Green Surfactants Powerpoint New Italy


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Green Surfactants Powerpoint New Italy

  1. 1. Green Surfactant Solutions for Personal Care
  2. 2. Facts About : Colonial Chemical <ul><li>20-year old surfactant company </li></ul><ul><li>Manufacture all of our own products </li></ul><ul><li>Sell and market our products through independent sales representatives and independent distributors worldwide </li></ul><ul><li>All about GREEN , safe, innovative surfactants </li></ul><ul><li>Strive to work in partnership with our sales reps and customers to provide for all surfactant needs and especially GREEN surfactant needs </li></ul>
  3. 3. Colonial’s Strategy <ul><li>Create a series of surfactants from a platform that will: </li></ul><ul><ul><li>Replace petroleum derived raw materials. </li></ul></ul><ul><ul><li>Use renewable resources as raw materials. </li></ul></ul><ul><ul><li>Use naturally derived raw materials. </li></ul></ul><ul><li>Develop safe materials for personal care formulations. </li></ul><ul><li>Develop mild materials for personal care formulations. </li></ul><ul><li>Develop products that are safe for the environment. </li></ul>
  4. 4. Facts About : What Consumers Want <ul><li>Most of us adults view our skin as sensitive. </li></ul><ul><li>Most consumers prefer personal care products that offer mildness; natural ingredients. </li></ul><ul><li>Now, with the green movement pressing forward, consumers want a green and sustainable profile in their personal care products. </li></ul>
  5. 5. Negative Views: Straight From the Marketplace <ul><li>1,4-Dioxane </li></ul><ul><li>Ethylene Oxide </li></ul><ul><li>Sulfates </li></ul><ul><li>Propylene Glycol </li></ul><ul><li>PEG’s </li></ul><ul><li>DEA </li></ul><ul><li>MEA </li></ul><ul><li>Parabens </li></ul><ul><li>Kathon </li></ul><ul><li>Formaldehyde </li></ul>
  6. 6. Positive Views : Straight From the Marketplace <ul><li>Organic </li></ul><ul><li>Naturally Derived </li></ul><ul><li>Preservative Free </li></ul><ul><li>Nourishing </li></ul><ul><li>Biodegradable </li></ul><ul><li>ECO-Friendly Products </li></ul><ul><li>Green Products </li></ul><ul><li>Sustainable Products </li></ul><ul><li>From Renewable Resources </li></ul>
  7. 7. The New AND Ever-Changing Consumer: <ul><li>Shows more interest in what they are putting in their hair and on their skin. </li></ul><ul><li>Reads labels. </li></ul><ul><li>Listens to cosmetologists. </li></ul><ul><li>Visits spas. </li></ul><ul><li>Watches investigative reports on TV. </li></ul><ul><li>Uses the internet for everything including how to find information on ingredients in shampoo, for instance: </li></ul><ul><li>Environmental Working Group, http:// / </li></ul><ul><li>Needs products manufactured by those who can and will use labeling to differentiate their products. </li></ul><ul><li>Has grown the popularity of health food stores and “healthy” grocery stores. </li></ul>
  8. 8. What is a Naturally Derived Surfactant? <ul><li>Colonial Definition: </li></ul><ul><li>The source of the major raw material and major components in the surfactant are from natural, plant derived sources. </li></ul><ul><li>The surfactants are readily biodegradable causing no harm to the environment. </li></ul><ul><li>The surfactants are comparable in performance to those in the past. </li></ul>
  9. 9. Reasons to Use Natural Surfactants: <ul><li>Greater consumer acceptance </li></ul><ul><li>Natural products provide formulations with vitamins and healing components from plants </li></ul><ul><li>Excellent toxicity profiles </li></ul><ul><li>Less damaging to hair, eyes and skin </li></ul><ul><li>More stable raw material pricing </li></ul><ul><li>The raw material source is renewable </li></ul><ul><li>Safer for the environment </li></ul>
  10. 10. What does Colonial Offer? <ul><li>Ingredients for your next generation of products. </li></ul><ul><li>Ingredients that have great marketing attributes. </li></ul><ul><li>Ingredients that are much safer for consumers to use. </li></ul><ul><li>Ingredients that are going to allow your products to perform better. </li></ul><ul><li>Ingredients that meet the consumer demand for “natural”. </li></ul><ul><li>Ingredients that are safe for the environment. </li></ul>
  11. 11. <ul><li>Naturally derived surfactants from: </li></ul><ul><ul><li>Coconuts </li></ul></ul><ul><ul><li>Corn </li></ul></ul><ul><ul><li>Avocados </li></ul></ul><ul><ul><li>Olives </li></ul></ul><ul><ul><li>Cocoa Beans </li></ul></ul><ul><ul><li>Sunflowers </li></ul></ul>What does Colonial Offer?
