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01 crystal structure of solids

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  • 1. CHAPTER 1 The Crystal Structure of Solids 2009/2010 1Department of Microelectronics & Computer Engineering
  • 2. Semiconductor Materials • possible elements for making Group Group Group III IV V semiconductor materials B •Si most well known semiconductor. C Al C P and Ge can also be semiconductors. Ga Si As In Ge Sb • Other possibilities combinations of A portion of the periodic table III and V group. Eg. GaAs 2009/2010 2Department of Microelectronics & Computer Engineering
  • 3. Elemental and Compound Semiconductors Binary Semiconductor ( 2 elements): Si1-xGex, SiC Ternary Semiconductor (3 elements): AlxGa1-xP Quaternary Semiconductor (4 elements) : AlGaAsP•Single element  elemental semiconductor•More than one element  compound semiconductor Properties of comp semi can be controlled by changing the concn of the elements 2009/2010 3Department of Microelectronics & Computer Engineering
  • 4. GaN and ZnO are recently discovered semiconductor materials which are promising materials for laser diodes (blue light). These laser diodes are used in blue-ray DVD recorders. Blue light having smaller wavelength helps in lowering the resolution and increasing the packing density of bits. A light emitting diode 2009/2010 4Department of Microelectronics & Computer Engineering
  • 5. Types of Solids Grain Grain- boundaryThree general types of solids : (a) amorphous, (b) polycrystalline and(c) crystalline 2009/2010 5 Department of Microelectronics & Computer Engineering
  • 6. Amorphous Si Advantages• Low temperature deposition (~ 250°C)• Large Area deposition possible at lowcost Disadvantages • Low conductivity • Cannot be used for High speed circuits 2009/2010 6 Department of Microelectronics & Computer Engineering
  • 7. Uses of amorphous-Si Solar cells Thin Film Transistors for LCDsEfficiency: 6-10% Mobility: 1cm2/Vs 2009/2010 7 Department of Microelectronics & Computer Engineering
  • 8. polycrystalline-SiGate for MOSFETsSemiconductor layer for TFTs (recentdevelopment)Polycrystalline silicon has higher conductivity as compared toamorphous silicon. 2009/2010 8Department of Microelectronics & Computer Engineering
  • 9. Crystal In a very broad sense crystal means something that repeats So even a wall paper with a repeating pattern is a crystal !! 2009/2010 9Department of Microelectronics & Computer Engineering
  • 10. Lattice and unit cell Lattice : A regular periodic arrangement of points in space as in the arrangement of atoms or molecules in a crystal. Each point in the lattice is a lattice point. It can be an atom, a group of atoms, an ion or a molecule. Unit cell : A small volume of a crystal that can be used to reproduce the entire crystal Lattice pointTwo dimensional representation of Two dimensional representation of a singlea single crystal lattice crystal lattice with various possible unit cells 2009/2010 10 Department of Microelectronics & Computer Engineering
  • 11. The relationship between the cell and the lattice is characterized by threevectors a, b and c. These vectors need not to be perpendicular to eachother and need not to be of the same length. Every equivalent lattice pointin the crystal can be found using the equation – r = pa + qb + sc (1.1) A generalized primitive unit cell A PRIMITIVE CELL is the Smallest unit cell! 2009/2010 11 Department of Microelectronics & Computer Engineering
  • 12. Basic Crystal StructuresThe easiest 3-D lattice to work with is the simple cubic lattice (SCC) which haslattice points on all the corners of a cube. The Cubic (Isometric) crystal system ischaracterized by its total symmetry. It has three crystallographic axes that are allperpendicular to each other and equal in length. The cubic system has one latticepoint on each of the cubes four corners. Simple Body centered Face centered cubic cubic cubic Different possible cubic lattices 12 2009/2010 Department of Microelectronics & Computer Engineering
  • 13. Lattice constant 2009/2010 13Department of Microelectronics & Computer Engineering
  • 14. Other crystal structures Crystal structures which are combinations of these are also possible. 2009/2010 13Department of Microelectronics & Computer Engineering
  • 15. FCC FCC lattice structure has high packing density See Video and Quiz question on packing density. Al, Cu, Ni, Pd, Ag, Ce, Pt, Au, Pb... 2009/2010 14Department of Microelectronics & Computer Engineering
  • 16. BCC CsClAlso Na, K, V, Cr, Fe, Rb, Nb, Mo, Cs, Ba, Eu, Ta etc. have BCC lattice structure. SCC is the most spacious crystal structure with least packing density. So nature does not prefer SCC it !! Almost no naturally occurring crystal has SCC structure. 2009/2010 15 Department of Microelectronics & Computer Engineering
  • 17. Atomium in Brussels has BCC structure !! 2009/2010 16Department of Microelectronics & Computer Engineering
