................................... 135 1-Chloro-2-cyanoethane ............................................. 156Carbona ...................................................................... 135 1-Chloro-2-nitrobenzene ............................................. 151Carbonic acid anhydride ............................................ 132 1-Chloro-4-methylbenzene .......................................... 158Carbonic acid gas ...................................................... 132 10-Chloro-5,10-dihydrophenarsazine (DM) ................ 489Carbonic acid, diethyl ester ........................................ 197 Chloroacetaldehyde .................................................... 142Carbonic anhydride .................................................... 132 2-Chloroacetaldehyde ................................................. 142Carbonic difluoride oxide ............................................ 136 Chloroacetaldehyde monomer .................................... 142Carbonic ether ............................................................ 197 Chloroacetaphenone ................................................... 144 13
  • 18. Alphabetical Material IndexChloroacetic acid ........................................................ 489 1-Chloropropane ......................................................... 489Chloroacetic acid chloride .......................................... 146 2-Chloropropane ......................................................... 489Chloroacetic acid, ethyl ester ..................................... 239 3-Chloropropanenitrile ................................................ 156Chloroacetic acid, methyl ester ................................... 332 Chloropropene .............................................................. 70Chloroacetic chloride .................................................. 146 2-Chloropropene ......................................................... 489Chloroacetone, stabilized ............................................ 489 3-Chloropropene ........................................................... 70Chloroacetonitrile ........................................................ 143 Chloropropham ........................................................... 489Chloroacetyl chloride .................................................. 146 2-Chloropropionic acid ............................................... 1552-Chloroacrylic acid, methyl ester .............................. 333 3-Chloropropionitrile ................................................... 156Chloroaldehyde ........................................................... 142 3-Chloropropyl octyl sulfoxide ..................................... 489Chlorobenzene ............................................................ 147 Chloropropylene ........................................................... 70Chlorobenzilate ........................................................... 489 1-Chloropropylene ...................................................... 4892-Chlorobuta -1,3-diene .............................................. 154 Chloropropylene oxide ................................................ 227Chlorobutadiene .......................................................... 154 Chlorosulfane .............................................................. 432Chlorobutane .............................................................. 148 Chlorosulfonic acid ..................................................... 1571-Chlorobutane ........................................................... 148 Chlorosulfuric acid ...................................................... 1572-Chlorobutane ........................................................... 489 Chlorothalonil .............................................................. 489Chlorocarbonic acid, ethyl ester ................................. 240 Chlorotoluene .............................................................. 158Chlorocyan ................................................................. 165 3-Chlorotoluene .......................................................... 489Chlorocyanogen ......................................................... 165 4-Chlorotoluene .......................................................... 158Chlorodibromomethane ............................................... 489 Chlorotrifluoride .......................................................... 141Chlorodifluoromethane ................................................ 489 Chlorotrifluoroethane ................................................... 489Chloroethanal .............................................................. 142 Chlorotrifluoroethylene ................................................ 4582-Chloroethanal .......................................................... 142 Chlorotrifluoromethane ................................................ 490Chloroethane .............................................................. 238 Chlorotrimethylsilane ................................................... 462Chloroethane .............................................................. 453 Chlorovinylarsine dichloride ........................................ 3062-Chloroethane sulfonyl chloride ................................. 489 Chlorovinyldichloroarsine ............................................ 306Chloroethanenitrile ...................................................... 143 Chloroxuron ................................................................ 490Chloroethanol .............................................................. 244 Chlorpyrifos ................................................................ 1592-Chloroethanol .......................................................... 244 Chlorthiophos .............................................................. 490Chloroethene .............................................................. 470 Chlorylen .................................................................... 4532-Chloroethyl chlorocarbonate .................................... 149 Choline chloride carbamate ........................................ 1302-Chloroethyl vinyl ether ............................................. 489Chloroethylene ............................................................ 470 Chromic acetate ......................................................... 490Chloroform .................................................................. 150 Chromic acid .............................................................. 490Chloroformate ............................................................. 149 Chromic anhydride ..................................................... 490Chloroformic acid, isopropyl ester .............................. 302 Chromic sulfate ........................................................... 490Chloroformyl chloride .................................................. 390 Chromium (dust) ......................................................... 490Chlorohydrins ............................................................. 489 Chromium oxychloride ................................................ 490Chloromethane ............................................................ 331 Chromous chloride ...................................................... 490(Chloromethyl) benzene ............................................... 96 Chrysene .................................................................... 490Chloromethyl cyanide ................................................. 143 Cinnamenol ................................................................. 425Chloromethyl ether ...................................................... 188 cis-Butene .................................................................. 118Chloromethyl ethyl ether ............................................. 489 Citric acid ................................................................... 490Chloromethyl methyl ether ........................................... 489 Citrus red No. 2 .......................................................... 4901-(Chloromethyl)-4-nitrobenzene ................................ 489 CK .............................................................................. 165Chloromethyloxirane ................................................... 227 Clorox ......................................................................... 4222-Chloronaphthalene ................................................... 489 CN .............................................................................. 144Chloronitrobenzene ..................................................... 151 CO .............................................................................. 134Chlorophenyl methane .................................................. 96 Coal gas ..................................................................... 4904-Chlorophenyl phenyl ether ....................................... 489 Coal naphtha ................................................................. 902-Chlorophenylthiourea ............................................... 152 Coal oil ........................................................................ 304Chloropicrin ................................................................ 153 Cobalt ......................................................................... 490Chloropicrin: methyl chloride ...................................... 489 Cobalt acetate ............................................................. 490Chloropivaloyl chloride ................................................ 489 Cobalt bromide ............................................................ 490Chloroprene ................................................................ 154 Cobalt carbonyl ........................................................... 49014
  • 19. Alphabetical Material IndexCobalt chloride ............................................................ 490 Cyanobenzene .............................................................. 91Cobalt fluoride ............................................................. 490 Cyanobromide ............................................................ 164Cobalt formate ............................................................ 490 Cyanoethane .............................................................. 407Cobalt nitrate ............................................................... 490 2-Cyanoethyl alcohol .................................................. 245Cobalt sulfamate ......................................................... 490 Cyanoethylene .............................................................. 63Cobalt sulfate .............................................................. 490 Cyanogen ................................................................... 163Cocculus ..................................................................... 491 Cyanogen bromide ..................................................... 164Coconut oil: edible ...................................................... 491 Cyanogen chloride ...................................................... 165Colchicine ................................................................... 491 Cyanogen iodide ......................................................... 166Collodion ..................................................................... 491 Cyanogen monoiodide ................................................ 166 2-Cyanohydrin ............................................................ 245Copper ........................................................................ 491 Cyanomethane .............................................................. 56Copper acetate ........................................................... 491 Cyanomethanol ........................................................... 268Copper acetoarsenite ................................................. 491 2-Cyanopropane ......................................................... 295Copper arsenite .......................................................... 491 Cyanotoluene .............................................................. 385Copper bromide .......................................................... 491 2-Cyanpropene ........................................................... 322Copper chloride .......................................................... 491 Cyanuric chloride ....................................................... 167Copper cyanide .......................................................... 491 Cycasin ...................................................................... 492Copper fluoroborate .................................................... 491 Cyclobutane ................................................................ 492Copper formate ........................................................... 491 Cycloheptane .............................................................. 168Copper glycinate ......................................................... 491 Cycloheptatriene ......................................................... 492Copper iodide ............................................................. 491 Cycloheptene .............................................................. 492Copper lactate ............................................................ 491 1,4-Cyclohexadiene dioxide .......................................... 92Copper naphthenate ................................................... 491 Cyclohexane ............................................................... 169Copper nitrate ............................................................. 491 Cyclohexanol .............................................................. 492Copper oxalate ............................................................ 491 Cyclohexanone ........................................................... 170Copper subacetate ...................................................... 491 Cyclohexanone peroxide ............................................. 492Copper sulfate ............................................................ 491 Cyclohexatriene ............................................................ 90Copper sulfate, ammoniated ....................................... 491 Cyclohexene ............................................................... 492Copper tartrate ............................................................ 491 Cyclohexenyl trichlorosilane ........................................ 492Coumaphos ................................................................ 491 Cycloheximide ............................................................ 171Coumatetralyl .............................................................. 491 Cyclohexyl acetate ...................................................... 4921,3-CPD ..................................................................... 192 Cyclohexyl isocyanate ................................................ 492CR (dibenzo (b,f)-1,4-oxazepine) ............................... 491 Cyclohexylamine ......................................................... 172Creosote, coal tar ....................................................... 491 Cyclohexylketone ........................................................ 170Cresols ....................................................................... 491 Cyclohexylmethane ..................................................... 334Cresyl glycidyl ether ................................................... 491 1,3-Cyclopentadiene dimer ......................................... 192Cresylate spent caustic solution .................................. 491Crimidine .................................................................... 491 Cyclopentane .............................................................. 173Croton oil .................................................................... 491 Cyclopentanol ............................................................. 492Crotonal ...................................................................... 160 Cyclopentanone .......................................................... 492Crotonaldehyde .......................................................... 160 Cyclopentene .............................................................. 174Crotonaldehyde (E) .................................................... 160 Cyclopentimine ........................................................... 399Crude oil ..................................................................... 491 Cyclopropane ............................................................. 175CS .............................................................................. 145 2,4-D .......................................................................... 176CTFE ........ .................................................................. 458 Dakins solution ............................................................ 422Cumene ...................................................................... 301 Dalapon ...................................................................... 492Cumene hydroperoxide ............................................... 161 DCE ............................................................................ 473Cumyl hydroperoxide .................................................. 161 1,1-DCE ..................................................................... 473Cupferron ................................................................... 491 1,1-DCE ..................................................................... 185Cupriethylene diamine solution ................................... 491 1,2-DCE ..................................................................... 186Curmol ........................................................................ 301 DCEE ........................................................................... 184Cyanazine .................................................................. 492 DCP ............................................................................ 1922-Cyano-2-propanol ...................................................... 55 DDC ........................................................................... 209Cyanoacetic acid ........................................................ 162 DDD ........................................................................... 492Cyanoacetonitrile ........................................................ 310 DDP ............................................................................ 377 15
  • 20. Alphabetical Material Index4,4-DDT ..................................................................... 492 Dibenzoyl peroxide ..................................................... 493DEA ............................................................................ 195 Dibenzyl ether ............................................................. 178DEAE ......................................................................... 196 Diborane ..................................................................... 179Decaborane ................................................................ 177 Diboron hexahydride ................................................... 179Decaborane (14) ........................................................ 177 1,2-Dibromo-3-chloropropane ..................................... 493Decaborane tetrahydride ............................................ 177 Dibromoethane ........................................................... 247Decabromodiphenyl oxide ........................................... 492 1,2-Dibromoethane ..................................................... 247Decahydronaphthalene ............................................... 492 Dibromomethane ......................................................... 180Decaldehyde ............................................................... 492 Dibutyl phenol ............................................................. 493Decanoic acid ............................................................ 492 Dibutyl phthalate ......................................................... 4931-Decene .................................................................... 492 Dicamba ..................................................................... 493DEK ............................................................................ 201 Dichlobenil .................................................................. 493Demeton ..................................................................... 492 Dichlone ..................................................................... 493Demeton-s-methyl ....................................................... 492 Dichloricide ................................................................ 182DEN ............................................................................ 195 Dichloro (2-chlorovinyl) arsine .................................... 306Denatured alcohol ....................................................... 232 Dichloro-1,2-propane .................................................. 412DETA .......................................................................... 198 1,4-Dichloro-2-butene ................................................. 183Deuterium ................................................................... 492 1,3-Dichloro-2-propanone ........................................... 181Dextrose solution ......................................................... 492 Dichloroacetic acid ..................................................... 4931,1-Di(tert-butylperoxy)cyclohexane ........................... 493 Dichloroacetic acid, methyl ester ................................ 336Diacetone alcohol ....................................................... 492 1,3-Dichloroacetone ................................................... 181Diacetone alcohol peroxide ......................................... 492 Dichloroacetyl chloride ............................................... 493Diacetyl ...................................................................... 492 Dichloroacetylene ....................................................... 493Diacetylmethane ......................................................... 381 1,4-Dichlorobenzene ................................................... 182Diaflan ........................................................................ 458 3,3-Dichlorobenzidine ................................................ 493Diakon ........................................................................ 348 Dichlorobromomethane ............................................... 493Dialifos ........................................................................ 492 Dichlorobutene ............................................................ 183Diallate ........................................................................ 492 1,4-Dichlorobutene ..................................................... 183Diallyl ether ................................................................. 492 2,2-Dichlorodiethyl ether ............................................ 184Diallylamine ................................................................ 492 Dichlorodifluoromethane ............................................. 493Diamide ...................................................................... 278 Dichlorodimethylsilane ................................................ 210Diamine ...................................................................... 278 Dichlorodimethylsilicon ............................................... 210Diamine hydrate ......................................................... 278 Dichloroethane ............................................................ 248Diamine sulfate ........................................................... 279 1,1-Dichloroethane ..................................................... 1852,2-Diaminodiethylamine ............................................ 198 1,1-Dichloroethane ..................................................... 4734,4-Diaminodiphenyl ether ......................................... 493 1,2-Dichloroethane ..................................................... 2481,2- Diaminoethane .................................................... 246 Dichloroether .............................................................. 184Diaminotoluene ........................................................... 449 Dichloroethylarsine ..................................................... 241Diaminotoluene (mixed isomers) ................................. 493 1,1-Dichloroethylene ................................................... 4732,4-Diaminotoluene ..................................................... 449 1,2-Dichloroethylene ................................................... 186Diammonium sulfate .................................................... 493 Dichloroethylphenylsilane ........................................... 259Diammonium sulfide ...................................................... 79 Dichloroethylsilane ...................................................... 242Diammonium sulfite ....................................................... 80 2,2-Dichloroisopropyl ether ......................................... 494Diatol .......................................................................... 197 Dichloromethane ......................................................... 187Diazan ........................................................................ 226 Dichloromethyl benzene ................................................ 98Diazinon ..................................................................... 493 Dichloromethyl ether ................................................... 188Diazomethane ............................................................. 493 Dichloromethylphenylsilane ......................................... 494Dibenzo (A,E) pyrene ................................................. 493 Dichloromethylsilane ................................................... 337Dibenzo (A,H) anthracene .......................................... 493 Dichloromonofluoromethane ....................................... 494Dibenzo (A,H) pyrene ................................................. 493 2,4-Dichlorophenol ...................................................... 494Dibenzo (A,I) pyrene .................................................. 493 Dichlorophenoxyacetic acid ........................................ 176Dibenzo (A,J) acridine ................................................ 493 2,4-Dichlorophenoxyacetic acid .................................. 176Dibenzo (A,L) pyrene ................................................. 493 Dichlorophenoxyacetic esters ..................................... 494Dibenzo (b,f)-1,4-oxazepine (CR) ............................... 4937H-Dibenzo (C,G) carbazole ....................................... 493 Dichlorophenyl phosphine ........................................... 388Dibenzofuran .............................................................. 493 Dichlorophenylarsine .................................................. 38616
  • 21. Alphabetical Material Index1,2-Dichloropropane ................................................... 412 Diethylene glycol monobutyl ether acetate .................. 494Dichloropropene ......................................................... 190 Diethylene glycol monoethyl ether ............................... 4941,3-Dichloropropene ................................................... 190 Diethylene glycol monomethyl ether ............................ 4942,3-Dichloropropene ................................................... 494 Diethylene oxide ......................................................... 224Dichloropropionic acid ................................................ 494 Diethylene oxide ......................................................... 443Dichloropropylene ....................................................... 190 Diethylene oximide ...................................................... 357Dichlorosilane ............................................................. 191 1,4-Diethylenedioxide ................................................. 224Dichlorosilicone .......................................................... 191 Diethylenetriamine ...................................................... 198Dichlorosulfane ........................................................... 429 Diethylenimide oxide ................................................... 357Dichlorotetrafluoroethane ............................................ 494 Diethylethanolamine .................................................... 1961,2-Dichlorotriethylamine ........................................... 235 1,2-Diethylhydrazine ................................................... 2002,2-Dichlorotriethylamine ........................................... 494 Diethylketone .............................................................. 201Dichlorvos ................................................................... 494 Diethylphosphate ........................................................ 494Dicofol ........................................................................ 494 3,3-Diethylthiadicarbocyanine iodide ......................... 226Dicrotophos ................................................................ 494 Difluorine .................................................................... 262Dicyan ........................................................................ 163 Difluorine monoxide .................................................... 3761,4-Dicyanobutane ....................................................... 65 Difluorochloromethane ................................................ 495Dicyanogen ................................................................ 163 Difluorodichloromethane ............................................. 495Dicyanomethane ......................................................... 310 Difluoroethane .............................................................. 202Dicyclopentadiene ...................................................... 192 1,1-Difluoroethane ...................................................... 202Dieldrin ....................................................................... 494 1,1-Difluoroethylene .................................................... 495Diepoxybutane ............................................................ 193 Difluorophosphoric acid .............................................. 4951,2,3,4-Diepoxybutane ................................................ 193 Diglycidyl ether ........................................................... 495Diesel ......................................................................... 194 Diheptyl phthalate ....................................................... 495Diesel fuel ................................................................... 194 Dihydrogen dioxide ..................................................... 287Diethanol amine .......................................................... 494 Dihydrogen selenide ................................................... 2881,1-Diethoxyethane ....................................................... 50 Dihydrooxirene ........................................................... 2541,2-Diethoxyethane ..................................................... 250 2,3-Dihydropyran ....................................................... 495Diethyl ........................................................................ 112 1,4-Dihydroxy-2-butyne .............................................. 1242,6-Diethyl aniline ....................................................... 494 Diisobutyl amine ......................................................... 495Diethyl benzene .......................................................... 494 Diisobutyl carbinol ...................................................... 495Diethyl carbamazine citrate ........................................ 494 Diisobutyl ketone ......................................................... 495Diethyl carbonate ........................................................ 197 Diisobutyl pthalate ....................................................... 495Diethyl cellosolve ......................................................... 250 Diisobutylene .............................................................. 495Diethyl chlorophosphate .............................................. 494 Diisodecyl phthalate .................................................... 495Diethyl ether ............................................................... 199 Diisononyl phthalate .................................................... 495Diethyl ethylphosphate ................................................ 494 Diisooctyl phthalate ..................................................... 495Diethyl glycol .............................................................. 250 Diisopropanol amine ................................................... 495Diethyl oxide ............................................................... 199 Diisopropyl benzene (all isomers) ............................... 495Diethyl phthalate ......................................................... 494 Diisopropyl benzene hydroperoxide ............................ 495Diethyl p-nitrophenyl thiophosphate ............................ 377 Diisopropyl ether ......................................................... 495Diethyl stilbestrol ......................................................... 494 Diisopropylamine ........................................................ 203Diethyl sulfate ............................................................. 494 Diketene ..................................................................... 204Diethyl sulfide ............................................................. 494 Dimefox ...................................................................... 495Diethyl zinc ................................................................. 495 Dimethoate .................................................................. 495Diethylaluminum chloride (DEA) ................................. 494 1,2-Dimethoxyethane .................................................. 205Diethylaluminum hydride ............................................. 494 Dimethyl ...................................................................... 228Diethylamine ............................................................... 195 Dimethyl adipate ......................................................... 495(Diethylamino) ethane ................................................. 456 4-Dimethyl aminoazobenzene ..................................... 495Diethylaminoethanol .................................................... 196 Dimethyl aminobenzene .............................................. 2082-Diethylaminoethanol ................................................. 196Diethylene ether .......................................................... 224 Dimethyl carbonate ..................................................... 495Diethylene glycol ......................................................... 494 Dimethyl cellosolve ...................................................... 205Diethylene glycol dibutyl ether .................................... 494 Dimethyl ether ............................................................. 212Diethylene glycol dimethyl ether .................................. 494 1,1- Dimethyl ethylamine ............................................. 117Diethylene glycol monobutyl ether ............................... 494 Dimethyl ethylphosphonate ......................................... 495 17
  • 22. Alphabetical Material IndexDimethyl glutarate ....................................................... 495 2,4-Dinitro-1-aminobenzamine .................................... 220Dimethyl hydrogen phosphite ...................................... 495 2,4-Dinitroaniline ......................................................... 220Dimethyl ketone ............................................................ 54 2,4-Dinitrobenzamine .................................................. 220Dimethyl mercury ....................................................... 495 1,2-Dinitrobenzene ..................................................... 221Dimethyl monosulfide .................................................. 218 1,3-Dinitrobenzene ..................................................... 2212,2-Dimethyl octanoic acid ......................................... 495 1,4-Dinitrobenzene ..................................................... 221Dimethyl phenylamine ................................................. 208 Dinitrobenzenes .......................................................... 221Dimethyl phthalate ....................................................... 496 Dinitrochlorobenzene .................................................. 496Dimethyl polysiloxane .................................................. 496 Dinitrocresol ............................................................... 222Dimethyl succinate ...................................................... 496 Dinitrogen monoxide ................................................... 371Dimethyl sulfate .......................................................... 217 Dinitrogen tetroxide ..................................................... 365Dimethyl sulfide .......................................................... 218 2,4-Dinitro-o-cresol ..................................................... 222Dimethyl sulfoxide ....................................................... 496 4,6-Dinitro-o-cyclohexyl phenol .................................. 496Dimethyl terephthalate ................................................. 496 Dinitrophenol ............................................................... 223Dimethyl tetracholorterephthalate ................................ 496 2,4-Dinitrophenol ........................................................ 223Dimethyl thiophosphoryl chloride ................................ 216 2,4-Dinitrotoluene ....................................................... 496Dimethyl zinc .............................................................. 219 Di-n-octyl phthalate ..................................................... 496Dimethylacetamide ...................................................... 206 Dinofan ....................................................................... 223Dimethylacetone ......................................................... 201 Dinonyl phthalate ........................................................ 496Dimethylamide acetate ................................................ 206 Dinoterb ...................................................................... 496Dimethylamidoethoxyphosphoryl cyanide ................... 436 Di-n-propylamine ........................................................ 225Dimethylamine ............................................................ 207 Dioctyl adipate ............................................................ 496Dimethylamine, solution .............................................. 495 Dioctyl phthalate ......................................................... 4962-Dimethylaminoethanol .............................................. 495 Dioctyl sodium sulfosuccinate ..................................... 496Dimethylanaline .......................................................... 208 Dioform ....................................................................... 1861,2-Dimethylbenzene .................................................. 477 1,4-Dioxane ................................................................ 2241,3-Dimethylbenzene .................................................. 477 Dioxathion ................................................................... 4961,4-Dimethylbenzene .................................................. 477 Dioxygen ..................................................................... 375Dimethylbenzyl hydroperoxide .................................... 161 DIPA ........................................................................... 2032,2-Dimethylbutane ..................................................... 359 Dipentene ................................................................... 496Dimethylcarbamic chloride .......................................... 209 Diphacinone ............................................................... 496Dimethylcarbamoyl chloride ........................................ 209 Diphenamide ............................................................... 496Dimethylcarbinol ......................................................... 297 Diphenyl ..................................................................... 496Dimethyldichlorosilane ................................................ 210 Diphenyl ether ............................................................ 496Dimethylene diamine ................................................... 246 Diphenylamine ............................................................ 496Dimethylene oxide ....................................................... 254 Diphenylamine chloroarsine ........................................ 496Dimethylenimine ......................................................... 253 Diphenyldichlorosilane ................................................ 4961,1-Dimethylethane ..................................................... 293 Diphenylmethane diisocyanate ................................... 496Dimethylethanolamine ................................................. 495 Diphosgene ................................................................ 4961,1-Dimethylethyl hydroperoxide ................................. 120 Diphosphorus pentasulfide .......................................... 394Dimethylformamide ..................................................... 213 Dipotassium persulfate ................................................ 401Dimethylhexane dihydroperoxide ................................ 495 Diproanoate ................................................................ 1601,1-Dimethylhydrazine ................................................ 214 Dipropylamine ............................................................. 225Dimethylmethane ........................................................ 402 Dipropylene glycol ...................................................... 4962,4-Dimethylphenol ..................................................... 495 Dipropylene glycol dibenzoate .................................... 496Dimethylphosphoro chloridothioate ............................. 216 Dipropylene glycol methyl ether .................................. 496Dimethyl-p-nitrophenyl thiophosphate ......................... 349 Diquat ......................................................................... 4962,2-Dimethylpropane ................................................... 496 Direct black 38 ............................................................ 4962,2-Dimethylpropane-1,3-diol ...................................... 496 Direct blue 6 ............................................................... 496Dimetilan ..................................................................... 496 Direct brown 95 .......................................................... 496Di-n-amyl phthalate ..................................................... 493 Distilled mustard ............................................................ 99Di-n-amylamine .......................................................... 493 Disulfoton .................................................................... 496Di-n-butyl ether ........................................................... 493 Disulfur dichloride ....................................................... 432Di-n-butyl ketone ......................................................... 493 Disulfuric acid ............................................................. 374Di-n-butyl phthalate ..................................................... 493 Di-tert-butyl peroxide ................................................... 493Di-n-butylamine .......................................................... 493 Dithane A-4 ................................................................ 22118