  12. 12. <ul><li>Alkylpolyglucoside surfactants are synthesized by reacting corn starch glucose with a coconut oil derived alcohol by the Fischer synthesis. Alkyl polyglucosides are nonionic in nature, nitrogen-free and ethylene oxide-free and dioxane free. This discussion is about Colonial’s patented work on derivatization of APG’s for use as primary surfactants in personal care application. </li></ul><ul><li>APG’s themselves are known as a natural choice for personal care products because of the level of detergency, mildness, foaming, low color, and no nitrosamine issues. </li></ul><ul><li>At Colonial we take these very desirable starting materials and derivatize them to give them greater functionality and application in personal care formulations. The resulting derivatives have a broader range of application, easier to formulate, are milder and generally have more desirable properties than that of the starting nonionic APG. </li></ul>Green Surfactant Solutions
  13. 13. Green Surfactant Solutions <ul><li>Our starting point: </li></ul><ul><li>Alkyl Poly Glucoside </li></ul>
  14. 14. Poly Suga ® Product Line
  15. 15. What We Do at Colonial <ul><li>Poly APG - average of 11 repeat units. The Poly APG made by Colonial has a molecular weight of approximately 15,000 </li></ul>
  16. 16. Colonial Poly Suga ® Products <ul><li>* Derived from Suga ® , Alkyl Polyglucosides * </li></ul><ul><ul><li>Poly Suga ® Quat – polymeric alkyl polyglucoside cationic conditioners </li></ul></ul><ul><ul><li>Poly Suga ® Phos – polymeric alkyl polyglucoside anionic surfactants </li></ul></ul><ul><ul><li>Poly Suga ® Nate – polymeric alkyl polyglucoside sulfonates </li></ul></ul><ul><ul><li>Poly Suga ® Betaine – polymeric alkyl polyglucoside betaines </li></ul></ul><ul><ul><li>Poly Suga ® Mate – polymeric alkyl polyglucosides sulfosuccinate </li></ul></ul>
  17. 17. The Essence of Poly Suga ® Surfactants <ul><li>It is all about irritation and how </li></ul><ul><li>Poly Suga ® Surfactants compare to other well known surfactants used in the formulation of personal care products. </li></ul>
  18. 18. Poly Suga ® Quat Quaternized Polymeric Alkylpolyglucosides Global Acceptance
  19. 19. Poly Suga ® Quat Structure
  20. 20. Facts About Products Containing Poly Suga  Quat <ul><li>1,4-Dioxane Free </li></ul><ul><li>Mild for eyes and skin </li></ul><ul><li>Conditions hair but much milder than traditional quats like SAC and CTAC. </li></ul><ul><li>Conditions but does not build up on hair </li></ul><ul><li>Not harmful to the environment </li></ul><ul><li>Do not contain preservatives when shipped to you </li></ul><ul><li>Can be used for formulating preservative free or reducing reliance on commonly used preservatives products. </li></ul>
  21. 21. TYPICAL PROPERTIES Poly Suga ® Quat TM-1218P TM-8610P L-1010P L-1210P S-1010P S-1210P Color, Gardner < 1 < 1 1 < 1 < 1 < 1 Activity, % 29.7 31.8 29.9 28.5 28.8 29.4 Viscosity (as is), cps 1338 35 55 76 23 9400 Odor pH (10% aqueous) 7.00 7.25 7.56 7.59 7.45 7.52 Appearance, 10% aqueous Clear Clear Clear Clear Clear Clear
