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Msds l 540 Msds l 540 Document Transcript

  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 1 of 8 Product name: Niax® silicone L-540 1. PRODUCT AND COMPANY IDENTIFICATION Product name: Niax® silicone L-540 Chemical name: Polyalkyleneoxidemethylsiloxane copolymer Use(s): Used in polyurethane foam manufacturing. Supplier: GE Canada 1063 Copperstone Drive Pickering, Ontario L1W 3V8, Canada Manufacturer: GE Silicones 3500 South State Route 2 Friendly, WV 26146, USA Prepared by/For MSDS, Product Product Safety Department Safety, or regulatory inquiries, call: 304-652-8446 or 304-652-8155 Issue date: 2006.06.23 Emergency telephone number: CANUTEC (24 hours) 613-996-6666 2. COMPOSITION / INFORMATION ON INGREDIENTS COMPONENT CAS# %W/W Polyalkylene glycol- WHMIS Non-Haz Trade secret 30.0 - 60.0 % Polyalkyleneoxidemethylsiloxane copolymer-WHMIS- Trade secret 30.0 - 60.0 % Non-Haz Polyalkylene glycol-WHMIS-Non-Haz Trade secret 7.0 - 13.0 % Octamethylcyclotetrasiloxane 556-67-2 0.1 - 0.5 % 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW WARNING! MAY CAUSE EYE IRRITATION. CONTAINS OCTAMETHYLCYCLOTETRASILOXANE WHICH MAY CAUSE REPRODUCTIVE EFFECTS BASED ON ANIMAL DATA.
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 2 of 8 Product name: Niax® silicone L-540 4. FIRST AID MEASURES Swallowing Give water to drink. Obtain medical attention. Skin Remove contaminated clothing. Wash skin with soap and water. Obtain medical attention if discomfort persists. Inhalation Remove to fresh air. Obtain medical attention. Notes to physician There is no specific antidote. Treatment of overexposure should be directed at the control of symptoms and the clinical condition of the patient. 5. FIRE-FIGHTING MEASURES Flash point: 103 °C Flammable limits Lower limit: Not available Upper limit: Not available Hazardous combustion products Burning can produce the following combustion products: Oxides of carbon. Oxides of silicon. Carbon monoxide is highly toxic if inhaled; carbon dioxide in sufficient concentrations can act as an asphyxiant. Acute overexposure to the products of combustion may result in irritation of the respiratory tract. Special fire fighting procedures Do not direct a solid stream of water or foam into hot, burning pools: this may cause frothing and increase fire intensity. Special protective equipment for firefighters Self-contained breathing apparatus. Body covering protective clothing. Extinguishing media Suitable: Large fires: - alcohol-type foam or universal-type foams Small fires: - CO2 - dry chemical Unsuitable: None. Unusual fire and explosion hazards None known.
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 3 of 8 Product name: Niax® silicone L-540 6. ACCIDENTAL RELEASE MEASURES Personal precautions Avoid contact with eyes and skin. Avoid contact with liquid and vapors. Wear suitable protective equipment. Environmental precautions Prevent runoff. Methods for cleaning up Cover with absorbent or contain. Collect for disposal. Observe government regulations. 7. HANDLING AND STORAGE HANDLING Handling precautions Do not swallow. Do not get in eyes, on skin, on clothing. Avoid breathing vapor, aerosol and mist. Use with adequate ventilation. Wash thoroughly after handling. STORAGE Storage requirements Keep away from heat and flame. Keep container closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION PERSONAL PROTECTION Respiratory protection Self-contained breathing apparatus in high vapor concentrations. Hand protection / protective gloves Recommended order of use: 4H Butyl Neoprene Nitrile (NBR) PVC-coated Eye protection Monogoggles Skin protection Chemical protective clothing.
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 4 of 8 Product name: Niax® silicone L-540 Other protective equipment Eye bath Safety shower ENGINEERING CONTROLS Ventilation General mechanical room ventilation is satisfactory for normal handling and storage operations. Special, local ventilation is needed at points where vapors can be expected to escape to the workplace air. EXPOSURE LIMITS Component Type Value Remark Octamethylcyclotetrasil TWA, Internal Exposure 5.0 ppm oxane Limit Consult local authorities for acceptable provincial values. 9. PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Physical state Liquid Color Clear, pale Odor Polyether Odor threshold No data available. OTHER PROPERTIES Boiling point > 150 °C at STP unless specified below. Copolymer Melting point < 0 °C at STP unless specified below. pH Not available Specific gravity (H2O=1) 1.0300 at 25 °C ( 1,013 hPa) Vapor pressure < 1.33 hPa (1.00 mmHg) at 20 °C Vapor density (air=1) Heavier than air Solubility in water Soluble Evaporation rate (Butyl <1 Acetate=1) Partitioning coefficient No data available. Flash point 103 °C Method: Pensky-Martens closed cup ASTM D 93 Percent volatiles Not determined
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 5 of 8 Product name: Niax® silicone L-540 Molecular weight Copolymer 10. STABILITY AND REACTIVITY Stability: Stable. Stability - Conditions to avoid None known. Incompatible materials None currently known. Hazardous polymerization: Will not occur. Hazardous polymerization - Conditions to avoid None known. 11. TOXICOLOGICAL INFORMATION SWALLOWING Acute effects May cause the following effects: - abdominal discomfort - nausea - vomiting May affect the gastrointestinal and respiratory systems, kidneys, liver, heart,|and cause severe CNS depression and death. Lung damage may result from accidental aspiration. Long-term oral exposure affected the brain, heart, liver, kidney, and bladder in laboratory animals. SKIN ABSORPTION Acute effects No evidence of harmful effects from available information. INHALATION Acute effects Short-term harmful health effects are not expected from vapor generated at ambient temperature. An ingredient in the controlled product has a major effect on the CNS, causing initial excitation (tremors, increased locomotor activity) followed by depression (incoordination, narcosis, anaesthesia). Acute exposure affects behaviour, performance, sleep cycle, the respiratory and cardiovascular systems and kidneys. An ingredient in the controlled product is a respiratory irritant, a CNS depressant and anaesthetic, causing headache, dizziness, acute behavioral effects (hilarity, irritability, confusion), impaired reaction time, poor coordination, visual disturbances, collapse, death as well as reversible kidney and liver damage.