  • 23. Alphabetical Material IndexDithiabutane ................................................................ 211 Endothion ................................................................... 497Dithiazanine iodide ..................................................... 226 Endrin ......................................................................... 497Dithiobiuret ................................................................. 497 Endrin aldehyde .......................................................... 497Ditridecyl phthalate ..................................................... 497 Enterotoxin B .............................................................. 497Diundecyl phthalate .................................................... 497 EPI ............................................................................. 227Diuron ......................................................................... 497 Epichlorhydrin ............................................................ 227Divinyl ......................................................................... 111 EPN ............................................................................ 497Divinylene Oxide ......................................................... 270 Epoxy propane ............................................................ 414DM (10-Chloro-5,10-dihydrophenarsazine ) ................ 497 1,2-Epoxybutane ......................................................... 119DMA ........................................................................... 206 1,4-Epoxybutane ......................................................... 443DMA ........................................................................... 207 Epoxyethane ............................................................... 254DMAC ......................................................................... 206 1,2-Epoxyethane ......................................................... 254DMCC ......................................................................... 209 Epoxyethylbenzene ..................................................... 426DMF ............................................................................ 213 1,2-Epoxypropane ...................................................... 414DMFA ......................................................................... 213 Erythrene .................................................................... 111DMH ........................................................................... 214 Estradiol 17 b .............................................................. 497DMPD ......................................................................... 215 Estrone ....................................................................... 497DMS ........................................................................... 218 Ethanal .......................................................................... 51DMSO ......................................................................... 497 Ethanamine ................................................................. 233DNA ............................................................................ 220 Ethane ........................................................................ 228DNBP ......................................................................... 497 Ethane dinitrate ........................................................... 1632,4-DNP ...................................................................... 223 Ethanediol dimethyl ether ............................................ 205Dodecanol .................................................................. 497 Ethanenitrile .................................................................. 56Dodecene ................................................................... 497 Ethanethiol .................................................................. 257Dodecyl diphenyl ether disulfonate ............................. 497 Ethanoic acid ................................................................ 52Dodecyl methacrylate ................................................. 497 Ethanoic anhydride ....................................................... 53Dodecyl sulfate, diethanolamine salt ........................... 497 Ethanol ........................................................................ 232Dodecyl sulfate, magnesium salt ................................. 497 Ethanolamine .............................................................. 229Dodecyl sulfate, sodium salt ........................................ 497 Ethanoyl bromide .......................................................... 57Dodecyl sulfate, triethanolamine salt ........................... 497 Ethanoyl chloride .......................................................... 58Dodecyl/pentadecyl methacrylate ............................... 497 Ethene ........................................................................ 243Dodecylbenzene ......................................................... 497 Ethenoxide .................................................................. 254Dodecylbenzene sulfonic acid .................................... 497 Ethenylbenzene .......................................................... 425Dodecylbenzene sulfonic acid, ................................... 497 Ether ........................................................................... 199Dodecylbenzene sulfonic acid, calcium salt ................ 497Dodecylbenzene sulfonic acid, sodium salt ................. 497 Etherin ........................................................................ 243Dodecyltrichlorosilane ................................................. 497 Ethienocarb ................................................................ 497Dorlone ....................................................................... 190 Ethine ........................................................................... 59Doryl ........................................................................... 130 Ethinylcarbinol ............................................................ 404Dowcide 7 ................................................................... 379 Ethinylestradiol ............................................................ 498Dowclene LS ............................................................... 453 Ethion ......................................................................... 498Dowfume W-85............................................................ 247 1,2-Ethlyene dichloride ............................................... 248Dowfume MC-2........................................................... 326 Ethoprophos ............................................................... 498Dowtherm ................................................................... 497 Ethoxy triglycol ............................................................ 498Dry ice ........................................................................ 132 Ethoxydihydropyran .................................................... 498Dursban ...................................................................... 159 2-Ethoxyethanol .......................................................... 251Dutch oil ..................................................................... 248 2-Ethoxyethyl ethyl ether ............................................. 250EB .............................................................................. 234 Ethoxyethylbenzene .................................................... 498ECH ............................................................................ 227 Ethoxylated dodecanol ................................................ 498ED .............................................................................. 241 Ethoxylated nonylphenol .............................................. 498EDB ............................................................................ 247 Ethoxylated pentadecanol ........................................... 498EGM ........................................................................... 252 Ethoxylated tetradecanol ............................................. 498EGME ......................................................................... 252 Ethoxylated tridecanol ................................................. 498Elemental phosphorus ................................................. 392 Ethyl 2-propenoate ...................................................... 231Endosulfan .................................................................. 497 Ethyl acetate ............................................................... 230Endosulfan sulfate ....................................................... 497 Ethyl acetoacetate ...................................................... 498 19
  • 24. Alphabetical Material IndexEthyl acrylate .............................................................. 231 Ethyl sulfocyanate ....................................................... 260Ethyl alcohol ............................................................... 232 Ethyl t-butyl ether ........................................................ 499Ethyl aluminum dichloride ........................................... 498 Ethyl thiocyanate ........................................................ 260Ethyl aluminum sesquichloride .................................... 498 Ethyl vinyl ether .......................................................... 471Ethyl amyl ketone ........................................................ 498 Ethyl-3-ethoxypropionate ............................................ 499Ethyl azinphos ............................................................ 498 2-Ethyl-3-propyl acrolein ............................................. 499Ethyl bromide .............................................................. 498 Ethylacetylene ............................................................ 498Ethyl bromoacetate ..................................................... 498 Ethylaldehyde ............................................................... 51Ethyl butanoate ........................................................... 237 Ethylamine .................................................................. 233Ethyl butanol ............................................................... 498 Ethylbenzene .............................................................. 234Ethyl butyl ether .......................................................... 498 Ethyl-bis- ) 2 - c h l o r o e t h y l ) amine............... 235Ethyl butyrate .............................................................. 237 Ethylbutylamine ........................................................... 236Ethyl carbamate .......................................................... 498 Ethyldichloroarsine ..................................................... 241Ethyl carbonate ........................................................... 197 Ethylene ...................................................................... 243Ethyl cellosolve ............................................................ 251 Ethylene bromide ........................................................ 247Ethyl chloride .............................................................. 238 Ethylene carboxylic acid ............................................... 62Ethyl chlorocarbonate ................................................. 240 Ethylene chloride ........................................................ 248Ethyl chloroformate ..................................................... 240 Ethylene chlorohydrin ................................................. 244Ethyl chloromethanoate ............................................... 240 Ethylene cyanohydrin ................................................. 245Ethyl chlorothioformate ............................................... 498 Ethylene dibromide ..................................................... 247Ethyl cyanide .............................................................. 407 Ethylene dichloride ..................................................... 186Ethyl cyclohexane ....................................................... 498 Ethylene dichloride ..................................................... 248Ethyl dichlorosilane ..................................................... 242 Ethylene fluoride ......................................................... 202Ethyl ethanoate ........................................................... 230 Ethylene fluorohydrin .................................................. 249Ethyl ether .................................................................. 199 Ethylene glycol ............................................................ 498Ethyl formate ............................................................... 255 Ethylene glycol acetate ............................................... 498Ethyl glycol ................................................................. 251 Ethylene glycol diacetate ............................................ 498Ethyl glyme ................................................................. 250 Ethylene glycol diethyl e t h e r ................................. 250Ethyl hexaldehyde ....................................................... 499 Ethylene glycol dimethyl ether ..................................... 2052-Ethyl hexanoic acid ................................................. 499 Ethylene glycol ethyl ether .......................................... 2512-Ethyl hexanol ........................................................... 499 Ethylene glycol isopropyl ether ................................... 498Ethyl hexyl tallate ......................................................... 499 Ethylene glycol methyl ether ....................................... 2522-Ethyl hexylamine ...................................................... 499 Ethylene glycol monobutyl ether .................................. 498Ethyl hydrosulfide ....................................................... 257 Ethylene glycol monobutyl ether acetate ..................... 498Ethyl ketone ................................................................ 201 Ethylene glycol monoethyl ether .................................. 251Ethyl lactate ................................................................ 499 Ethylene glycol monoethyl ether acetate ..................... 498Ethyl mercaptan .......................................................... 257 Ethylene glycol monomethyl ether ............................... 252Ethyl methacrylate ...................................................... 499 Ethylene glycol phenyl ether ....................................... 498Ethyl methane sulfonate .............................................. 499 Ethylene oxide ............................................................ 254Ethyl methanoate ........................................................ 255 Ethylene tetrachloride ................................................. 439Ethyl methyl ether ....................................................... 499 Ethylene thiourea ........................................................ 499Ethyl methyl ketone ..................................................... 338 Ethylene trichloride ..................................................... 454Ethyl monochloroacetate ............................................. 239 Ethylenediamine ......................................................... 246Ethyl N,N’-dimethylphosphoramidocyanidate .............. 436 Ethylenediamine tetracetic acid .................................. 498Ethyl nitrate ................................................................. 499 Ethyleneimine ............................................................. 253Ethyl nitrile .................................................................... 56 Ethylformic acid .......................................................... 406Ethyl oxide .................................................................. 199 Ethylic acid ................................................................... 52Ethyl phenol ................................................................ 499 Ethylidene norbornene ................................................ 499Ethyl phosphonothioic dichloride ................................. 499 Ethylidine chloride ...................................................... 185Ethyl phosphorodichloridate ........................................ 499 Ethylidine dichloride .................................................... 185Ethyl pirimifos ............................................................. 499 Ethylimine ................................................................... 253Ethyl propenoate ......................................................... 231 Ethyloxide ................................................................... 254Ethyl rhodanate ........................................................... 260 Ethylphenyl dichlorosilane ........................................... 259Ethyl silicate ................................................................ 499 Ethylphosphonous dichloride ...................................... 499Ethyl sulfate ................................................................ 499 Ethylphosphonous difluoride ....................................... 499Ethyl sulfhydrate ......................................................... 257 Ethylphosphonyl difluoride .......................................... 49920
  • 25. Alphabetical Material IndexEthyl-S ........................................................................ 235 Fonofos ...................................................................... 5002-Ethyltoluene ............................................................. 499 Forane 22B ................................................................. 500Ethyltrichlorosilane ...................................................... 261 Formaldehyde ............................................................. 267Ethyne .......................................................................... 59 Formaldehyde cyanohydrin ........................................ 268ETN ............................................................................ 233 Formalin ...................................................................... 267ETOH .......................................................................... 232 Formamide .................................................................. 500Eufin ........................................................................... 197 Formetanate hydrochloride ......................................... 500F 12 ............................................................................ 499 Formic acid ................................................................ 269F 22 ............................................................................ 499 Formic acid, isopropyl ester ....................................... 303FAA ............................................................................ 263 Formic acid, ethyl ester .............................................. 255Fenamiphos ................................................................ 499 Formic acid, methyl ester ........................................... 339Fenitrothion ................................................................. 499 Formic ether ............................................................... 255Fensulfothion .............................................................. 499 Formothion .................................................................. 500Ferric ammonium citrate ............................................. 499 Formparanate ............................................................. 500Ferric ammonium oxalate ............................................ 499 Formyl hydrazino-4-(5-nitro-2-furyl)thiazole ................ 500Ferric chloride ............................................................ 499 Formyl trichloride ........................................................ 150Ferric fluoride ............................................................. 499 2-Formylfuran ............................................................. 271Ferric glycerophosphate ............................................. 499 Formylic acid .............................................................. 269Ferric nitrate ............................................................... 500 Fosthietan ................................................................... 500Ferric sulfate ............................................................... 500 Fostox ......................................................................... 377Ferrous ammonium sulfate .......................................... 500 Fosvex ........................................................................ 441Ferrous chloride ......................................................... 500 Freon 10 ..................................................................... 135Ferrous fluoroborate ................................................... 500 Freon 12 ..................................................................... 500Ferrous oxalate ........................................................... 500 Freon 150 ................................................................... 248Ferrous sulfate ............................................................ 500 Freon 152 ................................................................... 202Fire damp ................................................................... 315 Freon 20 ..................................................................... 150FKS ............................................................................ 265 Freon 22 ..................................................................... 500Flue gas ...................................................................... 134 Freon 40 ..................................................................... 331Fluenetil ...................................................................... 500 Fuberidazole ............................................................... 500Fluoboric acid ............................................................. 500 Fuel oil #1 ................................................................... 304Fluometuron ................................................................ 500 Fuel oil #2 ................................................................... 194Fluoranthene ............................................................... 500 Fuel oil, No. 2 ............................................................. 500Fluorene ..................................................................... 500 Fumaric acid ............................................................... 500Fluoric acid ................................................................. 286 Fumette ....................................................................... 317 Fuming sulfuric acid ................................................... 374Fluorine ...................................................................... 262 Furadan ...................................................................... 131Fluorine monoxide ....................................................... 376 Furadan 3G ................................................................ 131Fluorine oxide ............................................................. 376 Furaldehyde ................................................................ 271Fluoroacetamide ......................................................... 500 2-Furaldehyde ............................................................ 271Fluoroacetic acid ........................................................ 263 Furan .......................................................................... 2702-Fluoroacetic acid ..................................................... 263 Furfural ....................................................................... 271Fluoroacetyl chloride ................................................... 500 2-Furfural .................................................................... 2712-Fluoroaniline ............................................................ 500 Furfuryl alcohol ........................................................... 5004-Fluoroaniline ............................................................ 500 Furodan ...................................................................... 131Fluorobenzene ............................................................ 264 Fusel oil ...................................................................... 500Fluoroethanoic acid .................................................... 263 GA .............................................................................. 4362-Fluoroethanol ........................................................... 249 GAA .............................................................................. 62Fluoroethene ............................................................... 472 Gallic acid ................................................................... 5001-Fluoroethene ............................................................ 472 Gallium metal ............................................................... 500Fluoroethylene ............................................................ 472 Gallium trichloride ....................................................... 500Fluorophosgene .......................................................... 136 Gasoline ...................................................................... 272Fluorosilicic acid ......................................................... 265 GD .............................................................................. 423Fluorosulfonic acid ...................................................... 266 GDME ......................................................................... 205Fluorosulfuric acid ...................................................... 266 Gelan I ........................................................................ 4364-Fluorotoluene ........................................................... 500 Germane ..................................................................... 500Fluosilicic acid ............................................................ 265 Gettysolve B ................................................................ 276 21
  • 26. Alphabetical Material IndexGlacial acetic acid ........................................................ 52 Hexahydrobenzene ..................................................... 169Glacial acrylic acid ....................................................... 62 Hexahydropyridine ...................................................... 399Glutaraldehyde solution ............................................... 501 Hexahydrotoluene ....................................................... 334Glycerine .................................................................... 501 Hexamethyl phosphoramide ........................................ 501Glycerol trinitrate ......................................................... 366 Hexamethylene ............................................................ 169Glycidaldehyde ........................................................... 501 Hexamethylene diisocyanate ....................................... 501Glycidyl methacrylate .................................................. 501 Hexamethylene tetramine ............................................ 501Glycinol ....................................................................... 229 Hexamethylenediamine ............................................... 501Glycol cyanohydrin ..................................................... 245 Hexamethyleneimine ................................................... 501Glycol dimethyl ether ................................................... 205 Hexane ........................................................................ 276Glycol methyl ether ..................................................... 252 Hexanedinitrile .............................................................. 65Glycolonitrile ............................................................... 268 Hexanoic acid ............................................................. 129Glyconitrile .................................................................. 268 1-Hexanol .................................................................... 501Glyme ......................................................................... 205 Hexanon ...................................................................... 170Glyme-1 ...................................................................... 250 2-Hexanone ................................................................ 329Glyoxal ........................................................................ 501 Hexene ........................................................................ 277Gly-oxide ..................................................................... 466 1-Hexene .................................................................... 277Glyphosate .................................................................. 273 2-Hexene .................................................................... 502Grain alcohol ............................................................... 232 3-Hexene .................................................................... 502Grasex ........................................................................ 138 Hexone ........................................................................ 343H ................................................................................... 99 Hexyl acetate .............................................................. 502Halon 10001 ................................................................ 341 Hexylene ..................................................................... 277Halon 1001 .................................................................. 326 Hexylene glycol ........................................................... 502HCl .............................................................................. 284 HF ............................................................................... 286HCN ............................................................................ 285 HN1 ............................................................................ 235HD ................................................................................ 99 HN1 (N-ethyl-2,2’-di(chloroethyl) amine ...................... 502Hendecane ................................................................. 501 HN2 ............................................................................ 311Heptachlor .................................................................. 501 HN3 ............................................................................ 464Heptachlor epoxide ..................................................... 501 Hydracrylonitrile .......................................................... 245Heptachlorodibenzofurans .......................................... 501 Hydrazine ................................................................... 278Heptachlorodibenzo-p-dioxins ..................................... 501 Hydrazine hydrate ...................................................... 278Heptamethylene .......................................................... 168 Hydrazine hydrogen sulfate ........................................ 279Heptanes ..................................................................... 274 Hydrazine monosulfate ................................................ 279Heptanoic acid ............................................................ 501 Hydrazine sulfate ......................................................... 279Heptanol ...................................................................... 501 Hydrazinium sulfate .................................................... 2792-Heptanone ............................................................... 325 Hydrazoic acid, sodium salt ........................................ 4191-Heptene ................................................................... 275 Hydrazomethane ......................................................... 340Heptyl acetate ............................................................. 501 Hydrochloric acid ....................................................... 280Heptylene .................................................................... 275 Hydrochloric ether ...................................................... 238Hexachloroacetone ..................................................... 501 Hydrocyanic acid ....................................................... 285Hexachlorobenzene .................................................... 501 Hydrocyanic acid solution ........................................... 285Hexachlorobutadiene ................................................... 501 Hydrocyanic acid, sodium salt .................................... 420Hexachlorocyclohexanes ............................................. 501 Hydrofluoric acid ........................................................ 281Hexachlorocyclopentadiene ........................................ 501 Hydrofluoric acid ........................................................ 286Hexachlorodibenzofurans ............................................ 501 Hydrofuran .................................................................. 443Hexachlorodibenzo-p-dioxins ...................................... 501 Hydrogen .................................................................... 282Hexachloroethane ....................................................... 501 Hydrogen arsenic ......................................................... 87Hexachloronaphthalene ............................................... 501 Hydrogen bromide ...................................................... 283Hexachlorophene ........................................................ 501 Hydrogen bromide, anhydrous .................................... 283Hexadecyl sulfate, sodium salt .................................... 501 Hydrogen carboxylic acid ........................................... 269Hexadecyl trimethyl ammonium chloride ..................... 501 Hydrogen chloride ...................................................... 284Hexaethyl tetraphosphate ............................................ 501 Hydrogen chloride solution .......................................... 280Hexafluoroacetone ...................................................... 501 Hydrogen cyanide ...................................................... 285Hexafluoroethane ........................................................ 501 Hydrogen dioxide ........................................................ 287Hexafluosilicic acid ..................................................... 265 Hydrogen fluoride ....................................................... 286Hexahydroanaline ....................................................... 172 Hydrogen fluoride, solution ......................................... 28122
  • 27. Alphabetical Material IndexHydrogen hexafluorosilicate ........................................ 265 Isodrin ........................................................................ 502Hydrogen iodide, anhydrous ....................................... 502 Isofluorphate ............................................................... 502Hydrogen nitrate ......................................................... 361 Isohexene ................................................................... 350Hydrogen oxide ........................................................... 287 Isooctaldehyde ............................................................ 502Hydrogen peroxide ...................................................... 287 Isooctane .................................................................... 502Hydrogen peroxide (35% solution) .............................. 502 Isooctyl alcohol ........................................................... 502Hydrogen phosphide ................................................... 391Hydrogen selenide ...................................................... 288 Isopentadiene ............................................................. 296Hydrogen sulfate ......................................................... 431 Isopentane .................................................................. 502Hydrogen sulfide ......................................................... 289 Isophorone .................................................................. 5022-Hydroperoxy-2-methylpropene ................................. 120 Isophorone diamine .................................................... 502Hydroquinone ............................................................. 502 Isophorone diisocyanate (IPDI) .................................. 502Hydrosulfuric acid ....................................................... 289 Isophthalic acid ........................................................... 5023-Hydroxy-1-propyne .................................................. 404 Isoprene ..................................................................... 296Hydroxyacetonitrile ..................................................... 268 Isopropanol ................................................................. 297Hydroxybenzene ......................................................... 384 Isopropanolamine ....................................................... 2982-Hydroxyethyl acrylate .............................................. 502 Isopropene cyanide .................................................... 3222-Hydroxyisobutyronitrile .............................................. 55 Isopropenyl acetate .................................................... 502Hydroxylamine ............................................................ 290 Isopropenyl methyl ketone .......................................... 345Hydroxylamine sulfate ................................................. 502 Isopropenylbenzene .................................................... 299Hydroxypropinonitrile .................................................. 305 Isopropyl alcohol ......................................................... 2972-Hydroxypropinonitrile ............................................... 305 isopropyl amine salt .................................................... 4973-Hydroxypropionitrile ................................................. 245 Isopropyl bromide ....................................................... 109Hydroxypropyl acrylate ............................................... 502 Isopropyl chloride ....................................................... 502Hydroxypropyl methacrylate ........................................ 291 Isopropyl chlorocarbonate .......................................... 3022-Hydroxypropylamine ................................................ 298 Isopropyl chloroformate .............................................. 3022-Hydroxytriethylamine ............................................... 196 Isopropyl cyanide ....................................................... 295Hypochlorite ................................................................ 422 Isopropyl cyclohexane ................................................ 502Hyponitrous ether ....................................................... 258 Isopropyl ether ............................................................ 502Indeno(1,2,3-CD)pyrene ............................................. 502 Isopropyl formate ........................................................ 303Inerton DW-DMC ........................................................ 210 Isopropyl methyl ketone .............................................. 327Inerton-DMCS ............................................................. 210 Isopropyl nitrate .......................................................... 503Iodine cyanide ............................................................ 166 Isopropyl nitrile ........................................................... 295Iodomethane ............................................................... 341 Isopropyl percarbonate ............................................... 503Iron (powder) .............................................................. 502 Isopropyl peroxydicarbonate ....................................... 503Iron carbonyl .............................................................. 292 Isopropyl propionate ................................................... 503Iron pentacarbonyl ...................................................... 292 Isopropylamine ........................................................... 300Isobenzan ................................................................... 502 Isopropylcyanohydrin ................................................... 55Isobutane .................................................................... 293 Isopropylidene acetone ............................................... 312Isobutanol ................................................................... 502 4,4-Isopropylidenediphenol ........................................ 502Isobutenyl methyl ketone ............................................. 312 Isopropylmethylpyrazolyl dimethyl carbonate.............. 502Isobutyl aldehyde ........................................................ 502 Isothiocyanic acid, methyl ester .................................. 346Isobutyl formate .......................................................... 502 Isothiourea .................................................................. 446Isobutyl methyl carbinol .............................................. 342 Jet A ........................................................................... 304Isobutyl methyl ketone ................................................. 343 JP-1 ............................................................................ 304Isobutylamine .............................................................. 502 JP-4 ............................................................................ 272Isobutylene ................................................................. 294 JP-4 ............................................................................ 304Isobutylethene ............................................................. 350 K ................................................................................. 400Isobutyric acid ............................................................ 502 Kepone ....................................................................... 503Isobutyronitrile ............................................................ 295 Kerosene .................................................................... 304Isocumene .................................................................. 409 Kerosine ..................................................................... 304Isocyanatoethane ....................................................... 256 Ketene ........................................................................ 503Isocyanic acid, ethyl ester .......................................... 256 Ketene dimer .............................................................. 204Isocyanic acid, methyl ester ....................................... 344 Kwik-Kil ....................................................................... 4241-Isocyanobutane ....................................................... 121 L ................................................................................. 306Isodecaldehyde .......................................................... 502 Lacquer ...................................................................... 503 23