  22. 22. Poly Suga ® Quat TM-1218P TM-8610P L-1010P L-1210P S-1010P S-1210P Immed. 125 180 165 170 165 145 1 minute 115 160 155 160 150 135 5 minutes 110 155 145 155 140 130 Draves Wetting (1% active), seconds 7.4 3.6 5.6 10.6 12.5 18.8
  23. 23. Poly Suga ® Phos Naturally Derived Anionic Surfactants Global Acceptance
  24. 24. Poly Suga ® Phos Structure
  25. 25. <ul><li>Naturally derived, from plants </li></ul><ul><li>Do not strip hair and scalp; gently clean </li></ul><ul><li>Made from renewable resources </li></ul><ul><li>Bring plant nutrients to the scalp </li></ul><ul><li>Not harmful to the environment </li></ul><ul><li>Do not sting or irritate eyes or skin </li></ul><ul><li>Proven to reduce stripping of color from hair </li></ul><ul><li>Do not contain preservatives when shipped to you </li></ul>Facts About Products Containing Poly Suga  Phos
  26. 26. TYPICAL PROPERTIES Poly Suga ® Phos 6.8 Immediate Draves Wetting (1 % active), seconds 100 140 5 minutes 115 145 1 minute 135 165 Immediate Ross-Miles Foam Height (1%, 25C, tap water), mm 7.71 7.75 pH (10% aqueous) mild, fatty alcohol mild, fatty alcohol Odor 4250 20 Viscosity (cps), 25°C 38.6 38.8 Activity % 1 <1 Color, Gardner (ASTM D1544-98) Poly Suga ® Phos 1200P Poly Suga ® Phos 1000P
  27. 27. <ul><li>Application Possibilities: </li></ul><ul><ul><li>Hair Relaxers </li></ul></ul><ul><ul><ul><li>High pH conditions with low foam, usually made as a viscous crème </li></ul></ul></ul><ul><ul><ul><li>Poly Suga ® Phos 1000P and 1200P as emulsifiers and anti-irritants </li></ul></ul></ul><ul><ul><li>Depilatories </li></ul></ul><ul><ul><li>AHA and BHA products </li></ul></ul><ul><ul><ul><li>Low pH Conditions with high foam </li></ul></ul></ul><ul><ul><ul><li>Salicylic Acid for Acne Scrubs </li></ul></ul></ul><ul><ul><ul><li>Exfoliators with fruit acids </li></ul></ul></ul><ul><ul><ul><li>Shampoos for post-relaxer treatment </li></ul></ul></ul><ul><ul><li>Body Wash </li></ul></ul><ul><ul><li>Makeup Removal </li></ul></ul><ul><ul><li>Diaper Wipes </li></ul></ul><ul><ul><li>Reduced Color Loss Shampoos </li></ul></ul>Poly Suga ® Phos Naturally Derived Anionic Surfactants
  28. 29. Poly Suga ® Nate Poly - APG - Sulfonate A Primary Surfactant Positioned for Global Acceptance
  29. 30. Poly Suga ® Nate Structure
  30. 31. <ul><li>Does not strip hair and scalp </li></ul><ul><li>Gently cleans </li></ul><ul><li>Made from renewable, sustainable resources </li></ul><ul><li>Contains no preservatives when shipped to you </li></ul><ul><li>Does not sting or irritate eyes or skin </li></ul>Facts About Products Containing Poly Suga ® Nate
  31. 32. Poly Suga ® Nate Sulfonated Alkyl Glucosides vs. Alpha Olefin Sulfonate 100P 160P Color, Gardner (ASTM D1544-98) < 1 < 1 Activity, % 40.5 38.6 Viscosity (cps), 25°C 25 12,500 Odor mild, fatty alcohol mild, fatty alcohol pH (10% aq) 7.0 7.3
  32. 33. Poly Suga ® Nate Sulfonated Alkyl Glucosides vs. Alpha Olefin Sulfonate 100P 160P Ross Miles Foam (1%, 25C, tap water), mm Immed. 165 150 1 min. 155 125 5 min. 150 125 Draves Wetting (1 % active), seconds 5.0 7.3