  • 18. Hexagonal structureThe Hexagonal crystal system has four crystallographic axes consisting of threeequal horizontal or equatorial (a, b, and d) axes at 120º, and one vertical (c) axisthat is perpendicular to the other three. Hexagonal structure is characterized byclose packing density. Quartz Snow flake 2009/2010 17 Department of Microelectronics & Computer Engineering
  • 19. Diamond structure 2009/2010 18 Department of Microelectronics & Computer Engineering
  • 20. The Diamond Structure The tetrahedral structure of closest neighbors in the diamond latticeThe tetrahedral structure is basically a body-centered cubic with four of the corneratoms missing. Every atom in the tetrahedral structure has four nearest neighborswith equal distance. This is the basic building block of the diamond lattice. 2009/2010 19 Department of Microelectronics & Computer Engineering
  • 21. The diamond structure Bottom half (a) and top half (b) portions of diamond lattice. 2009/2010 20Department of Microelectronics & Computer Engineering
  • 22. The Diamond Structure The diamond structure can also be interpreted as two Interpenetrating FCCs. See video in course material. 2009/2010 21Department of Microelectronics & Computer Engineering
  • 23. Zincblend structure in GaAs Covalent + Ionic bondingZincblend structure is similar to diamond structure, but atoms inpenetrating FCC are different. 2009/2010 22 Department of Microelectronics & Computer Engineering
  • 24. Crystal plane and Miller IndicesSurface or plane through the crystal can be described by the intercepts ofthe plane along the a, b and c axes used for the lattice. Reciprocal of theseintercepts are called the miller indices.Three lattice planes – (a) (100) plane, (b) (110) plane and (c) (111) plane 2009/2010 23 Department of Microelectronics & Computer Engineering
  • 25. Miller indicesThe plane (a) is parallel to the b and c axes so the intercepts are given as 1,infinite and infinite. Taking reciprocal, we obtain Miller indices as (1,0,0), sothe plane is referred to as (100) plane. Any plane parallel to this isequivalent and is referred to as the (100) plane. 2009/2010 24 Department of Microelectronics & Computer Engineering
  • 26. For an example on how to find the Miller indices of a plane, refer to example 1.2 in thereference book.For an example on how to find the surface density of atoms on a particular crystal plane,refer to example 1.3 in the reference book. 2009/2010 25 Department of Microelectronics & Computer Engineering
  • 27. Atomic Bonding Covalent bonding Strong Ionic bonding Metallic bonding Weak Van der Waals bonding 2009/2010 26Department of Microelectronics & Computer Engineering
  • 28. Covalent bondingRepresentation of (a) hydrogen valenceelectrons and (b) covalent bonding in hydrogenmolecule Representation of (a) silicon valence electrons and (b) covalent bonding in the silicon crystal 2009/2010 27 Department of Microelectronics & Computer Engineering
  • 29. K L M N 6 C 1s2 2s22p2 14 Si 1s2 2s22p6 3s23p2 32 Ge 1s2 2s22p6 3s23p63d10 4s24p2 Atomic structure for C, Si and GeSilicon has only 2 unpaired electrons. Then why does Si form 4covalent bonds? 2009/2010Department of Microelectronics & Computer Engineering
  • 30. HybridizationPromotion of one electron from s-orbital to p-orbital to form four orbitals ofequal energy is hybridisation. This happens so that all available energy states inthe outermost shell are occupied. Else it will lead to instability.With electrons in two different kinds of orbitals, we cannot get four identicalcovalent bonds. Hybridisation results in four similar electronis and henceideantical bonds. 2009/2010 29 Department of Microelectronics & Computer Engineering
  • 31. Shape of s & p orbitalsin n=3 shell beforehybridisation. 2009/2010 30 Department of Microelectronics & Computer Engineering
  • 32. Valence electron cloudOrbitals in n=3 shell after hybridisation The silicon atom in its crystalline surroundings has a similarly shaped electron cloud 2009/2010 31 Department of Microelectronics & Computer Engineering
  • 33. Similar hybridisation phenomenon happens in carbon. Above figure isafter bonding with Hydrogen in CH4. 2009/2010 32 Department of Microelectronics & Computer Engineering
  • 34. Metallic bondingSodium has the electronic structure 1s22s22p63s1. When sodium atoms come together, the electron inthe 3s atomic orbital of one sodium atom shares space with the corresponding electron on aneighbouring atom to form a molecular orbital - in much the same sort of way that a covalent bond isformed.The difference, however, is that each sodium atom is being touched by eight other sodium atoms(BCC structure) and the sharing occurs between the central atom and the 3s orbitals on all of theeight other atoms. And each of these eight is in turn being touched by eight other sodium atoms andso on. So electrons are shared over a large distance and this makes flow of electrons easy.This same reason also makes metals malleable !! 2009/2010 33 Department of Microelectronics & Computer Engineering