  • 28. Alphabetical Material IndexLacquer thinner .......................................................... 503 Magnesium phosphide ................................................ 504Lactic acid .................................................................. 503 Malathion .................................................................... 504Lactonitrile .................................................................. 305 Maleic acid ................................................................. 504Lasiocarpine ............................................................... 503 Maleic anhydride ........................................................ 504Laughing gas .............................................................. 371 Maleic hydrazide ......................................................... 504Lauric acid .................................................................. 503 Malonic acid dinitrile ................................................... 310Lauroyl peroxide ......................................................... 503 Malonic dinitrile ........................................................... 310Lauroyl peroxide (<42%) ............................................ 503 Malonic mononitrile ..................................................... 162Lauryl mercaptan ........................................................ 503 Malononitrile ................................................................ 310Lead ........................................................................... 503 m-Aminopyridine ........................................................... 73Lead acetate ............................................................... 503 Maneb ......................................................................... 504Lead arsenate ............................................................. 503 Manganese (dust) ....................................................... 504Lead azide (wetted with >20% water) .......................... 503 MAOH ......................................................................... 342Lead chloride .............................................................. 503 MAPP gas ................................................................... 320Lead fluoride ............................................................... 503 Marsh gas ................................................................... 315Lead fluoroborate ........................................................ 503 MB .............................................................................. 326Lead iodide ................................................................. 503 MBA.............................................................................. 311Lead nitrate ................................................................. 503 MBK ............................................................................ 329Lead phosphate .......................................................... 503 MCB ........................................................................... 147Lead stearate .............................................................. 503 MCE ........................................................................... 436Lead sulfate ................................................................ 503 m-Chloronitrobenzene ................................................. 151Lead sulfide ................................................................ 503 m-Dinitrobenzene ....................................................... 221Lead tetraacetate ........................................................ 503 MEA ............................................................................ 229Lead thiocyanate ........................................................ 503 MEA ............................................................................ 233Lead thiosulfate ........................................................... 503 Mechlorethanamine ..................................................... 311Lead tungstate ............................................................ 503 MEK ............................................................................ 338Lentin .......................................................................... 130 Melamine .................................................................... 504Leptophos ................................................................... 503 Melinite ....................................................................... 397Lewisite ....................................................................... 306 Mephosfolan ............................................................... 504Li ................................................................................ 309 Mercaptobenzene ....................................................... 387Lindane ....................................................................... 503 Mercaptodimethur ....................................................... 504Linseed oil, boiled ....................................................... 503 Mercaptomethane ....................................................... 347Linseed oil, raw ........................................................... 503 Mercuric acetate ......................................................... 504Liquefied natural gas ................................................... 307 Mercuric ammonium chloride ...................................... 504Liquefied petroleum gas .............................................. 308 Mercuric chloride ........................................................ 504Liquid chlorine ............................................................ 139 Mercuric cyanide ........................................................ 504Liquid oxygen ............................................................. 375 Mercuric iodide ........................................................... 504Litharge ...................................................................... 503 Mercuric nitrate .......................................................... 504Lithium ........................................................................ 309 Mercuric oxide ............................................................ 504Lithium aluminum hydride ........................................... 503 Mercuric sulfate .......................................................... 504Lithium bichromate ...................................................... 504 Mercuric sulfide .......................................................... 504Lithium borohydride .................................................... 504 Mercuric thiocyanate .................................................. 504Lithium chromate ........................................................ 504 Mercurous acetate ...................................................... 504Lithium hydride ........................................................... 504 Mercurous chloride ..................................................... 504Lithium metal ............................................................... 309 Mercurous nitrate ........................................................ 504LNG ............................................................................ 307 Mercury ...................................................................... 504Lorsban ...................................................................... 159 Mercury fulminate (wetted >20% water) ...................... 504LOX ............................................................................ 375 Mercury oxide ............................................................. 504LPG ............................................................................ 308 Mesityl oxide ............................................................... 312Luprisol ....................................................................... 406 Mestranol .................................................................... 504Lye ............................................................................. 421 Mesyl chloride ............................................................. 316M-1 ............................................................................. 306 Metaldehyde ............................................................... 504Mace ........................................................................... 144 Metaphos .................................................................... 349Madone ....................................................................... 170 meta-Xylene ................................................................ 477Magnesium (powder) .................................................. 504 Methacetone ............................................................... 201Magnesium perchlorate ............................................... 504 Methacrolein diacetate ................................................ 50524
  • 29. Alphabetical Material IndexMethacrylaldehyde ...................................................... 505 Methyl butenol ............................................................. 505Methacrylic acid ......................................................... 313 Methyl butyl ketone ..................................................... 329Methacrylic acid chloride ............................................ 314 Methyl butyrate ........................................................... 330Methacrylic anhydride ................................................ 505 Methyl cellosolve ......................................................... 252Methacrylonitrile .......................................................... 322 Methyl chloride ............................................................ 331Methacryloyl chloride .................................................. 314 Methyl chloroacetate ................................................... 332Methacryloyloxyethyl isocyanate ................................. 505 Methyl chloroformate ................................................... 505Methaldehyde ............................................................. 267 Methyl chloromethyl ether ........................................... 505Methallyl chloride ........................................................ 505 Methyl cyanide .............................................................. 56Methamidophos ........................................................... 505 Methyl cyclohexanone ................................................. 505Methanal ..................................................................... 267 Methyl cyclopentadiene dimer ..................................... 505Methane ...................................................................... 315 Methyl cyclopentadienyl manganese tricarbonyl......... 505Methane carboxylic acid ............................................... 52 Methyl dichloroacetate ................................................ 336Methane sulfuryl chloride ............................................ 316 Methyl dichloroarsine .................................................. 505Methane trichloride ..................................................... 150 Methyl dichloroethanoate ............................................ 336Methanearsonic acid, sodium salt ............................... 505 Methyl disulfide ........................................................... 211Methanecarbonitrile ...................................................... 56 Methyl ether ................................................................ 212Methanephosphonyl chloride ....................................... 352 1-Methyl ethyl alcohol ................................................. 297Methanesulfonic acid chloride ..................................... 316 Methyl ethyl ketone ..................................................... 338Methanesulfonyl f l o u r i d e . . . . . . . . . . . . . ............ 317 Methyl ethyl pyridine ................................................... 506Methanesulfonyl chloride ............................................. 316 3-(1-Methyl ethyl) phenyl methyl carbamate ................ 506Methanethiol ................................................................ 347 Methyl fluoroacetate .................................................... 506Methanoic acid ........................................................... 269 Methyl fluorosulfate ..................................................... 506Methanol ..................................................................... 318 Methyl formal .............................................................. 506Methiocarb .................................................................. 505 Methyl formate ............................................................ 339Methomyl .................................................................... 505 Methyl heptyl ketone ................................................... 5062-Methoxy-2-methylpropane ........................................ 328 Methyl hydride ............................................................ 3153-Methoxybutyl acetate ............................................... 505 Methyl hydroxide ......................................................... 318Methoxycarbonylethylene ............................................ 321 Methyl iodide ............................................................... 341Methoxychlor ............................................................... 505 Methyl isobutenyl ketone ............................................. 3122-Methoxyethanol ........................................................ 252 Methyl isobutyl carbinol ............................................... 342Methoxyethyl mercuric acetate .................................... 505 Methyl isobutyl ketone ................................................. 343Methoxyethylene ......................................................... 474 Methyl isocyanate ....................................................... 3441-Methoxyethylene ...................................................... 474 Methyl isopropenyl ketone ........................................... 345Methoxymethyl isocyanate .......................................... 505 Methyl isopropyl ketone .............................................. 327Methyl 2-benzimidazole carbamate ............................. 505 Methyl isothiocyanate ................................................. 346Methyl 2-chloroacrylate ............................................... 333 Methyl ketone ................................................................ 54Methyl 2-chloropropenoate .......................................... 333 2-Methyl lactonitrile ....................................................... 55Methyl 2-methyl-2-propenoate ..................................... 348 Methyl mercaptan ....................................................... 347Methyl acetate ............................................................. 319 Methyl mercaptopropionaldehyde ............................... 506Methyl acetic acid ....................................................... 406 Methyl mercuric dicyanamide ..................................... 506Methyl acetic ester ...................................................... 319 Methyl mercury ........................................................... 506Methyl acetoacetate .................................................... 505 Methyl methacrylate .................................................... 348Methyl acetone ............................................................ 505 Methyl methane sulfonate ............................................ 506Methyl acetylene ......................................................... 505 Methyl methanoate ...................................................... 339Methyl acetylene-allene mixture .................................. 320 Methyl monochloroacetate .......................................... 332Methyl acrylate ............................................................ 321 Methyl mustard ............................................................ 346Methyl acrylonitrile ...................................................... 322 1-Methyl naphthalene .................................................. 506Methyl alcohol ............................................................. 318 Methyl nitrite ............................................................... 506Methyl amyl acetate .................................................... 505 3-Methyl nitrosoaminopropionitrile ............................... 506Methyl amyl alcohol ..................................................... 342 Methyl orthosilicate ..................................................... 506Methyl amyl ketone ..................................................... 325 Methyl oxide ................................................................ 212Methyl azinphos .......................................................... 505 Methyl parathion ......................................................... 349Methyl azoxymethanol acetate ..................................... 505 Methyl PCT ................................................................. 216Methyl benzoate .......................................................... 505 Methyl pentyl ketone ................................................... 325Methyl bromide ........................................................... 326 Methyl phenkapton ...................................................... 506 25
  • 30. Alphabetical Material IndexMethyl phosphonic dichloride ...................................... 352 Methylchloroform ........................................................ 453Methyl phosphonothioic dichloride .............................. 353 Methylcyclohexane ...................................................... 334Methyl phosphonous dichloride ................................... 506 Methylcyclopentane .................................................... 335Methyl phosphorous dichloride .................................... 353 Methyldichlorosilane .................................................... 337Methyl propenoate ...................................................... 321 Methylethene................................................................ 411Methyl propionate ....................................................... 506 4-Methylene ................................................................ 204Methyl propyl ether ..................................................... 506 Methylene acetone ...................................................... 356Methyl propyl ketone ................................................... 506 Methylene bichloride ................................................... 1871-Methyl pyrrolidone ................................................... 506 Methylene bromide ...................................................... 180Methyl rhodanate ........................................................ 354 Methylene chloride ...................................................... 187Methyl salicylate .......................................................... 506 Methylene cyanide ...................................................... 310Methyl styrene ............................................................ 475 Methylene cyanohydrin ............................................... 268Methyl sulfate .............................................................. 217 4,4-Methylene dianiline .............................................. 505Methyl sulfhydrate ....................................................... 347 Methylene dibromide ................................................... 180Methyl sulfide .............................................................. 218 Methylene dichloride ................................................... 187Methyl sulfocyanate .................................................... 354 Methylene diisocyanate .............................................. 506Methyl tert-butyl ether ................................................. 328 Methylene oxide ......................................................... 267Methyl thiocyanate ...................................................... 354 4,4-Methylene-bis-(2-chloroaniline) ............................ 505Methyl trichloroacetate ................................................ 506 4,4-Methylene-bis-(2-methyaniline) ............................ 505Methyl vinyl ether ........................................................ 474 Methylene-bis-(phenyliIsocyanate) (or MBI) ............... 505Methyl vinyl ketone ...................................................... 356 Methylethylamine ........................................................ 506Methyl zinc .................................................................. 219 1-Methylethylamine ..................................................... 3002-Methyl-1,3-butadiene ............................................... 296 Methylethylene ............................................................ 4112-Methyl-1-butene ....................................................... 505 Methylhydrazine .......................................................... 3403-Methyl-1-butene ....................................................... 505 1-Methylhydrazine ...................................................... 3402-Methyl-1-butenone ................................................... 345 Methylmethane ............................................................ 2282-Methyl-1-nitroanthraquinone .................................... 506 Methyl-n-butanoate ..................................................... 3302-Methyl-1-pentene ..................................................... 506 Methyl-n-butyrate ........................................................ 3304-Methyl-1-pentene ..................................................... 350 Methylol ...................................................................... 3181-Methyl-1-phenylethene ............................................. 299 Methyloxirane .............................................................. 4141-Methyl-2-aminoethanol ............................................. 298 Methylpentamethylene ................................................. 3353-Methyl-2-butanone ................................................... 327 Methylpentane ............................................................. 5062-Methyl-2-butene ....................................................... 505 methylphosphonofluoridate .......................................... 4232-Methyl-2-hydroxy-3-butyne ...................................... 506 Methylphosphonothioic acid ........................................ 4784-Methyl-2-pentanol .................................................... 342 Methylphosphonyl dichloride ....................................... 5062-Methyl-2-pentene ..................................................... 506 Methylpiperidine .......................................................... 5064-Methyl-2-pentene ..................................................... 506 2-Methylpropane ......................................................... 2932-Methyl-2-propenoic acid .......................................... 313 2-Methylpropene ......................................................... 2943-Methyl-3-butene-2-one ............................................. 345 2-Methylpropenenitrile ................................................. 3224-Methyl-3-penten-2-one ............................................. 312 Methyltetrahydrofuran ................................................. 5062-Methyl-4-pentanone ................................................. 343 Methyltrichloro silane .................................................. 3552-Methyl-5-vinyl pyridine (MVP) .................................. 506 Methyltrichloromethane ............................................... 4532-Methyl-6-ethyl aniline ............................................... 506 Metolachlor ................................................................. 506Methylacryl chloride .................................................... 314 Metolcarb .................................................................... 5062-Methylacrylic acid, methyl ester ............................... 348 Mevinphos ................................................................... 507Methylaldehyde ........................................................... 267 Mexacarbate ............................................................... 507Methylamine ................................................................ 323 MFA ............................................................................ 263Methylamine ................................................................ 324 MFB ............................................................................ 264Methylaziridine ............................................................ 413 MIBC .......................................................................... 342Methylbenzene ............................................................ 448 MIBK ........................................................................... 312Methylbenzol ............................................................... 448 MIBK ........................................................................... 3431-Methylbutadiene ....................................................... 380 MIC ............................................................................. 3442-Methylbutadiene ....................................................... 296 3-MIC ......................................................................... 3423-Methylbutan-2-one ................................................... 327 Michler’s ketone .......................................................... 507Methylcarbinol ............................................................. 232 MIK ............................................................................. 343Methylcarbylamine ...................................................... 344 Mineral naphtha ............................................................ 9026
  • 31. Alphabetical Material IndexMineral oil ................................................................... 507 MVP (2-Methyl-5-vinyl pyridine) .................................. 507Mineral spirits ............................................................. 358 Myrcene ..................................................................... 507Miostat ........................................................................ 130 N- propanolamine ....................................................... 512MIPK ........................................................................... 327 N-(2-chlorophenylthiourea) ......................................... 152Mirbane oil .................................................................. 363 N-(2-methylphenyl) thiourea ....................................... 351Mirex ........................................................................... 507 N,N’-diacetyl benzidine ............................................... 492MIT ............................................................................. 346 N,N’-dibutyl hexamethylene diamine ............................ 493MITC ........................................................................... 346 N,N-diethyl aniline ....................................................... 494MMA ........................................................................... 324 N,N-diethylethanamine ................................................ 456MMA ........................................................................... 348 N,N-dimethyl cyclohexylamine .................................... 495MME ........................................................................... 348 N,N-dimethyl formamide ............................................. 213MMH ........................................................................... 340 N,N-dimethylacetamide .............................................. 206MNBK ......................................................................... 329 N,N-dimethylaniline ..................................................... 208m-Nitrophenol ............................................................. 508 N,N-dimethyl-p-phenylenediamine .............................. 215m-Nitrotoluene ............................................................. 370 Nabam ........................................................................ 507Molecular oxygen ........................................................ 375 Nafenopin ................................................................... 507Molten phosphorus ...................................................... 392 Naled .......................................................................... 507Molybdinum trioxide .................................................... 507 N-aminoethyl piperazine ............................................. 482Monoallylamine ............................................................. 68 n-Amyl acetate ............................................................ 484Monobutylamine .......................................................... 116 n-Amyl alcohol .............................................................. 82Monochlorethane ........................................................ 238 n-Amyl chloride ........................................................... 484Monochlorobenzene .................................................... 147 n-Amyl mercaptan ....................................................... 484Monochloroethylene .................................................... 470 n-Amyl nitrate ............................................................. 484Monochloromethane .................................................... 331 n-Amyl nitrite ............................................................... 484Monochlorotetrafluoroethane ....................................... 507 Naphtha......................................................................... 358Monochlorotrifluoromethane ........................................ 507 Naphtha: coal tar ......................................................... 507Monocrotaline ............................................................. 507 Naphtha: stoddard solvent ........................................... 507Monocrotophos ........................................................... 507 Naphtha: VM & P ........................................................ 507Monoethanolamine ...................................................... 229 Naphthalene ................................................................ 507Monoethylamine .......................................................... 233 Napthylthiourea ........................................................... 507Monoethyldichlorosilane .............................................. 242 Napthylurea ................................................................ 507Monofluoroacetate ...................................................... 263 Naramycin .................................................................. 171Monofluorobenzene .................................................... 264 Natural gas .................................................................. 307Monofluoroethene ....................................................... 472 Natural gas .................................................................. 315Monoisopropanolamine ............................................... 298 Naturium ..................................................................... 418Monomethylamine ....................................................... 323 n-Butane ..................................................................... 112Monomethylhydrazine ................................................. 340 n-Butanol .................................................................... 487Morpholine .................................................................. 357 n-Butene ..................................................................... 118Motor fuel .................................................................... 272 n-Butyl acetate ............................................................ 113Motor spirit .................................................................. 272 n-Butyl alcohol ............................................................ 487 n-Butyl bromide .......................................................... 108Mous-con .................................................................... 479 n-Butyl carbinol ............................................................. 82Mouse-Rid .................................................................. 424 n-Butyl chloroformate .................................................. 487MPTD ......................................................................... 353 n-Butyl isocyanate ...................................................... 121MSF ............................................................................ 317 n-Butyl mercaptan ....................................................... 122MTBE .......................................................................... 328 n-Butyl methacrylate ................................................... 487m-Toluidine ................................................................. 451 n-Butylacrylate ............................................................ 114Muriatic acid ............................................................... 280 n-Butylamine ............................................................... 116Muriatic ether .............................................................. 238 n-Butylaniline .............................................................. 487Mustard gas .................................................................. 99 n-Butylchloride ............................................................ 148Mustard HD ................................................................... 99 n-Butylene .................................................................. 118Mustargen ................................................................... 311 n-Butyric acid ............................................................. 487Muster ......................................................................... 273 NCI-C54262 ................................................................ 473Mustine ....................................................................... 311 n-Decyl acrylate ......................................................... 492Mustine hydrochloride ................................................. 507 n-Decyl alcohol ........................................................... 492MVK ............................................................................ 356 n-Decyl benzene ......................................................... 492 27
  • 32. Alphabetical Material IndexN-dipropylamine ......................................................... 225 Nitrogen gas ............................................................... 364Neodecanoic acid ....................................................... 507 Nitrogen liquid ............................................................. 364Neon ........................................................................... 507 Nitrogen monoxide ...................................................... 362Neoprene .................................................................... 154 Nitrogen mustard ......................................................... 311N-ethyl cyclohexylamine ............................................. 498 Nitrogen mustard ......................................................... 464N-ethyl-2,2-di(chloroethyl) amine (HN1) ..................... 498 Nitrogen mustard hydrochloride .................................. 508N-ethyl-2-2 di(chloroethyl) amine (HN1) ..................... 507 Nitrogen mustard N-oxide ............................................ 508N-ethylaniline .............................................................. 498 Nitrogen mustard N-oxide hydrochloride ..................... 508N-ethylbutylamine ....................................................... 236 Nitrogen oxide ............................................................. 362N-formyldimethylamine .............................................. 213 Nitrogen oxide ............................................................. 365n-Heptane ................................................................... 274 Nitrogen oxide ............................................................. 371n-Heptene ................................................................... 275 Nitrogen oxychloride ................................................... 369n-Hexaldehyde ............................................................ 501 Nitrogen tetroxide ........................................................ 365n-Hexane .................................................................... 276 Nitrogen trifluoride ...................................................... 508Nickel .......................................................................... 507 Nitroglycerin ............................................................... 366Nickel acetate ............................................................. 507 Nitromethane ............................................................... 367Nickel ammonium sulfate ............................................. 507 5-Nitro-o-anisidine ...................................................... 508Nickel bromide ............................................................ 507 Nitrophen .................................................................... 223Nickel carbonyl............................................................ 360 2-Nitrophenol .............................................................. 508Nickel chloride ............................................................ 507 3-Nitrophenol .............................................................. 508Nickel cyanide ............................................................ 507 4-Nitrophenol .............................................................. 508Nickel fluoroborate ...................................................... 507 Nitropropane ............................................................... 368Nickel formate ............................................................. 507 1-Nitropropane ............................................................ 368Nickel hydroxide ......................................................... 507 2-Nitropropane ............................................................ 368Nickel nitrate ............................................................... 507 4-Nitropyridine-1-oxide ............................................... 508Nickel subsulfide ......................................................... 508 Nitro-Sil ......................................................................... 74Nickel sulfate ............................................................... 508 Nitrostarch (dry or wetted with <20% water) ............... 509Nickel tetracarbonyl .................................................... 360 Nitrostarch (wetted with >20% water) .......................... 509Nicotine ...................................................................... 508 Nitrosyl chloride .......................................................... 369Nicotine sulfate ........................................................... 508 Nitrosylsulfuric acid .................................................... 509Nitrador ....................................................................... 222 2-Nitrotoluene ............................................................. 370Nitralin ........................................................................ 508Nitric acid ................................................................... 361 3-Nitrotoluene ............................................................. 370Nitric oxide .................................................................. 362 4-Nitrotoluene ............................................................. 370Nitrilotriacetic acid ...................................................... 508Nitrilotriacetic acid, disodium salt ................................ 508 Nitrotoluenes ............................................................... 370Nitrilotriacetic acid, sodium salt ................................... 508 3-Nitrotoluol ................................................................. 370Nitrilotriacetic acid, trisodium salt ................................ 508 Nitrous acid, ethyl ester .............................................. 2585-Nitroacenaphthene ................................................... 508 Nitrous oxide ............................................................... 3714-Nitroaniline ............................................................... 508 N-methyl aniline .......................................................... 505Nitrobenzene ............................................................... 363 N-methyl-2,2-di(chloroethyl) amine ............................ 508Nitrobenzol .................................................................. 363 N-methyl-methanamine ............................................... 2074-Nitrobiphenyl ............................................................ 508 N-N’-bis-(2-aminoethyl)-1,2-ethanediamine ................. 457Nitrocarbol .................................................................. 367 N-nitrosodiethanolamine .............................................. 508Nitrocellulose (with >25% water) ................................. 508 N-nitrosodiethylamine ................................................. 508Nitrocellulose (with plasticizer >18%) .......................... 508 N-nitrosodimethylamine ............................................... 508Nitrochlorobenzene ..................................................... 151 N-nitrosodi-n-butylamine ............................................. 508Nitrochloroform ........................................................... 153 N-nitrosodi-n-propylamine ........................................... 508Nitrocresols ................................................................. 508 N-nitrosodiphenylamine .............................................. 509Nitrocyclohexane ........................................................ 508 N-nitrosomethylethylamine .......................................... 509Nitroethane ................................................................. 508 N-nitrosomethylvinylamine ........................................... 509Nitrofan ....................................................................... 222 N-nitrosomorpholine .................................................... 509Nitrofen ....................................................................... 508 N-nitroso-N-ethyl urea ................................................. 509Nitrogen ...................................................................... 364 N-nitroso-N-methyl urea .............................................. 509Nitrogen chloride oxide ............................................... 369 N-nitroso-N-methyl urethane ....................................... 509Nitrogen dioxide .......................................................... 365 N-nitrosonornicotine .................................................... 50928