  33. 34. Poly Suga ® Nate <ul><li>Application Possibilities: </li></ul><ul><ul><li>Sulfate-Free Shampoos </li></ul></ul><ul><ul><li>Low & High pH Shampoos </li></ul></ul><ul><ul><li>Bath Gels </li></ul></ul><ul><ul><li>Body Washes </li></ul></ul><ul><ul><li>Facial Cleansers </li></ul></ul><ul><ul><li>Baby Cleansing Products </li></ul></ul><ul><ul><li>Personal Care Wipes </li></ul></ul><ul><ul><li>Reduced Color Loss Shampoos </li></ul></ul>
  34. 36. Poly Suga ® Betaine Naturally Derived Extremely Mild Betaine
  35. 37. Poly Suga ® Betaine Structure
  36. 38. <ul><li>Contains no amidopropyl linkage </li></ul><ul><li>Much milder than traditional betaines </li></ul><ul><li>Made from renewable, sustainable resources </li></ul><ul><li>Contains no preservatives when shipped to you </li></ul><ul><li>Does not sting or irritate eyes or skin </li></ul><ul><li>Provides long lasting foam </li></ul><ul><li>1,4-Dioxane free, no ethylene oxide </li></ul><ul><li>Can be used at higher levels than traditional betaine </li></ul>Facts About Products Containing Poly Suga  Betaine
  37. 39. POLY SUGA ® BETAINE TYPICAL PROPERTIES   Poly Suga ® Betaine C Poly Suga ® Betaine L Appearance Clear, amber liquid Clear, amber liquid Color, Gardner 1 2 Activity, % 40 40 pH (10% aqueous) 7 7   Ross-Miles Foam Height (1% active), mm Immediate 180 135 1 minute 165 115 5 minutes 160 110   Draves Wetting (1 % active), seconds   5 minutes 3.3 5.7
  39. 41. Poly Suga ® Mate Naturally Derived Extremely Mild Surfactant Foaming and Wetting Properties
  40. 42. Poly Suga ® Mate Structure
  41. 43. <ul><li>Mild to eyes and skin </li></ul><ul><li>Made from renewable, sustainable resources </li></ul><ul><li>Contains no preservatives when shipped to you </li></ul><ul><li>Provides quick flash foam </li></ul><ul><li>Sulfate-free and Sulfonate-free </li></ul><ul><li>No 1,4-Dioxane </li></ul><ul><li>No Ethylene Oxide </li></ul>Facts About Products Containing Poly Suga  Mate
  42. 44. TYPICAL PROPERTIES Poly Suga ® Mate 6.0 3.9 Draves Wetting (1% active), seconds 115 165 5 minutes 120 170 1 minute 140 190 Immediate Ross-Miles Foam Height (1% active), mm 6.0 – 8.0 6.0 – 8.0 pH (10% aqueous) 37.0 – 39.0 37.0 – 39.0 & Solids 3 max. 3 max. Color, Gardner ’98 Clear Liquid Clear Liquid Appearance Poly Suga ® Mate L Poly Suga ® Mate D
  43. 45. Poly Suga ® Mate <ul><li>Application Possibilities: </li></ul><ul><ul><li>Body Cleansers </li></ul></ul><ul><ul><li>Bubble Bath </li></ul></ul><ul><ul><li>Conditioning Shampoos </li></ul></ul><ul><ul><li>Bath Gels </li></ul></ul><ul><ul><li>Facial Washes </li></ul></ul>
  44. 46. The Breakthrough Technology That is Poly Suga ® <ul><li>In the past, a formulator started with irritating materials and built the formulation to mitigate irritation. Poly Suga ® products allow a formulator to start formulating with low or non-irritating products and build consumer desired aesthetic properties knowing irritation to eyes and skin will not be a problem. This breakthrough allows the formulation of low or non-irritating, shampoos, body washes, bath gels, and personal cleansing products. </li></ul>