  • 35. Van der Waals bond Effective center of the positive charge is not the same as the negative one, e.g., HF molecule. The electric dipole interacts with the other dipole. Inert Gas Elements – He, Ne, Ar, Kr, Xe FCC 2009/2010 34Department of Microelectronics & Computer Engineering
  • 36. Hydrogen bonding Van der Waal’s bonds in water 2009/2010 35Department of Microelectronics & Computer Engineering
  • 37. Graphene 3D crystal 2D crystalDiamond is one of the hardest material in nature because covalent bonding is verystrong. In graphite, bonding between 2 graphene layers is weak Van der Waals bonding.This makes graphite very soft and graphene layers can be easily separated.Recently a single layer of graphene has been found to be a promising semiconductormaterial. 2009/2010 36 Department of Microelectronics & Computer Engineering
  • 38. Carbon nanotube (1D crystal) Carbon nano-tubes are formed by rolling a single layer of graphene. These are used to make quantum devices !! 2009/2010 37 Department of Microelectronics & Computer Engineering
  • 39. Ionic Bond • Bond between two oppositely charged ions. 2009/2010 38Department of Microelectronics & Computer Engineering
  • 40. Imperfections in solidsLattice imperfection is any deviation from perfect periodic arrangement of latticepoints. Point defects can be in the form of vacancy (missing atom), substitutionalimpurity (atom replaced by another atom) or interstitial impurity (additionalimpurity not at lattice point) Substitutional impurity Interstitial or a vacancy impurity Point defects 2009/2010 39 Department of Microelectronics & Computer Engineering
  • 41. Line Defects Edge dislocation is a type of line defect. 2009/2010 40Department of Microelectronics & Computer Engineering
  • 42. Plane & Volume Defects Precipitates are a type of volume defectGrain boundaries aretype of plane defect 2009/2010 41 Department of Microelectronics & Computer Engineering
  • 43. Crystalline defects in semiconductors.Defect Type ExamplesPoint Vacancies, interstitials, impurity atomsLine DislocationsPlane Stacking faults, twins and grain boundariesVolume Precipitates and voids 2009/2010 42 Department of Microelectronics & Computer Engineering
  • 44. Growth of Semiconductor Materials• Growth from Melt• Epitaxial growth 2009/2010 43 Department of Microelectronics & Computer Engineering
  • 45. Growth from meltCzochralski method Silicon ingot from czochralski process Larger diameter , impurity from crucible 2009/2010 44 Department of Microelectronics & Computer Engineering
  • 46. µ-Czochralski (Grain-Filter) Process with Excimer-Laser Excimer-laser Melt SolidRemnant solid at the Grains formed afterbottom crystallisation.acts as a seed 3µmInitially holes which act as seeds are formed by photolithography. Thenexcimer laser is used to melt silicon. Square shaped grains are formed atthe seed locations. 2009/2010 45 Department of Microelectronics & Computer Engineering
  • 47. Epitaxial growth Single-crystalline layer growth on a single-crystalline substrate with the same crystal structure Homo-epitaxy Hetero-epitaxy Si on Si Si on SiGe, AlGaAs on GaAs by means of Chemical vapor deposition (CVD) Liquid Phase Epitaxy (LPE) Molecular Beam Epitaxy (MBE) 2009/2010 46 Department of Microelectronics & Computer Engineering
  • 48. Chemical Vapour Deposition (CVD) Used mainly for silicon but also for SiGe, GaN Good for production, safety consideration 2009/2010 47Department of Microelectronics & Computer Engineering
  • 49. Liquid Phase Epitaxy (LPE) Melt Heater Substrate Used for GaAs, InP, HgCdTe High quality compound semiconductors, difficult to monitor 2009/2010 48Department of Microelectronics & Computer Engineering
  • 50. Molecular BeamEpitaxy (MBE)Physical process Used for GaAs, GaN Precise growth monitor, high quality (compound) semiconductor layers, slow growth rate 2009/2010 49 Department of Microelectronics & Computer Engineering
  • 51. Floating zone method (for purifying silicon ingot) Floating zone method relies on the segregation co-efficient. For this process to be used for purification this co- efficient should be less than 1. 2009/2010 50 Department of Microelectronics & Computer Engineering
  • 52. Segregation coefficient (k0) Impurity concentration ratio between the solid and liquid Poly Liquid Single-crystalline 2009/2010 51 Department of Microelectronics & Computer Engineering
  • 53. Ko D (x 10-4 cm2/s) B 0.8 2.4 Al 0.002 7.0 Ga 0.008 4.8 In 0.0004 6.9 C 0.07 2 P 0.35 2.3 As 0.3 3.3 Sb 0.023 1.5 O 1.40 3.3Oxygen cannot be removed by floating zone method because itssegregation coefficient is more than 1. The diffusion co-efficient (D)determines the speed of purification. 2009/2010 52 Department of Microelectronics & Computer Engineering
  • 54. Si wafer fabrication SiO2 Metallic Si Pure trichlorosilane Si 3SiCl4 2H2 4SiHCl3 SiC SiO2 Si SiO CO Pure poly-Si 99.999999999 Wafer Single-crystalline Si 2009/2010 53 Department of Microelectronics & Computer Engineering