  • 33. Alphabetical Material IndexN-nitrosopiperidine ...................................................... 509 Oxacyclopentane ........................................................ 443N-nitrosopyrrolidine .................................................... 509 Oxalic acid .................................................................. 509N-nitrososarcosine ...................................................... 509 Oxalonitrile .................................................................. 163NO .............................................................................. 362 Oxalyl cyanide ............................................................ 163n-Octane ..................................................................... 372 Oxammonium .............................................................. 290Nonane ....................................................................... 509 Oxamyl ........................................................................ 509Nonanol ...................................................................... 509 Oxane ......................................................................... 254Nonene ....................................................................... 509 2-H-1,4-oxazine .......................................................... 357Nonylphenol ................................................................ 509 Oxetanone ................................................................... 204Norbormide ................................................................. 509 2-Oxetanone ............................................................... 405Norethisterone ............................................................ 509 Oxides of nitrogen ....................................................... 365n-Pentane ................................................................... 382 Oxidoethane ................................................................ 254N-phenylthiourea ......................................................... 389 Oxirane ....................................................................... 254N-phosphonomethylglycine ......................................... 273 Oxyacyclopropane ...................................................... 254n-Propyl benzene ....................................................... 409 Oxybenzene ................................................................ 384n-Propyl chloroformate ............................................... 410 Oxydisulfoton .............................................................. 509n-Propyl mercaptan .................................................... 403 Oxygen ....................................................................... 375n-Propyl nitrate ........................................................... 512 Oxygen difluoride ........................................................ 376n-Undecylbenzene ...................................................... 519 Oxymethylene ............................................................. 267o-Aminopyridine ........................................................... 73 Ozone ......................................................................... 510o-Anisidine .................................................................. 484 Paint thinner ............................................................... 510o-Anisidine hydrochloride ........................................... 484 Paint, latex .................................................................. 510o-Chlorobenzylidine malononitrile ............................... 145 Paint, oil base ............................................................. 510o-Chloronitrobenzene ................................................. 151 p-Aminopyridine ........................................................... 73o-Chlorophenol ........................................................... 489 Panfuran S ................................................................. 510Octachloronaphthalene ............................................... 509 p-Anisidine .................................................................. 484Octamethyl diphosphoramide ...................................... 509 Paradichlorobenzene .................................................. 182Octane ........................................................................ 372 Paraformaldehyde ...................................................... 510Octanoic acid ............................................................. 509 Paraldehyde ............................................................... 510Octanol ....................................................................... 509 Paramoth .................................................................... 182Octene ........................................................................ 373 Paraquat ..................................................................... 5101-Octene ..................................................................... 373 Paraquat methosulfate ................................................ 510Octyl epoxy tallate ....................................................... 509 Parathion .................................................................... 377Octylene ..................................................................... 373o-Dinitrobenzene ........................................................ 221 para-Xylene ................................................................ 477Oil of bitter almonds .................................................... 363 Parazene .................................................................... 182Oil of turpentine .......................................................... 465 Paris green ................................................................. 510Oil of Vitrol .................................................................. 431 p-Benzoquinone ............................................................ 92Olamine ...................................................................... 229 PCE ............................................................................ 439Oleic acid ................................................................... 509 p-Chloroaniline ............................................................ 489Oleic acid, potassium salt ........................................... 509 p-Chloro-m-cresol ....................................................... 489Oleic acid, sodium salt ................................................ 509 p-Chloronitrobenzene ................................................. 151Oleum ......................................................................... 374 p-Chloro-o-toluidine .................................................... 489o-Nitrobenzene ........................................................... 363 p-Chlorotoluene .......................................................... 158o-Nitrophenol .............................................................. 508 PCP ............................................................................ 379o-Nitrotoluene ............................................................. 370 p-Cresidine ................................................................. 491o-Phenyl phenate, sodium .......................................... 510 p-Cymene ................................................................... 492o-Phenyl phenol .......................................................... 510 PDB ............................................................................ 182Orange oil SS ............................................................. 509 p-Dichlorobenzene ...................................................... 182Ordram(or Molinate) .................................................... 509 p-Dinitrobenzene ........................................................ 221ortho-Xylene ............................................................... 477 p-Dioxane ................................................................... 224Orvinylecarbinol ............................................................ 67 Pentaborane monohydride .......................................... 378Osmium tetroxide ........................................................ 509 Pentacarbonyliron ....................................................... 292o-Toluidine .................................................................. 451 1,2,3,7,8-Pentachlorodibenzofurans ........................... 510o-Tolyl thiourea ........................................................... 351 Pentachlorodibenzo-p-dioxins ..................................... 510Oxacyclopentadiene .................................................... 270 Pentachloroethane ...................................................... 510 29
  • 34. Alphabetical Material IndexPentachlorophenate, sodium ....................................... 510 Phenylcarboxyamide ..................................................... 89Pentachlorophenol ...................................................... 379 Phenylcarbylamine chloride ........................................ 510Pentadecanol .............................................................. 510 Phenylcyanide .............................................................. 91Pentadecylamine ........................................................ 510 Phenyldichloroarsine .................................................. 3861,3-Pentadiene ........................................................... 380 Phenylenediamine ...................................................... 510Pentadione .................................................................. 381 Phenylethane .............................................................. 2342,4-Pentadione ........................................................... 381 Phenylethylene ........................................................... 425Pentaerythritol ............................................................. 510 Phenylhydrazine hydrochloride .................................. 510Pentaerythritol tetranitrate (PETN) .............................. 510 Phenylic acid .............................................................. 384Pentamethylene .......................................................... 173 Phenylmercuric acetate .............................................. 510Pentan-2,4-dione ........................................................ 381 Phenylmethane ........................................................... 448Pentanoic acid ............................................................ 510 2-Phenyloxirane .......................................................... 4261-Pentanol .................................................................... 82 Phenylphosphine dichloride ........................................ 3883-Pentanone ............................................................... 201 1-Phenylpropane ........................................................ 4091-Pentene ................................................................... 510 2-Phenylpropane ........................................................ 3012-Pentene ................................................................... 510 2-Phenylpropylene ...................................................... 2991-Pentyl alcohol ............................................................ 82 Phenylthiocarbamide .................................................. 389Pentyltrichlorosilane ...................................................... 83 Phenylthiourea ............................................................ 389Pepper spray .............................................................. 510 Phorate ....................................................................... 511Peracetic acid ............................................................ 510 Phosacetim ................................................................. 511PERC ......................................................................... 439 Phosfolan .................................................................... 511Percarbamide ............................................................. 466 Phosgen ..................................................................... 390Perchlor ...................................................................... 439 Phosgene ................................................................... 390Perchloric acid (50 to 72%) ........................................ 383 Phosmet ...................................................................... 511Perchloroethylene ....................................................... 439 Phosphamidon ............................................................ 511Perchloromethyl mercaptan ........................................ 510 Phosphine ................................................................... 391Perchloryl fluoride ....................................................... 510 Phosphoric acid .......................................................... 511Perclene ..................................................................... 439 Phosphoric sulfide ...................................................... 394Perfluoroethylene ........................................................ 442 Phosphorochloridothioic acid, O,O-dimethyl ester ...... 216PETN (Pentaerythritol tetranitrate) .............................. 510 Phosphorous hydride .................................................. 391Petrol .......................................................................... 272 Phosphorous trihydride ............................................... 391Petrolatum ................................................................... 510 Phosphorus ................................................................ 392Petroleum ................................................................... 358 Phosphorus (amorphous red) ..................................... 511Petroleum distillate ...................................................... 358 Phosphorus (black) ..................................................... 511Petroleum ether .......................................................... 358 Phosphorus bromide ................................................... 395Petroleum gas, liquefied .............................................. 308 Phosphorus chloride ................................................... 396Petroleum naphtha ...................................................... 358 Phosphorus chloride oxide .......................................... 393 Phosphorus oxide trichloride ....................................... 393Petroleum solvent ........................................................ 358 Phosphorus oxychloride .............................................. 393Phenanthrene ............................................................. 510 Phosphorus oxytrichloride ........................................... 393Phenic acid ................................................................ 384 Phosphorus pentachloride .......................................... 511Phenol ........................................................................ 384 Phosphorus pentafluoride ........................................... 511Phenol trinitrate ........................................................... 397 Phosphorus pentasulfide ............................................. 394Phenyl alcohol ............................................................ 384 Phosphorus pentoxide ................................................. 511Phenyl chloride ........................................................... 147 Phosphorus persulfide ................................................ 394Phenyl fluoride ............................................................ 264 Phosphorus tribromide ................................................ 395Phenyl isocyanate ...................................................... 510 Phosphorus trichloride ................................................ 396Phenyl mercaptan ....................................................... 387 Phosphoryl chloride .................................................... 393Phenyl phosphorous dichloride ................................... 388 Phosporous trioxide .................................................... 511Phenyl phosphorous thiodichloride ............................. 511Phenyl silatrane .......................................................... 511 Phosvin ....................................................................... 479Phenyl trichloromethane ............................................... 93 Phthalic anhydride ...................................................... 5111-Phenyl-2-thiourea .................................................... 389 Pic-chlor ..................................................................... 153Phenylacetonitrile ....................................................... 385 Picfume ...................................................................... 153Phenylamine ................................................................. 85 Picoline ....................................................................... 511Phenylarsine dichloride .............................................. 386 Picral .......................................................................... 39730
  • 35. Alphabetical Material IndexPicric acid .................................................................. 397 2-Propanol .................................................................. 297Picride ........................................................................ 153 3-Propanolide ............................................................. 405Picrotoxin .................................................................... 511 2-Propanone ................................................................. 54Pimelic ketone ............................................................ 170 Propargite ................................................................... 512Pinacolyl alcohol ......................................................... 511 Propargyl bromide ...................................................... 110Pinacolyl methylphosphonofluoridate .......................... 423 Propellant 12 ............................................................... 512Pine oil ........................................................................ 511 2-Propen-1-amine ......................................................... 68Pinene ........................................................................ 398 2-Propenal .................................................................... 60Piperazine .................................................................. 511 Propenamide ................................................................ 61Piperidine ................................................................... 399 2-Propenamine ............................................................. 68Piperylene .................................................................. 380 Propene ...................................................................... 411Piprotal ....................................................................... 511 1-Propene ................................................................... 411Platinum tetrachloride ................................................. 511 Propene acid ................................................................ 62PMFP ......................................................................... 423 Propene oxide ............................................................. 414p-Nitrobenzene ........................................................... 363 Propene-3-yltrichlorosilane ........................................... 72p-Nitrophenol .............................................................. 508 Propenenitrile ............................................................... 63p-Nitrotoluene ............................................................. 370 2-Propenenitrile ............................................................ 63Polybrominated biphenyls ........................................... 511 Propenoic acid ............................................................. 62Polybutene .................................................................. 511 2-Propenoic acid .......................................................... 62Polychlorinated biphenyls ........................................... 511 Propenoic acid, ethyl ester ......................................... 231Polyethylene polyamines ............................................. 511 Propenoic acid, methyl ester ...................................... 321Polyphosphoric acid ................................................... 511 Propenol ....................................................................... 67Polypropylene ............................................................. 511 2-Propenol .................................................................... 67Polypropylene glycol ................................................... 511 Propenoyl chloride ........................................................ 64Polypropylene glycol methyl ether ............................... 511 Propenyl alcohol ........................................................... 67Ponceau 3R ................................................................ 511 2-Propenyl bromide ...................................................... 69Potassium ................................................................... 400 Propenyl chloride .......................................................... 70Potassium arsenite ...................................................... 511 2-Propenyl chloroformate ............................................. 71Potassium binoxalate ................................................... 511 Propiolactone .............................................................. 405Potassium bromate ..................................................... 511 Propionaldehyde ......................................................... 512Potassium chlorate ...................................................... 511 Propionic acid ............................................................ 406Potassium chromate ................................................... 511 Propionic anhydride ................................................... 512Potassium cyanide ...................................................... 511 Propionic nitrile ........................................................... 407Potassium dichloro-s-triazinetrione ............................. 512 Propionitrile ................................................................ 407Potassium dichromate ................................................. 512 Propoxur ..................................................................... 512Potassium fluoride ...................................................... 512 1-Propyl acetate ......................................................... 408Potassium hydroxide ................................................... 512 Propyl bromide ........................................................... 109Potassium hydroxide solution ...................................... 512 Propyl chlorocarbonate ............................................... 410Potassium iodide ......................................................... 512 Propyl chloroformate ................................................... 410Potassium oxalate ....................................................... 512 2-Propyl chloroformate ............................................... 302Potassium permanganate ............................................ 512 Propyl cyanide ............................................................ 126Potassium peroxide ..................................................... 512 Propyl mercaptan ....................................................... 403Potassium peroxydisulfate ........................................... 401 Propylacetone ............................................................. 329Potassium persulfate ................................................... 401 Propylamine ................................................................ 512Potassium silver cyanide ............................................. 512 2-Propylamine ............................................................ 300Progesterone .............................................................. 512 Propylene ................................................................... 411Promecarb .................................................................. 512 1-Propylene ................................................................ 411Prometryne ................................................................. 512 Propylene butylene polymer ........................................ 512Propadiene ................................................................. 512 Propylene dichloride ................................................... 412Propadiene mixture ..................................................... 320 Propylene glycol ......................................................... 512Propane ...................................................................... 402 Propylene glycol ethyl ether ........................................ 512Propane sultone .......................................................... 512 Propylene glycol methyl ether ..................................... 5121,2-Propanediol-1-methacrylate .................................. 291 Propylene glycol monomethacrylate ............................ 291Propanethiol ................................................................ 403 Propylene oxide .......................................................... 4141-Propanethiol ............................................................ 403 Propylene tetramer ..................................................... 512Propanoic acid ........................................................... 406 Propylene trimer ......................................................... 512 31
  • 36. Alphabetical Material Index1,2-Propylenediamine ................................................. 512 sec-Butanol ................................................................. 487Propyleneimine ........................................................... 413 sec-Butyl alcohol ......................................................... 487Propylnitrile ................................................................. 407 sec-Butylamine ........................................................... 4872-Propynol .................................................................. 404 sec-Propyl alcohol ...................................................... 297Propynyl alcohol ......................................................... 404 Selenic acid ................................................................ 513Prothoate .................................................................... 512 Selenium dihydride ..................................................... 288Prozoin ....................................................................... 406 Selenium dioxide ......................................................... 513Prussic acid ................................................................ 285 Selenium hexafluoride ................................................. 513Prussite ...................................................................... 163 Selenium oxychloride .................................................. 513PS .............................................................................. 153 Selenium trioxide ......................................................... 513p-tert-Butyl phenol ....................................................... 487 Selenium(powder) ....................................................... 513p-Toluene sulfonic acid ............................................... 517 Semicarbazide hydrochloride ..................................... 513p-Toluidin .................................................................... 451 Sewer gas ................................................................... 289p-Tolyl chloride ........................................................... 158 Sextone ....................................................................... 170PTU ............................................................................ 389 Silane ......................................................................... 513Pyrene ........................................................................ 512 Silica, crystalline ......................................................... 513Pyrethrins ................................................................... 512 Silica, gel .................................................................... 5134-Pyridinamine ............................................................. 73 Silicochloroform .......................................................... 455Pyridine ...................................................................... 415 Silicofluoric acid ......................................................... 2654-Pyridylamine .............................................................. 73 Silicon (powder) .......................................................... 513Pyriminil ...................................................................... 512 Silicon chloride ........................................................... 417Pyrogallic acid ............................................................ 512 Silicon dioxide (sand) ................................................. 513Pyrophosphoric acid, tetraethyl ester ......................... 441 Silicon tetrachloride .................................................... 417Pyrosulfuryl chloride ................................................... 512 Silver ........................................................................... 513Pyrrolidine .................................................................. 513 Silver acetate .............................................................. 5132-Pyrrolidone .............................................................. 513 Silver carbonate .......................................................... 513Quinoline ..................................................................... 513 Silver iodate ................................................................ 513Quinone ........................................................................ 92 Silver nitrate ................................................................ 513R 12 ............................................................................ 513 Silver oxide ................................................................. 513R 20 (refrigerant) ........................................................ 150 Silver sulfate ............................................................... 514R 22 ............................................................................ 513 Silvex .......................................................................... 514R1113 ......................................................................... 458 Simazine ..................................................................... 514R40 ............................................................................. 331 Sinox ........................................................................... 222R50 ............................................................................. 315 Skellysolve A ............................................................... 382Range oil ..................................................................... 304 Soda lye ..................................................................... 421 Sodium ....................................................................... 418Ratal ........................................................................... 479 Sodium 2-mercaptobenzothiazol solution .................... 514Refrigerant 12 ............................................................. 513 Sodium alkyl sulfates ................................................... 514Refrigerant 22 ............................................................. 513 Sodium alkylbenzene sulfonates ................................. 514Refrigerant R717 ........................................................... 74 Sodium amide ............................................................. 514Resorcinol ................................................................... 513 Sodium arsenate ......................................................... 514Ricin ........................................................................... 513 Sodium arsenite .......................................................... 514Rodeo ......................................................................... 273 Sodium azide .............................................................. 419Ro-Dex ........................................................................ 424 Sodium bifluoride ........................................................ 514Roundup ..................................................................... 273 Sodium bisulfite .......................................................... 514Rubbing alcohol .......................................................... 297 Sodium borate ............................................................ 514Rubidium ..................................................................... 513 Sodium borohydride ................................................... 515s-(2-Bis(1-methylethyl)amino)ethyl) o-ethylester ......... 478 Sodium borohydride (15% or less) ............................. 514Saccharin ................................................................... 513 Sodium cacodylate ..................................................... 514Safrole ........................................................................ 513 Sodium chlorate .......................................................... 514Salicylaldehyde ........................................................... 513 Sodium chlorate solution ............................................. 514Salicylic acid .............................................................. 513 Sodium chromate ........................................................ 514Saltpeter ..................................................................... 513 Sodium dichloro-s-triazinetrione ................................. 514Sand acid ................................................................... 265 Sodium dichromate ..................................................... 514Sarin ........................................................................... 416 Sodium ferrocyanide .................................................. 514Saxitoxin ..................................................................... 513 Sodium fluoride ........................................................... 51432
  • 37. Alphabetical Material IndexSodium fluoroacetate .................................................. 514 Sulfur anhydride ......................................................... 434Sodium fluorosilicate ................................................... 514 Sulfur chloride ............................................................ 432Sodium hydrate .......................................................... 421 Sulfur chloride oxide ................................................... 445Sodium hydride .......................................................... 515 Sulfur dioxide .............................................................. 430Sodium hydrosulfide solution ...................................... 514 Sulfur hydride ............................................................. 289Sodium hydroxide ....................................................... 421 Sulfur monochloride .................................................... 432Sodium hypochlorite ................................................... 422 Sulfur mustard .............................................................. 99Sodium hypochlorite solution ...................................... 422 Sulfur oxide ................................................................. 430Sodium methylate ....................................................... 515 Sulfur oxychloride ....................................................... 435Sodium nitrate ............................................................. 514 Sulfur pentafluoride ..................................................... 515Sodium nitrite .............................................................. 514 Sulfur phosphide ......................................................... 394Sodium oxalate ............................................................ 514 Sulfur subchloride ....................................................... 432Sodium perchlorate ..................................................... 514 Sulfur tetrafluoride....................................................... 433Sodium persulfate ....................................................... 514 Sulfur trioxide .............................................................. 434Sodium phosphate ...................................................... 514 Sulfureted hydrogen ................................................... 289Sodium phosphate, tribasic ......................................... 514 Sulfuric acid ............................................................... 431Sodium phosphide ...................................................... 515 Sulfuric acid, dimethyl ester ........................................ 217Sodium saccharin ....................................................... 515 Sulfuric acid, fuming ................................................... 374 Sulfuric anhydride ...................................................... 434Sodium selenate ......................................................... 515 Sulfuric chlorohydrin ................................................... 157Sodium selenite .......................................................... 515 Sulfuric oxide .............................................................. 434Sodium silicate ............................................................ 515 Sulfuric oxychloride .................................................... 435Sodium sulfate ............................................................ 515 Sulfurous acid ............................................................. 515Sodium sulfide ............................................................ 515 Sulfurous acid anhydride ............................................ 430Sodium sulfite ............................................................. 515 Sulfurous acid, diammonium salt ................................... 80Sodium tellurite ........................................................... 515 Sulfurous anhydride .................................................... 430Sodium thiocyanate .................................................... 515 Sulfurous oxide ........................................................... 430Solvent 111 ................................................................. 453 Sulfurous oxychloride ................................................. 445Soman ........................................................................ 423 Sulfuryl chloride............................................................. 435Sorbitol ....................................................................... 515 Supracide ................................................................... 515Spirits of turpentine ..................................................... 465 Sweet spirit of nitre ..................................................... 258Stannous fluoride ........................................................ 515 T ................................................................................. 515Stearic acid ................................................................ 515 Tabun ......................................................................... 436Sterigmatocystin ......................................................... 515 Tall oil ......................................................................... 515s-Tetrachloroethane .................................................... 438 Tannic acid ................................................................. 515Stibine ........................................................................ 515 Tar .............................................................................. 515Stoddard solvent ......................................................... 358 t-Butanol ..................................................................... 115Strontium chromate ..................................................... 515 t-Butyl alcohol ............................................................. 115Strychnine .................................................................. 424 t-Butyl methyl ether ..................................................... 328Strychnine sulfate ....................................................... 515 t-Butylamine ................................................................ 117Styrene ....................................................................... 425 TCE ............................................................................ 454Styrene monomer ....................................................... 425 TCM ............................................................................ 150Styrene oxide .............................................................. 426 TDI .............................................................................. 450Styrene-7,8-oxide ....................................................... 426 2,4-TDI ....................................................................... 450Styrol .......................................................................... 425 TEA ............................................................................ 456Styrolene .................................................................... 425 Tear gas ..................................................................... 144Suberane .................................................................... 168 TEL ............................................................................. 440Sucrose ...................................................................... 515 Tellurium (powder) ...................................................... 515Sulfallate ..................................................................... 515 Tellurium fluoride ......................................................... 437Sulfan ......................................................................... 434 Tellurium hexafluoride ................................................. 437Sulfinyl chloride .......................................................... 445 Telmicid ...................................................................... 226Sulfolane ..................................................................... 427 Telmid ......................................................................... 226Sulfolane-W ................................................................ 427 Telone C ..................................................................... 190Sulfonyl chloride ......................................................... 435 Temik ............................................................................ 66Sulfotep ...................................................................... 515 TEN ............................................................................ 456Sulfur .......................................................................... 428 TEP ............................................................................ 441 33