  45. 49. Why Poly Suga ® Products? <ul><li>Naturally derived </li></ul><ul><li>Sustainable raw material base </li></ul><ul><li>Safe for humans </li></ul><ul><li>Safe for the environment </li></ul><ul><li>No Ethylene Oxide </li></ul><ul><li>No 1,4-Dioxane </li></ul><ul><li>Contain no preservatives when shipped to you </li></ul><ul><li>Functional in a variety of formulations </li></ul><ul><li>They provide what consumers want </li></ul>
  46. 50. WWW.GREENSTARPRODUCTS.ORG <ul><li>Developed by industry professionals </li></ul><ul><li>Rating of the “naturalness” of a product </li></ul><ul><li>Can be used by anyone to rate an ingredient </li></ul><ul><li>Can be used to rate a total formulation </li></ul><ul><li>Is non-commercial </li></ul><ul><li>It’s FREE! </li></ul>
  47. 53. GREEN STAR RATINGS CONTINUED Product Rating Poly Suga ® Betaine L 5.68 Poly Suga ® Betaine C 5.56 Poly Suga ® Nate 100P 6.50 Poly Suga ® Nate 160P 6.74 Poly Suga ® Quat S-1210P 7.47 Poly Suga ® Quat L-1010P 7.06 Poly Suga ® Sil C-35P 5.18 Poly Suga ® Sil C-800P 2.43 Cola ® Quat PDQ 5.87 Cola ® Teric LAB 6.34
  48. 54. GREEN STAR RATINGS Product Rating Cola ® Lipid C 4.53 Cola ® Lipid BP 5.19 Cola ® Lipid SAFL 5.20 Cola ® Lipid SUN 5.19 Cola ® Lipid OL 5.19 Cola ® Lipid ST 5.12 Cola ® Lipid RC 5.30 Cola ® Lipid DLO 6.71 Cola ® Lipid GS 5.19 Cola ® Lipid M 4.54 Cola ® Liqid DC 6.16 Cola ® Liqid DO 6.72 Cola ® Liqid DS 6.73 Cola ® Liqid DA 6.71
  49. 55. 1,4-Dioxane <ul><li>Causes adverse health affects </li></ul><ul><ul><li>Liver changes </li></ul></ul><ul><ul><li>Increase in white blood cell count </li></ul></ul><ul><li>Labeled as “carcinogenic contaminant” in suit against Whole Foods, California </li></ul><ul><li>Harmful levels found in multiple brands of children’s bath products </li></ul><ul><li>Myth vs. Fact </li></ul>
  50. 57. California Suit Against Whole Foods for Carcinogen in Body Care Products, with Corporate Puff Response from CEO John Mackey and the Truth from Nutritionist Cheryl Rounds Organic&quot; Megamerchant Waited Til Only After Suit Was Filed to Remove Offending Body Care Products! Time to Dump Your Shares? Santa Fe, New Mexico 7/07/2008 03:44 AM GMT (TransWorldNews) California Suit Against Whole Foods for Carcinogen in Body Care Products By Ronnie Cummins, Founder, Organic Consumers Association, and Prepared here by Stephen Fox, Managing Editor, Santa Fe Sun News California Files Lawsuit Against Whole Foods, Avalon, and Others Whose Products Tested Positive for Carcinogenic 1,4-Dioxane in OCA Study Details are here: OAKLAND, CA - Reacting in part to a study released by the Organic Consumers Association (OCA) in March of this year, but also based on their own testing, the Attorney General of California has filed a major lawsuit against body care household-cleaning product companies whose products recently tested highest for the carcinogenic contaminant 1,4-Dioxane.    