||Lethal cardiac irregularities may occur in predisposed individuals. Chronic exposure causes inflammation and degeneration of the respiratory lining, permanent hearing loss, behavioral changes and decreased learning and toxic changes in the optic nerve in experimental animals. CNS disturbances (headache, dizziness, abnormal gait, tremors, memory loss, incoordination), reduced dexterity, reduced ability to concentrate have been reported following long-term occupational exposure to an ingredient in the controlled product which may have involved simultaneous exposure to other solvents. An extensive review of available data suggests there may be peripheral nerve effects (paraesthesia, reduced conduction velocity), hearing
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 6 of 8 Product name: Niax® silicone L-540 damage and reversible liver and kidney damage, abnormal numbers of blood cells, but that no completely adequate studies are available. SKIN CONTACT Acute effects In experimental animals, an ingredient in the controlled product causes damage to the upper skin layers within 15 minutes, which may extend into the lower skin layers within an hour. May cause skin damage due to degreasing action. Prolonged contact may result in: - drying of the skin - defatting of the skin - development of fissures - dermatitis EYE CONTACT Acute effects Causes irritation. Causes the following effects: - stinging - discomfort - pain May cause the following effects: - excess redness of the conjunctivae - swelling of the conjunctivae Medical conditions aggravated by exposure A knowledge of the available toxicology information and of the physical and chemical properties of the material suggests that overexposure is unlikely to aggravate existing medical conditions. Other effects of exposure Solvents such as benzene and chlorinated hydrocarbons are toxicologically synergistic products in combination with an ingredient in the controlled product. SIGNIFICANT DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH The following information is based on analogy with a similar material: This material was negative in a Salmonella Typhimurium/ Escherichia coli mutagenicity assay. Octamethylcyclotetrasiloxane: Repeated exposure to octamethylcyclotetrasiloxane by inhalation (300 ppm) or by the oral route in rodents produced increased liver weight, which was generally reversible after exposure ceased. Repeated exposure by inhalation in pregnant rats (700 ppm) did not produce any developmental effects, but certain reproductive parameters (reduction in mean live litter size, and implantation sites) were affected. The relevance of these data to humans is unclear. Further studies are on-going. Octamethylcyclotetrasiloxane was not clastogenic in an in-vivo bone marrow chromosomal assay in Sprague Dawley rats following inhalation of vapor. A 2 yr. combined chronic/carcinogenicity assay was conducted on octamethylcyclotetrasiloxane (D4). Fischer-344 rats were exposed by whole-body vapor inhalation 6 hrs/day, 5 days/week for up to 104 weeks to 0, 10, 30, 150 or 700 ppm of D4. A statistically significant increase in incidence of (uterine) endometrial cell hyperplasia and uterine adenomas (benign tumors) were observed in female rats at 700 ppm. Since these effects only occurred at 700 ppm, a level that greatly exceeds typical workplace or consumer exposure, it is unlikely that industrial, commercial or consumer uses of products containing D4 would result in a significant risk to humans.
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 7 of 8 Product name: Niax® silicone L-540 12. ECOLOGICAL INFORMATION All available ecological data have been taken into account for the development of the hazard and precautionary information contained in this Material Safety Data Sheet. 13. DISPOSAL CONSIDERATIONS General: Incinerate in a furnace where permitted under appropriate federal, provincial, and local regulations. 14. TRANSPORT INFORMATION TDG - Canada This product is not regulated by TDG. IMDG Classification This product is not regulated by IMDG. ICAO Classification This product is not regulated by ICAO. 15. REGULATORY INFORMATION WHMIS CLASSIFICATION D2A Very toxic material causing other effects. CPR Compliance This product has been classified with the hazard criteria of the CPR, and the MSDS contains all the information required by CPR. CHEMICAL INVENTORY Canada: The ingredients of this product are on the DSL. Europe: The ingredients of this mixture are on the EINECS inventory. United States: The ingredients of this product are listed on the TSCA inventory or are exempt. Australia: This product, or the components, is listed or exempt from listing on the Australian Inventory of Chemical Substances (AICS). Japan: This product, or the components, is listed or exempt from listing on the Existing and New Chemical Substances (ENCS) list. Korea: This product is listed on the Existing Chemicals List (ECL). Philippines: This product, or the components, is listed or exempt from listing on the Philippines Inventory of Chemicals and Chemical Substances (PICCS).
  • MATERIAL SAFETY DATA SHEET Revision: 1.0 2006.06.23 Page: 8 of 8 Product name: Niax® silicone L-540 16. OTHER INFORMATION RECOMMENDED USES AND RESTRICTIONS Please consult the product and/or application information bulletins for this product. LEGEND STP Standard temperature and pressure W/W Weight/Weight The opinions expressed herein are those of qualified experts within GE Silicones. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and of these opinions and the conditions of use of this product are not within the control of GE Silicones, it is the user's obligation to determine the conditions of safe use of the products.