  • 38. Alphabetical Material IndexTEPP .......................................................................... 441 Thallous carbonate ...................................................... 516Terbufos ..................................................................... 515 Thallous chloride ......................................................... 516Terephthalic acid ........................................................ 515 Thallous malonate ....................................................... 516Terphenyl .................................................................... 515 Thallous sulfate ........................................................... 516Terpinolene ................................................................. 515 THF ............................................................................. 443tert-Butyl ether ............................................................ 487 4-Thiapentanal ............................................................ 516tert-Butyl hydroperoxide .............................................. 120 Thioacetamide ............................................................ 516tert-Butyl peroxybenzoate ........................................... 487 Thioacetic acid ........................................................... 516tert-Butylamine ............................................................ 117 Thiobencarb ................................................................ 516tert-Octyl mercaptan ................................................... 509 Thiobutyl alcohol ......................................................... 122Testosterone and its esters ......................................... 515 Thiocarbamide ............................................................ 446TETA ........................................................................... 457 Thiocarbazide ............................................................. 516Tetrabutyl titanate ........................................................ 515 Thiocyanic acid, ethyl ester ........................................ 260Tetracarbonyl nickel .................................................... 360 Thiocyanomethane ...................................................... 3542,3,7,8- Tetrachlorodibenzofurans .............................. 515 4,4-Thiodianiline ......................................................... 5162,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) .............. 515 Thiodiglycol ................................................................. 516Tetrachloroethane ....................................................... 438 Thioethanol ................................................................. 2571,1,2,2-Tetrachloroethane ........................................... 438 Thioethylalcohol .......................................................... 257Tetrachloroethylene .................................................... 439 Thiofanox .................................................................... 516Tetrachloromethane .................................................... 135 Thiolane-1,1-dioxide .................................................... 427Tetrachlorosilane ......................................................... 417 Thiomethyl alcohol ...................................................... 347Tetrachlorotitanium ...................................................... 447 Thionazin .................................................................... 516Tetrachlorvinphos ........................................................ 515 Thionyl chloride .......................................................... 445Tetradecanol ............................................................... 515 Thiophan sulfone ......................................................... 4271-Tetradecene ............................................................ 516 Thiophenol .................................................................. 387Tetradecyl benzene .................................................... 516 Thiophos ..................................................................... 377Tetraethyl dithiopyrophosphate ................................... 516 Thiophosgene ............................................................. 516Tetraethyl lead ............................................................ 440 Thiophosphoric anhydride .......................................... 394Tetraethyl pyrophosphate ............................................ 441 2-Thiopropane ............................................................ 218Tetraethyl tin ............................................................... 516 Thiosemicarbazide ...................................................... 516Tetraethylene glycol .................................................... 516 Thiourea ..................................................................... 446Tetraethylene pentamine ............................................. 516 Thiourea (2-chlorophenyl) ........................................... 152Tetraethylplumbane ..................................................... 440 2-Thiourea .................................................................. 446Tetrafluoroethylene ..................................................... 442 Thiram ........................................................................ 516Tetrafluorohydrazine ................................................... 516 Thorium dioxide .......................................................... 516Tetrafluoromethane ..................................................... 516 Thorium nitrate ............................................................ 516Tetrafluorosulfurane .................................................... 433 TIBAL ......................................................................... 459Tetrahydro-1,4-oxazine ............................................... 357 Titanium (IV) chloride ................................................. 447Tetrahydrofuran .......................................................... 443 Titanium chloride ......................................................... 447Tetrahydronaphthalene ............................................... 516 Titanium dioxide .......................................................... 516Tetrahydrothiophene-1 ................................................ 427 Titanium tetrachloride .................................................. 447Tetramethyl lead .......................................................... 516 TL 214 ........................................................................ 2411,2,3,5-Tetramethylbenzene ........................................ 516 TL 69 .......................................................................... 386Tetramethylene cyanide ................................................ 65 TMA ............................................................................ 461Tetramethylene oxide .................................................. 443 TNM ............................................................................ 444Tetramethylene sulfone ............................................... 427 TNT ............................................................................. 463Tetramethylsilane ........................................................ 516 Toluene ....................................................................... 448Tetran ......................................................................... 444 Toluene 2,4-diisocyanate ............................................ 450Tetranitromethane ....................................................... 444 Toluene diamine .......................................................... 449Tetrasol ....................................................................... 135 Toluene diisocyanate .................................................. 450Tetrodotoxin ................................................................ 516 Toluene-2,4-diamine ................................................... 449Thallium ...................................................................... 516 2,4-Toluenediamine .................................................... 449Thallium acetate .......................................................... 516 Toluidines ................................................................... 451Thallium carbonate ...................................................... 516 Toluol .......................................................................... 448Thallium nitrate ............................................................ 516 Tolu-sol ....................................................................... 448Thallium sulfate ........................................................... 516 1-(2-Tolyl)thiourea ...................................................... 35134
  • 39. Alphabetical Material IndexToxaphene .................................................................. 517 Trichlorosilane ............................................................ 1892,4,5-TP (or Silvex) ..................................................... 517 Trichlorosilane ............................................................ 455trans-2-Butenal ........................................................... 160 2,4,6-Trichloro-s-triazine ............................................. 167trans-Butene ............................................................... 118 Trichloro-s-triazinetrione ............................................. 517Tri ............................................................................... 453 2,2,2’-Trichlorotriethylamine ...................................... 464TRI .............................................................................. 454 Trichlorotrifluoroethane ............................................... 517Triamiphos .................................................................. 517 Trichlorovinylsilicon ..................................................... 476Triaziquone ................................................................. 517 Tri-clor ........................................................................ 153Triazofos ..................................................................... 517 Tridecane ................................................................... 517Tribromoborane .......................................................... 100 Tridecanol ................................................................... 517Tribromophosphine ..................................................... 395 1-Tridecene ................................................................ 517Tributyl phosphate ....................................................... 517 Tridecyl benzene ........................................................ 517Tributylamine .............................................................. 517 Trien ........................................................................... 457 Triethane ..................................................................... 453Tricarbonyl methyl cyclopentadienyl manganese ........ 517 Triethanol amine ......................................................... 517Trichlor ....................................................................... 454Trichlorfon .................................................................. 517 Triethoxysilane ............................................................ 517Trichloro(chloromethyl)silane ...................................... 517 Triethyl aluminum ........................................................ 5171,1,2-Trichloro-1,2,2-trifluoroethane ........................... 517 Triethyl benzene ......................................................... 518Trichloroacetaldehyde ................................................. 138 Triethyl phosphate ....................................................... 518Trichloroacetic acid .................................................... 517 Triethyl phosphite ........................................................ 518Trichloroacetic acid chloride ....................................... 452 Triethylamine .............................................................. 456Trichloroacetyl chloride ............................................... 452 Triethylene glycol ........................................................ 518Trichloroallysilane ......................................................... 72 Triethylene thiophosphoramide ................................... 518Trichloroamylsilane ....................................................... 83 Triethylenetetramine .................................................... 457Trichlorobenzene ........................................................ 517 Trifluoro chloroethylene .............................................. 4581,2,4-Trichlorobenzene ............................................... 517 Trifluoroacetic acid ..................................................... 518Trichloroborane .......................................................... 101 Trifluoroboron ............................................................. 102Trichloroboron ............................................................ 101 Trifluorochlorine .......................................................... 141Trichlorobutene ........................................................... 517 3-Trifluoromethylaniline ............................................... 518Trichlorobutylsilane ..................................................... 123 Trifluralin ..................................................................... 518Trichloroethanal .......................................................... 138 Triisobutylalane ........................................................... 4591,1,1-Trichloroethane .................................................. 453 Triisobutylaluminum .................................................... 459Trichloroethene ........................................................... 454 Triisobutylene ............................................................. 518Trichloroethyenylsilane ............................................... 476 Triisopropanol amine ................................................... 518Trichloroethyl silicon ................................................... 261 Trilon 83 ...................................................................... 436Trichloroethylene ........................................................ 454 Trimethoxysilane ......................................................... 460Trichloroethylsilane ..................................................... 261 2,4,6-Trimethyl aniline ................................................. 518Trichlorofluoromethane ............................................... 517 Trimethyl benzene ....................................................... 518Trichloroform .............................................................. 150 Trimethyl phosphite ..................................................... 518Trichloromethane ........................................................ 150 Trimethyl tin chloride ................................................... 518Trichloromethylsilane .................................................. 355 Trimethylacetic acid .................................................... 518Trichloromethylsilicon ................................................. 355 Trimethylacetyl chloride .............................................. 518Trichloromonosilane .................................................... 455 Trimethylamine ............................................................ 461Trichloronate ............................................................... 517 Trimethylchlorosilane .................................................. 462Trichloronitromethane ................................................. 153 Trimethylene ............................................................... 1752,4,6-Trichlorophenol .................................................. 517 Trimethylhexamethylene diisocyanate ......................... 5182-(2,4,5-Trichlorophenoxy)propanoic acid, ................. 517 Trimethylhexamethylenediamine .................................. 5182-(2,4,5-Trichlorophenoxy)propanoic acid . . . . . . . . . . 517 Trimethylmethane ........................................................ 2932,4,5-Trichlorophenoxyacetic acid .............................. 517 Trinitrobenzene ........................................................... 5182,4,5-Trichlorophenoxyacetic acid, sodium salt .......... 517 Trinitrobenzene(wetted with >30% water) .................... 518Trichlorophenylsilane .................................................. 517 Trinitrobenzoic acid (wetted with >30% water) ............ 518Trichlorophosphine ..................................................... 396 Trinitrobenzoic acid wetted with >30% water) ............. 5181,2,3-Trichloropropane ............................................... 517 Trinitroglycerin ............................................................ 366Trichlorormethyl benzene .............................................. 93 Trinitrophenol .............................................................. 397Trichlorortoluene ........................................................... 93 Trinitrotoluene ............................................................. 463 35
  • 40. Alphabetical Material Index2,4,6-Trinitrotoluene .................................................... 463 Vinyl allyl ether ............................................................ 519Tri-p-cresyl phosphate ................................................ 517 Vinyl amide ................................................................... 61Triphenyl tin chloride ................................................... 518 Vinyl benzene ............................................................. 425Tripropylene glycol ...................................................... 518 Vinyl bromide .............................................................. 469Tripropylene glycol methyl ether ................................. 518 Vinyl chloride .............................................................. 470Tris-(2,3-dibromopropyl) phosphate ............................ 518 Vinyl chloride monomer .............................................. 470Tris-(2-chloroethyl) amine ........................................... 464 Vinyl cyanide ................................................................ 63Tris(aziridinyl)phosphine oxide .................................... 518 Vinyl ethyl ether .......................................................... 471Trithion ........................................................................ 518 Vinyl fluoride ............................................................... 472Trixylenyl phosphate ................................................... 518 Vinyl formic acid ........................................................... 62Trona .......................................................................... 100 Vinyl isobutyl ether ...................................................... 519Trypan blue ................................................................. 518 Vinyl methyl ether ....................................................... 474TS 160 ........................................................................ 464 Vinyl methyl ketone ..................................................... 356Turpentine ................................................................... 465 Vinyl neodecanoate .................................................... 519Turpentine oil .............................................................. 465 Vinyl toluene ............................................................... 475Turpentine spirits ........................................................ 465 Vinylcarbinol ................................................................. 67TX 60 .......................................................................... 478 Vinylethylene .............................................................. 111UDMH ......................................................................... 214 Vinylidene chloride ..................................................... 473Undecane ................................................................... 518 Vinylsilicon trichloride ................................................. 476Undecanoic acid ......................................................... 518 Vinyltrichlorosilane ...................................................... 476Undecanol ................................................................... 518 Vorlex ......................................................................... 3461-Undecene ................................................................ 518 Vulnoc AB ..................................................................... 75Unifume ...................................................................... 247 VX .............................................................................. 478unsym-Dimethylhydrazine ........................................... 214 Weedone .................................................................... 176Uracil mustard ............................................................. 519 White caustic .............................................................. 421Uranium hexafluoride .................................................. 519 White phosphorus ....................................................... 392Uranium metal (pyrophoric) ........................................ 519 Wood alcohol .............................................................. 318Uranium peroxide ........................................................ 519 Wood ether ................................................................. 212Uranyl acetate ............................................................. 519 Woodtreat ................................................................... 379Uranyl nitrate .............................................................. 519 Xenon ......................................................................... 520Uranyl sulfate .............................................................. 519 Xylenes ....................................................................... 477Urea ............................................................................ 519 Xylenol ........................................................................ 519Urea hydrogen peroxide ............................................. 466 2,6-Xylidine ................................................................ 519Urea peroxide ............................................................. 466 Xylol ............................................................................ 477Urea-ammonium nitrate solution .................................. 519 Yellow phosphorus ...................................................... 392Urethane ..................................................................... 519 Yperite .......................................................................... 99USAFST-40 ................................................................ 322VAC ............................................................................ 468 Zectran ....................................................................... 519Valeraldehyde ............................................................. 519 Zinc ............................................................................ 520Valeric acid ................................................................ 519 Zinc acetate ................................................................ 519VAM ............................................................................ 468 Zinc ammonium chloride ............................................. 519Vanadium ................................................................... 519 Zinc arsenate .............................................................. 519Vanadium oxychloride ................................................. 467 Zinc bichromate .......................................................... 519Vanadium oxytrichloride .............................................. 467 Zinc borate .................................................................. 519Vanadium pentoxide .................................................... 519 Zinc bromide ............................................................... 519Vanadium trichloride oxide .......................................... 467 Zinc carbonate ............................................................ 519Vanadyl sulfate ........................................................... 519 Zinc chloride ............................................................... 519Vanadyl trichloride ...................................................... 467 Zinc chromate ............................................................. 519Vapotone .................................................................... 441 Zinc cyanide ............................................................... 519VC .............................................................................. 470 Zinc dialkyldithiophosphate ......................................... 519VCM ........................................................................... 470 Zinc methyl ................................................................. 219VDC ............................................................................ 473 Zinc phosphide ........................................................... 479Vidden D ..................................................................... 190Vinyl A Monomer ........................................................ 468 ZP ............................................................................... 479Vinyl acetate ............................................................... 468Vinyl acetylene ........................................................... 51936
  • 41. UN/NA Number Index
  • 42. UN/NA Number Index0027 Black powder, granular ..................................... 486 1049 Hydrogen .......................................................... 2820028 Black powder, compressed ............................... 486 1050 Hydrogen Chloride (Anhydrous) ........................ 2840028 Black powder, pellets ......................................... 486 1051 Hydrogen Cyanide (Stabilized) ......................... 2850076 Dinitrophenol ..................................................... 223 1052 Hydrogen Fluoride (Anhydrous) ........................ 2860129 Lead azide (wetted with >20% water) ................ 503 1053 Hydrogen Sulfide .............................................. 2890135 Mercury fulminate (wetted >20% water) ............ 504 1055 Isobutylene ........................................................ 2940143 Nitroglycerin ...................................................... 366 1060 Methyl Acetylene, Propadiene Mixture (Stabilized)0144 Nitroglycerin ...................................................... 366 3200146 Nitrostarch (dry or wetted with <20% water) ...... 509 1061 Methylamine (Anhydrous) ................................. 3230154 Picric Acid ........................................................ 397 1062 Methyl Bromide ................................................. 3260209 Trinitrotoluene ................................................... 463 1063 Methyl Chloride ................................................. 3310213 Trinitrobenzene ................................................. 518 1064 Methyl Mercaptan .............................................. 3470215 Trinitrobenzoic acid (wetted with >30% water) .. 518 1065 Neon ................................................................. 5070331 AN/FO ................................................................. 84 1066 Nitrogen ............................................................ 3640343 Nitrocellulose (with plasticizer >18%) ................ 508 1067 Nitrogen Dioxide ................................................ 3650411 Pentaerythritol tetranitrate (PETN) ..................... 510 1069 Nitrosyl Chloride ................................................ 3690411 PETN (Pentaerythritol tetranitrate) ..................... 510 1070 Nitrous Oxide ..................................................... 3711001 Acetylene ............................................................ 59 1072 Oxygen .............................................................. 3751005 Ammonia(Anhydrous) ......................................... 74 1073 Oxygen .............................................................. 3751006 Argon ................................................................ 484 1075 Liquefied Petroleum Gas (Lpg) .......................... 3081008 Boron Trifluoride ............................................... 102 1076 Diphosgene ....................................................... 4961009 Bromotrifluoromethane ...................................... 486 1076 Phosgene .......................................................... 3901010 Butadiene (Inhibited) ......................................... 111 1077 Propylene .......................................................... 4111011 Butane ............................................................... 112 1079 Sulfur Dioxide (Liquefied) .................................. 4301012 Butylene ............................................................ 118 1081 Tetrafluoroethylene (Inhibited) ........................... 4421013 Carbon Dioxide ................................................. 132 1082 Trifluoro Chloroethylene (Inhibited) ................... 4581016 Carbon Monoxide .............................................. 134 1083 Trimethylamine (Anhydrous) ............................. 4611017 Chlorine ............................................................ 139 1085 Vinyl Bromide (Inhibited) ................................... 4691018 Chlorodifluoromethane ...................................... 489 1086 Vinyl Chloride (Inhibited Or Stabilized) .............. 4701018 Difluorochloromethane ...................................... 495 1087 Vinyl Methyl Ether (Inhibited) ............................ 4741018 F 22 .................................................................. 499 1088 Acetal .................................................................. 501018 Freon 22 ........................................................... 500 1089 Acetaldehyde ...................................................... 511018 R 22 .................................................................. 513 1090 Acetone ............................................................... 541018 Refrigerant 22 ................................................... 513 1092 Acrolein Inhibited) ............................................... 601022 Chlorotrifluoromethane ...................................... 490 1093 Acrylonitrile (Inhibited) ........................................ 631023 Coal gas ............................................................ 490 1098 Allyl Alcohol ......................................................... 671026 Cyanogen ......................................................... 163 1099 Allyl Bromide ....................................................... 691027 Cyclopropane .................................................... 175 1100 Allyl Chloride ....................................................... 701028 Dichlorodifluoromethane .................................... 493 1104 n-Amyl acetate .................................................. 4841028 Difluorodichloromethane .................................... 495 1105 Amyl Alcohol ....................................................... 821028 F 12 .................................................................. 499 1107 n-Amyl chloride ................................................. 4841028 Freon 12 ........................................................... 500 1108 1-Pentene ......................................................... 5101028 Propellant 12 ..................................................... 512 1110 Methyl Amyl Ketone ........................................... 3251028 R 12 .................................................................. 513 1111 n-Amyl mercaptan ............................................. 4841028 Refrigerant 12 ................................................... 513 1112 n-Amyl nitrate .................................................... 4841029 Dichloromonofluoromethane .............................. 494 1113 n-Amyl nitrite ..................................................... 4841030 Difluoroethane ................................................... 202 1114 Benzene .............................................................. 901032 Dimethylamine (Anhydrous) .............................. 207 1120 n-Butanol ........................................................... 4871033 Dimethyl Ether ................................................... 212 1120 n-Butyl alcohol ................................................... 4871035 Ethane ............................................................... 228 1120 sec-Butanol ....................................................... 4871036 Ethylamine ........................................................ 233 1120 sec-Butyl alcohol ............................................... 4871037 Ethyl Chloride .................................................... 238 1120 T-Butyl Alcohol .................................................. 1151038 Ethylene ............................................................ 243 1123 n-Butyl Acetate .................................................. 1131039 Ethyl methyl ether .............................................. 499 1125 n-Butylamine ..................................................... 1161040 Ethylene Oxide .................................................. 254 1126 1-Bromobutane ................................................. 1081045 Fluorine ............................................................. 262 1127 2-Chlorobutane ................................................. 4891048 Hydrogen Bromide ............................................ 283 1127 Chlorobutane ..................................................... 14838
  • 43. UN/NA Number Index1129 Butyraldehyde ................................................... 125 1218 Isoprene (Inhibited) ........................................... 2961130 Camphor oil ....................................................... 488 1219 Isopropanol ....................................................... 2971131 Carbon Disulfide ............................................... 133 1221 Isopropylamine .................................................. 3001134 Chlorobenzene .................................................. 147 1222 Isopropyl nitrate ................................................ 5031135 Ethylene Chlorohydrin ....................................... 244 1223 Kerosene .......................................................... 3041143 Crotonaldehyde (Stabilized) .............................. 160 1224 Methyl Butyl Ketone ........................................... 3291145 Cyclohexane ..................................................... 169 1229 Mesityl Oxide ..................................................... 3121146 Cyclopentane .................................................... 173 1230 Methanol ............................................................ 3181147 Decahydronaphthalene ..................................... 492 1231 Methyl Acetate ................................................... 3191148 Diacetone alcohol .............................................. 492 1232 Methyl acetone .................................................. 5051149 Butyl ether ......................................................... 487 1233 Methyl amyl acetate ........................................... 5051149 Di-n-butyl ether ................................................. 493 1234 Methyl formal ..................................................... 5061149 tert-Butyl ether ................................................... 487 1235 Methylamine (Solution) ...................................... 3241150 1,2-Dichloroethylene ......................................... 186 1237 Methyl Butyrate ................................................. 3301153 Ethylene Glycol Diethyl Ether ............................ 250 1238 Methyl chloroformate ......................................... 5051154 Diethylamine ..................................................... 195 1239 Chloromethyl methyl ether ................................. 4891155 Diethyl Ether ..................................................... 199 1239 Methyl chloromethyl ether .................................. 5051156 Diethylketone .................................................... 201 1242 Methyldichlorosilane .......................................... 3371157 Diisobutyl ketone ............................................... 495 1243 Methyl Formate ................................................. 3391158 Diisopropylamine .............................................. 203 1244 Methylhydrazine ................................................ 3401159 Diisopropyl ether ............................................... 495 1245 Methyl Isobutyl Ketone ...................................... 3431160 Dimethylamine, solution ..................................... 495 1246 Methyl Isopropenyl Ketone (Inhibited) ............... 3451161 Dimethyl carbonate ........................................... 495 1247 Methyl Methacrylate (Inhibited) ......................... 3481162 Dimethyldichlorosilane ....................................... 210 1248 Methyl propionate .............................................. 5061163 1,1-Dimethylhydrazine ...................................... 214 1249 Methyl propyl ketone ......................................... 5061164 Dimethyl Sulfide ................................................ 218 1250 Methyltrichloro Silane ........................................ 3551165 1,4-Dioxane ....................................................... 224 1251 Methyl Vinyl Ketone ........................................... 3561170 Ethyl Alcohol ..................................................... 232 1255 Naphtha ............................................................. 3581171 Ethylene Glycol Monoethyl Ether ....................... 251 1255 Petroleum naphtha ............................................ 5101172 Ethylene glycol monoethyl ether acetate ............ 498 1256 Naphtha ............................................................. 3581173 Ethyl Acetate ..................................................... 230 1259 Nickel Carbonyl ................................................. 3601175 Ethylbenzene .................................................... 234 1261 Nitromethane ..................................................... 3671179 Ethyl butyl ether ................................................ 498 1262 Isooctane .......................................................... 5021180 Ethyl Butyrate .................................................... 237 1262 Octane .............................................................. 3721181 Ethyl Chloroacetate ................................................. 1263 Lacquer ............................................................. 5031182 Ethyl Chloroformate ........................................... 240 1263 Lacquer thinner ................................................. 5031183 Ethyl Dichlorosilane ........................................... 242 1263 Paint thinner ...................................................... 5101184 Ethylene Dichloride ........................................... 248 1263 Paint, oil base ................................................... 5101185 Ethyleneimine (Inhibited) ................................... 253 1264 Paraldehyde ...................................................... 5101188 Ethylene Glycol Monomethyl Ether .................... 252 1265 Isopentane ........................................................ 5021190 Ethyl Formate .................................................... 255 1267 Crude oil ........................................................... 4911191 Ethyl hexaldehyde ............................................. 499 1268 Naphtha ............................................................. 3581191 Isooctaldehyde .................................................. 502 1271 Naphtha: stoddard solvent ................................. 5071192 Ethyl lactate ....................................................... 499 1272 Pine oil .............................................................. 5111193 Methyl Ethyl Ketone ........................................... 338 1275 Propionaldehyde ............................................... 5121194 Ethyl Nutrate (Solutions) .................................... 258 1276 n-Prooylacetate ................................................. 4081196 Ethyltrichlorosilane ............................................ 261 1277 Propylamine ...................................................... 5121198 Formaldehyde (Solution) ................................... 267 1278 1-Chloropropane ............................................... 4891199 Furfural ............................................................. 271 1279 Propylene Dichloride ......................................... 4121201 Fusel oil ............................................................. 500 1280 Propylene Oxide ................................................ 4141202 Diesel Fuel ........................................................ 194 1281 Isopropyl Formate ............................................. 3031203 Gasoline ............................................................ 272 1282 Pyridine ............................................................ 4151206 Heptanes ........................................................... 274 1292 Ethyl silicate ...................................................... 4991207 n-Hexaldehyde .................................................. 501 1294 Toluene ............................................................. 4481208 Hexane .............................................................. 276 1295 Trichlorosilane ................................................... 4551212 Isobutanol .......................................................... 502 1296 Triethylamine ..................................................... 4561214 Isobutylamine .................................................... 502 1298 Trimethylchlorosilane ......................................... 462 39