  51. 58. Under California's &quot;Proposition 65&quot; consumer products that contain toxic levels of 1,4 Dioxane must have warning labels stating they may cause cancer.  1,4-Dioxane is typically produced as a byproduct when ingredients are ethoxylated with the petrochemical ethylene oxide, a process which has become standard practice for many cleansing and moisturizing products.   The suit, California v. Avalon Natural Products (manufacturer of the Alba brand), also names Whole Foods Market California (manufacturer of the Whole Foods 365 brand), Beaumont Products (manufacturer of the Citrus Magic brand), and Nutribiotic. It is unclear exactly which products manufactured by the aforementioned companies triggered the lawsuit, but all named companies have sold products that tested close to or in excess of 20 parts per million for 1,4-Dioxane in the OCA study released at the Natural Products Expo in Anaheim, CA in March . Last week OCA sent a letter to the four companies named in the California lawsuit to see if they are planning changes to their labeling or product formulations.  Only one company responded.  In a letter to the OCA, Beaumont Products wrote, &quot;Upon being notified that there was a problem with our product, we verified that the problem existed, then took immediate action.&quot; Beaumont has reformulated their products to remove the problematic ingredient, highlighting their dedication to providing safe products, in contrast to the lack of action taken by the other three companies. )
  52. 59. The AG's complaint  states that California wants, &quot;…preliminary injunctions, permanent injunctions, or other orders prohibiting the defendant(s) from exposing persons within the State of California to 1,4-dioxane without providing clear and reasonable warnings…&quot; The OCA's 1,4-dioxane study elevated the issue of fake 'natural' and 'organic' brands that utilize petrochemicals in their formulas in March, and now we are seeing labeling enforcement on a scale never seen before,&quot; says OCA National Director Ronnie Cummins. &quot;We used an independent laboratory and found that numerous 'natural' and 'organic' brands tested positive for 1,4-Dioxane, a cancer causing contaminant resulting from the petrochemical ethylene oxide being attached to one or more ingredients.&quot;
  53. 60. CANCER-CAUSING CHEMICAL FOUND IN CHILDREN'S BATH PRODUCTS Women’s Shampoos and Body Wash also Contaminated WASHINGTON — A hidden cancer-causing petrochemical has been found in dozens of children’s bath products and adults’ personal care products, at higher than acceptable levels. Laboratory tests released today revealed the presence of 1,4-Dioxane in products such as Hello Kitty Bubble Bath, Huggies Baby Wash, Johnson’s Baby Wash, Scooby-Doo Bubble Bath and Sesame Street Bubble Bath. The tests also found the carcinogen in Clairol Herbal Essences shampoo, Olay Complete Body Wash and many other personal care products. 1,4-Dioxane is a petroleum-derived contaminant considered a probable human carcinogen by the U.S. Environmental Protection Agency and a clear-cut animal carcinogen by the National Toxicology Program. It is also on California’s Proposition 65 list of chemicals known or suspected by the state to cause cancer or birth defects. Because it is a contaminant produced during manufacturing, the FDA does not require it to be listed as an ingredient on product labels.
  54. 61. Points of Interest <ul><li>Colonial’s Poly ® Suga products contain no 1,4-Dioxane. </li></ul><ul><li>Colonial’s Poly ® Suga products are polymer exempt in the EU and UK under REACH regulations. </li></ul>
  55. 62. Summary <ul><li>Green Technology for surfactants: </li></ul><ul><ul><li>Safe </li></ul></ul><ul><ul><li>Natural </li></ul></ul><ul><ul><li>Sustainable </li></ul></ul><ul><li>Colonial is large enough to develop new technology. </li></ul><ul><li>Colonial is small enough to be responsive to customer needs. </li></ul><ul><li>Working with customers through distribution partners is our future. </li></ul>
  56. 63. Colonial Poly Suga ® Products <ul><li>* Derived from Suga ® , Alkyl Polyglucosides * </li></ul><ul><ul><li>Poly Suga ® Quat – polymeric alkyl polyglucoside cationic conditioners </li></ul></ul><ul><ul><li>Poly Suga ® Phos – polymeric alkyl polyglucoside anionic surfactants </li></ul></ul><ul><ul><li>Poly Suga ® Nate – polymeric alkyl polyglucoside sulfonates </li></ul></ul><ul><ul><li>Poly Suga ® Betaine – polymeric alkyl polyglucoside betaines </li></ul></ul><ul><ul><li>Poly Suga ® Mate – polymeric alkyl polyglucosides sulfosuccinate </li></ul></ul>
  57. 64. Thank You for Listening