  • 44. UN/NA Number Index1299 Turpentine ......................................................... 465 1457 Calcium peroxide .............................................. 4881301 Vinyl Acetate (Inhibited) .................................... 468 1463 Chromic anhydride ........................................... 4901302 Vinyl Ethyl Ether (Inhibited) ............................... 471 1466 Ferric nitrate ..................................................... 5001303 Vinylidene Chloride ........................................... 473 1469 Lead nitrate ....................................................... 5031304 Vinyl isobutyl ether ............................................ 519 1475 Magnesium perchlorate ..................................... 5041305 Vinyltrichlorosilane ............................................ 476 1479 Potassium dichromate ....................................... 5121307 Xylenes ............................................................. 477 1479 Sodium dichromate ........................................... 5141310 Ammonium picrate (wet) .................................... 483 1484 Potassium bromate ............................................ 5111312 Borneol ............................................................. 486 1485 Potassium chlorate ............................................ 5111320 Dinitrophenol ..................................................... 223 1490 Potassium permanganate .................................. 5121328 Hexamethylene tetramine .................................. 501 1491 Potassium peroxide ........................................... 5121332 Metaldehyde ...................................................... 504 1492 Potassium Persulfate ......................................... 4011334 Naphthalene ...................................................... 507 1493 Silver nitrate ...................................................... 5131337 Nitrostarch (wetted with >20% water) ................ 509 1495 Sodium chlorate ................................................ 5141338 Phosphorus (amorphous red) ............................ 511 1498 Sodium nitrate ................................................... 5141340 Phosphorus Pentasulfide ................................... 394 1500 Sodium nitrite .................................................... 5141344 Picric Acid ........................................................ 397 1502 Sodium perchlorate ........................................... 5141346 Silicon (powder) ................................................ 513 1510 Tetranitromethane ............................................. 4441350 Sulfur ................................................................ 428 1511 Urea Peroxide ................................................... 4661354 Trinitrobenzene(wetted with >30% water) .......... 518 1541 Acetone Cyanohydrin (Stabilized) ....................... 551355 Trinitrobenzoic acid wetted with >30% water) .... 518 1545 Allyl isothiocyanate ............................................ 4821356 Trinitrotoluene ................................................... 463 1547 Aniline ................................................................. 851360 Calcium phosphide ............................................ 489 1549 Antimony tribromide .......................................... 4841366 Diethyl zinc ....................................................... 495 1549 Antimony trifluoride ........................................... 4841370 Dimethyl Zinc .................................................... 219 1551 Antimony potassium tartrate .............................. 4841381 Phosphorus ....................................................... 392 1556 Lewisite ............................................................. 3061385 Sodium sulfide ................................................... 515 1556 Methyl dichloroarsine ........................................ 5051396 Aluminum (dust) ................................................ 482 1556 Phenyldichloroarsine ......................................... 3861397 Aluminum phosphide ......................................... 482 1557 Arsenic disulfide ................................................ 4841400 Barium .............................................................. 485 1557 Arsenic trisulfide ............................................... 4841401 Calcium ............................................................. 488 1558 Arsenic ............................................................. 4841402 Calcium Carbide ............................................... 128 1559 Arsenic pentoxide .............................................. 4841404 Calcium hydride ................................................ 489 1560 Arsenic Trichloride .............................................. 861407 Cesium .............................................................. 489 1561 Arsenic acid ...................................................... 4841410 Lithium aluminum hydride .................................. 503 1561 Arsenic trioxide ................................................. 4841413 Lithium borohydride .......................................... 504 1564 Barium carbonate .............................................. 4851414 Lithium hydride ................................................. 504 1565 Barium cyanide ................................................. 4851415 Lithium .............................................................. 309 1566 Beryllium chloride .............................................. 4851418 Magnesium (powder) ......................................... 504 1566 Beryllium fluoride .............................................. 4851423 Rubidium ........................................................... 513 1566 Beryllium oxide .................................................. 4851426 Sodium borohydride .......................................... 515 1566 Beryllium sulfate ................................................ 4851427 Sodium hydride ................................................. 515 1567 Beryllium ........................................................... 4851428 Sodium .............................................................. 418 1569 Bromoacetone ................................................... 4861431 Sodium methylate .............................................. 515 1570 Brucine ............................................................. 4871432 Sodium phosphide ............................................. 515 1572 Cacodylic acid .................................................. 4871436 Zinc ................................................................... 520 1574 Calcium arsenite ............................................... 4881438 Aluminum nitrate ................................................ 482 1575 Calcium cyanide ............................................... 4881439 Ammonium dichromate ...................................... 483 1577 Dinitrochlorobenzene ........................................ 4961442 Ammonium Perchlorate ....................................... 78 1578 Chloronitrobenzene ........................................... 1511444 Ammonium persulfate ........................................ 483 1580 Chloropicrin ...................................................... 1531445 Barium chlorate ................................................. 485 1582 Chloropicrin: methyl chloride ............................. 4891446 Barium nitrate .................................................... 485 1584 Cocculus ........................................................... 4911447 Barium perchlorate ............................................ 485 1584 Picrotoxin .......................................................... 5111448 Barium permanganate ....................................... 485 1585 Copper acetoarsenite ........................................ 4911449 Barium peroxide ................................................ 485 1585 Paris green ....................................................... 5101452 Calcium chlorate ............................................... 488 1586 Copper arsenite ................................................ 4911454 Calcium nitrate .................................................. 488 1587 Copper cyanide ................................................ 49140
  • 45. UN/NA Number Index1589 Cyanogen Chloride (Inhibited) .......................... 165 1688 Sodium cacodylate ............................................ 5141592 p-Dichlorobenzene ............................................ 182 1690 Sodium fluoride ................................................. 5141593 Dichloromethane ............................................... 187 1692 Strychnine ......................................................... 4241594 Diethyl sulfate .................................................... 494 1692 Strychnine sulfate ............................................. 5151594 Ethyl sulfate ....................................................... 499 1695 Chloroacetone, stabilized .................................. 4891595 Dimethyl Sulfate ................................................ 217 1697 2-Chloro-Acetophenone .................................... 1441596 2,4-Dinitroaniline ............................................... 220 1698 Diphenylamine chloroarsine .............................. 4961597 Dinitrobenzenes ................................................ 221 1702 Tetrachloroethane ............................................. 4381599 Dinitrophenol ..................................................... 223 1704 Sulfotep ............................................................. 5151603 Ethyl bromoacetate ........................................... 498 1704 Tetraethyl dithiopyrophosphate .......................... 5161604 Ethylenediamine ................................................ 246 1707 Thallium sulfate .................................................. 5161605 Ethylene Dibromide ........................................... 247 1708 Toluidines .......................................................... 4511612 Hexaethyl tetraphosphate .................................. 501 1709 2,4-Toluenediamine ........................................... 4491616 Lead acetate ..................................................... 503 1710 Trichloroethylene ............................................... 4541617 Lead arsenate ................................................... 503 1711 2,6-Xylidine ....................................................... 5191624 Mercuric chloride .............................................. 504 1712 Zinc arsenate .................................................... 5191625 Mercuric nitrate ................................................. 504 1713 Zinc cyanide ..................................................... 5191627 Mercurous nitrate .............................................. 504 1714 Zinc Phosphide ................................................. 4791629 Mercuric acetate ............................................... 504 1715 Acetic Anhydride ................................................ 531629 Mercurous acetate ............................................ 504 1716 Acetyl Bromide .................................................... 571630 Mercuric ammonium chloride ............................ 504 1717 Acetyl Chloride .................................................... 581636 Mercuric cyanide .............................................. 504 1718 Butyl acid phosphate ......................................... 4871638 Mercuric iodide ................................................. 504 1722 Allyl Chloroformate .............................................. 711641 Mercuric oxide .................................................. 504 1723 Allyl iodide ......................................................... 4821641 Mercury oxide ................................................... 504 1724 Allyltrichlorosilane (Stabilized) ............................. 721645 Mercuric sulfate ................................................ 504 1726 Aluminum chloride ............................................. 4821646 Mercuric thiocyanate ........................................ 504 1727 Ammonium bifluoride ......................................... 4831648 Acetonitrile .......................................................... 56 1728 Amyltricholorsilane .............................................. 831649 Tetraethyl Lead ................................................. 440 1729 Anisoyl chloride ................................................. 4841651 ANTU ................................................................ 484 1730 Antimony pentachloride ..................................... 4841651 Napthylthiourea ................................................. 507 1732 Antimony pentafluoride ...................................... 4841652 Napthylurea ....................................................... 507 1733 Antimony trichloride .......................................... 4841653 Nickel cyanide ................................................... 507 1736 Benzoyl Chloride ................................................. 941654 Nicotine ............................................................. 508 1737 Benzyl Bromide ................................................... 951658 Nicotine sulfate .................................................. 508 1738 Benzyl Chloride(Usually Stabilized) ..................... 961660 Nitric Oxide ....................................................... 362 1739 Benzyl Chloroformate .......................................... 971661 4-Nitroaniline ..................................................... 508 1741 Boron Trichloride .............................................. 1011662 Nitrobenzene ..................................................... 363 1744 Bromine ............................................................ 1031663 2-Nitrophenol ..................................................... 508 1745 Bromine Pentafluoride ....................................... 1041663 3-Nitrophenol ..................................................... 508 1746 Bromine Trifluoride ............................................ 1051663 4-Nitrophenol ..................................................... 508 1747 Butyltrichlorosilane ............................................ 1231663 m-Nitrophenol .................................................... 508 1748 Calcium hypochlorite ......................................... 4881663 o-Nitrophenol ..................................................... 508 1749 Chlorine Trifluoride ............................................ 1411663 p-Nitrophenol ..................................................... 508 1751 Chloroacetic acid .............................................. 4891664 2-Nitrotoluene .................................................... 509 1752 Chloroacetyl Chloride ........................................ 1461664 4-Nitrotoluene .................................................... 509 1754 Chlorosulfonic Acid ........................................... 1571664 Nitrotoluenes ..................................................... 370 1755 Chromic acid .................................................... 4901669 Pentachloroethane ............................................ 510 1758 Chromium oxychloride ....................................... 4901670 Perchloromethyl mercaptan ............................... 510 1759 Ferrous chloride ................................................ 5001671 Phenol ............................................................... 384 1760 Dalapon ............................................................. 4921672 Phenylcarbylamine chloride .............................. 510 1760 Dichloropropionic acid ...................................... 4941673 Phenylenediamine ............................................. 510 1760 Methyl Phosphonothioic Dichloride ................... 3531674 Phenylmercuric acetate .................................... 510 1760 Nitric Acid ......................................................... 3611678 Potassium arsenite ............................................ 511 1760 Pentanoic acid .................................................. 5101680 Potassium cyanide ............................................ 511 1760 Valeric acid ....................................................... 5191685 Sodium arsenate ............................................... 514 1761 Cupriethylene diamine solution .......................... 4911687 Sodium Azide .................................................... 419 1762 Cyclohexenyl trichlorosilane .............................. 492 41
  • 46. UN/NA Number Index1764 Dichloroacetic acid ........................................... 493 1916 2,2-Dichlorodiethyl Ether .................................. 1841765 Dichloroacetyl chloride ...................................... 493 1919 Methyl Acrylate (Inhibited) ................................. 3211766 Dichlorophenyl Trichlorosilane .......................... 189 1920 Nonane ............................................................. 5091768 Difluorophosphoric acid .................................... 495 1921 Propyleneimine (Inhibited) ................................ 4131769 Diphenyldichlorosilane ...................................... 496 1922 Pyrrolidine ......................................................... 5131771 Dodecyltrichlorosilane ....................................... 497 1938 Bromoacetic acid .............................................. 4861773 Ferric chloride ................................................... 499 1942 Ammonium nitrate ............................................. 4831775 Fluoboric acid ................................................... 500 1942 Saltpeter ............................................................ 5131777 Fluorosulfonic Acid ........................................... 266 1955 Mechlorethanamine ........................................... 3111778 Fluorosilicic Acid ............................................... 265 1955 Tetrafluorohydrazine ......................................... 5161779 Formic Acid ...................................................... 269 1957 Deuterium ......................................................... 4921789 Hydrochloric Acid(Solution Greater Than 25%) . 280 1958 Dichlorotetrafluoroethane .................................. 4941790 Hydrofluoric Acid .............................................. 281 1959 1,1-Difluoroethylene .......................................... 4951791 Sodium Hypochlorite ......................................... 422 1961 Ethane ............................................................... 2281794 Lead sulfate ....................................................... 503 1962 Ethylene ............................................................ 2431805 Phosphoric acid ................................................ 511 1966 Hydrogen .......................................................... 2821806 Phosphorus pentachloride ................................. 511 1969 Isobutane .......................................................... 2931807 Phosphorus pentoxide ....................................... 511 1971 Methane ............................................................ 3151808 Phosphorus Tribromide ..................................... 395 1972 Liquefied Natural Gas (Lng) .............................. 3071809 Phosphorus Trichloride ..................................... 396 1972 Methane ............................................................ 3151810 Phosphorus Oxychloride ................................... 393 1975 Nitric Oxide ....................................................... 3621812 Potassium fluoride ............................................. 512 1977 Nitrogen ............................................................ 3641813 Potassium hydroxide ......................................... 512 1978 Propane ............................................................ 4021814 Caustic potash solution ..................................... 488 1982 Tetrafluoromethane ........................................... 5161814 Potassium hydroxide solution ............................ 512 1983 Chlorotrifluoroethane ......................................... 4891817 Pyrosulfuryl chloride ......................................... 512 1990 Benzaldehyde ..................................................... 881818 Silicon Chloride ................................................. 417 1991 Chloroprene (Inhibited) ..................................... 1541823 Sodium Hydroxide ............................................. 421 1993 Creosote, coal tar .............................................. 4911824 Sodium Hydroxide ............................................. 421 1993 Diesel Fuel ........................................................ 1941828 Sulfur Monochloride .......................................... 432 1993 Ethyl nitrate ....................................................... 4991829 Sulfur Trioxide ................................................... 434 1993 Fuel oil, No. 2 .................................................... 5001830 Sulfuric Acid ..................................................... 431 1994 Iron Pentacarbonyl ............................................ 2921831 Oleum ................................................................ 374 1999 Asphalt .............................................................. 4841833 Sulfurous acid ................................................... 515 1999 Asphalt blending stocks: roofers flux .................. 4841834 Sulfuryl Chloride ................................................ 435 1999 Asphalt blending stocks: straight run residue ..... 4841836 Thionyl Chloride ................................................ 445 1999 Tar .................................................................... 5151838 Titanium Tetrachloride ....................................... 447 2011 Magnesium phosphide ....................................... 5041839 Trichloroacetic acid ........................................... 517 2014 Hydrogen peroxide (35% solution) .................... 5021846 Carbon Tetrachloride ........................................ 135 2015 Hydrogen Peroxide (Stabilized, Greater Than 60%)1848 Propionic Acid .................................................. 406 2871860 Vinyl Fluoride (Inhibited) ................................... 472 2018 p-Chloroaniline .................................................. 4891865 n-Propyl nitrate ................................................. 512 2020 2,4,6-Trichlorophenol ........................................ 5171868 Decaborane ...................................................... 177 2021 o-Chlorophenol .................................................. 4891873 Perchloric Acid 50 To 72%) .............................. 383 2023 Epichlorhydrin ................................................... 2271885 Benzidine .......................................................... 485 2027 Sodium arsenite ................................................ 5141886 Benzylidene Chloride .......................................... 98 2029 Hydrazine .......................................................... 2781887 Bromochloromethane ........................................ 486 2030 Hydrazine .......................................................... 2781888 Chloroform ........................................................ 150 2031 Nitric Acid ......................................................... 3611889 Cyanogen Bromide ........................................... 164 2032 Nitric Acid ......................................................... 3611891 Ethyl bromide .................................................... 498 2036 Xenon ............................................................... 5201892 Ethyldichloroarsine ............................................ 241 2038 2,4-Dinitrotoluene .............................................. 4961897 Tetrachloroethylene ........................................... 439 2044 2,2-Dimethylpropane ......................................... 4961905 Selenic acid ...................................................... 513 2045 Isobutyl aldehyde .............................................. 5021910 Calcium oxide .................................................... 488 2046 p-Cymene ......................................................... 4921911 Diborane ........................................................... 179 2047 2,3-Dichloropropene ......................................... 4941915 Cyclohexanone ................................................. 170 2047 Dichloropropene ................................................ 19042
  • 47. UN/NA Number Index2048 Dicyclopentadiene ............................................. 192 2204 Carbonyl Sulfide ................................................ 1372049 Diethyl benzene ................................................ 494 2205 Adiponitrile .......................................................... 652050 Diisobutylene .................................................... 495 2209 Formaldehyde ................................................... 2672051 2-Dimethylaminoethanol .................................... 495 2212 Asbestos ........................................................... 4842051 Dimethylethanolamine ....................................... 495 2213 Paraformaldehyde ............................................. 5102052 Dipentene .......................................................... 496 2214 Phthalic anhydride ............................................ 5112053 Methyl Isobutyl Carbinol .................................... 342 2215 Maleic acid ........................................................ 5042054 Morpholine ........................................................ 357 2215 Maleic anhydride ............................................... 5042055 Styrene (Monomer, Inhibited) ............................ 425 2218 Acrylic Acid (Inhibited) ....................................... 622056 Tetrahydrofuran ................................................ 443 2222 Anisole .............................................................. 4842057 Nonene ............................................................. 509 2224 Benzonitrile ......................................................... 912057 Propylene trimer ................................................ 512 2225 Benzene sulfonyl chloride ................................. 4852058 Valeraldehyde ................................................... 519 2226 Benzotrichloride .................................................. 932059 Collodion ........................................................... 491 2227 n-Butyl methacrylate .......................................... 4872069 Ammonium nitrate-sulfate mixture ...................... 483 2229 p-tert-Butyl phenol ............................................. 4872070 Ammonium nitrate-phosphate mixture ................ 483 2232 Chloroacetaldehyde .......................................... 1422072 Ammonium nitrate fertilizers .............................. 483 2238 3-Chlorotoluene ................................................. 4892073 Ammonium Hydroxide ......................................... 77 2238 Chlorotoluene .................................................... 1582074 Acrylamide .......................................................... 61 2241 Cycloheptane .................................................... 1682075 Chloral (Anhydrous, Inhibited) ........................... 138 2242 Cycloheptene .................................................... 4922076 Cresols .............................................................. 491 2243 Cyclohexyl acetate ............................................ 4922077 alpha-Naphthylamine ......................................... 507 2244 Cyclopentanol ................................................... 4922078 Toluene Diisocyanate ........................................ 450 2245 Cyclopentanone ................................................ 4922079 Diethylenetriamine ............................................. 198 2246 Cyclopentene .................................................... 1742084 Acetyl peroxide solution ..................................... 482 2248 Di-n-butylamine ................................................. 4932085 Benzoyl peroxide ............................................... 485 2249 Dichloromethyl Ether ......................................... 1882087 Dibenzoyl peroxide ............................................ 493 2252 1,2-Dimethoxyethane ........................................ 2052093 Tert-Butyl Hydroperoxide ................................... 120 2253 N,N-Dimethylaniline ........................................... 2082094 Tert-Butyl Hydroperoxide ................................... 120 2256 Cyclohexene ..................................................... 4922097 tert-Butyl peroxybenzoate .................................. 487 2257 Potassium ......................................................... 4002102 Di-tert-butyl peroxide ......................................... 493 2258 1,2-Propylenediamine ....................................... 5122116 Cumene Hydroperoxide ..................................... 161 2259 Triethylenetetramine .......................................... 4572119 Cyclohexanone peroxide ................................... 492 2261 2,4-Dimethylphenol ........................................... 4952124 Lauroyl peroxide ................................................ 503 2261 Xylenol .............................................................. 5192131 Peracetic acid ................................................... 510 2262 Dimethylcarbamoyl Chloride .............................. 2092133 Isopropyl peroxydicarbonate ............................. 503 2265 Dimethylformamide ........................................... 2132163 Diacetone alcohol peroxide ............................... 492 2267 Dimethylphosphoro Chloridothioate ................... 2162171 Diisopropyl benzene hydroperoxide .................. 495 2271 Ethyl amyl ketone .............................................. 4982174 Dimethylhexane dihydroperoxide ....................... 495 2272 N-ethylaniline .................................................... 4982179 1,1-Di(tert-butylperoxy)cyclohexane .................. 493 2275 Ethyl butanol ...................................................... 4982186 Hydrogen Chloride (Anhydrous) ........................ 284 2276 2-Ethyl hexylamine ............................................ 4992188 Arsine ................................................................. 87 2277 Ethyl methacrylate ............................................. 4992189 Dichlorosilane ................................................... 191 2278 n-Heptene ......................................................... 2752190 Oxygen Difluoride .............................................. 376 2279 Hexachlorobutadiene ......................................... 5012192 Germane ........................................................... 500 2280 Hexamethylenediamine ...................................... 5012193 Hexafluoroethane .............................................. 501 2281 Hexamethylene diisocyanate ............................. 5012194 Selenium hexafluoride ....................................... 513 2282 1-Hexanol .......................................................... 5012195 Tellurium Hexafluoride ....................................... 437 2284 Isobutyronitrile ................................................... 2952197 Hydrogen iodide, anhydrous ............................. 502 2288 4-Methyl-1-Pentene ........................................... 3502198 Phosphorus pentafluoride .................................. 511 2289 Isophorone diamine ........................................... 5022199 Phosphine ......................................................... 391 2290 Isophorone diisocyanate (IPDI) ........................ 5022200 Allene ................................................................ 482 2291 Lead chloride .................................................... 5032200 Propadiene ....................................................... 512 2291 Lead fluoroborate .............................................. 5032201 Nitrous Oxide ..................................................... 371 2294 N-methyl aniline ................................................. 5052202 Hydrogen Selenide ............................................ 288 2295 Methyl Chloroacetate ......................................... 3322203 Silane ................................................................ 513 2296 Methylcyclohexane ............................................ 334 43
  • 48. UN/NA Number Index2297 Methyl cyclohexanone ....................................... 505 2383 Dipropylamine ................................................... 2252298 Methylcyclopentane ........................................... 335 2387 Fluorobenzene .................................................. 2642299 Methyl Dichloroacetate ...................................... 336 2388 4-Fluorotoluene ................................................. 5002300 Methyl ethyl pyridine ......................................... 506 2389 Furan ................................................................ 2702303 Isopropenylbenzene .......................................... 299 2393 Isobutyl formate ................................................. 5022308 Nitrosylsulfuric acid ........................................... 509 2396 Methacrylaldehyde ............................................ 5052310 Pentan-2,4-Dione .............................................. 381 2397 3-Methyl-2-Butanone ......................................... 3272312 Phenol ............................................................... 384 2398 Methyl Tert-Butyl Ether ...................................... 3282313 Picoline ............................................................. 511 2399 Methylpiperidine ................................................ 5062315 Polychlorinated biphenyls .................................. 511 2401 Piperidine .......................................................... 3992320 Tetraethylene pentamine ................................... 516 2402 Propanethiol ...................................................... 4032321 1,2,4-Trichlorobenzene ..................................... 517 2403 Isopropenyl acetate ........................................... 5022321 Trichlorobenzene .............................................. 517 2404 Propionitrile ....................................................... 4072322 Trichlorobutene ................................................. 517 2407 Isopropyl Chloroformate .................................... 3022323 Triethyl phosphite .............................................. 518 2409 Isopropyl propionate .......................................... 5032324 Triisobutylene .................................................... 518 2411 Butyronitrile ....................................................... 1262325 Trimethyl benzene ............................................. 518 2417 Carbonyl Fluoride .............................................. 1362327 Trimethylhexamethylenediamine ........................ 518 2418 Sulfur Tetrafluoride ............................................ 4332328 Trimethylhexamethylene diisocyanate ............... 518 2419 Bromotrifluoroethylene ...................................... 4862329 Trimethyl phosphite ........................................... 518 2420 Hexafluoroacetone ............................................. 5012330 Hendecane ........................................................ 501 2428 Sodium chlorate solution ................................... 5142330 Undecane .......................................................... 518 2431 o-Anisidine ........................................................ 4842331 Zinc chloride ..................................................... 519 2431 p-Anisidine ........................................................ 4842333 Allyl acetate ....................................................... 482 2432 N,N-diethyl aniline ............................................. 4942334 Allylamine ............................................................ 68 2435 Ethylphenyl Dichlorosilane ................................ 2592335 Allyl ethyl ether .................................................. 482 2436 Thioacetic acid .................................................. 5162337 Phenyl Mercaptan ............................................. 387 2438 Trimethylacetyl chloride ..................................... 5182339 2-Bromobutane ................................................. 486 2439 Sodium bifluoride .............................................. 5142340 2-Bromoethyl ethyl ether ................................... 486 2442 Trichloroacetyl Chloride .................................... 4522341 1-Bromo-3-methylbutane ................................... 486 2443 Vanadium Oxytrichloride ................................... 4672344 2-Bromopropane ............................................... 109 2446 Nitrocresols ....................................................... 5082345 3-Bromopropyne ............................................... 110 2447 Phosphorus ....................................................... 3922346 Butanedione ...................................................... 487 2448 Sulfur ................................................................ 4282346 Diacetyl ............................................................. 492 2449 Ammonium oxalate ............................................ 4832347 Butyl Mercaptan ................................................ 122 2451 Nitrogen trifluoride ............................................. 5082348 Butyl Acrylate(Inhibited) .................................... 114 2452 Ethylacetylene ................................................... 4982350 Butyl methyl ether .............................................. 487 2455 Methyl nitrite ...................................................... 5062351 Butyl nitrite ........................................................ 487 2456 2-Chloropropene ............................................... 4892353 Butyryl Chloride ................................................ 127 2459 2-Methyl-1-butene ............................................. 5052354 Chloromethyl ethyl ether .................................... 489 2460 2-Methyl-2-butene ............................................. 5052356 2-Chloropropane ............................................... 489 2462 Methylpentane ................................................... 5062356 Isopropyl chloride .............................................. 502 2464 Beryllium nitrate ................................................ 4852357 Cyclohexylamine ............................................... 172 2465 Potassium dichloro-s-triazinetrione ................... 5122359 Diallylamine ....................................................... 492 2465 Sodium dichloro-s-triazinetrione ........................ 5142360 Diallyl ether ....................................................... 492 2468 Trichloro-s-triazinetrione ................................... 5172361 Diisobutyl amine ................................................ 495 2470 Phenylacetonitrile .............................................. 3852362 1,1-Dichloroethane ............................................ 185 2471 Osmium tetroxide ............................................... 5092363 Ethyl Mercaptan ................................................ 257 2474 Thiophosgene .................................................... 5162364 n-Propyl Benzene ............................................. 409 2477 Methyl Isothiocyanate ........................................ 3462366 Diethyl Carbonate ............................................. 197 2480 Methyl Isocyanate ............................................. 3442368 alpha-Pinene ..................................................... 398 2481 Ethyl Isocyanate ................................................ 2562369 Ethylene glycol monobutyl ether ........................ 498 2485 n-Butyl Isocyanate ............................................ 1212370 Hexene .............................................................. 277 2487 Phenyl isocyanate ............................................. 5102375 Diethyl sulfide .................................................... 494 2488 Cyclohexyl isocyanate ....................................... 4922376 2,3-Dihydropyran .............................................. 495 2489 Diphenylmethane diisocyanate .......................... 4962378 2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) ..... 515 2489 Methylene-bis-(phenyliIsocyanate) (or MBI) ...... 50544
  • 49. UN/NA Number Index2490 2,2-Dichloroisopropyl ether ............................... 494 2668 Chloroacetonitrile .............................................. 1432490 Bis-(2-chloro-1-methyl ethyl) ether .................... 486 2670 Cyanuric Chloride ............................................. 1672490 Bis-(2-chloroisopropyl) ether ............................. 486 2671 Aminopyridines ................................................... 732491 Ethanolamine .................................................... 229 2672 Ammonium Hydroxide ......................................... 772493 Hexamethyleneimine .......................................... 501 2674 Sodium fluorosilicate ......................................... 5142496 Propionic anhydride .......................................... 512 2676 Stibine ............................................................... 5152501 Tris(aziridinyl)phosphine oxide .......................... 518 2683 Ammonium Sulfide(Solution) ............................... 792505 Ammonium fluoride ........................................... 483 2686 Diethylaminoethanol .......................................... 1962511 alpha-Chloropropionic Acid ............................... 155 2692 Boron Tribromide .............................................. 1002513 Bromoacetyl Bromide ........................................ 106 2693 Ammonium bisulfite ........................................... 4832514 Bromobenzene .................................................. 107 2693 Sodium bisulfite ................................................. 5142515 Bromoform ........................................................ 486 2699 Trifluoroacetic acid ........................................... 5182521 Diketene (Inhibited) ........................................... 204 2713 Acridine ............................................................ 4822529 Isobutyric acid .................................................. 502 2716 1,4-Butynediol ................................................... 1242531 Methacrylic Acid (Inhibited) .............................. 313 2725 Nickel nitrate ..................................................... 5072533 Methyl trichloroacetate ...................................... 506 2727 Thallium nitrate .................................................. 5162536 Methyltetrahydrofuran ....................................... 506 2729 Benzene hexachloride ....................................... 4852541 Terpinolene ....................................................... 515 2729 Hexachlorobenzene ........................................... 5012542 Tributylamine ..................................................... 517 2733 Ethylbutylamine ................................................. 2362548 Chlorine pentafluoride ....................................... 489 2734 Amines, liquid, corrosive, flammable n.o.s. ........ 2982553 Naphtha ............................................................. 358 2734 Ethyl-Bis- .......................................................... 2352553 Naphtha: coal tar ............................................... 507 2734 T-Butylamine ..................................................... 1172555 Nitrocellulose (with >25% water) ........................ 508 2738 n-Butylaniline ..................................................... 4872561 3-Methyl-1-butene ............................................. 505 2740 n-Propyl Chloroformate ...................................... 4102567 Pentachlorophenate, sodium ............................. 510 2742 Cholroethyl Chloroformate .................................. 1492574 Tri-p-cresyl phosphate ...................................... 517 2743 n-Butyl chloroformate ......................................... 4872578 Phosporous trioxide ........................................... 511 2749 Tetramethylsilane .............................................. 5162579 Piperazine ......................................................... 511 2757 Aldicarb ............................................................... 662584 Dodecylbenzene sulfonic acid ........................... 497 2757 Carbaryl (solid) .................................................. 4882585 p-Toluene sulfonic acid ..................................... 517 2757 Carbofuran ......................................................... 1312587 Benzoquinone ..................................................... 92 2757 Mexacarbate ..................................................... 5072588 Crimidine .......................................................... 491 2761 4,4-DDT ............................................................ 4922601 Cyclobutane ...................................................... 492 2761 Aldrin ................................................................. 4822603 Cycloheptatriene ............................................... 492 2761 DDD .................................................................. 4922605 Methoxymethyl isocyanate ................................. 505 2761 Dieldrin .............................................................. 4942606 Methyl orthosilicate ............................................ 506 2761 Endosulfan ........................................................ 4972608 Nitropropane ..................................................... 368 2761 Endrin ................................................................ 4972612 Methyl propyl ether ............................................ 506 2761 Lindane ............................................................. 5032618 Vinyl Toluene (Inhibited) .................................... 475 2761 Toxaphene ......................................................... 5172619 Benzyl dimethyl amine ....................................... 485 2762 Chlordane, flammable liquid ............................... 4882622 Glycidaldehyde ................................................. 501 2765 2-(2,4,5-Trichlorophenoxy)propanoic acid ........... 5172629 Sodium fluoroacetate ........................................ 514 2765 2,4,5-TP (or Silvex) ............................................ 5172630 Sodium selenate ................................................ 515 2765 2,4,5-Trichlorophenoxyacetic acid ...................... 5172630 Sodium selenite ................................................. 515 2765 2,4-D ................................................................. 1762642 Fluoroacetic Acid .............................................. 263 2765 Silvex ................................................................ 5142644 Methyl Iodide ..................................................... 341 2767 Phenylthiourea .................................................. 3892646 Hexachlorocyclopentadiene ............................... 501 2771 Thiram ............................................................... 5162647 Malononitrile ...................................................... 310 2781 Diquat ................................................................ 4962649 1,3-Dichloroacetone .......................................... 181 2781 Paraquat ............................................................ 5102653 Benzyl iodide .................................................... 485 2783 Chlorpyrifos ....................................................... 1592656 Quinoline ........................................................... 513 2783 Coumaphos ....................................................... 4912658 Selenium(powder) ............................................. 513 2783 Diazinon ............................................................ 4932661 Hexachloroacetone ............................................ 501 2783 Dichlorvos .......................................................... 4942662 Hydroquinone .................................................... 502 2783 Disulfoton .......................................................... 4962664 Dibromomethane ............................................... 180 2783 Ethion ................................................................ 4982667 Butyl toluene ...................................................... 487 2783 Fensulfothion ..................................................... 499 45
  • 50. UN/NA Number Index2783 Fonofos ............................................................. 500 2941 2-Fluoroaniline ................................................... 5002783 Malathion .......................................................... 504 2941 4-Fluoroaniline ................................................... 5002783 Methyl azinphos ................................................ 505 2948 3-Trifluoromethylaniline ...................................... 5182783 Methyl Parathion ............................................... 349 2965 Boron trifluoride: dimethyl etherate .................... 4862783 Mevinphos ......................................................... 507 2968 Maneb ............................................................... 5042783 Parathion ........................................................... 510 2976 Thorium nitrate .................................................. 5162783 Parathion ........................................................... 377 2978 Uranium hexafluoride ......................................... 5192783 Phosfolan .......................................................... 511 2979 Uranium metal (pyrophoric) ................................ 5192783 Prothoate .......................................................... 512 2981 Uranyl nitrate ..................................................... 5192783 Tetraethyl Pyrophosphate .................................. 441 3017 Amiton ............................................................... 4822783 Trichlorfon .......................................................... 517 3018 Dialifos .............................................................. 4922784 Mercaptodimethur .............................................. 504 3018 Dimefox ............................................................. 4952785 4-Thiapentanal ................................................... 516 3018 Phorate ............................................................. 5112789 Acetic Acid .......................................................... 52 3018 Tetraethyl Pyrophosphate .................................. 4412790 Acetic Acid .......................................................... 52 3018 Thionazin ........................................................... 5162798 Phenyl Phosphorous Dichloride ......................... 388 3022 1,2-Butylene Oxide (Stabilized) ......................... 1192799 Phenyl phosphorous thiodichloride .................... 511 3023 tert-Octyl mercaptan .......................................... 5092802 Copper chloride ................................................. 491 3055 2-(2-Aminoethoxy)ethanol .................................. 4822803 Gallium metal .................................................... 500 3073 2-Methyl-5-vinyl pyridine (MVP) ......................... 5062809 Mercury ............................................................. 504 3073 MVP (2-Methyl-5-vinyl pyridine) ......................... 5072811 Lead fluoride ...................................................... 503 3079 Methyl Acrylonitrile (Inhibited) ............................ 3222811 Selenium dioxide ............................................... 513 3083 Perchloryl fluoride .............................................. 5102815 N-aminoethyl piperazine .................................... 482 3152 Polybrominated biphenyls .................................. 5112820 n-Butyric acid .................................................... 487 3155 Pentachlorophenol ............................................. 3792821 Carbolic oil ........................................................ 488 3246 Methanesulfonyl Chloride ................................... 3162821 Phenol ............................................................... 384 3275 3-Chloropropionitrile ........................................... 1562826 Ethyl chlorothioformate ...................................... 498 3275 Lactonitrile ......................................................... 3052829 Caproic Acid ...................................................... 129 3275 Nitriles, toxic, flammable, n.o.s. ........................ 1622831 1,1,1-Trichloroethane ......................................... 453 3285 Vanadium .......................................................... 5192841 Di-n-amylamine ................................................. 493 9011 Camphene ......................................................... 4882842 Nitroethane ........................................................ 508 9026 4,6-Dinitro-o-cyclohexyl phenol .......................... 4962845 Ethylphosphonous dichloride ............................. 499 9037 Hexachloroethane .............................................. 5012845 Methyl phosphonous dichloride .......................... 506 9080 Ammonium Benzoate .......................................... 752850 Propylene tetramer ............................................ 512 9083 Ammonium Carbamate ........................................ 762854 Ammonium silicofluoride .................................... 483 9084 Ammonium carbonate ....................................... 4832862 Vanadium pentoxide .......................................... 519 9085 Ammonium chloride ........................................... 4832865 Hydroxylamine sulfate ....................................... 502 9086 Ammonium chromate ........................................ 4832870 Aluminum borohydride ....................................... 482 9087 Ammonium citrate ............................................. 4832871 Antimony (powder) ............................................. 484 9088 Ammonium fluoborate ........................................ 4832872 1,2-Dibromo-3-chloropropane ............................. 493 9089 Ammonium sulfamate ........................................ 4832874 Furfuryl alcohol .................................................. 500 9090 Ammonium Sulfite ............................................... 802875 Hexachlorophene ............................................... 501 9091 Ammonium tartrate ............................................ 4832876 Resorcinol ......................................................... 513 9092 Ammonium Thiocyanate ...................................... 812879 Selenium oxychloride ........................................ 513 9093 Ammonium thiosulfate ....................................... 4832881 Nickel ................................................................ 507 9096 Calcium chromate ............................................. 4882893 Lauroyl peroxide (<42%) .................................... 503 9099 Captan ............................................................... 4882901 Bromine chloride ................................................ 486 9100 Chromic sulfate ................................................. 4902902 Allethrin ............................................................. 482 9101 Chromic acetate ................................................ 4902920 Dichlorobutene .................................................. 183 9102 Chromous chloride ............................................. 4902922 Sodium hydrosulfide solution ............................. 514 9104 Cobalt formate ................................................... 4902924 Dichlorobutene .................................................. 183 9106 Copper acetate .................................................. 4912927 Ethyl phosphonothioic dichloride ....................... 499 9110 Copper sulfate, ammoniated .............................. 4912927 Ethyl phosphorodichloridate ............................... 499 9111 Copper tartrate .................................................. 4912931 Vanadyl sulfate .................................................. 519 9117 Ethylenediamine tetracetic acid ......................... 4982937 alpha-Methyl benzyl alcohol .............................. 505 9118 Ferric ammonium citrate .................................... 4992938 Methyl benzoate ................................................ 505 9119 Ferric ammonium oxalate .................................. 49946
  • 51. UN/NA Number Index9120 Ferric fluoride ..................................................... 4999121 Ferric sulfate ..................................................... 5009122 Ferrous ammonium sulfate ................................ 5009125 Ferrous sulfate .................................................. 5009138 Nickel ammonium sulfate .................................. 5079140 Nickel hydroxide ................................................ 5079147 Sodium phosphate ............................................. 5149153 Zinc acetate ...................................................... 5199154 Zinc ammonium chloride .................................... 5199156 Zinc bromide ...................................................... 5199157 Zinc carbonate ................................................... 5199180 Uranyl acetate ................................................... 5199184 Pyrethrins .......................................................... 5129188 Acrylyl Chloride ................................................... 649190 Ammonium permanganate ................................. 4839191 Chlorine Dioxide Hydrate ................................... 1409192 Fluorine ............................................................. 2629206 Methyl Phosphonic Dichloride ........................... 3529263 Chloropivaloyl chloride ....................................... 4899269 Trimethoxysilane ............................................... 460 47
  • 52. SpecificMaterialGuides
  • 53. ACETAL 3 UN 1088 2 0 Shipping Name: Acetal Other Names: Acetaldehyde ethylacetal PA Acetol NF 1,1-DiethoxyethaneHazards: Description:l Highly flammable l Colorless liquidl Container may BLEVE when exposed to fire l Pungent, woody odorl Vapors are heavier than air and will collect and stay in l Floats on the surface of water and is slightly soluble in low areas waterl Vapors may travel long distances to ignition sources l Highly flammable and flashback l Vapors are heavier than air and will collect and stay in lowl Vapors in confined areas (e.g., tanks, sewers, buildings) areas may explode when exposed to fire Operational Level Training Response:l Irritating to skin, eyes, nose and lungs RELEASE, NO FIRE:Awareness and Operational Level Training l Stop the release if it can be done safely from a distanceResponse: l Prevent material and runoff from entering sewers andl Stay upwind and uphill waterways if it can be done safely well ahead of the releasel Determine the extent of the problem l Use large amounts of water to disperse vapors - containl Isolate the area of release or fire and deny entry runoffl Remove all ignition sources l Consider the application of alcohol resistant (AFFF) foaml For container exposed to fire evacuate the area in all to spilled liquid to control vapors directions because of the risk of BLEVE l Ventilate confined area if it can be done without placingl Evacuate the immediate area and downwind for a large personnel at risk release FIRE:l Notify local health and fire officials and pollution control l Specially trained personnel operating from a safe distance agencies can fight fires using alcohol resistant (AFFF) foam or dryl If material or contaminated runoff enters waterways, notify chemical if available in sufficient amounts. Under favorable downstream users of potentially contaminated water conditions, experienced crews can use coordinated fog streams to sweep the flames off the surface of the burning liquid. Keep exposures cool to protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Provide Basic Life Support /CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 105-57-750
  • 54. ACETALDEHYDE 4 UN 1089 3 2 Shipping Name: Acetaldehyde Other Names: Acetic aldehyde PA Ethanal NF EthylaldehydeWARNING! l EXTREMELY FLAMMABLE! l MAY EXPLODE WITHOUT WARNING WHEN EXPOSED TO HEAT, DUST OR CORROSIVE OR OXIDIZING AGENTS!Hazards: Description:l Very irritating to skin and eyes, prolonged contact can l Colorless liquid cause burns l Pungent fruity odorl Container may BLEVE when exposed to fire l Soluble in waterl Fire fighting gear (including SCBA) does not provide l Extremely flammable adequate protection. If exposure occurs, remove and l Vapors are heavier than air and will collect and stay in low isolate gear immediately and thoroughly decontaminate areas personnel l Produces large amounts of vaporl Vapors are heavier than air and will collect and stay in low Operational Level Training Response: areas RELEASE, NO FIRE:l Vapors in confined areas (e.g., tanks, sewers, buildings) l Stop the release if it can be done safely from a distance may explode when exposed to fire l Prevent material and runoff from entering sewers andl Vapors may travel long distances to ignition sources and waterways if it can be done safely well ahead of the release flashback l Use large amounts of water to disperse vapors - containAwareness and Operational Level Training runoffResponse: l Ventilate confined area if it can be done without placingl Stay upwind and uphill personnel at riskl Determine the extent of the problem l Consider the application of alcohol resistant (AFFF) foaml Isolate the area of release or fire and deny entry to spilled liquid to control vaporsl Remove all ignition sources FIRE:l For container exposed to fire evacuate the area in all l Specially trained personnel operating from a safe distance directions because of the risk of BLEVE can fight fires using alcohol resistant (AFFF) foam or dryl Evacuate the immediate area and downwind for a large chemical if available in sufficient amounts. Under favorable release conditions, experienced crews can use coordinated fogl Notify local health and fire officials and pollution control streams to sweep the flames off the surface of the burning agencies liquid. Keep exposures cool to protect against re-ignition.l If material or contaminated runoff enters waterways, notify Do not direct straight streams into the liquid. downstream users of potentially contaminated water l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Provide Basic Life Support /CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 75-07-0 51
  • 55. ACETIC ACID 2 UN 2789 (More than 80%) 3 0 UN 2790 (Solution in water 1-80%) Shipping Name: UN 2789 Acetic acid, glacial PA UN 2790 Acetic Acid, solution, more than 10% NF but not more than 80% acid. Other Names: Ethanoic acid Glacial acetic acid Ethylic acid Methane carboxylic acidHazards: Description:l Very irritating to skin, eyes, nose and lungs; prolonged l Colorless liquid contact with skin can cause burns l Sour, pungent odor like vinegarl Fire fighting gear (including SCBA) does not provide l Soluble in water and produces heat when mixed with water adequate protection. If exposure occurs, remove and l Very flammable isolate gear immediately and thoroughly decontaminate l Vapors are heavier than air and will collect and stay in low personnel areasl Vapors are heavier than air and will collect and stay in low Operational Level Training Response: areas RELEASE, NO FIRE:l Container may BLEVE when exposed to fire l Stop the release if it can be done safely from a distancel Vapors may travel long distances to ignition sources and l Prevent material and runoff from entering sewers and flashback waterways if it can be done safely well ahead of the releasel Will attack many forms of rubber or plastic l Use large amounts of water to disperse vapors - containAwareness and Operational Level Training runoffResponse: l Consider the application of alcohol foam to spilled liquid tol Stay upwind and uphill control vaporsl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Isolate the area of release or fire and deny entry personnel at riskl Remove all ignition sources FIRE:l For container exposed to fire evacuate the area in all l Specially trained personnel operating from a safe distance directions because of the risk of BLEVE can fight fires using alcohol foam or dry chemical ifl Evacuate the immediate area and downwind for a large available in sufficient amounts or use fog streams to release extinguish burning liquid or dilute to a nonflammablel Notify local health and fire officials and pollution control mixture. Keep exposures cool to protect against re-ignition. agencies Do not direct straight streams into the liquid.l If material or contaminated runoff enters waterways, notify l Cool exposed containers with large quantities of water downstream users of potentially contaminated water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 64-19-752
  • 56. ACETIC ANHYDRIDE 2 UN 1715 3 1 Shipping Name: Acetic Anhydride Other Names: Acetic acid anhydride PA Acetyl anhydride NF Acetyl ether Acetyl oxide Ethanoic anhydrideHazards: Description:l Vapors and liquid are extremely irritating to skin, eyes, l Colorless liquid nose and lungs; skin and eye contact causes severe burns l Strong vinegar-like smell and blindness l Dissolves in water and reacts with water to form aceticl Fire fighting gear (including SCBA) does not provide acid (vinegar) and heat adequate protection. If exposure occurs, remove and l Very flammable isolate gear immediately and thoroughly decontaminate l Vapors are heavier than air and will collect and stay in low personnel areasl Container may BLEVE when exposed to fire Operational Level Training Response:l Vapors are heavier than air and will collect and stay in low RELEASE, NO FIRE: areas l Stop the release if it can be done safely from a distancel Reacts explosively with a large number of chemicals l Prevent material and runoff from entering sewers andAwareness and Operational Level Training waterways if it can be done safely well ahead of the releaseResponse: l Use large amounts of water well away from the release tol Stay upwind and uphill disperse vapors - contain runoffl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Remove all ignition sources personnel at riskl Isolate the area of release or fire and deny entry FIRE:l Evacuate or shelter in place the immediate area and l Use alcohol foam or dry chemical if available in sufficient downwind for a large release amounts or use fog streams to extinguish burning liquid orl For container exposed to fire evacuate the area in all dilute to a nonflammable mixture. Keep exposures cool to directions because of the risk of BLEVE protect against re-ignition. Do not direct straight streamsl Notify local health and fire officials and pollution control into the liquid. agencies l If material is not leaking, cool exposed containers withl If material or contaminated runoff enters waterways, notify large quantities of water from unattended equipment or downstream users of potentially contaminated water remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of expanding), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 108-24-7 53
  • 57. ACETONE 3 UN 1090 1 0 Shipping Name: Acetone Other Names: Dimethyl ketone PA Methyl ketone NF 2-PropanoneHazards: Description:l Highly flammable l Colorless liquidl Container may BLEVE when exposed to fire l Smells like fingernail polish removerl Irritating to skin, eyes, nose and lungs l Soluble in waterl Vapors may travel long distances to ignition sources and l Highly flammable flashback l Vapors are heavier than air and will collect and stay in lowl Vapors are heavier than air and will collect and stay in low areas areas l Produces large amounts of vaporl Vapors in confined areas (e.g., tanks, sewers, buildings) Operational Level Training Response: may explode when exposed to fire RELEASE, NO FIRE:Awareness and Operational Level Training l Stop the release if it can be done safely from a distanceResponse: l Prevent material and runoff from entering sewers andl Stay upwind and uphill waterways if it can be done safely well ahead of the releasel Determine the extent of the problem l Use large amounts of water to disperse vapors - containl Isolate the area of release or fire and deny entry runoffl Remove all ignition sources l Consider the application of alcohol resistant (AFFF) foaml For container exposed to fire evacuate the area in all to spilled liquid to control vapors directions because of the risk of BLEVE l Ventilate confined area if it can be done without placingl Evacuate the immediate area and downwind for a large personnel at risk release FIRE:l Notify local health and fire officials and pollution control l Specially trained personnel operating from a safe distance agencies can fight fires using alcohol resistant (AFFF) foam or dryl If material or contaminated runoff enters waterways, notify chemical if available in sufficient amounts. Under favorable downstream users of potentially contaminated water conditions, experienced crews can use coordinated fog streams to sweep the flames off the surface of the burning liquid. Keep exposures cool to protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of expanding), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 67-64-154
  • 58. ACETONE CYANOHYDRIN 2 (STABILIZED) 4 2 UN 1541 Shipping Name: Acetone cyanohydrin, stabilized PA NF Other Names: Acetocyanohydrin 2-Cyano-2-propanol 2-HydroxyisobutyronitrileIsopropylcyanohydrin 2-Methyl lactonitrileWARNING! l POISON! BREATHING THE VAPORS, SKIN CONTACT OR SWALLOWING THE MATERIAL CAN KILL YOU! PRODUCES CYANIDE IN THE BODY! l Fire fighting gear (including SCBA) provides NO protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l EXPOSURE TO HEAT WILL PRODUCE CYANIDE GAS!Hazards: Description:l Decomposes in water to form hydrogen cyanide l Colorless to light yellow liquidl Combustion products include the toxic gases hydrogen l Almond-like odor cyanide and nitrogen oxides l Soluble in waterl Vapors are heavier than air and will collect and stay in low l Decomposes in water to form hydrogen cyanide areas l Very flammablel Container may BLEVE when exposed to fire l Vapors are heavier than air and will collect and stay in lowAwareness and Operational Level Training areasResponse: Operational Level Training Response:l DO NOT ATTEMPT RESCUE! RELEASE, NO FIRE:l Stay upwind and uphill l Stop the release if it can be done safely from a distancel Determine the extent of the problem l Prevent material and runoff water from entering sewers andl Isolate the area of release or fire and deny entry waterways if it can be done safely well ahead of the releasel Evacuate or shelter in place the immediate area and l Use large amounts of fog to disperse vapors - contain downwind for a large release runoffl Remove all ignition sources l Consider the application of alcohol resistant (AFFF) foaml For container exposed to fire evacuate the area in all to large areas of spilled liquid to control vapors directions because of the risk of BLEVE FIRE:l Notify local health and fire officials and pollution control l If material is on fire and conditions permit, DO NOT agencies EXTINGUISH. Cool exposures using unattended monitors.l If material or contaminated runoff enters waterways, notify l Specially trained personnel operating from a safe distance downstream users of potentially contaminated water can fight fires using alcohol resistant (AFFF) foam or dry chemical if available in sufficient amounts or use fog streams to extinguish burning liquid or dilute to a nonflammable mixture. Keep exposures cool to protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of expanding), withdraw immediately to a secure location First Aid:l DO NOT ATTEMPT RESCUE!l The contaminated victim poses a health risk to the responderl Decontaminate the victim from a safe distance with a stream of water; have the victim remove clothing if possible; provide Basic Life Support/CPR as neededl Further decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Victims should be examined by a physician as soon as possiblel Do NOT perform mouth to mouth resuscitation; use a bag/mask apparatusl Note to physician: can produce cyanide toxicity, if symptoms indicate, initial treatment includes the cyanide antidote kit CAS: 75-86-5 55
  • 59. ACETONITRILE 3 UN 1648 2 0 Shipping Name: Acetonitrile Other Names: Cyanomethane Methanecarbonitrile PA Ethanenitrile Methyl cyanide NF Ethyl nitrileHazards: Description:l Breathing the vapors, skin contact or swallowing the liquid l Colorless liquid can kill you! Converted to cyanide in the body! l Sweet, ether-like smelll Firefighting gear (including SCBA) does not provide l Initially floats on the surface of water and is soluble in adequate protection. If exposure occurs, remove and water isolate gear immediately and thoroughly decontaminate l Highly flammable personnel l Vapors are heavier than air and will collect and stay in lowl Odor is not a reliable indicator of the presence of toxic areas amounts of vapor Operational Level Training Response:l Highly flammable RELEASE, NO FIRE:l Container may BLEVE when exposed to fire l Stop the release if it can be done safely from a distancel Vapors in confined areas (e.g., tanks, sewers, buildings) l Prevent material and runoff from entering sewers and may explode when exposed to fire waterways if it can be done safely well ahead of the releasel Vapors are heavier than air and will collect and stay in low l Use large amounts of water to disperse vapors - contain areas runoffl Vapors may travel long distances to ignition sources and l Consider the application of alcohol resistant (AFFF) foam flashback to spilled liquid to control vaporsl Combustion products include toxic hydrogen cyanide and l Ventilate confined area if it can be done without placing nitrogen oxides personnel at riskAwareness and Operational Level Training FIRE:Response: l If material is on fire and conditions permit, DO NOTl Do not put yourself in danger by entering a contaminated EXTINGUISH. Cool exposures using unattended monitors. area to rescue a victim l Specially trained personnel operating from a safe distancel Stay upwind and uphill can fight fires using alcohol resistant (AFFF) foam or dryl Determine the extent of the problem chemical if available in sufficient amounts. Under favorablel Remove all ignition sources conditions, specially trained personnel can usel BACK OFF! - Isolate a wide area around the release or coordinated fog streams to sweep the flames off the fire, deny entry and call for expert help surface of the burning liquid. Keep exposures cool tol For container exposed to fire evacuate the area in all protect against re-ignition. Do not direct straight streams directions because of the risk of BLEVE into the liquid.l Evacuate the immediate area and downwind for a large l Cool exposed containers with large quantities of water release from unattended equipment or remove intact containers ifl Notify local health and fire officials and pollution control it can be done safely agencies l If cooling streams are ineffective (venting sound increasesl If material or contaminated runoff enters waterways, notify in volume and pitch, tank discolors or shows any signs of downstream users of potentially contaminated water deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Note to physician: can cause cyanide poisoning; if symptoms indicate, treat with the cyanide antidote kit CAS: 75-05-856
  • 60. ACETYL BROMIDE 3 UN 1716 3 2 Shipping Name: Acetyl Bromide Other Names: Acetic acid bromide W Ethanoyl bromideWARNING! l POISON! BREATHING THE VAPORS CAN KILL YOU! SKIN AND EYE CONTACT CAUSES SEVERE BURNS AND BLINDNESS! l Firefighting gear (including SCBA) provides NO protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l DO NOT USE WATER! REACTS VIOLENTLY WITH WATER TO FORM TOXIC HYDROGEN BROMIDE GAS!Hazards: Description:l Highly flammable l Colorless liquidl Container may BLEVE when exposed to fire l Sharp, unpleasant acrid smelll Vapors are heavier than air and will collect and stay in low l Sinks in water and reacts violently with water to produce areas acetic acid and toxic and corrosive hydrogen bromidel Vapors may travel long distances to ignition sources and l Highly flammable flashback l Vapors are heavier than air and will collect and stay in lowl Vapors in confined areas (e.g., tanks, sewers, buildings) areas may explode when exposed to fire l Attacks and corrodes wood and most metals in thel Combustion products include toxic and corrosive hydrogen presence of moisture bromide Operational Level Training Response:Awareness and Operational Level Training RELEASE, NO FIRE:Response: l Stop the release if it can be done safely from a distancel Do not put yourself in danger by entering a contaminated l Prevent material and runoff from entering sewers and area to rescue a victim waterways if it can be done safely well ahead of the releasel Stay upwind and uphill l Use large amounts of water well away from the release tol Determine the extent of the problem disperse vapors - contain runoffl Remove all ignition sources l Ventilate confined area if it can be done without placingl Isolate the area of release or fire and deny entry personnel at riskl Evacuate the immediate area and downwind for a large FIRE: release l Approach fire with extreme caution; consider letting firel For container exposed to fire evacuate the area in all burn directions because of the risk of BLEVE l Do not allow water to come in contact with the material; ifl Notify local health and fire officials and pollution control material is on fire, use dry chemical to extinguish. If water agencies must be used, use in flooding quantitiesl If material or contaminated runoff enters waterways, notify l If material is not leaking, cool exposed containers with downstream users of potentially contaminated water large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 506-96-7 57
  • 61. ACETYL CHLORIDE 3 UN 1717 3 2 Shipping Name: Acetyl Chloride Other Names: Acetic acid chloride W PA Acetic chloride NF Ethanoyl chlorideWARNING! l POISON! BREATHING THE VAPORS CAN KILL YOU! SKIN AND EYE CONTACT CAUSES SEVERE BURNS AND BLINDNESS! l Firefighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l DO NOT USE WATER DIRECTLY ON MATERIAL! REACTS VIOLENTLY WITH WATER TO FORM TOXIC HYDROGEN CHLORIDE AND ACETIC ACID!Hazards: Description:l Highly flammable l Colorless to pale yellow fuming liquidl Vapors are heavier than air and will collect and stay in low l Pungent, irritating odor areas l Sinks in water and reacts violently with waterl Container may BLEVE when exposed to fire l Highly flammablel Vapors may travel long distances to ignition sources and l Vapors are heavier than air and will collect and stay in low flashback areasl Vapors in confined areas (e.g., tanks, sewers, buildings) l Produces large amounts of vapor may explode when exposed to fire Operational Level Training Response:l Combustion products include toxic hydrogen chloride RELEASE, NO FIRE:l Corrosive to most metals particularly in the presence of l Stop the release if it can be done safely from a distance moisture producing flammable hydrogen gas l Prevent material and runoff from entering sewers andAwareness and Operational Level Training waterways if it can be done safely well ahead of the releaseResponse: l Use large amounts of water well away from the material tol Do not put yourself in danger by entering a contaminated disperse vapors - contain runoff area to rescue a victim l Ventilate confined area if it can be done without placingl Stay upwind and uphill personnel at riskl Determine the extent of the problem FIRE:l Isolate the area of release or fire and deny entry l Do not allow water to come in contact with material; ifl Remove all ignition sources material is on fire, use dry chemical to extinguish; if waterl For container exposed to fire evacuate the area in all must be used, use in flooding quantities directions because of the risk of BLEVE l If material is not leaking, cool exposed containers withl Evacuate the immediate area and downwind for a large large quantities of water from unattended equipment or release remove intact containers if it can be done safelyl Notify local health and fire officials and pollution control l If cooling streams are ineffective (venting sound increases agencies in volume and pitch, tank discolors or shows any signs ofl If material or contaminated runoff enters waterway, notify deforming), withdraw immediately to a secure location downstream users of potentially contaminated water First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns rinse with water and apply a clean dry dressing CAS: 75-36-558
  • 62. ACETYLENE 4 (Dissolved) 0 3 UN 1001 PA Shipping Name: Acetylene, dissolved NF Other Names: Ethine EthyneWARNING! l EXTREMELY FLAMMABLE! l CONTAINER MAY EXPLODE WHEN EXPOSED TO FIRE!Hazards: Description:l Vapors in confined areas (e.g., tanks, sewers, buildings) l Colorless gas may explode when exposed to fire l Garlic or ether-like odorl Vapors may travel long distances to ignition sources and l Soluble in water flashback l Extremely flammablel Reacts explosively with many materials l Vapors are lighter than airl Exposure of cylinders to fire and flame or elevated l Often shipped and stored dissolved in acetone temperatures may cause cylinder to rupture or frangible l Not shipped by rail tank cars disc to burst, releasing entire contents of cylinder. l Cylinders have a fusible plug not a relief valve Ruptured or venting cylinders may rocket through Operational Level Training Response: buildings and/or travel a considerable distance RELEASE, NO FIRE:Awareness and Operational Level Training l Stop the release if it can be done safely from a distanceResponse: l Use large amounts of water to disperse vapors - containl Stay upwind runoffl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Remove all ignition sources personnel at riskl Isolate the area of release or fire and deny entry FIRE:l Evacuate the immediate area and downwind for a large l Do not extinguish the fire unless the flow of the gas can be release stopped and any remaining gas is out of the line. Speciallyl For container exposed to fire evacuate the area in all trained personnel may use fog lines to cool exposures and directions because of the risk of explosion let the fire burn itself outl Notify local health and fire officials and pollution control l Cool exposed containers with large quantities of water agencies from unattended equipment or remove intact containers ifl If contaminated runoff enters waterways, notify it can be done safely downstream users of potentially contaminated water l If cylinders are exposed to excessive heat from fire or flame contact, withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutesl Seek medical attention CAS: 74-86-2 59
  • 63. ACROLEIN 3 (INHIBITED) 4 3 UN 1092 Shipping Name: Acrolein, inhibited PA NF Other Names: Acrylaldehyde 2-Propenal Allyl aldehyde BiocideWARNING! l POISON! BREATHING THE VAPORS CAN KILL YOU! l Fire fighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l MAY REACT WITH ITSELF BLOCKING RELIEF VALVES LEADING TO TANK EXPLOSION!Hazards: Description:l Highly flammable l Colorless to yellow liquidl Container may BLEVE when exposed to fire l Sharp pungent odorl Irritating to eyes, nose and lungs l Floats on the surface of water and is soluble in waterl Vapors are heavier than air and will collect and stay in low l Highly flammable areas l Vapors are heavier than air and will collect and stay in lowl Vapors may travel long distances to ignition sources and areas flashback l Produces large amounts of vaporl Vapors in confined areas (e.g., tanks, sewers, buildings) Operational Level Training Response: may explode when exposed to fire RELEASE, NO FIRE:l Reacts with acids, alkalis and air producing a violent l Stop the release if it can be done safely from a distance reaction with itself l Prevent material and runoff water from entering sewers andl Prolonged contact with skin will cause burns waterways if it can be done safely well ahead of the releaseAwareness and Operational Level Training l Use large amounts of water to disperse vapors - containResponse: runoffl Do not put yourself in danger by entering a contaminated l Consider the application of alcohol resistant (AFFF) foam area to rescue a victim to large areas of spilled liquid to control vaporsl Stay upwind and uphill l Ventilate confined area if it can be done without placingl Determine the extent of the problem personnel at riskl Remove all ignition sources FIRE:l Isolate the area of release or fire and deny entry l If material is on fire and conditions permit, DO NOTl For container exposed to fire evacuate the area in all EXTINGUISH. Cool exposures using unattended monitors. directions because of the risk of BLEVE l Specially trained personnel operating from a safel Evacuate the immediate area and downwind for a large distance can fight fires using alcohol resistant (AFFF) release foam or dry chemical if available in sufficient amounts.l Notify local health and fire officials and pollution control Under favorable conditions, experienced crews can use agencies coordinated fog streams to sweep the flames off thel If material or contaminated runoff enters waterways, notify surface of the burning liquid. Keep exposures cool to downstream users of potentially contaminated water protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns decontaminate with water and apply a clean dry dressing CAS: 107-02-860
  • 64. ACRYLAMIDE 2 UN 2074 2 2 Shipping Name: Acrylamide Other Names: Acrylic amide PA Propenamide NF Vinyl amideWARNING! l MAY DECOMPOSE WITH HEAT AND REACT EXPLOSIVELY WITH ITSELF AT TEMPERATURES ABOVE 184° F RELEASING TOXIC AMMONIA GAS!Hazards: Description:l Irritating to skin, eyes, nose and lungs l White solidl Container may explode when exposed to fire l No odorl Vapors are heavier than air and will collect and stay in low l Initially sinks in water and is soluble in water areas l Very flammablel Combustion products include toxic nitrogen oxides l Vapors are heavier than air and will collect and stay in lowAwareness and Operational Level Training areasResponse: Operational Level Training Response:l Stay upwind RELEASE, NO FIRE:l Determine the extent of the problem l Cover material to protect from wind, rain or sprayl Isolate the area of release or fire and deny entry l Prevent contaminated runoff from entering sewers andl For container exposed to fire evacuate the area in all waterways if it can be done safely well ahead of the release directions because of the risk of explosion l Ventilate confined area if it can be done without placingl Notify local health and fire officials and pollution control personnel at risk agencies FIRE:l If material or contaminated runoff enters waterways, notify l Material does not easily burn; fight surrounding fire with an downstream users of potentially contaminated water agent other than water; if water must be used, use it in flooding quantities l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attention CAS: 79-06-1 61
  • 65. ACRYLIC ACID 2 (INHIBITED) 3 2 UN 2218 Shipping Name: Acrylic acid, inhibited PA NF Other Names: Acroleic acid Propene acid Ethylene carboxylic acid Propenoic acid GAA 2-Propenoic acid Glacial acrylic acid Vinyl formic acidWARNING! l MAY REACT WITH ITSELF BLOCKING RELIEF VALVES LEADING TO TANK EXPLOSION!Hazards: Description:l Vapors or liquid can cause burns to eyes, nose, skin and l Shipped as a colorless liquid lungs l Sharp rancid odorl Fire fighting gear (including SCBA) does not provide l Initally sinks in water and is soluble in water adequate protection. If exposure occurs, remove and l Very flammable isolate gear immediately and thoroughly decontaminate l Freezes at 56° F personnel Operational Level Training Response:l May react with itself without warning with explosive RELEASE, NO FIRE: violence l Stop the release if it can be done safely from a distancel Vapors may travel long distances to ignition sources and l Prevent material and runoff from entering sewers and flash back waterways if it can be done safely well ahead of the releaseAwareness and Operational Level Training l Use large amounts of water to disperse vapors - containResponse: runoffl Stay upwind and uphill l Consider the application of alcohol resistant (AFFF) foaml Determine the extent of the problem to spilled liquid to control vaporsl Isolate the area of release or fire and deny entry FIRE:l For container exposed to fire evacuate the area in all l Specially trained personnel operating from a safe distance directions because of the risk of BLEVE can fight fires using alcohol resistant (AFFF) foam or dryl Notify local health and fire officials and pollution control chemical if available in sufficient amounts or use fog agencies streams to extinguish burning liquid or dilute to al If material or contaminated runoff enters waterways, notify nonflammable mixture. Keep exposures cool to protect downstream users of potentially contaminated water against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns decontaminate with water and apply a clean dry dressing CAS: 79-10-762
  • 66. ACRYLONITRILE 3 (INHIBITED) 4 2 UN 1093 Shipping Name: Acrylonitrile, inhibited PA NF Other Names: Carbacryl 2-Propenenitrile Cyanoethylene Vinyl cyanide PropenenitrileWARNING! l POISON! BREATHING THE VAPORS, SKIN CONTACT OR SWALLOWING THE MATERIAL CAN KILL YOU! PRODUCES CYANIDE IN THE BODY! l Fire fighting gear (including SCBA) provides NO protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l MAY REACT WITH ITSELF WITHOUT WARNING BLOCKING RELIEF VALVES LEADING TO CONTAINER EXPLOSION!Hazards: Description:l Highly flammable l Colorless to light yellow liquidl Container may BLEVE when exposed to fire l Strong, pungent smell like onions or garlicl Vapors are heavier than air and will collect and stay in low l Floats on the surface of water and is moderately soluble in areas waterl Vapors may travel long distances to ignition sources and l Highly flammable flashback l Vapors are heavier than air and will collect and stay in lowl Prolonged contact with skin will cause burns areasl Combustion products include toxic cyanide gas and Operational Level Training Response: nitrogen oxide RELEASE, NO FIRE:Awareness and Operational Level Training l Stop the release if it can be done safely from a distanceResponse: l Prevent material and runoff from entering sewers andl Do not put yourself in danger by entering a contaminated waterways if it can be done safely well ahead of the release area to rescue a victim l Use large amounts of water to disperse vapors - containl Stay upwind and uphill runoffl Determine the extent of the problem l Consider the application of alcohol resistant (AFFF) foaml BACK OFF! - Isolate a wide area around the release or to control vapors fire, deny entry and call for expert help l Ventilate confined area if it can be done without placingl Evacuate the immediate area and downwind for a large personnel at risk release FIRE:l Remove all ignition sources l If material is on fire and conditions permit, DO NOTl For containers exposed to fire evacuate the area in all EXTINGUISH. Cool exposures using unattended monitors. directions because of the risk of BLEVE l Specially trained personnel operating from a safe distancel Notify local health and fire officials and pollution control can fight fires using alcohol resistant (AFFF) foam or dry agencies chemical if available in sufficient amounts. Under favorablel If material or contaminated runoff enters waterways, notify conditions, experienced crews can use coordinated fog downstream users of potentially contaminated water streams to sweep the flames off the surface of the burning liquid. Keep exposures cool to protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml The contaminated victim poses a risk to the responder. Decontaminate the victim from a safe distance with a stream of water. Provide Basic Life Support/CPR as needed, then further decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Victims should be examined by a physician as soon as possiblel Note to physician: can produce cyanide toxicity, if symptoms indicate, initial treatment includes the cyanide antidote kit CAS: 107-13-1 63
  • 67. ACRYLYL CHLORIDE 3 NA 9188 3 3 Other Names: Acrylic acid chloride Acryloyl chloride Propenoyl chlorideWARNING! l POISON! BREATHING THE GAS CAN KILL YOU! l Fire fighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l HEATED MATERIAL MAY REACT WITH ITSELF LEADING TO CONTAINER EXPLOSION!Hazards: Description:l Highly flammable l A liquidl Container may BLEVE when exposed to fire l Irritating odorl Severely irritating to skin, eyes, nose and lungs; prolonged l Sinks in water and decomposes in water to hydrochloric contact with skin may cause burns acidl Combustion products include toxic hydrogen chloride l Highly flammableAwareness and Operational Level Training Operational Level Training Response:Response: RELEASE, NO FIRE:l Do not put yourself in danger by entering a contaminated l Stop the release if it can be done safely from a distance area to rescue a victim l Prevent material and runoff from entering sewers andl Stay upwind and uphill waterways if it can be done safely well ahead of the releasel Determine the extent of the problem l Use large amounts of water to disperse vapors - containl Remove all ignition sources runoffl Isolate the area of release or fire and deny entry l Consider the application of foam to large areas of spilledl For container exposed to fire evacuate the area in all liquid to control vapors directions because of the risk of BLEVE FIRE:l Notify local health and fire officials and pollution control l Specially trained personnel operating from a safe distance agencies can fight fires using foam or dry chemical if available inl If material or contaminated runoff enters waterways, notify sufficient amounts. Under favorable conditions, downstream users of potentially contaminated water experienced crews can use coordinated fog streams to sweep the flames off the surface of the burning liquid. Keep exposures cool to protect against re-ignition. Do not direct straight streams into the liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns decontaminate with water and apply a clean dry dressing CAS: 814-68-664
  • 68. ADIPONITRILE 2 UN 2205 2 1 Shipping Name: Adiponitrile Other Names: Adipic acid dinitrile PA 1,4-Dicyanobutane NF Hexanedinitrile Tetramethylene cyanideWARNING! l POISON! BREATHING THE VAPORS, SWALLOWING THE MATERIAL OR SKIN CONTACT CAN KILL YOU! PRODUCES CYANIDE IN THE BODY! l Firefighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l EXPOSURE TO HEAT WILL PRODUCE TOXIC CYANIDE GAS!Hazards: Description:l Odor is not a reliable indicator of the presence of toxic l Colorless liquid amounts of vapor l Practically odorlessl Container may BLEVE when exposed to fire l Floats on the surface of water and is moderately soluble inl Vapors are heavier than air and will collect and stay in low water areas l Very flammablel Combustion or decomposition products upon heating l Vapors are heavier than air and will collect and stay in low include toxic hydrogen cyanide and nitrogen oxides areasAwareness and Operational Level Training l Freezes at 34° FResponse: Operational Level Training Response:l Do not put yourself in danger by entering a contaminated RELEASE, NO FIRE: area to rescue a victim l Stop the release if it can be done safely from a distancel Stay upwind and uphill l Prevent material and runoff from entering sewers andl Determine the extent of the problem waterways if it can be done safely well ahead of the releasel BACK OFF! - Isolate a wide area around the release or l Use large amounts of water to disperse vapors - contain fire, deny entry and call for expert help runoffl For container exposed to fire evacuate the area in all l Ventilate confined area if it can be done without placing directions because of the risk of BLEVE personnel at riskl Evacuate the immediate area and downwind for a large l Consider the application of alcohol resistant (AFFF) foam release to spilled liquid to control vaporsl Notify local health and fire officials and pollution control FIRE: agencies l Specially trained personnel operating from a safe distancel If material or contaminated runoff enters waterways, notify can fight fires using alcohol resistant (AFFF) foam or dry downstream users of potentially contaminated water chemical if available in sufficient amounts or use fog streams to extinguish burning liquid. Keep exposures cool to protect against re-ignition. Do not direct straight streams into liquid. l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl Note to physician: can produce cyanide toxicity; if symptoms indicate, initial treatment includes the cyanide antidote kit CAS: 111-69-3 65
  • 69. ALDICARB 0 UN 2757 2 0 Shipping Name: Carbamate pesticides, solid, toxic Other Names: Carbamyl TemikHazards: Description:l Container may explode when exposed to fire l White solidl Irritating to skin, eyes, nose and lungs l Slight sulfur-like odorl Decomposition products upon heating include toxic sulfur l Sinks in water and is insoluble in water oxides l NonflammableAwareness and Operational Level Training l A carbamate insecticideResponse: Operational Level Training Response:l Stay upwind and uphill RELEASE, NO FIRE:l Determine the extent of the problem l Cover material to protect from wind, rain or sprayl Isolate the area of release or fire and deny entry l Prevent material and runoff from entering sewers andl For container exposed to fire evacuate the area in all waterways if it can be done safely well ahead of the release directions because of the risk of explosion FIRE:l Notify local health and fire officials and pollution control l Material does not burn; fight surrounding fire with an agent agencies appropriate for the burning materiall If material or contaminated runoff enters waterways, notify l Cool exposed containers with large quantities of water downstream users of potentially contaminated water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Note to physician: a carbamate insecticide; if symptoms indicate, initial treatment includes atropine CAS: 116-06-366
  • 70. ALLYL ALCOHOL 3 UN 1098 4 1 Shipping Name: Allyl Alcohol Other Names: AA Orvinylecarbinol PA NF Allyl al 2-Propenol Propenyl alcohol Allylic alcohol Propenol VinylcarbinolWARNING! l POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU! l Fire fighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnelHazards: Description:l Highly flammable l Clear, colorless liquidl Container may BLEVE when exposed to fire l Pungent, mustard-like smelll Severely irritating to skin, eyes, nose and lungs; skin and l Initally floats on the surface of water and is soluble in water eye contact causes severe burns and blindness l Highly flammablel Vapors are heavier than air and will collect and stay in low l Vapors are heavier than air and will collect and stay in low areas areasl Vapors may travel long distances to ignition sources and Operational Level Training Response: flashback RELEASE, NO FIRE:l Vapors in confined areas (e.g., tanks, sewers, buildings) l Stop the release if it can be done safely from a distance may explode when exposed to fire l Prevent material and runoff water from entering sewers andAwareness and Operational Level Training waterways if it can be done safely well ahead of the releaseResponse: l Use large amounts of water to disperse vapors and dilutel Do not put yourself in danger by entering a contaminated standing pools of water area to rescue a victim l Consider the application of alcohol resistant (AFFF) foaml Stay upwind and uphill to spilled liquid to control vaporsl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Isolate the area of release or fire and deny entry personnel at riskl Remove all ignition sources FIRE:l For container exposed to fire evacuate the area in all l Specially trained personnel operating from a safe distance directions because of the risk of BLEVE can fight fires using alcohol resistant (AFFF) foam or dryl Evacuate the immediate area and downwind for a large chemical if available in sufficient amounts. Under favorable release conditions, experienced crews can use coordinated fogl Notify local health and fire officials and pollution control streams to sweep the flames off the surface of the burning agencies liquid. Keep exposures cool to protect against re-ignition.l If material or contaminated runoff enters waterways, notify Do not direct straight streams into the liquid. downstream users of potentially contaminated water l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Victims should be examined by a physician as soon as possiblel Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 107-18-6 67
  • 71. ALLYLAMINE 3 UN 2334 4 1 Shipping Name: Allylamine Other Names: 3-Aminopropene 2-Propenamine PA 3-Aminopropylene 2-Propen-1-amine NF MonoallylamineWARNING! l POISON! BREATHING THE VAPOR CAN KILL YOU! SKIN AND EYE CONTACT CAN CAUSE SEVERE BURNS AND BLINDNESS! l Fire fighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnelHazards: Description:l Highly flammable l Colorless to light yellow liquidl Container may BLEVE when exposed to fire l Ammonia-like odorl When heated may react with itself without warning with l Completely soluble in water explosive violence l Highly flammablel Vapors are heavier than air and will collect and stay in low l Vapors are heavier than air and will collect and stay in low areas areasl Vapors may travel long distances to ignition sources and l Produces large amounts of vapor flashback Operational Level Training Response:l Vapors in confined areas (e.g., tanks, sewers, buildings) RELEASE, NO FIRE: may explode when exposed to fire l Stop the release if it can be done safely from a distancel Combustion products include toxic nitrogen oxides l Prevent material and runoff water from entering sewers andAwareness and Operational Level Training waterways if it can be done safely well ahead of the releaseResponse: l Use large amounts of water to disperse vapors - containl Do not put yourself in danger by entering a contaminated runoff area to rescue a victim l Consider the application of alcohol resistant (AFFF) foaml Stay upwind and uphill only to large areas of spilled liquid to control vaporsl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Isolate the area of release or fire and deny entry personnel at riskl Remove all ignition sources FIRE:l For container exposed to fire evacuate the area in all l Specially trained personnel operating from a safe distance directions because of the risk of BLEVE can fight fires using alcohol resistant (AFFF) foam or dryl Evacuate the immediate area and downwind for a large chemical if available in sufficient amounts. Under favorable release. conditions, experienced crews can use coordinated fogl Notify local health and fire officials and pollution control streams to sweep the flames off the surface of the burning agencies liquid. Keep exposures cool to protect against re-ignition.l If material or contaminated runoff enters waterways, notify Do not direct straight streams into the liquid. downstream users of potentially contaminated water l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 107-11-968
  • 72. ALLYL BROMIDE 3 UN 1099 3 1 Shipping Name: Allyl Bromide Other Names: Bromoallylene PA 3-Bromo-1-propene NF 3-Bromopropylene 2-Propenyl bromideWARNING! l POISON! BREATHING THE VAPOR CAN KILL YOU! l Firefighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnelHazards: Description:l Severely irritating to skin, eyes, nose and lungs; prolonged l Colorless to light yellow liquid contact with skin can cause burns l Pungent, unpleasant smelll Highly flammable l Sinks in water and is slightly soluble in waterl Container may BLEVE when exposed to fire l Highly flammablel When heated may react with itself without warning with l Vapors are heavier than air and will collect and stay in low explosive violence areasl Vapors are heavier than air and will collect and stay in low l Produces large amounts of vapor areas Operational Level Training Response:l Vapors may travel long distances to ignition sources and RELEASE, NO FIRE: flashback l Stop the release if it can be done safely from a distancel Vapors in confined areas (e.g., tanks, sewers, buildings) l Prevent material and runoff from entering sewers and may explode when exposed to fire waterways if it can be done safely well ahead of releasel Combustion produces toxic hydrogen bromide gas l Use large amounts of water to disperse vapors - containAwareness and Operational Level Training runoffResponse: l Consider the application of foam to large areas of spilledl Do not put yourself in danger by entering a contaminated liquid to control vapors area to rescue a victim l Ventilate confined area if it can be done without placingl Stay upwind and uphill personnel at riskl Determine the extent of the problem FIRE:l Remove all ignition sources l Use foam or dry chemical if available in sufficientl Isolate the area of release or fire and deny entry amounts; under favorable conditions, experienced crewsl For container exposed to fire evacuate the area in all can use coordinated fog streams to sweep the flames off directions because of the risk of BLEVE the surface of the burning liquid. Keep exposures cool tol Evacuate the immediate area and downwind for a large protect against re-ignition. Do not direct straight streams release into the liquidl Notify local health and fire officials and pollution control l Cool exposed containers with large quantities of water agencies from unattended equipment or remove intact containers ifl If material or contaminated runoff enters waterways, notify it can be done safely. downstream users of potentially contaminated water l If cooling streams are ineffective (venting sound increases in volume and pitch, tank discolors or shows any signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 106-95-6 69
  • 73. ALLYL CHLORIDE 3 UN 1100 3 1 Shipping Name: Allyl Chloride Other Names: Chlorallylene Chloropropylene PA Chloropropene Propenyl chloride NF 3-ChloropropeneWARNING! l POISON! BREATHING THE VAPOR CAN KILL YOU! l Fire fighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnelHazards: Description:l Severely irritating to skin, eyes, nose and lungs; prolonged l Colorless to yellow-brown or red liquid contact with skin can cause burns l Sharp and irritating odorl Highly flammable l Floats on water and is insoluble in waterl Container may BLEVE when exposed to fire l Highly flammablel When heated, may react with itself without warning with l Vapors are heavier than air and will collect and stay in low explosive violence areasl Vapors are heavier than air and will collect and stay in low Operational Level Training Response: areas RELEASE, NO FIRE:l Vapors may travel long distances to ignition sources and l Stop the release if it can be done safely from a distance flashback l Prevent material and runoff from entering sewers andl Vapors in confined areas (e.g., tanks, sewers, buildings) waterways if it can be done safely well ahead of the release may explode when exposed to fire l Use large amounts of water to disperse vapors - containl Combustion produces the toxic gas hydrogen chloride and runoff phosgene l Consider the application of foam to large areas of spilledAwareness and Operational Level Training liquid to control vaporsResponse: l Ventilate confined area if it can be done without placingl Do not put yourself in danger by entering a contaminated personnel at risk area to rescue a victim FIRE:l Stay upwind and uphill l Use foam or dry chemical if available in sufficientl Determine the extent of the problem amounts; under favorable conditions, experienced crewsl Remove all ignition sources can use coordinated fog streams to sweep the flames offl Isolate the area of release or fire and deny entry the surface of the burning liquid. Keep exposures cool tol For container exposed to fire evacuate the area in all protect against re-ignition. Do not direct straight streams directions because of the risk of BLEVE into the liquidl Evacuate the immediate area and downwind for a large l Cool exposed containers with large quantities of water release from unattended equipment or remove intact containers ifl Notify local health and fire officials and pollution control it can be done safely. agencies l If cooling streams are ineffective (venting sound increasesl If material or contaminated runoff enters waterways, notify in volume and pitch, tank discolors or shows any signs of downstream users of potentially contaminated water expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 107-05-170
  • 74. ALLYL CHLOROFORMATE 3 UN 1722 3 1 Shipping Name: Allyl Chloroformate Other Names: Allyl chlorocarbonate PA 2-Propenyl chloroformate NFHazards: Description:l Severely irritating to skin, eyes, nose and lungs l Colorless liquidl Fire fighting gear (including SCBA) does not provide l Extremely irritating smell adequate protection. If exposure occurs, remove and l Sinks in water and is insoluble in water and reacts with isolate gear immediately and thoroughly decontaminate water to form allyl alcohol and chloroformic acid personnel l Highly flammablel Highly flammable l Vapors are heavier than air and will collect and stay in lowl Container may BLEVE when exposed to fire areasl When heated may react with itself without warning with Operational Level Training Response: explosive violence RELEASE, NO FIRE:l Vapors are heavier than air and will collect and stay in low l Stop the release if it can be done safely from a distance areas l Prevent material and runoff from entering sewers andl Vapors may travel long distances to ignition sources and waterways if it can be done safely well ahead of the release flashback l Use large amounts of water to disperse vapors - containl Vapors in confined areas (e.g., tanks, sewers, buildings) runoff may explode when exposed to fire l Consider the application of foam to large areas of spilledAwareness and Operational Level Training liquid to control vaporsResponse: l Ventilate confined area if it can be done without placingl Do not put yourself in danger by entering a contaminated personnel at risk area to rescue a victim FIRE:l Stay upwind and uphill l Use foam or dry chemical if available in sufficientl Determine the extent of the problem amounts. Under favorable conditions, experienced crewsl Remove all ignition sources can use coordinated fog streams to sweep the flames offl Isolate the area of release or fire and deny entry the surface of the burning liquid. Keep exposures cool tol For container exposed to fire evacuate the area in all protect against re-ignition. Do not direct straight streams directions because of the risk of BLEVE into the liquidl Evacuate the immediate area and downwind for a large l Cool exposed containers with large quantities of water release from unattended equipment or remove intact containers ifl Notify local health and fire officials and pollution control it can be done safely agencies l If cooling streams are ineffective (unvented containerl If material or contaminated runoff enters waterways, notify distorts, bulges or shows any other signs of expanding), downstream users of potentially contaminated water withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 2937-50-0 71
  • 75. ALLYLTRICHLOROSILANE 3 (STABILIZED) 3 2 UN 1724 W Shipping Name: Allyltrichlorosilane, stabilized PA NF Other Names: Acetylsilicon trichloride Propene-3-yltrichlorosilane TrichloroallysilaneWARNING! l POISON! BREATHING THE VAPOR CAN KILL YOU! SKIN AND EYE CONTACT CAN CAUSE SEVERE BURNS AND BLINDNESS! l Firefighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel l DO NOT USE WATER ON MATERIAL! REACTS VIGOROUSLY WITH WATER TO FORM TOXIC HYDROCHLORIC ACID!Hazards: Description:l Highly flammable l Colorless liquidl Container may BLEVE when exposed to fire l Pungent smelll Vapors are heavier than air and will collect and stay in low l Reacts vigorously with water to form hydrochloric acid areas l Highly flammablel Vapors may travel long distances to ignition sources and l Vapors are heavier than air and will collect and stay in low flashback areasl Vapors in confined areas (e.g., tanks, sewers, buildings) Operational Level Training Response: may explode when exposed to fire RELEASE, NO FIRE:l Combustion products include toxic hydrogen chloride l Stop the release if it can be done safely from a distanceAwareness and Operational Level Training l Prevent material and runoff from entering sewers andResponse: waterways if it can be done safely well ahead of the releasel Do not put yourself in danger by entering a contaminated l Use large amounts of water well away from the material to area to rescue a victim disperse vapors - contain runoffl Stay upwind and uphill l Ventilate confined area if it can be done without placingl Determine the extent of the problem personnel at riskl BACK OFF! - Isolate a wide area around the release or FIRE: fire, deny entry and call for expert help l If material is on fire and conditions permit, DO NOTl Remove all ignition sources EXTINGUISHl For container exposed to fire evacuate the area in all l Material reacts with water but can be extinguished with low directions because of the risk of BLEVE or medium expansion AFFF foam or dry chemical ifl Evacuate the immediate area and downwind for a large available in sufficient amounts release l If material is not leaking, cool exposed containers withl Notify local health and fire officials and pollution control large quantities of water from unattended equipment or agencies remove intact containers if it can be done safelyl If material or contaminated runoff enters waterways, notify l If cooling streams are ineffective (venting sound increases downstream users of potentially contaminated water in volume and pitch, tank discolors or shows any signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Victims should be examined by a physician as soon as possiblel Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 107-37-972
  • 76. AMINOPYRIDINES 1 UN 2671 4 0 Shipping Name: Aminopyridines Other Names: 4-Aminopyridine Avitrol m-Aminopyridine 4-Pyridinamine o-Aminopyridine 4-Pyridylamine p-AminopyridineWARNING! l POISON! BREATHING THE DUST, SWALLOWING THE MATERIAL OR SKIN CONTACT WILL KILL YOU! l Firefighting gear (including SCBA) does not provide adequate protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnelHazards: Description:l Container may explode when exposed to fire l White powderl Irritating to skin, eyes, nose and lungs l No odorl Combustion products include toxic nitrogen oxides l Sinks in water and is moderately soluble in waterAwareness and Operational Level Training l FlammableResponse: Operational Level Training Response:l Do not put yourself in danger by entering a contaminated RELEASE, NO FIRE: area to rescue a victim l Prevent contaminated runoff from entering sewers andl Stay upwind waterways if it can be done safely well ahead of the releasel Determine the extent of the problem l Cover material to protect from wind, rain or sprayl Isolate the area of release or fire and deny entry FIRE:l For container exposed to fire evacuate the area in all l Material does not easily burn; fight surrounding fire with an directions because of the risk of explosion agent appropriate for the burning materiall Evacuate or shelter in place the immediate area and l If material is on fire and conditions permit, DO NOT downwind for a large release EXTINGUISH. Cool exposures using unattended monitors.l Notify local health and fire officials and pollution control l Cool exposed containers with large quantities of water agencies from unattended equipment or remove intact containers ifl If material or contaminated runoff enters waterways, notify it can be done safely downstream users of potentially contaminated water l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Toxic effects may be delayed CAS: 504-24-5 (para, p-); 504-59-0 (ortho, o-); 462-08-8 (meta, m-) 73
  • 77. AMMONIA 1 (ANHYDROUS) 3 0 UN 1005 PA NF Shipping Name: Ammonia, anhydrous Other Names: AM-FOL Refrigerant R717 Ammonia, anhydrous Nitro-Sil Anhydrous ammoniaWARNING! l POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU! l Fire fighting gear including SCBA does not provide adequate protection. If exposure to the chemical occurs, remove and isolate gear immediately and thoroughly decontaminate personnel. l DO NOT ADD WATER TO LIQUID AMMONIA! WILL INCREASE EVAPORATION!Hazards: Description:l Contact with liquid may cause frostbite l May be shipped or stored as a compressed gas orl Severely irritating to skin, eyes, nose, throat and lungs, cryogenic liquid may cause burns l Strong, pungent odorl May burn or explode in closed spaces (e.g., tanks, l Soluble in water sewers, buildings) l Flammablel Produces a toxic, visible or invisible gas cloud which may l Gas is lighter then air but may hug the ground when cool hug the ground when cool Operational Level Training Response:l Containers may BLEVE or explode when exposed to fire RELEASE, NO FIRE:l Corrosive to metals l Stop the release if you can do it safely from a distanceAwareness and Operational Level Training l DO NOT PUT WATER ON LIQUID AMMONIAResponse: l Prevent material and runoff from entering sewers andl Do not put yourself in danger by entering a contaminated waterways if it can be done safely well ahead of the release area to rescue a victim l Use large amounts of water well away from the release tol Stay upwind and uphill disperse vapors - contain runoffl Determine the extent of the problem l Ventilate confined area if it can be done without placingl Isolate the area of release or fire and deny entry personnel at riskl Evacuate or shelter in place the immediate area and FIRE: downwind for a large release l Material does not easily burn; fight surrounding fire with anl For containers exposed to fire evacuate the area in all agent appropriate for the burning material directions because of the risk of BLEVE or explosion l If material is not leaking, cool exposed containers withl Notify local health and fire officials and pollution control large quantities of water from unattended equipment or agencies remove intact containers if it can be done safelyl If material or contaminated runoff enters waterways, notify l If cooling streams are ineffective (venting sound increases downstream users of potentially contaminated water in volume and pitch, tank discolors or shows any signs of deforming), withdraw immediately to a secure location First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl Frostbite - warm injured area in very warm waterl Toxic effects may be delayedl For skin burns decontaminate with water and apply a clean dry dressing CAS: 7664-41-774
  • 78. AMMONIUM BENZOATE 1 NA 9080 2 0 Other Names: Vulnoc ABHazards: Description:l Irritating to skin, eyes, nose and lungs l Colorless solidl Container may explode when exposed to fire l Odorlessl Combustion or decomposition products upon heating l Sinks in water and is moderately soluble in water include toxic nitrogen oxides l FlammableAwareness and Operational Level Training Operational Level Training Response:Response: RELEASE, NO FIRE:l Stay upwind l Cover material to protect from wind, rain or sprayl Determine the extent of the problem l Prevent contaminated runoff from entering sewers andl Isolate the area of release or fire and deny entry waterways if it can be done safely well ahead of the releasel For container exposed to fire evacuate the area in all FIRE: directions because of the risk of explosion l Material does not easily burn; fight surrounding fire with anl Notify local health and fire officials and pollution control agent appropriate for the burning material agencies l Cool exposed containers with large quantities of waterl If material or contaminated runoff enters waterways, notify from unattended equipment or remove intact containers if downstream users of potentially contaminated water it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attention CAS: 1863-63-4 75
  • 79. AMMONIUM CARBAMATE 1 NA 9083 1 1 Other Names: Ammonium aminoformate Carbamic acid, ammonium saltHazards: Description:l Irritating to skin, eyes, nose and lungs l White crystalsl Container may explode when exposed to fire l Ammonia-like smelll Combustion and decomposition products upon heating l Soluble in water include toxic nitrogen oxides and ammonia l FlammableAwareness and Operational Level Training l Slowly releases ammonia upon contact with airResponse: Operational Level Training Response:l Stay upwind and uphill RELEASE, NO FIRE:l Determine the extent of the problem l Cover material to protect from wind, rain or sprayl Isolate the area of release or fire and deny entry l Prevent material and runoff from entering sewers andl Notify local health and fire officials and pollution control waterways if it can be done safely well ahead of the release agencies l Ventilate confined area if it can be done without placingl If material or contaminated runoff enters waterways, notify personnel at risk downstream users of potentially contaminated water FIRE: l Material does not easily burn; fight surrounding fire with an agent appropriate for the burning material l Cool exposed containers with large quantities of water from unattended equipment or remove intact containers if it can be done safely l If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid:l Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attention CAS: 1111-78-076
  • 80. AMMONIUM HYDROXIDE 1 UN 2672 (10 to 35% Ammonia in water) 2 0 UN 2073 (35 to 50% Ammonia in water) Shipping Name: Ammonia Solutions Other Names: Ammonia monohydrate Ammonia water Ammonia solution Aqueous ammoniaHazards: Description:l Severely irritating to skin, eyes, nose and lungs; skin and l Colorless to milky white colored liquid eye contact can cause severe burns and blindness l Ammonia-like odorl Fire fighting gear (including SCBA) does not provide l Soluble in water adequate protection. If exposure occurs, remove and l Flammable isolate gear immediately and thoroughly decontaminate l Vapors are lighter than air but may hug the ground when personnel cooll May burn or explode in closed spaces (e.g., tanks, Operational Level Training Response: sewers, buildings) RELEASE, NO FIRE:l Decomposes upon heating to produce toxic ammonia and l Stop the release if it can be done safely from a distance nitrogen oxide gases l Prevent material and runoff from entering sewers andl Vapors are lighter than air but may hug the ground when waterways if it can be done safely well ahead of the release cool l Use large amounts of water to disperse vapors - containAwareness and Operational Level Training runoffResponse: l Ventilate confined area if it can be done without placingl Do not put yourself in danger by entering a contaminated personnel at risk area to rescue a victim FIRE:l Stay upwind and uphill l Material does not easily burn; fight surrounding fire with anl Determine the extent of the problem agent appropriate for the burning materiall Isolate the area of release or fire and deny entry l Cool exposed containers with large quantities of waterl Evacuate or shelter in place the immediate area and from unattended equipment or remove intact containers if downwind for a large release it can be done safelyl For container exposed to fire evacuate the area in all l If cooling streams are ineffective (unvented container directions because of the risk of BLEVE distorts, bulges or shows any other sign of expanding),l Notify local health and fire officials and pollution control withdraw immediately to a secure location agenciesl If material or contaminated runoff enters waterways, notify downstream users of potentially contaminated water First Aid:l Do not put yourself in danger by entering a contaminated area to rescue a victiml Provide Basic Life Support/CPR as neededl Decontaminate the victim as follows: t Inhalation - remove the victim to fresh air and give oxygen if available t Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes t Eye - rinse eyes with large volumes of water or saline for 15 minutes t Swallowed - do not make the victim vomitl Seek medical attentionl For skin burns decontaminate with water and apply a clean dry dressing CAS: 1336-21-6 77
  • 81. AMMONIUM PERCHLORATE 0 UN 1442 1 4 UN 0402 OX Shipping Name: Ammonium perchlorate PA Other Names: Ammonium perchlorate high explosive NF Ammonium perchlorate oxidizerWARNING! l HIGHLY EXPLOSIVE! HEAT, FRICTION OR SHOCK MAY CAUSE MATERIAL TO EXPLODE! l STRONG OXIDIZER! WILL INCREASE THE INTENSITY OF A FIRE; MAY CAUSE FIRE UPON CONTACT WITH COMBUSTIBLES!Hazards: Description:l Irritating to skin and eyes l White solidl Decomposition products upon heating include toxic l Odorless nitrogen oxides and ammonia l Sinks in water and dissolves slowly in waterAwareness and Operational Level Training l Nonflammable but may cause combustibles to igniteResponse: Operational Level Training Response:l Do not put yourself in danger by entering a contaminated RELEASE, NO FIRE: area to rescue a victim l Keep released material wetl Stay upwind l Prevent material and runoff from entering sewers andl Determine the extent of the problem waterways if it can be done safely well ahead of the releasel BACK OFF! - Isolate a wide area around the release or FIRE: fire deny entry and call for expert help l Approach fire with extreme caution; consider letting firel For container exposed to fire evacuate a wide area in all burn directions because of the high risk of explosion l Material does not burn, fight surrounding fire with an agentl Notify local health and fire officials and pollution control appropriate for the material burning agencies l Cool exposed containers with large quantities of waterl If material or contaminated runoff enters waterways, notify from unattended equipment or remove intact containers if downstream users of potentially contaminated water it can be done safely